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Methanol (CH$_3$OH) and formaldehyde (H$_2$CO) are chemically coupled organic molecules proposed to act as an intermediate step between simple molecules and more complex prebiotic compounds. Their abundance distributions across disks regulate the prebiotic potential of material at different disk radii. We present observations of multiple methanol and formaldehyde transitions toward the Herbig Ae disk HD 100546 obtained with ALMA, building upon the previous serendipitous detection of methanol in this source. We find that methanol has a higher rotational temperature ($T_\mathrm{rot}$) than formaldehyde towards both the centrally concentrated emission component in the inner disk ($0-110$ au) and a radially separate dust ring farther out in the disk ($180-260$ au). $T_\mathrm{rot}$ decreases for methanol and formaldehyde from the inner ($152^{+35}_{-27}$ K and $76^{+9}_{-8}$ K) to the outer disk ($52^{+8}_{-6}$ K and $31^{+2}_{-2}$ K), suggesting that we are tracing two different chemical environments. $T_\mathrm{rot}$ for both species in the inner disk is consistent with thermal desorption as the origin, while the outer disk reservoir is driven by non-thermal desorption. The CH$_3$OH/H$_2$CO column density ratio decreases from $14.6^{+5.2}_{-4.6}$ in the inner disk to $1.3^{+0.3}_{-0.2}$ in the outer disk, consistent with modelling predictions. The CH$_3$OH/H$_2$CO column density ratio for the inner disk is consistent with the median value in the range of column density ratios compiled from Solar System comets which would have formed at a similar distance. This supports the notion that interstellar ice is inherited and preserved by protoplanetary disks around solar-mass and intermediate-mass stars as we are seeing 'fresh' ice sublimation, as well as providing more evidence for the presence of prebiotic precursor molecules in planet-forming regions., Comment: 35 pages, 16 figures

ALMA has revealed that the millimetre dust structures of protoplanetary discs are extremely diverse. It has been proposed that the strength of H$_2$O emission in the inner disc particularly depends on the influx of icy pebbles from the outer disc, a process that would correlate with the outer dust disc radius, and that could be prevented by pressure bumps. This work aims to assess the influence of pressure bumps on the inner disc's molecular reservoirs. Using JWST's MIRI/MRS, we compared the observational emission properties of H$_2$O, HCN, C$_2$H$_2$, and CO$_2$ with the outer dust disc structure from ALMA observations, in eight discs with confirmed gaps in ALMA observations, and two discs with gaps of tens of astronomical units in width, around stars with $M_\star \geq 0.45M_{\odot}$. We used new visibility plane fits of the ALMA data to determine the outer dust disc radius and identify substructures in the discs. We find that the presence of a dust gap does not necessarily result in weak H$_2$O emission. Furthermore, the relative lack of colder H$_2$O-emission seems to go hand in hand with elevated emission from carbon-bearing species. The discs with cavities and extremely wide gaps appear to behave as a somewhat separate group, with stronger cold H$_2$O emission and weak warm H$_2$O emission. We conclude that fully blocking radial dust drift from the outer disc seems difficult to achieve. However, there does seem to be a dichotomy between discs that show a strong cold H$_2$O excess and ones that show strong emission from HCN and C$_2$H$_2$. Better constraints on the influence of the outer dust disc structure and inner disc composition require more information on substructure formation timescales and disc ages, along with the importance of trapping of volatiles like CO and CO$_2$ into more strongly bound ices like H$_2$O and chemical transformation of CO into less volatile species., Comment: Accepted for publication in A&A. 29 pages, 12 figures and 10 tables

