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Production of phosphoric acid generates a calcium sulfate byproduct known as phosphogypsum (PG). PG is not considered a suitable standalone road base material because of concerns such as strength and presence of radionuclides. This paper investigates the latter, specifically the influence of blending PG with common alkaline road base aggregates - limerock (LR) and recycled concrete aggregate (RCA) - on radionuclide leaching. Radionuclide leaching from several PG sources was assessed for gross alpha, gross beta, uranium, and combined radium (226 + 228). Solution pH affected Ra 226 mobility, with minimum concentrations exhibited at a pH in the range of 6 to 8. Mobile Ra 226 concentrations in RCA blends decreased compared to original PG; Ra 226 mobility initially increased at low LR replacements but decreased with increasing mass of LR (50 %-75 %). The data suggest an additional mechanism beyond pH alone impacted Ra 226 mobility from the blends, possibly the binding or substitution of radium by elevated concentrations of Ba, Sr, or Ca. Blending with RCA resulted in radionuclide concentrations below respective drinking water thresholds, mitigating leaching concern from PG-RCA road base blends. PG-LR blends can meet regulatory limits when incorporating appropriate PG sources, providing an avenue for PG-amended road base materials. The blending approach reduced Ra 226 mobility from PG-amended base, accommodating more PG use, serving as an alternative scenario to end-of-life stacking., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Timothy G. Townsend, Dreyton J. Lott, and Kate D. Weiksnar report financial support was provided by The Mosaic Company. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

The incineration of municipal solid waste (MSW) produces byproducts known as MSW incineration (MSWI) ash. The reuse of MSWI ash as a construction material prevails in several areas of the world, namely Europe and Asia, however, reuse in the United States (US) lags due to regulatory requirements for disposal practices. Developing a recycling program for MSWI ash provides an alternative end-of-life disposal scenario for material currently landfilled and supplements the reliability of mining of natural aggregates. This study provides a programmatic review of the past decade of challenges and opportunities a local government in the US has experienced to implement a recycling program for their MSWI bottom ash (BA) as a construction aggregate in road materials, such as hot mix asphalt, concrete pavement, and road base. The regulatory and practical challenges in the U.S. are presented, including meeting mechanical and environmental performance requirements (e.g., strength and leaching-to-groundwater). The novel approach to overcoming these challenges include blending MSWIBA from two facilities with common aggregates, creating suitable construction materials. Interfacing with local and state agencies, such as the Department of Environmental Protection and Transportation resulted in additional testing to establish the MSWIBA as a beneficial use material and obtain essential approvals for advancing reuse opportunities. This paper synthesizes available data regarding the challenges, opportunities, and implementation of this recycling program by reviewing the experiences of an MSWI facility in the US to provide fundamental guidance to those considering similar applications. Implications: The reuse of municipal solid waste incinerator bottom ash (MSWIBA) lags in the United States (US) due to regulatory limitations and lack of precedence. This manuscript details the steps of a local government in the US to establishing a novel recycling program for their MSWIBA, including performance evaluation, regulatory interfacing, and outreach. This critical review provides a comprehensive document containing appropriate considerations required to implement similar MSWIBA recycling programs in the US and offers lawmakers, policymakers, and MSWI operators knowledge regarding opportunities and challenges associated with pursuing this avenue.

The optimization of alternative materials in concrete production continues to garner considerable attention in order to meet sustainability goals and supplement natural materials. Portland limestone cement (PLC) and municipal solid waste incineration (MSWI) bottom ash (BA) have been proposed separately as green cement and coarse aggregate supplement in low-strength concrete production, creating sustainable products and alternative disposal scenario for a waste material. This study discusses the impact of advanced ash processing techniques on aggregates and presents the performance of concrete incorporating both of these products with PLC for the first time. Two sources of MSWI BA were investigated, one as-produced (TMR) and one processed with novel advanced metals recovery (AMR). The AMR process reduced total Al content in ash compared to TMR (20,500 vs 17,000 mg/kg), though not aluminum oxide content, as the AMR process targets metallic aluminum. A composition study on both aggregates supports a reduction in ferrous and non-ferrous metals following the AMR process. All control and test mixes met 28-day compressive strength requirements (17 Mpa). Both AMR and TMR MSWI BA-amended concretes yielded compressive strengths below control specimens (no ash) ranging from 17 to 23 MPa, with little to no difference observed dependent on MSWI BA processing. The life-cycle discussion supports benefits deriving from supplementing naturally mined materials and recovering ferrous and nonferrous metals with the AMR process., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Timothy G. Townsend, Christopher C. Ferraro, Kate D. Weiksnar, Ethan J. Marks, Margaret J. Deaderick, Isabella Mejia-Ruiz report financial support was provided by Solid Waste Authority of Palm Beach County. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Thermal landfill leachate evaporator systems can reduce the volume of leachate by up to 97%, while releasing water vapor and producing residuals (volume-reduced leachate and sludge) that are managed on-site. On-site thermal evaporators offer landfill operators leachate management autonomy without being subject to increasingly stringent wastewater treatment plant requirements. However, little is known about the partitioning of PFAS within these systems, nor the extent to which PFAS may be emitted into the environment via vapor. In this study, feed leachate, residual evaporated leachate, sludge, and condensed vapor were sampled at two active full-scale thermal landfill leachate evaporators and from a laboratory-scale leachate evaporation experiment. Samples were analyzed for 91 PFAS via ultra-high pressure liquid chromatography - tandem mass spectrometry (UHPLC-MS/MS). Similar trends were observed from Evaporator 1, Evaporator 2, and the laboratory-scale evaporator; ∑PFAS were concentrated in the residual evaporated leachate during evaporation by a factor of 5.3 to 20. All condensed vapors sampled (n = 5) contained PFAS, predominantly 5:3 fluorotelomer carboxylic acid (5:3FTCA), (full-scale vapors 729 - 4087 ng/L PFAS; lab-scale vapor 61.0 ng/L PFAS). For Evaporators 1 and 2, an estimated 9 - 24% and 10%, respectively, of the PFAS mass entering the evaporators in leachate was released with vapor during the days of sample collection. '., Competing Interests: Declaration of Competing Interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests. John A. Bowden reports financial support was provided by Hinkley Center for Solid and Hazardous Waste Management. Timothy G. Townsend reports a relationship with Hinkley Center for Solid and Hazardous Waste Management that includes: employment. Timothy G. Townsend is currently employed as Executive Director of the Hinkley Center for Solid and Hazardous Waste Management. This employment relationship began after funding was awarded for the research in this manuscript, and Timothy G. Townsend was not involved in the grant selection process which funded the work. Timothy G. Townsend’s involvement with the project was limited to manuscript revision and writing feedback. John A. Bowden, corresponding author, was the project principal investigator and primary decision-maker. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

