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This study aimed to investigate the effect of chemical-free two-stage hydrothermal and mechanical refining pretreatment on improving the sugar yields during enzymatic hydrolysis of forest residue biomass (FRB) and optimize the pretreatment conditions. Hot-water pretreatment experiments were performed using a central composite design for three variables: temperature (160–200 °C), time (10–20 min), and solid loading (10–20%). Hydrothermally pretreated biomass was subsequently pretreated using three cycles of disk refining. The combined pretreatment was found to be highly effective in enhancing sugar yields during enzymatic hydrolysis, with almost 99% cellulose conversion for biomass pretreated at 213.64 °C, 15 min, and 15% solid loading. However, the xylose concentrations in the hydrolysate were found to be low under these conditions due to sugar degradation. Thus, less severe optimum pretreatment conditions (194.78 °C, 12.90 min, and 13.42% solid loading) were predicted using a second-order polynomial model. The response surface model optimized the hydrothermal pretreatment of FRB and predicted the glucan, xylan, and overall conversions of 94.57%, 79.78%, and 87.84%, respectively, after the enzymatic hydrolysis. The model-predicted biomass conversion values were validated by the experimental results. [ABSTRACT FROM AUTHOR]

There are millions of older buildings in the colder climate regions of the world where envelope upgrades are needed to improve the indoor quality of buildings, reduce energy costs, and lower greenhouse gas (GHG) emissions. This study assessed the global warming potential (GWP) with and without accounting for CO2 uptake in trees (biogenic carbon) for 20- and 100-year timespans of an exterior insulation panel. The panels consisted of six different materials with three-ply cross-laminated timber (CLT) as its main component. The net GWP100-Uptake impact when explicitly accounting for biogenic CO2 uptake over a 100-year time period was 7.2 kgCO2-eq/m2 which was 92.7% lower than if it was not included (GWP100-Fossil of 98.7 kgCO2-eq/m2). Using a 20-year GWP increased the impact of the GWP fossil by 21.7% and the CO2 uptake scenario by 298%. The major contributor was the energy used for manufacturing panel's materials (53%), with embodied carbon in bio-products primarily responsible for offsetting emissions. The findings will be helpful for policymakers in setting net-zero carbon emission goals for embodied and operational impacts of building materials. [ABSTRACT FROM AUTHOR]

Nanochitin, especially in the form of chitin nanowhiskers (ChNWs), represents a significant advance in biopolymer technology due to its high specific surface area, superior tensile strength, and excellent thermal stability. Derived from crustacean waste, which contains 15–40% of chitin, these materials provide a sustainable option that diverts waste from landfills and contributes to environmental conservation. Traditional methods of isolating nanochitin are energy-intensive and generate substantial waste. This study introduces a more sustainable method using inexpensive ionic liquids (ILs) such as [Hmim][HSO4] and [HN222][HSO4], which bypass the costly and destructive steps of traditional procedures. This study also identified the byproduct in IL-mediated chitin hydrolysis reaction as calcium sulfate dihydrate and presented a solution to circumvent the byproduct formation. The effectiveness of the [HN222][HSO4] IL in producing ChNWs from both purified chitin and crustacean biomass was assessed, showing a high yield and maintaining the purity and structural integrity of chitin, thereby demonstrating a significant reduction in the environmental footprint of ChNW production. [ABSTRACT FROM AUTHOR]

The bioeconomy is a complex, multivariate, and interdisciplinary system that requires a comprehensive assessment of its independent parts if it is to be understood fully. Hence, this article presents a holistic perspective of industry, public policy, and education aspects of the US bioeconomy. It is premised on the idea that a successful bioeconomy industry relies on the balanced development of all stages of the supply chain. For this balance to be struck, a strong interdisciplinary workforce must find novel solutions to multifaceted problems across the entirety of the supply chain. These solutions require innovative technologies that can improve the climate benefit of bioproducts, decrease their production costs, and make them more economically competitive. Increasing consumer education and awareness about the bioeconomy goes hand in hand with the development of a robust market for bioproducts. To guide these interdependent efforts, public policies must encourage demand, support competitive markets, promote the entry of renewable options, and stimulate growth by reducing financial barriers. We contend that a combination of policies is likely to be more effective than any singular policy on its own. Supporting the bioeconomy also entails attending to an existing lack of public awareness as well as workforce‐ready professionals. To address these gaps, the USA must increase the intensity and intentionality of its efforts to educate students about the bioeconomy, particularly at the K‐12 level. Furthermore, these efforts should encompass both formal and informal learning contexts in order to meet the workforce challenges facing the bioeconomy now and in the future. © 2021 The Authors. Biofuels, Bioproducts and Biorefining published by Society of Industrial Chemistry and John Wiley & Sons Ltd. [ABSTRACT FROM AUTHOR]