Radial drift of icy pebbles can have a large impact on the chemistry of the inner regions of protoplanetary disks. Compact dust disks ($\lesssim$50 au) are suggested to have a higher (cold) H$_2$O flux than more extended disks, likely due to efficient radial drift bringing H$_2$O-rich material to the inner disk, where it can be observed with JWST. We present JWST MIRI/MRS observations of the disk CX Tau taken as a part of the Mid-INfrared Disk Survey (MINDS) GTO program, a prime example of a drift-dominated disk. This compact disk seems peculiar: the source possesses a bright CO$_2$ feature instead of the bright H$_2$O expected based on its efficient radial drift. We aim to provide an explanation for this finding. We detect molecular emission from H$_2$O, $^{12}$CO$_2$, $^{13}$CO$_2$, C$_2$H$_2$, HCN, and OH in this disk, and even demonstrate a potential detection of CO$^{18}$O. Analysis of the $^{12}$CO$_2$ and $^{13}$CO$_2$ emission shows the former to be tracing a temperature of $\sim$450 K, whereas the $^{13}$CO$_2$ traces a significantly colder temperature ($\sim$200 K). H$_2$O is also securely detected both at shorter and longer wavelengths, tracing a similar temperature of $\sim$500-600 K as the CO$_2$ emission. We also find evidence for a colder, $\sim$200 K H$_2$O component at longer wavelengths, which is in line with this disk having strong radial drift. The cold $^{13}$CO$_2$ and H$_2$O emission indicate that radial drift of ices likely plays an important role in setting the chemistry of the inner disk of CX Tau. Potentially, the H$_2$O-rich gas has already advected onto the central star, which is now followed by an enhancement of comparatively CO$_2$-rich gas reaching the inner disk, explaining the enhancement of CO$_2$ emission in CX Tau. The comparatively weaker H$_2$O emission can be explained by the source's low accretion luminosity. (abridged), Comment: 23 pages, 17 figures, accepted for publication in Astronomy & Astrophysics

The ongoing physical and chemical processes in planet-forming disks set the stage for planet formation. The asymmetric disk around the young star Oph-IRS 48 has one of the most well-characterised chemical inventories, showing molecular emission from a wide variety of species at the dust trap. One of the explanations for the asymmetric structure is dust trapping by a perturbation-induced vortex. We aim to constrain the excitation properties of the molecular species SO$_2$, CH$_3$OH, and H$_2$CO. We further characterise the extent of the molecular emission, through the determination of important physical and chemical timescales at the location of the dust trap. We also investigate whether the potential vortex can influence the observable temperature structure of the gas. Through a pixel-by-pixel rotational diagram analysis, we create rotational temperature and column density maps for SO$_2$ and CH$_3$OH, while temperature maps for H$_2$CO are created using line ratios. We find temperatures of $T\sim$55 K and $T\sim$125 K for SO$_2$ and CH$_3$OH, respectively, while the line ratios point towards temperatures of T$\sim$150-300 K for H$_2$CO. The rotational diagram of CH$_3$OH is dominated by scatter and subsequent non-LTE RADEX calculations suggest that both CH$_3$OH and H$_2$CO must be sub-thermally excited. The temperatures suggest that SO$_2$ comes from a layer deep in the disk, while CH$_3$OH and H$_2$CO originate from a higher layer. While a potential radial gradient is seen in the temperature map of SO$_2$, we do not find any hints of a vortex influencing the temperature structure. The determined turbulent mixing timescale is not able to explain the emitting heights of the molecules, but the photodissociation timescales are able to explain the wider azimuthal extents of SO$_2$ and H$_2$CO compared to CH$_3$OH, where a secondary, gas-phase formation reservoir is required for H$_2$CO., Comment: Accepted for publication in Astronomy and Astrophysics

The removal of angular momentum from protostellar systems drives accretion onto the central star and may drive the dispersal of the protoplanetary disk. Winds and jets can contribute to removing angular momentum from the disk, though the dominant process remain unclear. To date, observational studies of resolved disk winds have mostly targeted highly inclined disks. We report the detection of extended H2 and [Ne II] emission toward the young stellar object SY Cha with the JWST Mid-InfraRed Instrument Medium Resolution Spectrometer (MIRI-MRS). This is one of the first polychromatic detections of extended H2 toward a moderately inclined, i=51.1 degrees, Class II source. We measure the semi-opening angle of the H2 emission as well as build a rotation diagram to determine the H2 excitation temperature and abundance. We find a wide semi-opening angle, high temperature, and low column density for the H2 emission, all of which are characteristic of a disk wind. We derive a molecular wind mass loss rate of 3+-2e-9 Msun/yr, which is high compared to the previously derived stellar accretion rate of 6.6e-10 Msun/yr. This suggests either that the stellar accretion and the disk wind are driven by different mechanisms or that accretion onto the star is highly variable. These observations demonstrate MIRI-MRS's utility in expanding studies of resolved disk winds beyond edge-on sources., Comment: 16 pages, 14 figures, 4 tables, accepted for publication in ApJ