As regulatory frameworks for per- and polyfluoroalkyl substances (PFAS) evolve, the solid waste community seeks to manage PFAS risks effectively. Despite extensive research on PFAS in municipal solid waste (MSW) and wastewater sludge, there is limited information on a major global waste stream which seldom gleans regulatory oversight - construction and demolition debris (CDD). This study sampled a CDD processing facility to provide material-specific information on the PFAS profile within CDD. The bulk CDD accepted by this facility was separated into major categories, representatively sampled, then characterized for total available PFAS (∑ 92 PFAS). As reprocessed CDD is ultimately recycled or landfilled, often unencapsulated or in unlined landfills, the PFAS leaching potential was also examined using two leaching procedures. Among the categories assessed for total PFAS, carpeting, carpet padding, and gypsum drywall showed elevated concentrations compared to other components, with most of the PFAS mass contributed by precursor species. However, materials with the highest total PFAS, such as carpeting, did not necessarily exhibit the highest leaching, and leachate was predominantly composed of terminal species rather than precursors. Extrapolating these findings with national CDD generation and management data inventories suggests that despite MSW having higher total available PFAS concentrations, the leachability of PFAS from landfilled CDD is comparable, raising legitimate concerns with CDD disposal practices, particularly in unlined CDD landfills., Competing Interests: Declaration of Competing Interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests. Timothy Townsend reports financial support was provided by United States Environmental Protection Agency. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

This study explored the effect stage number and plant type have on ammonia-nitrogen (NH 3 -N) removal kinetics in a two-stage pilot-scale vertical flow constructed wetland (VFCW) system treating landfill leachate. Half of the VFCW columns were planted with Typha latifolia and the other half Scirpus californicus, and half of the columns were loaded with municipal solid waste landfill leachate (diluted to 1 part leachate to 2 parts total) with the effluent from these columns was collected in two separate barrels. The remaining columns were loaded with the effluent collected from the first columns, creating a two-stage VFCW system with four unique pairs to be tested. The leachate used here experienced no prior pre-treatment, and average influent concentrations of NH 3 -N for the first- and second-stage VFCWs were 508 and 321 mg L -1 , respectively- much higher than many other VFCW treatment systems. Some reduction in chemical oxygen demand was observed, as well as generation of nitrate and nitrite, evidence of nitrification. No apparent correlation between aboveground biomass and removal of NH 3 -N was observed. Overall removal efficiency of NH 3 -N through two stages of VFCWs was 53.7% for columns planted with T. latifolia and 58.3% for those planted with S. Californicus. Average NH 3 -N removal efficiencies for the first stage VFCWs were 32.7% and 34.3%, while those in the second stage were 31.3% and 36.5%; no significant difference was observed between the first and second stage, suggesting that stage number does not have a significant effect on the removal efficiency of NH 3 -N in the primary treatment of landfill leachate via VFCWs. However, average mass removal rates of NH 3 -N in the first stage were 166 and 175 mg L -1 d -1 ; the second stage was significantly lower at 99.4 and 112 mg L -1 d -1 , indicating that the first stage removed more pollutants overall., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

In recent years, soil screening levels have been adopted by regulatory agencies for certain per- and polyfluoroalkyl substances (PFAS) to assess the risk of groundwater contamination through leaching. These soil screening levels, determined using an established equilibrium-based partitioning equation, have high variability among regulatory groups largely attributed to the diverse reported partitioning coefficients in the literature. This variability between reported partitioning coefficients, and subsequently soil screening levels, is due to the complex leaching behavior of PFAS not being predicted well by the standard equilibrium-based model. This has led one regulatory group to require batch leaching to assess risk rather than setting default soil screening levels based on partitioning equations. In this work, we conducted leaching experiments on five field-sampled soils impacted by aqueous film-forming foams (AFFF), following Leaching Environmental Assessment Framework (LEAF) Method 1316 and compared the results to expected leaching utilizing an equilibrium-based partitioning equation commonly employed by regulatory agencies to establish soil screening levels. Our analysis found among the six PFAS detected in the soils, which have regulatory leaching thresholds established, the partitioning values assumed by the U.S. EPA exhibited the highest accuracy in predicting leachate concentrations. These partitioning values predicted actual leaching within a ± 20 % margin of error for approximately 50 % of sample points, highlighting limitations in relying solely on equilibrium-based partitioning values as predictors of leaching behavior. This discrepancy between predicted and actual leaching has implications for site managers and regulatory entities overseeing PFAS-contaminated sites, suggesting that soil screening level determinations for PFAS might need to be revised to account for the unique transport characteristics of PFAS., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier B.V.)

Elevated per- and polyfluoroalkyl substance (PFAS) concentrations have been reported in municipal solid waste (MSW) landfill leachate with higher levels in wet and warmer subtropical climates. Information about landfill leachate characteristics is much more limited in tropical climates. In this study, 20 landfill leachate samples were collected from three MSW landfills on the tropical island of Puerto Rico and results were compared against landfills nationally and within Florida, USA. The samples collected in Puerto Rico underwent physical-chemical analysis, as well as a quantitative analysis of 92 PFAS. Samples described in this study include discrete leachate types, such as leachate, gas condensate, and leachate which has undergone on-site treatment (e.g., RO treatment, phytoremediation, lagoons). A total of 51 PFAS were detected above quantitation limits, including perfluorohexylphosphonic acid, a perfluoroalkyl acid (PFAA) which has not been reported previously in landfill leachate. ∑PFAS concentrations in this study (mean: 38,000 ng L -1 ), as well as concentrations of individual PFAS, are significantly higher than other reported MSW landfill leachate concentrations. The profiles of leachates collected from on-site treatment systems indicate possible transformation of precursor PFAS as a result of treatment processes - oxidizing conditions, for example, may facilitate aerobic transformation, increase the concentrations of PFAAs, and possibly increase the apparent ∑PFAS concentration. Extreme climate events, including rising temperatures and more frequent hurricanes, have placed additional strain on the solid waste management infrastructure on the island - adding complexity to an already challenging PFAS management issue. As concern grows over PFAS contamination in drinking water, these findings should inform solid waste and leachate management decisions in order to minimize PFAS emissions in island environments., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

