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1. Process-Controlled Regiodivergent Copper-Catalyzed Azide-Alkyne Cycloadditions: Tailor-made Syntheses of 4- and 5-Bromotriazoles from Bromo(phosphoryl)ethyne

Author

Haruo Akashi, Tomoyo Seo, Yasuhiro Okuda, Akihiro Orita, Kazuto Imafuku, and Yoshiyuki Tsuchida

Subjects
chemistry.chemical_classification, 010405 organic chemistry, Organic Chemistry, Alkyne, 010402 general chemistry, 01 natural sciences, Biochemistry, Combinatorial chemistry, 0104 chemical sciences, chemistry.chemical_compound, chemistry, Copper catalyzed, Azide, Physical and Theoretical Chemistry
Abstract

We developed a regiodivergent syntheses of 4- and 5-bromo-substituted 1,2,3-triazoles in copper-catalyzed azide–alkyne cycloadditions (CuAACs) by taking advantage of bromo(phosphoryl)ethyne 1 as a ...

Published
2020

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