Stable isotopic ratios constitute powerful tools for unraveling the thermal and irradiation history of volatiles. In particular, we can use our knowledge of the isotopic fractionation processes active during the various stages of star, disk and planet formation to infer the origins of different volatiles with measured isotopic patterns in our own solar system. Observations of planet-forming disks with the Atacama Large Millimeter/submillimeter Array (ALMA) now readily detect the heavier isotopologues of C, O and N, while the isotopologue abundances and isotopic fractionation mechanisms of sulfur species are less well understood. Using ALMA observations of the SO and SO2 isotopologues in the nearby, molecule-rich disk around the young star Oph-IRS 48 we present the first constraints on the combined 32S/34S and 32S/33S isotope ratios in a planet-forming disk. Given that these isotopologues likely originate in relatively warm gas (>50 K), like most other Oph-IRS 48 volatiles, SO is depleted in heavy sulfur while SO2 is enriched compared to solar system values. However, we cannot completely rule out a cooler gas reservoir, which would put the SO sulfur ratios more in line with comets and other solar system bodies. We also constrain the S18O/SO ratio and find the limit to be consistent with solar system values given a temperature of 60 K. Together these observations show that we should not assume solar isotopic values for disk sulfur reservoirs, but additional observations are needed to determine the chemical origin of the abundant SO in this disk, inform on what isotopic fractionation mechanism(s) are at play, and aid in unravelling the history of the sulfur budget during the different stages of planet formation., Comment: Accepted AJ on 30th August 2024

The inner disk of the young star PDS 70 may be a site of rocky planet formation, with two giant planets detected further out. Solids in the inner disk may inform us about the origin of this inner disk water and nature of the dust in the rocky planet-forming regions. We aim to constrain the chemical composition, lattice structure, and grain sizes of small silicate grains in the inner disk of PDS 70, observed both in JWST/MIRI MRS and Spitzer IRS. We use a dust fitting model, called DuCK, based on a two-layer disk model. We use Gaussian Random Field and Distribution of Hollow Spheres models to obtain two sets of dust opacities. The third set of opacities is obtained from aerosol spectroscopy. We use stoichiometric amorphous silicates, forsterite, and enstatite in our analysis. We also used iron-rich and magnesium-rich amorphous silicate and fayalite dust species to study the iron content. The Gaussian Random Field opacity agrees well with the observed spectrum. In both MIRI and Spitzer spectra, amorphous silicates are the dominant dust species. Crystalline silicates are dominated by iron-poor olivine. We do not find strong evidence for enstatite. Moreover, the MIRI spectrum indicates larger grain sizes than the Spitzer spectrum, indicating a time-variable small grain reservoir. The inner PDS 70 disk is dominated by a variable reservoir of optically thin warm amorphous silicates. We suggest that the small grains detected in the inner PDS 70 disk are likely transported inward from the outer disk as a result of filtration and fragmentation at the ice line. In addition, the variation between MIRI and Spitzer data can be explained by the grain growth over 15 years and a dynamical inner disk where opacity changes occur resulting from the highly variable hot innermost dust reservoir., Comment: 18 pages, 13 figures, Accepted by A&A

With the advent of JWST, we acquire unprecedented insights into the physical and chemical structure of the inner regions of planet-forming disks where terrestrial planet formation occurs. The very low-mass stars (VLMS) are known to have a high occurrence rate of the terrestrial planets around them. Exploring the chemical composition of the gas in these inner regions of the disks can aid a better understanding of the connection between planet-forming disks and planets. The MIRI mid-Infrared Disk Survey (MINDS) project is a large JWST Guaranteed Time program to characterize the chemistry and physical state of planet-forming and debris disks. We use the JWST-MIRI/MRS spectrum to investigate the gas and dust composition of the planet-forming disk around the very low-mass star Sz28 (M5.5, 0.12\,M$_{\odot}$). We use the dust-fitting tool (DuCK) to determine the dust continuum and to get constraints on the dust composition and grain sizes. We use 0D slab models to identify and fit the molecular spectral features, yielding estimates on the temperature, column density and the emitting area. To test our understanding of the chemistry in the disks around VLMS, we employ the thermo-chemical disk model {P{\tiny RO}D{\tiny I}M{\tiny O}} and investigate the reservoirs of the detected hydrocarbons. We explore how the C/O ratio affects the inner disk chemistry. JWST reveals a plethora of hydrocarbons, including \ce{CH3}, \ce{CH4}, \ce{C2H2}, \ce{^{13}CCH2}, \ce{C2H6}, \ce{C3H4}, \ce{C4H2} and \ce{C6H6} suggesting a disk with a gaseous C/O\,>\,1. Additionally, we detect \ce{CO2}, \ce{^{13}CO2}, \ce{HCN}, and \ce{HC3N}. \ce{H2O} and OH are absent in the spectrum. We do not detect PAHs. Photospheric stellar absorption lines of \ce{H2O} and \ce{CO} are identified. Notably, our radiation thermo-chemical disk models are able to produce these detected hydrocarbons in the surface layers of the disk when the ..., Comment: accepted for publication in A&A