Composting municipal food waste is a key strategy for beneficially reusing methane-producing waste that would otherwise occupy landfill space. However, land-applied compost can cycle per- and polyfluoroalkyl substances (PFAS) back into the food supply and the environment. We partnered with a pilot-scale windrow composting facility to investigate the sources and fate of 40 PFAS in food waste compost. A comparison of feedstock materials yielded concentrations of ∑PFAS under 1 ng g -1 in mulch and food waste and at 1380 ng g -1 in leachate from used compostable food contact materials. Concentrations of targeted ∑PFAS increased with compost maturity along the windrow (1.85-23.1 ng g -1 ) and in mature stockpiles of increasing curing age (12.6-84.3 ng g -1 ). Among 15 PFAS quantified in compost, short-chain perfluorocarboxylic acids (PFCAs) - C5 and C6 PFCAs in particular - led the increasing trend, suggesting biotransformation of precursor PFAS into these terminal PFAS through aerobic decomposition. Several precursor PFAS were also measured, including fluorotelomer carboxylic acids (FTCAs) and polyfluorinated phosphate diesters (PAPs). However, since most targeted analytical methods and proposed regulations prioritize terminal PFAS, testing fully matured compost would provide the most relevant snapshot of PFAS that could be land applied. In addition, removing co-disposed food contact materials from the FW feedstock onsite yielded only a 37 % reduction of PFAS loads in subsequent compost, likely due to PFAS leaching during co-disposal. Source-separation of food contact materials is currently the best management practice for meaningful reduction of PFAS in food waste composts intended for land application., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: John A. Bowden reports financial support was provided by US Environmental Protection Agency. John A. Bowden reports financial support was provided by Hinkley Center for Solid and Hazardous Waste Management. Timothy G. Townsend reports financial support was provided by US Environmental Protection Agency. Timothy G. Townsend reports financial support was provided by Hinkley Center for Solid and Hazardous Waste Management. Co-author Stephan Barron is the owner and operator of the composting facility from which samples for this study were collected. We felt that it was important to include Stephan as a co-author because he had to facilitate our access to sample collection and provide information about his composting process, which was then incorporated into the manuscript. Stephan was not involved in any way in sample processing, data analysis and interpretation, or manuscript writing. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

PER: and polyfluoroalkyl substances (PFAS) have been measured in aqueous components within landfills. To date, the majority of these studies have been conducted in Florida. This current study aimed to evaluate PFAS concentrations in aqueous components (leachate, gas condensate, stormwater, and groundwater) from four landfills located outside of Florida, in Pennsylvania, Colorado, and Wisconsin (2 landfills). The Pennsylvania landfill also provided the opportunity to assess a leachate treatment system. Sample analyses were consistent across studies including the measurements of 26 PFAS and physical-chemical parameters. For the four target landfills, average PFAS concentrations were 6,900, 22,000, 280, and 260 ng L -1 in the leachate, gas condensate, stormwater, and groundwater, respectively. These results were not significantly different than those observed for landfills in Florida except for the significantly higher PFAS concentrations in gas condensate compared to leachate. For on-site treatment at the Pennsylvania landfill, results suggest that the membrane biological bioreactor (MBBR) system performed similarly as aeration-based leachate treatment systems at Florida landfills resulting in no significant decreases in ∑ 26 PFAS. Overall, results suggest a general consistency across US regions in PFAS concentrations within different landfill liquid types, with the few differences observed likely influenced by landfill design and local climate. Results confirm that leachate exposed to open air (e.g., in trenches or in treatment systems) have lower proportions of perfluoroalkyl acid precursors relative to leachate collected in enclosed pipe systems. Results also confirm that landfills without bottom liner systems may have relatively higher PFAS levels in adjacent groundwater and that landfills in wetter climates tend to have higher PFAS concentrations in leachate., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Per- and polyfluoroalkyl substances (PFAS) have been found at high levels within landfill environments. To assess PFAS distributions, this study aimed to evaluate PFAS mass flux leached from disposed solid waste and within landfill reservoirs by mass balance analyses for two full-scale operational Florida landfills. PFAS mass flux in different aqueous components within landfills were estimated based on PFAS concentrations and water flow rates. For PFAS concentration, 26 PFAS, including 18 perfluoroalkyl acids (PFAAs) and 8 PFAA-precursors, were measured in samples collected from the landfills or estimated based on previous studies. Flow rates of aqueous components (rainfall, evapotranspiration, runoff, stormwater, groundwater, leakage, gas condensate, and leachate) were evaluated through the Hydrologic Evaluation of Landfill Performance model, water balance, and Darcy's Law. Results showed that the average PFAS mass flux leached from the solid waste standardized by area was estimated as 36.8 g/ha-yr, which was approximately 1 % to 3 % of the total amount of PFAS within the solid waste. The majority of PFAS leached from the solid waste (95 % to 97 %) is captured by the leachate collection system, with other aqueous components representing much smaller fractions (stormwater system at 3 % to 5 %, and gas condensate and groundwater at < 1 %). Also, based on the results, we estimate that PFAS releases will likely occur at least over 40 years. Overall, these results can help prioritize components for waste management and PFAS treatment during the anticipated landfill release periods., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Studies of per- and polyfluoroalkyl substances (PFAS) fluctuations at landfills have focused on municipal solid waste (MSW) leachate. Few studies exist that evaluate fluctuations (defined by the coefficient of variation, CV) in MSW incinerator ash (MSWA) landfill leachate and that evaluate PFAS fluctuations in stormwater, groundwater, and treated liquids on-site. In this study, aqueous landfill samples (leachate, treated leachate, stormwater, gas condensate, ambient groundwater, and effluent from a groundwater remediation system) were collected from a MSW and an MSWA landfill geographically located within close proximity (less than 40 km). The objective of this study was to compare the leachate compositions between these two landfill types and to evaluate temporal variations. Results indicated that the CV of total detected PFAS concentrations in leachate was higher for the MSW landfill (CV = 43 %) compared to the MSWA landfill (CV = 16 %). The total detected PFAS concentration in MSW leachate samples (mean: 9641 ng/L) was higher than in MSWA leachate samples (mean: 2621 ng/L) (p < 0.05). Within a landfill, PFAS concentrations were correlated (r s  > 0.6, p < 0.05) with alkalinity, total organic carbon (TOC), and ammonia. Results from the on-site leachate treatment system at the MSW landfill indicated reductions in COD, TOC, and ammonia; however, the ∑ 26 PFAS concentration increased 3 % after the treatment. Overall, results demonstrated that differences between landfill types and fluctuations in PFAS within landfills should be considered when designing landfill leachate collection and treatment systems to remove PFAS. The comparative analysis in this study can provide insights into optimizing leachate management for MSW and MSWA landfills., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

