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Radiative cooling by molecules is a crucial process for hydrodynamic escape, as it can efficiently remove the thermal energy driving the outflow, acquired through X-ray and extreme UV absorption. Carbon oxides, such as CO and CO2, and their photochemical products are anticipated to serve as vital radiative cooling sources not only in atmospheres dominated by carbon oxides but also in H2-rich atmospheres. However, their specific effects on the hydrodynamic escape, especially in H2-rich atmospheres, have been inadequately investigated. In this study, we conduct 1-D hydrodynamic escape simulations for H2-rich atmospheres incorporating CO, CO2, and their chemical products on an Earth-mass planet. We consider detailed radiative cooling processes and chemical networks related to carbon oxides to elucidate their impacts on the hydrodynamic escape. In the escape outflow, CO2 undergoes rapid photolysis, producing CO and atomic oxygen, while CO exhibits photochemical stability compared to CO2. The H2 oxidation by atomic oxygen results in the production of OH and H2O. Consequently, the hydrodynamic escape is significantly suppressed by the radiative cooling effects of CO, H2O, OH, and H3+ even when the basal mixing fraction of CO and CO2 is lower than ~0.01. These mechanisms extend the lifetime of H2-rich atmospheres by about one order of magnitude compared to the case of pure hydrogen atmospheres on early Earth, which also results in negligible escape of heavier carbon- and nitrogen-bearing molecules and noble gases., Comment: 47 pages, 9 figures

Earth is expected to have acquired a reduced proto-atmosphere enriched in H2 and CH4 through the accretion of building blocks that contain metallic Fe and/or the gravitational trapping of surrounding nebula gas. Such an early, wet, reduced atmosphere that covers a proto-ocean would then ultimately evolve toward oxidized chemical compositions through photochemical processes that involve reactions with H2O-derived oxidant radicals and the selective escape of hydrogen to space. During this time, atmospheric CH4 could be photochemically reprocessed to generate not only C-bearing oxides but also organics. However, the branching ratio between organic matter formation and oxidation remains unknown despite its significance on the abiotic chemical evolution of early Earth. Here, we show via numerical analyses that UV absorptions by gaseous hydrocarbons such as C2H2 and C3H4 significantly suppress H2O photolysis subsequent CH4 oxidation during the photochemical evolution of a wet proto-atmosphere enriched in H2 and CH4. As a result, nearly half of the initial CH4 converted to heavier organics along with the deposition of prebiotically essential molecules such as HCN and H2CO on the surface of a primordial ocean for a geological timescale order of 10-100 Myr. Our results suggest that the accumulation of organics and prebiotically important molecules in the proto-ocean could produce a soup enriched in various organics, which might have eventually led to the emergence of living organisms., Comment: 35 pages, 12 figures

The isotopic signature of atmospheric carbon offers a unique tracer for the history of the Martian atmosphere and the origin of organic matter on Mars. Photolysis of CO$_{2}$ is known to induce strong isotopic fractionation of carbon between CO$_{2}$ and CO. However, its effect on the carbon isotopic compositions in the Martian atmosphere remains uncertain. Here we develop a 1-D photochemical model considering isotopic fractionation via photolysis of CO$_{2}$ to estimate the vertical profiles of the carbon isotopic compositions of CO and CO$_{2}$ in the Martian atmosphere. We find that CO is depleted in $^{13}$C compared with CO$_{2}$ at each altitude due to the fractionation via CO$_{2}$ photolysis: the minimum value of $\delta ^{13}$C in CO is about $-170$ per mil under the standard eddy diffusion setting. This result supports the hypothesis that fractionated atmospheric CO is responsible for the production of the $^{13}$C-depleted organic carbon in Martian sediments detected by Curiosity Rover through the conversion of CO into organic materials and their deposition on the surface. The photolysis and transport-induced fractionation of CO we report here leads to a $\sim 15$ % decrease in the amount of inferred atmospheric loss when combined with the present-day fractionation of the atmosphere and previous studies of carbon escape to space. The fractionated isotopic composition of CO in the Martian atmosphere may be observed by ExoMars Trace Gas Orbiter (TGO) and ground-based telescopes, and escaping ion species produced by the fractionated carbon-bearing species may be detected by Martian Moons eXploration (MMX) in the future., Comment: 13 pages, 6 figures