The MRS mode of the JWST-MIRI instrument gives insights into the chemical richness and complexity of the inner regions of planet-forming disks. Here, we analyse the H$_2$O-rich spectrum of the compact disk DR Tau. We probe the excitation conditions of the H$_2$O transitions observed in different wavelength regions across the entire spectrum using LTE slab models, probing both the rovibrational and rotational transitions. These regions suggest a radial temperature gradient, as the excitation temperature (emitting radius) decreases (increases) with increasing wavelength. To explain the derived emitting radii, we require a larger inclination for the inner disk (i~20-23 degrees) compared to the outer disk (i~5 degrees), agreeing with our previous analysis on CO. We also analyse the pure rotational spectrum (<10 micron) using a large, structured disk (CI Tau) as a template, confirming the presence of the radial gradient, and by fitting multiple components to further characterise the radial and vertical temperature gradients present in the spectrum. At least three temperature components (T~180-800 K) are required to reproduce the rotational spectrum of H$_2$O arising from the inner ~0.3-8 au. These components describe a radial temperature gradient that scales roughly as ~R$^{-0.5}$ in the emitting layers. As the H$_2$O is mainly optically thick, we derive a lower limit on the abundance ratio of H$_2$O/CO~0.17, suggesting a potential depletion of H$_2$O. Similarly to previous work, we detect a cold H$_2$O component (T~180 K) originating from near the snowline. We cannot conclude if an enhancement of the H$_2$O reservoir is observed following radial drift. A consistent analysis of a larger sample of compact disks is necessary to study the importance of drift in enhancing the H$_2$O abundances., Comment: Accepted for publication in Astronomy & Astrophysics on 05/07/2024

Most stars form in multiple systems whose properties can significantly impact circumstellar disk evolution. We investigate the physical and chemical properties of the equal-mass, small separation (~66 mas, ~9 au) DF Tau binary system. Previous observations indicated that only DF Tau A has a circumstellar disk. We present JWST-MIRI MRS observations of DF Tau. The MIRI spectrum shows a forest of H2O lines and emission from CO, C2H2, HCN, CO2, and OH. LTE slab models are used to determine the properties of the gas, and we analyze high angular spatial and spectral resolution data from ALMA, VLTI-GRAVITY, and IRTF-iSHELL to aid in the interpretation of the JWST data. The 1.3 mm ALMA continuum data show two equal-brightness sources of compact (R<3 au) emission, with separations and movement consistent with astrometry from VLTI-GRAVITY and the known orbit. This is interpreted as a robust detection of a disk around DF Tau B, which we suggest may host a small (~1 au) cavity to reconcile all observations. The disk around DF Tau A is expected to be a full disk, and spatially and spectrally resolved dust and gas emission points to hot, close-in (<0.2 au) material. Hot (~500-1000 K) H2O, HCN, and C2H2 emission in the MIRI data likely originate in the DF Tau A disk, while a cold (<200 K) H2O component with an extended emitting area is consistent with an origin from both disks. Despite the very compact outer disks, the inner disk composition and conditions are similar to isolated systems, suggesting that the close binary nature is not a driving factor in setting the inner disk chemistry. However, constraining the geometry of the disks, for instance, via higher resolution ALMA observations, would provide additional insight into the mid-infrared gas emission. JWST observations of spatially resolved binaries will be important for understanding the impact of binarity on inner disk chemistry more generally., Comment: Accepted to A&A on June 15th, 2024. Calibrated ALMA data are available at https://zenodo.org/records/11215003. Reduced JWST-MIRI MRS spectra will be available at Spexodisks.com and available by request to the corresponding author