With regulations for per-and polyfluoroalkyl substances (PFAS) impending, the abundance of these chemicals of emerging concern in municipal solid waste (MSW) landfill leachate increasingly challenges landfill operators to seek on-site leachate pre-treatment options. This two-staged study explores the potential reuse of biochar derived from construction and demolition debris (CDD) wood as an in-situ PFAS sorbent for application within MSW landfill leachate collection systems. Batch leaching tests were first used to examine the feasibility of capturing PFAS from landfill leachate using two sources of CDD-wood-derived biochar. Then, columns were used to test the in-situ sorption capabilities of the same biochars under simulated landfill conditions. All leachates were characterized for pH, chemical oxygen demand, ammonia-nitrogen, and 92 PFAS. Seventeen PFAS were detected in the batch leaching experiment, and nine PFAS were detected in column leachates. In the batch leaching scenario, Biochar 1 achieved a maximum of 29% PFAS reduction compared to controls. Columns containing Biochar 1 generated leachates with PFAS concentrations 50% to 80% higher than those in control columns for the duration of the experiment. Columns containing Biochar 2 generated leachates with PFAS concentrations 44% less than controls in week 1 and similar concentrations in weeks 2, 3, and 4. In this study, PFAS removal from landfill leachate using biochar derived from CDD wood was not significant. Further research on biochar derived from CDD wood is needed before it can be recommended as an in-situ landfill leachate pre-treatment method., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Timothy G. Townsend reports financial support was provided by US Environmental Protection Agency. John A. Bowden reports financial support was provided by US Environmental Protection Agency. Timothy G. Townsend reports financial support was provided by Construction and Demolition Recycling Association. The Construction and Demolition Recycling Association provided samples evaluated in the study. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Ltd.)

This study analyzed spent activated carbon (AC) from a landfill gas (LFG) treatment system for an expanded suite of lesser studied volatile metals, revealing elevated levels of As and Sb in the LFG, exceeding those previously reported, with minimum average concentrations of 640 µg m -3 and 590 µg m -3 , respectively. The annual release of As and Sb through landfill gas was found to be significant, surpassing leachate emissions by an order of magnitude. Extrapolating these findings to all US landfills suggests that the release of As and Sb through landfill gas could be a major, previously overlooked source of these metals in global emission estimates, underscoring the need to include them when developing future inventories. The spent AC was further found to exceed US toxicity limits established for As, classifying it as hazardous waste under US regulations. However, findings suggest that the AC scrubber employed at the landfill effectively prevented substantial releases of As and Sb. This research emphasizes that landfill gas is a primary contributor to environmental release of As and Sb from landfills, even more so than leachate, highlighting the significance of implementing effective LFG treatment measures to mitigate the release of volatile metal emissions., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

The number of clinical trials is rapidly growing, and automation of literature processing is becoming desirable but unresolved. Our purpose was to assess and increase the readiness of clinical trial reports for supporting automated retrieval and implementation in public health practice. We searched the Medline database for a random sample of clinical trials of HIV/AIDS management with likely relevance to public health in Africa. Five authors assessed trial reports for inclusion, extracted data, and assessed quality based on the FAIR principles of scientific data management (findable, accessible, interoperable, and reusable). Subsequently, we categorized reported results in terms of outcomes and essentials of implementation. A sample of 96 trial reports was selected. Information about the tested intervention that is essential for practical implementation was largely missing, including personnel resources needed 32·3% (.95 CI: 22·9-41·6); material/supplies needed 33·3% (.95 CI: 23·9-42·8); major equipment/building investment 42·8% (CI: 33·8-53·7); methods of educating providers 53·1% (CI: 43·1-63·4); and methods of educating the community 27·1% (CI: 18·2-36·0). Overall, 65% of studies measured health/biologic outcomes, among them, only a fraction showed any positive effects. Several specific design elements were identified that frequently make clinical trials unreal and their results unusable. To sort and interpret clinical trial results easier and faster, a new reporting structure, a practice- and retrieval-oriented trial outline with numeric outcomes (PROTON) table was developed and illustrated. Many clinical trials are either inconsequential by design or report incomprehensible results. According to the latest expectations of FAIR scientific data management, all clinical trial reports should include a consistent and practical impact-oriented table of clinical trial results., Competing Interests: Conflict of interest statement All authors declare no competing interests.