We introduce a new flexible one-dimensional photochemical model named Photochemical and RadiatiOn Transport model for Extensive USe (PROTEUS), which consists of a Python graphical user interface (GUI) program and Fortran 90 modules. PROTEUS is designed for adaptability to many planetary atmospheres, for flexibility to deal with thousands of or more chemical reactions with high efficiency, and for intuitive operation with GUI. Chemical reactions can be easily implemented into the Python GUI program in a simple string format, and users can intuitively select a planet and chemical reactions on GUI. Chemical reactions selected on GUI are automatically analyzed by string parsing functions in the Python GUI program, then applied to the Fortran 90 modules to simulate with the selected chemical reactions on a selected planet. PROTEUS can significantly save the time for those who need to develop a new photochemical model; users just need to write chemical reactions in the Python GUI program and just select them on GUI to run a new photochemical model.

A model of geocoronal solar wind charge exchange (SWCX) emission was built and compared to five Suzaku detections of bright geocoronal SWCX events. An exospheric neutral hydrogen distribution model, charge exchange cross sections, solar wind ion data taken with the ACE and WIND satellites, and magnetic field models of the Earth's magnetosphere are all combined in order to predict time-variable geocoronal SWCX emission depending on line-of-sight directions of the Suzaku satellite. The modeled average intensities of O VII emission lines were consistent with the observed ones within a factor of three in four out of the five cases except for an event in which a line-of-sight direction was toward the night side of the high-latitude magnetosheath and a major geomagnetic storm was observed. Those of O VIII emission lines were underestimated by a factor of three or more in all the five cases. On the other hand, the modeled O VII and O VIII light curves reproduced the observed ones after being scaled by ratios between the observed and modeled average intensities. In particular, short-term variations due to line-of-sight directions traversing cusp regions during an orbital motion of the Suzaku satellite were reproduced. These results are discussed in the context of model uncertainties., Comment: 47 pages, 23 figures, accepted for publication in PASJ

Atmospheres play a crucial role in planetary habitability. Around M dwarfs and young Sun-like stars, planets receiving the same insolation as the present-day Earth are exposed to intense stellar X-rays and extreme-ultraviolet (XUV) radiation. This study explores the fundamental question of whether the atmosphere of present-day Earth could survive in such harsh XUV environments. Previous theoretical studies suggest that stellar XUV irradiation is sufficiently intense to remove such atmospheres completely on short timescales. In this study, we develop a new upper-atmospheric model and re-examine the thermal and hydrodynamic responses of the thermospheric structure of an Earth-like N2-O2 atmosphere, on an Earth-mass planet, to an increase in the XUV irradiation. Our model includes the effects of radiative cooling via electronic transitions of atoms and ions, known as atomic line cooling, in addition to the processes accounted for by previous models. We demonstrate that atomic line cooling dominates over the hydrodynamic effect at XUV irradiation levels greater than several times the present level of the Earth. Consequentially, the atmosphere's structure is kept almost hydrostatic, and its escape remains sluggish even at XUV irradiation levels up to a thousand times that of the Earth at present. Our estimates for the Jeans escape rates of N2-O2 atmospheres suggest that these 1 bar atmospheres survive in early active phases of Sun-like stars. Even around active late M dwarfs, N2-O2 atmospheres could escape significant thermal loss on timescales of gigayears. These results give new insights into the habitability of terrestrial exoplanets and the Earth's climate history., Comment: Published 2022 September 29 in ApJ

Terrestrial planets currently in the habitable zones around M dwarfs likely experienced a long-term runaway greenhouse condition because of a slow decline in host-stellar luminosity in its pre-main sequence phase. Accordingly, they might have lost significant portions of their atmospheres including water vapor at high concentration by hydrodynamic escape induced by the strong stellar XUV irradiation. However, the atmospheric escape rates remain highly uncertain due partly to a lack of understanding of the effect of radiative cooling in the escape outflows. Here we carry out 1-D hydrodynamic escape simulations for an H$_{2}$-H$_{2}$O atmosphere on a planet with mass of $1M_{\oplus}$ considering radiative and chemical processes to estimate the atmospheric escape rate and follow the atmospheric evolution during the early runaway greenhouse phase. We find that the atmospheric escape rate decreases with the basal H$_{2}$O/H$_{2}$ ratio due to the energy loss by the radiative cooling of H$_{2}$O and chemical products such as OH and H$_{3}^{+}$: the escape rate of H$_{2}$ becomes one order of magnitude smaller when the basal H$_{2}$O/H$_{2}=0.1$ than that of the pure hydrogen atmosphere. The timescale for H$_{2}$ escape exceeds the duration of the early runaway greenhouse phase, depending on the initial atmospheric amount and composition, indicating that H$_{2}$ and H$_{2}$O could be left behind after the end of the runaway greenhouse phase. Our results suggest that temperate and reducing environments with oceans could be formed on some terrestrial planets around M dwarfs., Comment: 15 pages, 7 figures