This work aims to measure the mass accretion rate, the accretion luminosity, and more generally the physical conditions of the warm emitting gas in the inner disk of the very low-mass star 2MASS-J16053215-1933159. We investigate the source mid-infrared spectrum for atomic and molecular hydrogen line emission. We present the full James Webb Space Telescope (JWST) Mid-InfraRed Instrument (MIRI) Medium Resolution Spectrometer (MRS) spectrum of the protoplanetary disk around the very low-mass star 2MASS-J16053215-1933159 from the MINDS GTO program, previously shown to be abundant in hydrocarbon molecules. We analyzed the atomic and molecular hydrogen lines in this source by fitting one or multiple Gaussian profiles. We then built a rotational diagram for the H2 lines to constrain the rotational temperature and column density of the gas. Finally, we compared the observed atomic line fluxes to predictions from two standard emission models. We identify five molecular hydrogen pure rotational lines and 16 atomic hydrogen recombination lines. The spectrum indicates optically thin emission for both species. We use the molecular hydrogen lines to constrain the mass and temperature of the warm emitting gas. The HI (7-6) recombination line is used to measure the mass accretion rate and luminosity onto the central source. HI recombination lines can also be used to derive the physical properties of the gas using atomic recombination models. The JWST-MIRI MRS observations for the very low-mass star 2MASS-J16053215-1933159 reveal a large number of emission lines, many originating from atomic and molecular hydrogen because we are able to look into the disk warm molecular layer. Their analysis constrains the physical properties of the emitting gas and showcases the potential of JWST to deepen our understanding of the physical and chemical structure of protoplanetary disks, Comment: 11 pages, 9 figures, 2 tables

The MRS mode of the JWST-MIRI instrument has been shown to be a powerful tool to characterise the molecular gas emission of the inner region of planet-forming disks. Here, we analyse the spectrum of the compact T-Tauri disk DR Tau, which is complemented by high spectral resolution (R~60000-90000) CO ro-vibrational observations. Various molecular species, including CO, CO$_2$, HCN, and C$_2$H$_2$ are detected in the JWST-MIRI spectrum, for which excitation temperatures of T~325-900 K are retrieved using LTE slab models. The high-resolution CO observations allow for a full treatment of the line profiles, which show evidence for two components of the main isotopologue, $^{12}$CO: a broad component tracing the Keplerian disk and a narrow component tracing a slow disk wind. Rotational diagrams yield excitation temperatures of T>725 K for CO, with consistently lower temperatures found for the narrow components, suggesting that the disk wind is launched from a larger distance. The inferred excitation temperatures for all molecules suggest that CO originates from the highest atmospheric layers close to the host star, followed by HCN and C$_2$H$_2$, which emit, together with $^{13}$CO, from slightly deeper layers, whereas the CO$_2$ originates from even deeper inside or further out in the disk. Additional analysis of the $^{12}$CO line wings hint at a misalignment between the inner (i~20 degrees) and outer disk (i~5 degrees). Finally, we emphasise the need for complementary high-resolution CO observations, as in combination with the JWST-MIRI observations they can be used to characterise the CO kinematics and the physical and chemical conditions of the other observed molecules with respect to CO., Comment: Accepted for publication in Astronomy & Astrophysics on 20/03/2024

The study of protoplanetary disks has become increasingly important with the Kepler satellite finding that exoplanets are ubiquitous around stars in our galaxy and the discovery of enormous diversity in planetary system architectures and planet properties. High-resolution near-IR and ALMA images show strong evidence for ongoing planet formation in young disks. The JWST MIRI mid-INfrared Disk Survey (MINDS) aims to (1) investigate the chemical inventory in the terrestrial planet-forming zone across stellar spectral type, (2) follow the gas evolution into the disk dispersal stage, and (3) study the structure of protoplanetary and debris disks in the thermal mid-IR. The MINDS survey will thus build a bridge between the chemical inventory of disks and the properties of exoplanets. The survey comprises 52 targets (Herbig Ae stars, T Tauri stars, very low-mass stars and young debris disks). We primarily obtain MIRI/MRS spectra with high S/N (~100-500) covering the complete wavelength range from 4.9 to 27.9 {\mu}m. For a handful of selected targets we also obtain NIRSpec IFU high resolution spectroscopy (2.87-5.27 {\mu}m). We will search for signposts of planet formation in thermal emission of micron-sized dust - information complementary to near-IR scattered light emission from small dust grains and emission from large dust in the submillimeter wavelength domain. We will also study the spatial structure of disks in three key systems that have shown signposts for planet formation, TW Hya and HD 169142 using the MIRI coronagraph at 15.5 {\mu}m and 10.65 {\mu}m respectively and PDS70 using NIRCam imaging in the 1.87 {\mu}m narrow and the 4.8 {\mu}m medium band filter. ..., Comment: accepted for publication in PASP