Per- and polyfluoroalkyl substances (PFAS) are widespread, persistent environmental contaminants that have been linked to various health issues. Comprehensive PFAS analysis often relies on ultra-high-performance liquid chromatography coupled with high-resolution mass spectrometry (UHPLC HRMS) and molecular fragmentation (MS/MS). However, the selection and fragmentation of ions for MS/MS analysis using data-dependent analysis results in only the topmost abundant ions being selected. To overcome these limitations, All Ions fragmentation (AIF) can be used alongside data-dependent analysis. In AIF, ions across the entire m / z range are simultaneously fragmented; hence, precursor-fragment relationships are lost, leading to a high false positive rate. We introduce IonDecon, which filters All Ions data to only those fragments correlating with precursor ions. This software can be used to deconvolute any All Ions files and generates an open source DDA formatted file, which can be used in any downstream nontargeted analysis workflow. In a neat solution, annotation of PFAS standards using IonDecon and All Ions had the exact same false positive rate as when using DDA; this suggests accurate annotation using All Ions and IonDecon. Furthermore, deconvoluted All Ions spectra retained the most abundant peaks also observed in DDA, while filtering out much of the artifact peaks. In complex samples, incorporating AIF and IonDecon into workflows can enhance the MS/MS coverage of PFAS (more than tripling the number of annotations in domestic sewage). Deconvolution in complex samples of All Ions data using IonDecon did retain some false fragments (fragments not observed when using ion selection, which were not isotopes or multimers), and therefore DDA and intelligent acquisition methods should still be acquired when possible alongside All Ions to decrease the false positive rate. Increased coverage of PFAS can inform on the development of regulations to address the entire PFAS problem, including both legacy and newly discovered PFAS.

The continuous growth of annual production and consumption of polyethylene terephthalate (PET) is coined with increasing waste that leaks into the environment, landfills and oceans as microplastics and nano plastics fragments. Upcycling the recycled PET to make a feedstock for the fast-growing material-extrusion additive manufacturing (MEX-AM) technology can contribute to the solution and supports the concept of sustainable materials. In this work, extrudable filaments comprising recycled polyethylene terephthalate (rPET) with low-cost additives, such as pyromellitic dianhydride (PMDA) as a chain extender, styrene-ethylene-butylene-styrene terpolymer functionalized with maleic anhydride (SEBS-g-MA), a thermal modifier and toughening agent, ethylene-ethyl acrylate-glycidyl methacrylate terpolymer (E-EA-GMA), a functional reactive elastomeric impact modifier and ethylene-ethyl-acrylate (EEA), a non-reactive elastomeric impact modifier, have been fabricated using the twin-screw extruder. The optimum extrusion process parameters for producing uniform filaments of different rPET compounded formulations have been identified, this includes the extrusion die temperature of 280 °C and the screw speed of 150 ± 3 rpm. The compounded filaments are then printed into standard ASTM test specimens for thermal characterization and mechanical characterization, including glass transition and melting temperatures, crystallinity and crystallization temperature, tensile strength, tensile modulus, ductility, flexural strength, and Izod impact energy. Furthermore, the melt flow index for the filaments was measured. More significantly, the experimental data showed that compounding rPET with such additives in the reactive twin-screw extrusion process results in uniform filaments that display advantageous thermal and mechanical properties and can be used as a feedstock in the MEX-AM technology. This study suggests that compounding the recycled PET pellets with low-cost additives while extruding them into filaments for MEX-AM offers excellent potential to make high-value-added customized products from a sustainable polymer feedstock, such as prototyping, tooling, testing components or end-use internal components for small machines and cars., (© 2023. Springer Nature Limited.)

This study explores modifying a sandy soil with a low solid to liquid partitioning coefficient (K d ) by adding amendments including iron-rich industrial slag byproducts and biochars, which contain sorption sites for trace metals present in MSWI ash leachate (notably Sb, cited as a concern for reuse applications). K d values for Sb were determined for the sandy soil to be as low as 1.6 ± 0.1 L/kg. With amendments, K d values varied from 1.4 ± 0.2 L/kg for combined ash leachate exposed to a blend of sandy soil and 20% iron slag, to 990 L/kg for combined ash leachate exposed to a blend of sandy soil and 20% magnetic solids. A blend of 20% magnetic solids showed orders of magnitude increase beyond 100% sandy soil. The biochars showed limited capacity to reduce leached Sb in the ash-derived leachate, which is likely due to negative surface charges of the biochars and Sb at basic pH. A risk assessment (US EPA IWEM) performed using experimental K d for each blend suggests that using soil amendments could reduce leached concentrations at points of concern, which could open additional avenues for ash reuse., Competing Interests: Declaration of Competing Interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Dr. Timothy Townsend reports financial support was provided by Hinkley Center for Solid and Hazardous Waste Management., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Concentrations of 25 inorganic elements were measured in both bulk ash and individual ash components from residuals at three municipal solid waste incineration (MSWI) facilities in the US (two combined ash (CA) and one bottom ash (BA)). Concentrations were assessed based on particle size and component to understand the contribution from each fraction. The results found that among facilities, the finer size fractions contained elevated concentrations of trace elements of concern (As, Pb, Sb) when compared to the coarse fraction, but concentrations varied among facilities depending on the type of ash and differences in advanced metals recovery processes. This study focused on several constituents of potential concern, As, Ba, Cu, Pb, and Sb, and found that the main components of MSWI ash (glass, ceramic, concrete, and slag) are sources of these elements in the ash streams. For many elements, concentrations were significantly higher in CA bulk and component fractions opposed to BA streams. An acid treatment procedure and scanning electron microscopy/energy-dispersive x-ray spectroscopy analysis revealed that some elements, such as As in concrete, are result of the inherent properties of the component, but other elements, such as Sb, form on the surface during or after incineration and can be removed. Some Pb and Cu concentrations were attributed to inclusions in the glass or slag introduced into the material during the incineration process. Understanding the contributions of each ash component provides critical information for developing strategies to reduce trace element concentrations in ash streams to promote reuse opportunities., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: All Authors report financial support was provided by Hinkley Center for Solid and Hazardous Waste Management., (Copyright © 2023. Published by Elsevier Ltd.)