Suzaku detected an enhancement of soft X-ray background associated with solar eruptions on 2013 April 14-15. The solar eruptions were accompanied by an M6.5 solar flare and a coronal mass ejection with magnetic flux ropes. The enhanced soft X-ray background showed a slight variation in half a day and then a clear one in a few hours. The former spectrum was composed of oxygen emission lines, while the later one was characterized by a series of emission lines from highly ionized carbon to silicon. The soft X-ray enhancement originated from geocoronal solar wind charge exchange. However, there appeared to be no significant time correlation with the solar wind proton flux measured by the ACE and WIND satellites. From other solar wind signatures, we considered that an interplanetary shock associated with the coronal mass ejection and a turbulent sheath immediately behind the shock compressed the ambient solar wind ions and then resulted in the soft X-ray enhancement. Furthermore, the enriched emission lines were presumed to be due to an unusual set of ion abundances and ionization states within the coronal mass ejection. We found a better time correlation with the solar wind alpha flux rather than the solar wind proton flux. Our results suggest that the solar wind proton flux is not always a good indicator of geocoronal solar wind charge exchange, especially associated with coronal mass ejections. Instead, the solar wind alpha flux should be investigated when such a soft X-ray enhancement is detected in astronomical observations., Comment: 19 pages, 11 figures, accepted for publication in PASJ

Mars was observed in X-rays during April 3-5 2008 for 82 ksec with the Japanese Suzaku observatory. Mars has been known to emit X-rays via the scattering of solar X-rays and via the charge exchange between neutral atoms in the exosphere and solar wind ions. Past theoretical studies suggest that the exospheric neutral density may vary by a factor of up to 10 over the solar cycle. To investigate a potential change of the exospheric charge exchange emission, Mars was observed with Suzaku at solar minimum. Significant signals were not detected at the position of Mars in the energy band of 0.2-5 keV. A 2 sigma upper limit of the O VII line flux in 0.5-0.65 keV was 4.3$\times10^{-5}$ ph cm$^{-2}$ s$^{-1}$. Comparing this upper limit to the past Chandra and XMM-Newton observations conducted near solar maximum, it was found that the exospheric density at solar minimum does not exceed that near solar maximum by more than 6-70 times., Comment: 17 pages, 7 figures, accepted for publication in PASJ

We present an analysis of a Suzaku observation taken during the geomagnetic storm of 2005 August 23-24. We found time variation of diffuse soft X-ray emission when a coronal mass ejection hit Earth and caused a geomagnetic storm. The diffuse emission consists of fluorescent scattering of solar X-rays and exospheric solarwind charge exchange. The former is characterized by a neutral oxygen emission line due to strong heating of the upper atmosphere during the storm time, while the latter is dominated by a sum of C V, C VI, N VI, N VII, O VII, and O VIII emission lines due to the enhanced solar wind flux in the vicinity of the exosphere. Using the solar wind data taken with the ACE and WIND satellites,a time correlation between the solar wind and the strong O VII line flux were investigated. We estimated necessary column densities for the solar X-ray scattering and exospheric SWCX. From these results, we argue that a part of the solar wind ions enter inside the magnetosphere and cause the SWCX reaction., Comment: 33 pages, 16 figures, accepted for publication in PASJ

We report the detection of a time variable OVII line emission in a deep 100 ks Suzaku X-ray Imaging Spectrometer spectrum of the Galactic Ridge X-ray emission. The observed line intensity is too strong (11+/-2 line unit or photon cm^-2 s^-1 str^-1) to be emitted inside the heavily obscured Galactic disk. It showed a factor of two time variation which shows a significant (~4 sigma) correlation with the solar wind O^7+ ion flux. The high line intensity and the good time correlation with the solar wind strongly suggests that it originated from geocoronal solar wind charge exchange emission. We discuss the X-ray line intensity considering a line of sight direction and also theoretical distribution models of the neutral hydrogen and solar wind around the Earth. Our results indicate that X-ray observationsof geocoronal solar wind charge exchange emission can be used to constrain these models., Comment: 14 pages, 5 figures; accepted to PASJ