Observations of disks with the Atacama Large Millimeter/submillimeter Array (ALMA) allow us to map the chemical makeup of nearby protoplanetary disks with unprecedented spatial resolution and sensitivity. The typical outer Class II disk observed with ALMA is one with an elevated C/O ratio and a lack of oxygen-bearing complex organic molecules, but there are now some interesting exceptions: three transition disks around Herbig Ae stars all show oxygen-rich gas traced via the unique detections of the molecules SO and CH3OH. We present the first results of an ALMA line survey at 337 to 357 GHz of such disks and focus this paper on the first Herbig Ae disk to exhibit this chemical signature - HD 100546. In these data, we detect 19 different molecules including NO, SO and CH3OCHO (methyl formate). We also make the first tentative detections of H213CO and 34SO in protoplanetary disks. Multiple molecular species are detected in rings, which are, surprisingly, all peaking just beyond the underlying millimeter continuum ring at 200 au. This result demonstrates a clear connection between the large dust distribution and the chemistry in this flat outer disk. We discuss the physical and/or chemical origin of these sub-structures in relation to ongoing planet formation in the HD 100546 disk. We also investigate how similar and/or different the molecular make up of this disk is to other chemically well-characterised Herbig Ae disks. The line-rich data we present motivates the need for more ALMA line surveys to probe the observable chemistry in Herbig Ae systems which offer unique insight into the composition of disk ices, including complex organic molecules., Comment: Accepted to AJ, 25 pages, 11 figures

The Atacama Large Millimeter/submillimeter Array (ALMA) can probe the molecular content of planet-forming disks with unprecedented sensitivity. These observations allow us to build up an inventory of the volatiles available for forming planets and comets. Herbig Ae transition disks are fruitful targets due to the thermal sublimation of complex organic molecule (COM) and likely H2O-rich ices in these disks. The IRS 48 disk shows a particularly rich chemistry that can be directly linked to its asymmetric dust trap. Here, we present ALMA observations of the IRS 48 disk where we detect 16 different molecules and make the first robust detections of H213CO, 34SO, 33SO and c-H2COCH2 (ethylene oxide) in a protoplanetary disk. All of the molecular emissions, aside from CO, are colocated with the dust trap and this includes newly detected simple molecules such as HCO+, HCN and CS. Interestingly, there are spatial offsets between different molecular families, including between the COMs and sulphur-bearing species, with the latter being more azimuthally extended and located radially further from the star. The abundances of the newly detected COMs relative to CH3OH are higher than the expected protostellar ratios, which implies some degree of chemical processing of the inherited ices during the disk lifetime. These data highlight IRS 48 as a unique astrochemical laboratory to unravel the full volatile reservoir at the epoch of planet and comet formation and the role of the disk in (re)setting chemical complexity., Comment: Accepted to AJ, 21 pages, 7 figures

SY Cha is a T Tauri star surrounded by a protoplanetary disk with a large cavity seen in the millimeter continuum but has the spectral energy distribution (SED) of a full disk. Here we report the first results from JWST-MIRI Medium Resolution Spectrometer (MRS) observations taken as part of the MIRI mid-INfrared Disk Survey (MINDS) GTO Program. The much improved resolution and sensitivity of MIRI-MRS compared to Spitzer enables a robust analysis of the previously detected H2O, CO, HCN, and CO2 emission as well as a marginal detection of C2H2. We also report the first robust detection of mid-infrared OH and ro-vibrational CO emission in this source. The derived molecular column densities reveal the inner disk of SY Cha to be rich in both oxygen and carbon bearing molecules. This is in contrast to PDS 70, another protoplanetary disk with a large cavity observed with JWST, which displays much weaker line emission. In the SY Cha disk, the continuum, and potentially the line, flux varies substantially between the new JWST observations and archival Spitzer observations, indicative of a highly dynamic inner disk., Comment: 19 pages, 10 figures, 5 tables, accepted for publication in ApJ