The leachate collection system (LCS) and leak detection system (LDS) flow rate data from 240 cells (or a combination of cells) at 54 municipal solid-waste landfills (located in seven US states) with double-liner systems were analyzed to assess the performance of the primary liner system. The average LCS leachate collection rates for the study sites ranged from 380 L ha -1 day -1 (40.7 gal. acre -1 day -1 ) to 22,400 L ha -1 day -1 (2,390 gal. acre -1 day -1 ) on a sitewide basis, and the average LDS leachate collection rates ranged from 1.8 L ha -1 day -1 (0.2 gal. acre -1 day -1 ) to 577 L ha -1 day -1 (61.7 gal. acre -1 day -1 ) on a sitewide basis. Assuming all leachate generated is collected either by the LCS or LDS, the data suggest that the primary liner systems' aggregated efficiency is over 98%. The collection efficiency at sites that used a composite liner (geomembrane underlain by a geosynthetic clay liner or a compacted clay liner) system was not statistically different from the sites that used only a geomembrane as the primary liner (geomembrane underlain by a permeable layer) (median of 99% for both types). Leakage rates were compared with those estimated from the equations used by the hydrologic evaluation of landfill performance (HELP) model. The comparison suggests that the equations used by the HELP model to estimate leakage through the liner overestimate the leakage rate through geomembrane primary liners but underestimate the leakage rate through composite primary liners based on the HELP-model-default defect size and suggested defect frequency. It is also possible that groundwater intrusion could contribute to a portion of the leachate collected from the LDS because leachate quality data collected from a few sites indicated the LCS leachate had a higher concentration of most constituents than the leachate collected from LDS.

The environmental risks associated with the storage, reuse, and disposal of unencapsulated reclaimed asphalt pavement (RAP) has been previously examined, but because of a lack of standardized column testing protocols and recent interest on emerging constituents with higher toxicity, questions surrounding leaching risks from RAP continue. To address these concerns, RAP from six, discrete stockpiles in Florida was collected and leach tested following the most up-to-date, standard column leaching protocol - United States Environmental Protection Agency (US EPA) Leaching Environmental Assessment Framework (LEAF) Method 1314. Sixteen EPA priority polycyclic aromatic hydrocarbons (PAHs), 23 emerging PAHs, identified through relevance in literature, and heavy metals were investigated. Column testing showed minimal leaching of PAHs; only eight compounds, three priority PAHs and five emerging PAHs, were released at quantifiable concentrations, and where applicable, were below US EPA Regional Screening Levels (RSL). Though emerging PAHs were identified more frequently, in most cases, priority compounds dominated contributions to overall PAH concentration and benzo(a)pyrene (BaP) equivalent toxicity. Except for arsenic, molybdenum, and vanadium in two samples, metals were found below limits of detection (LOD) or below risk thresholds. Arsenic and molybdenum concentrations diminished over time with increased exposure to liquid, but elevated vanadium concentrations persisted in one sample. Further batch testing linked vanadium to the aggregate component of the sample, unlikely to be encountered in typical RAP sources. As demonstrated by generally low constituent mobility observed during testing, the leaching risks associated with the beneficial reuse of RAP are limited, and under typical reuse conditions, factors of dilution and attenuation would likely reduce leached concentrations below relevant risk-based thresholds at a point of compliance. When considering emerging PAHs with higher toxicities, analyses indicated minimal impact to overall leachate toxicity, further suggesting that with proper management, this heavily recycled waste stream is unlikely to pose leaching risk., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Variable chemistries of liquids from landfills can potentially impact levels of per- and polyfluoroalkyl substances (PFAS). The objective of the current study was to evaluate relationships between physical-chemical properties (bulk measurements, oxygen demand components, and metals) and PFAS concentrations in different types of aqueous landfill samples. Aqueous landfill samples were collected from 39 landfill facilities in Florida, United States. These samples included leachates from landfills that receive different waste types, such as municipal solid waste incineration ash (MSWA), construction and demolition debris (C&D), and municipal solid waste (MSW). Additional aqueous landfill samples were sourced from treated landfill leachate, gas condensate, stormwater, and groundwater from within and near the landfill boundaries. Results showed significant correlations (p < 0.05) between ∑ 26 PFAS and alkalinity (r s  = 0.83), total organic carbon (TOC) (r s  = 0.84), and ammonia (r s  = 0.79) for all leachate types. Other physical-chemical parameters that were significantly correlated (r s  > 0.60, p < 0.05) with PFAS included specific conductivity, chemical oxygen demand (COD), and to a lesser extent, total dissolved solids (TDS) and total solids (TS). For gas condensates, PFAS was significantly correlated with TOC. Stormwater and groundwater, within and near the landfill boundaries, had considerably lower levels of PFAS and had a minimal correlation between PFAS and physical-chemical parameters. Although PFAS concentrations and physical-chemical parameters and their correlations varied between different types of aqueous landfill samples, results suggest that physical-chemical properties can be useful indicators of relative PFAS concentrations within a leachate type. More research is needed to validate the mechanisms that relate physical-chemical parameters to PFAS concentrations in landfill leachates., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Per- and polyfluoroalkyl substances (PFAS) are ubiquitously present in our indoor living environments. Dust is thought to accumulate PFAS released indoors and serve as an exposure pathway for humans. Here, we investigated whether spent air conditioning (AC) filters can be exploited as opportunistic samplers of airborne dust for assessing PFAS burden in indoor environments. Used AC filters from campus facilities (n = 19) and homes (n = 11) were analyzed for 92 PFAS via targeted ultra-high pressure liquid chromatography - tandem mass spectrometry (UHPLC-MS/MS). While 27 PFAS were measured (in at least one filter), the predominant species were polyfluorinated dialkylated phosphate esters (diPAPs), with the sum of 6:2-, 8:2-, and 6:2/8:2diPAPs accounting for approximately 95 and 98 percent of ∑ 27 PFAS in campus and household filters, respectively. Exploratory screening of a subset of the filters revealed the presence of additional species of mono-, di-, and tri-PAPs. Considering the constant human exposure to dust indoors and the potential of PAPs to degrade into terminal species with well-established toxicological risks, assessing dust for these precursor PFAS warrants further investigation with respect to both human health and PFAS loading to landfills from this under studied waste stream., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

While per- and polyfluoroalkyl substances (PFAS) have been reported extensively in municipal solid waste (MSW) landfill leachate,they have rarely been quantified in landfill gas or in discrete landfill liquids such as landfill gas condensate (LGC), and the potential for PFAS to partition to the condensate has not been reported. LGC and leachate collected from within gas wells known as gas well pump-out (GWP) from three MSW landfills underwent physical-chemical characterization and PFAS analysis to improve understanding of the conditions under which these liquids form and to illuminate PFAS behavior within landfills. LGC was observed to be clear liquid containing ammonia and alkalinity while GWP strongly resembled leachate - dark in color, high in chloride and ammonia. Notably, arsenic and antimony were found in concentrations exceeding regulatory thresholds by over two orders of magnitude in many LGC samples. LGC contained a lower average concentration of ΣPFAS (19,000 ng L) compared to GWP (56,000 ng L); however, LGC contained more diversity of PFAS, with 53 quantified compared to 44 in GWP. LGC contained proportionally more precursor PFAS than GWP, including more semi-volatile PFAS which are rarely measured in water matrices, such as fluorotelomer alcohols and perfluoroalkane sulfonamido ethanols. This study provides the first detailed comparison of these matrices to inform timely leachate management decisions., Competing Interests: Declaration of Competing Interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Timothy Townsend reports financial support was provided by United States Environmental Protection Agency., (Copyright © 2023. Published by Elsevier B.V.)

