1. Phase transformation kinetics in polycrystalline Fe_xAl_1-x (x>0.6) alloys: Experiment and Simulation
- Author
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Nazarov, Artem A., Pashenkin, Igor Y., Tatarskiy, Dmitry A., Yunin, Pavel A., Churin, Sergey A., Sapozhnikov, Maksim V., Fraerman, Andrey A., Bohra, Murtaza, and Polushkin, Nikolay I.
- Subjects
Condensed Matter - Materials Science - Abstract
The presence of defects of different kinds, e.g., vacancies, voids, dislocations, grain boundaries, and surfaces, in realistic materials can strongly modify and even dictate the thermodynamics of phase transformations. Our study demonstrates, both theoretically and experimentally, that in the ordering of Fe_xAl_1-x (x>0.6) alloys subjected to high-temperature treatment, the relaxation of the as-prepared chemically disordered alloy into the ordered B2 state is hampered by another process. A manifestation of this is an increase in the alloy's magnetization. A plausible explanation for a non-monotonous behavior of the magnetization we observe is segregation of Al into structural defects, e.g., grain boundaries, and thus purification of the Fe host lattice. Qualitatively, experimental findings reported here are supported by molecular dynamics simulation of the phase transformation kinetics in Fe_xAl_1-x. These studies can be useful for choosing the preparation strategy for functional alloys., Comment: 7 pages, 4 figures, 1 table
- Published
- 2024