The composition of a forming planet is set by the material it accretes from its parent protoplanetary disk. Therefore, it is crucial to map the chemical make-up of the gas in disks to understand the chemical environment of planet formation. This paper presents molecular line observations taken with the Atacama Large Millimeter/submillimeter Array of the planet-hosting disk around the young star HD 169142. We detect N2H+, CH3OH, [CI], DCN, CS, C34S, 13CS, H2CS, H2CO, HC3N and c-C3H2 in this system for the first time. Combining these data with the recent detection of SO and previously published DCO+ data, we estimate the location of H2O and CO snowlines and investigate radial variations in the gas phase C/O ratio. We find that the HD 169142 disk has a relatively low N2H+ flux compared to the disks around Herbig stars HD 163296 and MWC 480 indicating less CO freeze-out and place the CO snowline beyond the millimetre disk at ~150 au. The detection of CH3OH from the inner disk is consistent with the H2O snowline being located at the edge of the central dust cavity at ~20 au. The radially varying CS/SO ratio across the proposed H2O snowline location is consistent with this interpretation. Additionally, the detection of CH3OH in such a warm disk adds to the growing evidence supporting the inheritance of complex ices in disks from the earlier, colder stages of star formation. Finally, we propose that the giant HD 169142 b located at 37 au is forming between the CO2 and H2O snowlines where the local elemental make of the gas is expected to have C/O=1.0., Comment: Accepted A&A 13th August 2023

The understanding of planet formation has changed recently, embracing the new idea of pebble accretion. This means that the influx of pebbles from the outer regions of planet-forming disks to their inner zones could determine the composition of planets and their atmospheres. The solid and molecular components delivered to the planet-forming region can be best characterized by mid-infrared spectroscopy. With Spitzer low-resolution (R=100, 600) spectroscopy, this approach was limited to the detection of abundant molecules such as H2O, C2H2, HCN and CO2. This contribution will present first results of the MINDS (MIRI mid-IR Disk Survey, PI: Th. Henning) project. Due do the sensitivity and spectral resolution (R~1500-3500) provided by JWST we now have a unique tool to obtain the full inventory of chemistry in the inner disks of solar-types stars and brown dwarfs, including also less abundant hydrocarbons and isotopologues. The Integral Field Unit (IFU) capabilities enable at the same time spatial studies of the continuum and line emission in extended sources such as debris disks, the flying saucer and also the search for mid-IR signatures of forming planets in systems such as PDS70. These JWST observations are complementary to ALMA and NOEMA observations of the outer disk chemistry; together these datasets provide an integral view of the processes occurring during the planet formation phase., Comment: 14 pages, 8 figures, authors version of the manuscript submitted 22.1.2023 for the Faraday Discussion "Astrochemistry at high resolution", accepted 21.3.2023

MIRI/MRS on board the JWST allows us to probe the inner regions of protoplanetary disks. Here we examine the disk around the classical T Tauri star Sz 98, which has an unusually large dust disk in the millimetre with a compact core. We focus on the H$_2$O emission through both its ro-vibrational and pure rotational emission. Furthermore, we compare our chemical findings with those obtained for the outer disk from Atacama Large Millimeter/submillimeter Array (ALMA) observations. In order to model the molecular features in the spectrum, the continuum was subtracted and LTE slab models were fitted. The spectrum was divided into different wavelength regions corresponding to H$_2$O lines of different excitation conditions, and the slab model fits were performed individually per region. We confidently detect CO, H$_2$O, OH, CO$_2$, and HCN in the emitting layers. The isotopologue H$^{18}_2$O is not detected. Additionally, no other organics, including C$_2$H$_2$, are detected. This indicates that the C/O ratio could be substantially below unity, in contrast with the outer disk. The H$_2$O emission traces a large radial disk surface region, as evidenced by the gradually changing excitation temperatures and emitting radii. The OH and CO$_2$ emission are relatively weak. It is likely that H$_2$O is not significantly photodissociated; either due to self-shielding against the stellar irradiation, or UV-shielding from small dust particles. The relative emitting strength of the different identified molecular features point towards UV-shielding of H$_2$O in the inner disk of Sz 98, with a thin layer of OH on top. The majority of the organic molecules are either hidden below the dust continuum, or not present. In general, the inferred composition points to a sub-solar C/O ratio (<0.5) in the inner disk, in contrast with the larger than unity C/O ratio in the gas in the outer disk found with ALMA., Comment: Updated to accepted version. Accepted by A&A on September 23 2023. 18 pages, 11 figures