This study investigated the behavior of per- and polyfluoroalkyl substances (PFAS) in multiple pilot-scale vertical flow constructed wetlands (VFCW) treating landfill leachate. Eight pilot-scale VFCW columns planted with Typha latifolia or Scirpus Californicus were fed untreated municipal solid waste (MSW) landfill leachate that was diluted with potable water at a 1:10 ratio (1 part leachate to 10 parts total) at a fixed daily hydraulic loading rate of 0.525 m d -1 . Ninety-two PFAS were examined and 18 PFAS were detected at quantifiable concentrations (7 precursor species and 11 terminal species). The average concentration of Σ 92 PFAS in the influent was 3,100 ng L -1 , which corresponded with minimal reduction in the effluents from the four VFCW (decreases ranged from 1% to 12% on average for Σ 18 PFAS); however, precursors 6:3 FTCA, 7:3 FTCA, N-MeFOSAA, and N-EtFOSAA concentrations decreased significantly in the VFCW effluents, and significant decreases in the concentrations of these PFAA-precursors were concurrent with a significant increase in concentrations of five PFAAs (PFBA, PFNA, PFBS, PFOS, and PFOSI). This trend indicates that from a regulatory perspective, standalone VFCWs are likely to produce an apparent PFAS increase, which may also be true for many other leachate treatment processes incorporating aerobic biological treatment. Additional treatment to address PFAS should be integrated prior to the use of any system, including VFCWs, for the treatment of constituents of concern in MSW landfill leachate., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Wastewater treatment plants generate a solid waste known as biosolids. The most common management option for biosolids is to beneficially reuse them as an agricultural amendment, but because of the risk of pathogen exposure, many regulatory bodies require pathogen reduction before biosolids reuse. Per- and polyfluoroalkyl substances (PFAS) are well documented in biosolids, but limited information is available on how biosolids treatment processes impact PFAS. Furthermore, quantification of PFAS has focused on perfluoroalkyl acids (PFAAs) which are a small fraction of thousands of PFAS known to exist. The objective of this study was to quantify 92 PFAS in biosolids collected from eight biosolids treatment facilities before and after four pathogen treatment applications: composting, heat treatment, lime treatment, and anaerobic digestion. Overall, total PFAS concentrations before and after treatment were dominated by PFAA precursor species, in particular, diPAPs which accounted for a majority of the mass of the Σ 92 PFAS. This differs from historic data that found PFAAs, primarily PFOS, to dominate total PFAS concentrations. Treatment options such as heat treatment and composting changed the ratio of PFAA precursors to PFAAs indicating a transformation of PFAS during treatment. This study finds that PFAA precursors are likely underrepresented by other studies and make up a larger percentage of the total PFAS concentration in biosolids than previously estimated.

Per- and polyfluoroalkyl substances (PFAS), found in many consumer products, are commonly disposed of in landfills at the end of their service lives. To identify landfill liquids that should be prioritized for treatment, this study aimed to evaluate PFAS levels in different aqueous samples from landfills and identify relationships between PFAS and landfill characteristics. Twenty-six PFAS including 11 perfluoroalkyl carboxylic acids (PFCAs), 7 perfluoroalkyl sulfonates (PFSAs), and 8 perfluoroalkyl acid precursors (PFAA-precursors) were measured in municipal solid waste (MSW) leachate, construction and demolition debris (CDD) leachate, municipal solid waste incineration (MSWI) ash leachate, gas condensate, stormwater, and groundwater from landfills. Based on the median, results show that PFAS levels in MSW leachate were the highest (10,000 ng L -1 ), CDD leachate were intermediate (6200 ng L -1 ), and MSWI ash leachate were the lowest (1300 ng L -1 ) among the leachates evaluated. PFAS levels in gas condensate (7000 ng L -1 ) were similar to MSW leachate. PFAS in stormwater and groundwater were low (medians were less than 500 ng L -1 ). Dominant subgroups included PFCAs and PFAA-precursors in all leachates. PFSAs were also found in CDD leachate, PFAA-precursors in gas condensate, and PFCAs in stormwater and groundwater. Landfill characteristics significantly correlated with ∑ 26 PFAS included waste proportions (percentage of MSWI ash in landfill, |r s | = 0.22), operational status (active or not, |r s | = 0.27) and rainfall (30-d cumulative rainfall, |r s | = 0.39). The results from this study can be used to prioritize which landfills and which reservoir of liquids (and corresponding subgroup of PFAS) to target for PFAS management., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The summer of 2020 marked a shift in public perception of police brutality and racism in the United States. Following the police murder of George Floyd and ensuing social unrest, the appropriate role and function of the police in communities have been a frequent topic of debate. Of particular concern is the intersection of policing and mental health where we see a pattern of police using excessive force disproportionately against persons with disabilities, especially mental health disabilities (Autistic Self Advocacy Network, 2017). The introduction of race only exacerbates this disparity (Saleh et al., 2018). Given the realities of these mental health inequities, the aim of this scoping review is to explore first response models/programs that emphasize a therapeutic intervention as an alternative to policing. Seventeen articles were selected for inclusion in the review, six exploratory or experimental studies and 11 review or discussion articles. Using findings from the review, we offer recommendations to help reimagine this country's approach to emergency response. We urge psychologists and other health care providers to step out of the clinic and engage the community in the development of crisis responses for mental health emergencies that are therapeutic rather than inflammatory, healing rather than harming. (PsycInfo Database Record (c) 2023 APA, all rights reserved).

