Search

We report on atomic-scale analyses of grain boundary (GB) structures and segregation in Nb3Sn coatings on Nb, prepared by the vapor-diffusion process, for superconducting radiofrequency (SRF) cavity applications, utilizing atom-probe tomography, high-resolution scanning transmission electron-microscopy and first-principles calculations. We demonstrate that the chemical composition of Nb3Sn GBs is correlated strongly with the diffusion of Sn and Nb at GBs during the coating process. In a sample coated with a relatively large Sn flux, we observe an interfacial width of Sn segregation at a GB of ∼3 nm, with a maximum concentration of ∼35 at.%. After post-annealing at 1100 °C for 3 h, the Sn segregated at GBs disappears and Nb segregation is observed subsequently at GBs, indicating that Nb diffused into the Nb3Sn GBs from the Nb substrate. It is also demonstrated that the amount of Sn segregation in a Nb3Sn coating can be controlled by: (i) Sn flux; and (ii) the temperatures of the Nb substrates and Sn source, which may affect the overall kinetics including GB diffusion of Sn and Nb. An investigation of the correlation between the chemical compositions of GBs and Nb3Sn SRF cavity performance reveals that the Nb3Sn SRF cavities with the best performance (high-quality factors at high accelerating electric-field gradients) do not exhibit Sn segregation at GBs. Our results suggest that the chemical compositions of GBs in Nb3Sn coatings for SRF cavities can be controlled by GB engineering and can be utilized to optimize fabrication of high-quality Nb3Sn coatings for SRF cavities.

Nb3Sn is a promising advanced material under development for superconducting radiofrequency cavities. Past efforts have been focused primarily on small development-scale cavities, but large, often multi-celled cavities, are needed for particle accelerator applications. In this work, we report on successful Nb3Sn coatings on Nb in a 1 m-long 9-cell Nb sample-host cavity at Fermilab. The geometry of the first coating with only one Sn source made it possible to study the influence of Sn flux on the microstructure. Based on these results, we postulate a connection between recently observed anomalously large thin grains and uncovered niobium spots observed in the past by other authors (Trenikhina et al 2018 Supercond. Sci. Technol. 32 015004). A phenomenological model to explain how these anomalously large grains could form is proposed. This model is invoked to provide possible explanations for literature results from several groups and to guide key process parameters to achieve uniform vapor-diffusion coatings, when applied to complex structures as the multi-cell cavity under study.

In Nb3Sn strands, hundreds or thousands of fine superconducting filaments are embedded in a metallic matrix for thermal and electrical stabilization. The transverse electrical resistivity between filaments plays a fundamental role in determining the ac losses, the thermal stability, and the current transfer length of the wire. The direct measurements of the transverse electrical resistances give useful information both for stability computations and to analyze the mechanical performance of the wire. In this paper, the interfilament resistances measured with a four-probe technique on a Nb 3Sn wire produced by Europa Metalli have been interpreted through a simulation code. A 2-D finite element method model of the wire cross-section and of a 3-D electrical circuit model of the wire sample have been applied to derive qualitative and quantitative information about the transverse electrical resistance matrix. A comparison with measurements performed on a Nb 3Sn wire with a different configuration shows the relevance of the wire layout in determining the interfilament resistance between filament bundles. © 2002-2011 IEEE.