The atmospheric composition of planets is determined by the chemistry of the disks in which they form. Studying the gas-phase molecular composition of disks thus allows us to infer what the atmospheric composition of forming planets might be. Recent observations of the IRS 48 disk have shown that (asymmetric) dust traps can directly impact the observable chemistry, through radial and vertical transport, and the sublimation of ices. The asymmetric HD 142527 disk provides another good opportunity to investigate the role of dust traps in setting the disk's chemical composition. In this work, we use archival ALMA observations of the HD 142527 disk to obtain an as large as possible molecular inventory, which allows us to investigate the possible influence of the asymmetric dust trap on the disk's chemistry. We present the first ALMA detections of [C I], 13C18O, DCO+, H2CO and additional transition of HCO+ and CS in this disk. In addition, we have acquired upper limits for non-detected species such as SO and CH3OH. For the majority of the observed molecules, a decrement in the emission at the location of the dust trap is found. For the main CO isotopologues continuum over-subtraction likely causes the observed asymmetry, while for CS and HCN we propose that the observed asymmetries are likely due to shadows cast by the misaligned inner disk. As the emission of the observed molecules is not co-spatial with the dust trap and no SO or CH3OH are found, thermal sublimation of icy mantles does not appear to play a major role in changing the gas-phase composition of the outer disk in HD 142527 disk. Using our observations of 13C18O and DCO+ and a RADMC-3D model, we determine the CO snowline to be located beyond the dust traps, favouring cold gas-phase formation of H2CO, rather than the hydrogenation of CO-ice and subsequent sublimation., Comment: Accepted for publication in A&A on 12/04/2023

Hot Jupiters form an enigmatic class of object with yet unclear formation pathways. Determination of their occurrence rates as function orbit, planet and stellar mass, and system age, can be an important ingredient for understanding how they form. To date, various Hot Jupiters have been discovered orbiting red giant stars and deriving their incidence would be highly interesting. In this study we aim to determine the number of Hot Jupiters in a well-defined sample of red giants, estimate their occurrence rate and compare it with that for A, F and G-type stars. A sample of 14474 red giant stars, with estimated radii between 2 and 5 $R_\odot$, was selected using Gaia to coincide with observations by the NASA TESS mission. Subsequently, the TESS light curves were searched for transits from Hot Jupiters. The detection efficiency was determined using injected signals, and the results further corrected for the geometric transit probability to estimate the occurrence rate. Three previously confirmed Hot Jupiters were found in the TESS data, in addition to one other TESS Object of Interest, and two M-dwarf companions. This results in an occurrence rate of $0.37^{+0.29}_{-0.09}$%. Due to the yet large uncertainties, this cannot be distinguished from that of A-, F- and G-type stars. We argue that it is unlikely that planet engulfment in expanding red giants plays yet an important role in this sample., Comment: Accepted for publication in A&A

We present JWST-MIRI MRS spectra of the protoplanetary disk around the low-mass T Tauri star GW Lup from the MIRI mid-INfrared Disk Survey (MINDS) GTO program. Emission from $^{12}$CO$_{2}$, $^{13}$CO$_{2}$, H$_{2}$O, HCN, C$_{2}$H$_{2}$, and OH is identified with $^{13}$CO$_{2}$ being detected for the first time in a protoplanetary disk. We characterize the chemical and physical conditions in the inner few au of the GW Lup disk using these molecules as probes. The spectral resolution of JWST-MIRI MRS paired with high signal-to-noise data is essential to identify these species and determine their column densities and temperatures. The $Q$-branches of these molecules, including those of hot-bands, are particularly sensitive to temperature and column density. We find that the $^{12}$CO$_{2}$ emission in the GW Lup disk is coming from optically thick emission at a temperature of $\sim$400 K. $^{13}$CO$_{2}$ is optically thinner and based on a lower temperature of $\sim$325 K, may be tracing deeper into the disk and/or a larger emitting radius than $^{12}$CO$_{2}$. The derived $N_{\rm{CO_{2}}}$/$N_{\rm{H_{2}O}}$ ratio is orders of magnitude higher than previously derived for GW Lup and other targets based on \textit{Spitzer}-IRS data. This high column density ratio may be due to an inner cavity with a radius in between the H$_{2}$O and CO$_{2}$ snowlines and/or an overall lower disk temperature. This paper demonstrates the unique ability of JWST to probe inner disk structures and chemistry through weak, previously unseen molecular features., Comment: 15 pages, 10 figures. Accepted to ApJL