Phosphogypsum (PG) samples from four distinct sources in the Southeastern US were analyzed to explore the variation in total metal content between newly generated (fresh) PG and PG disposed of in phosphogypsum stacks for different lengths of time (stack). Fresh PG exhibited greater total metal concentrations relative to stack PG, including those identified in the literature as important from a risk assessment perspective (As, Cd, Co, Cr, Cu, Pb, and Zn). The pH varied between fresh and stack PG, with some stack samples exhibiting lower pH than fresh samples, however the relationship between pH and age of sample was not linear. Stack samples with pH values similar to fresh samples possessed lower concentrations of total inorganic metals than fresh samples suggesting that process water drainage and stack location play an important role in the reusability of PG as they can affect the pH of stack PG and total inorganic metal concentrations. Overall observations show that stacking PG for three or more years prior to beneficial reuse provides a construction material with lower total metal concentrations than fresh PG., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: All Authors reports financial support was provided by The Mosaic Company., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Antimony is used extensively in consumer goods, including single use plastic bottles, electronics, textiles and automobile brakes, which are disposed of in landfills at the end of their service lives. As a result, Sb is a constituent of concern in landfill emissions. Previous research has focused on leachate (liquid) and waste incineration flue gas emissions; however, Sb has the potential to volatilize through chemical and microbial processes within a landfill. In this study, iron-amended granular activated carbon was used to adsorb volatile metals directly from gas in a full-scale landfill gas collection system. Metals were quantified using acid digestion and ICP-AES analysis. Antimony concentrations far exceeded those previously reported, at up to 733 μg m -3 (mean: 254 μg m -3 ). In addition to Sb, As was also measured at high levels compared to previous research, as high as 740 μg m -3 (mean: 178 μg m -3 ). Using US EPA landfill and landfill gas databases, total Sb emissions via landfill gas are estimated to be approximately 27.3 kg day -1 in the US. Based on other estimates of national and global Sb emissions, this corresponds to approximately 4.5% of total US atmospheric emissions of Sb and 0.42% of global atmospheric emissions. Sb mass release via landfill gas is approximately 3.9 times higher than via leachate emissions. Although gas emissions are higher than expected, the vast majority (99.9%) of Sb present in landfilled MSW remains within the waste mass indefinitely. In addition to these mass release estimates, this experiment suggests that iron-amended activated carbon may offer significant metals removal from LFG, especially in the first months of new well operation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Many consumer and industrial products, industrial wastes and dewatered sludge from municipal wastewater treatment plants containing per- and polyfluoroalkyl substances (PFAS) are disposed of in landfills at the end of their usage, with PFAS in these products leached into landfill leachates. On-site leachate treatment is one possible method to reduce PFAS in leachates. Many landfills are equipped with on-site leachate treatment systems, but few full-scale facilities have been systematically evaluated for PFAS concentration changes. The objective of this study was to evaluate a cross-section of full-scale on-site landfill treatment systems to measure changes in PFAS concentrations. Leachate samples were collected before and after treatment from 15 facilities and were evaluated for 26 PFAS, including 11 perfluoroalkyl carboxylic acids (PFCAs), 7 perfluoroalkyl sulfonic acids (PFSAs), and 8 perfluoroalkyl acid precursors (PFAA-precursors). Transformation of precursors was evaluated by the total oxidizable precursor (TOP) assay. Results showed no obvious reductions in total measured PFAS (∑ 26 PFAS) for on-site treatment systems including ponds, aeration tanks, powdered activated carbon (PAC), and sand filtration. Among evaluated on-site treatment systems, only systems fitted with reverse osmosis (RO) showed significant reductions (98-99 %) of ∑ 26 PFAS in the permeate. Results from the TOP assay showed that untargeted PFAA-precursors converted into targeted short-chain PFCAs increasing ∑ 26 PFAS in oxidized samples by 30 %, on average. Overall, results of this study confirm the efficacy of RO systems and suggest the presence of additional precursors beyond those measured in this study., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Per- and polyfluoroalkyl substances (PFAS) have been found at relatively elevated concentrations in landfill leachates. Some landfill facilities treat physical-chemical parameters of their leachates using on-site leachate treatment systems before discharge. The objective of this study was to evaluate whether changes in physical-chemical parameters of leachate at on-site treatment systems (including bulk measurements, oxygen demanding components, and metals) were associated with concentration changes in PFAS. Leachates were evaluated at 15 on-site treatment facilities which included pond systems, aeration tanks, powdered activated carbon (PAC), sand filtration, reverse osmosis (RO) and combination treatment processes. Results show that most physical-chemical parameters and PFAS were significantly reduced in RO systems (over 90 %). For pond systems, statistically significant correlations (r s  > 0.6, p < 0.05) were observed between ∑ 26 PFAS changes and the changes in pH, alkalinity, ammonia, and some metals. Significant correlations were also found between ∑ 8 PFAAs precursors changes and specific conductivity (SPC), pH, alkalinity, ammonia, and metals changes. For aeration tank systems, significant correlations (r s  > 0.6, p < 0.05) were observed between ∑ 26 PFAS changes and changes in total dissolved solids and zinc, and between the changes of ∑ 8 PFAAs precursors and field pH. These correlations are believed to be associated with rainfall dilution and precipitation of calcium carbonate and other metals as leachate is introduced to the atmosphere., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

One hundred and seventeen street sweeping samples were collected and analyzed for per- and polyfluoroalkyl substances (PFAS). Fifty-six samples were collected in one city (Gainesville, Florida) allowing for an in-depth city-wide characterization. Street sweepings from five other urban areas, (Orlando, n = 15; Key West, n = 15; Pensacola, n = 12; Tampa, n = 13; and Daytona Beach, n = 6) were analyzed to provide a city-to-city comparison of PFAS. Within our analytical workflow, 37 PFAS were quantified across all samples, while the maximum number of PFAS quantified at one site was 26. Of those PFAS quantified in Gainesville, 60% were perfluoroalkyl acids (PFAAs) and 33% were precursors to PFAA. Among the PFAAs, short-chain perfluoroalkyl carboxylic acids (PFCAs) were the dominant class representing 26% of the total PFAS by concentration. In the comparison across different urban cities, the dominant compound by concentration and frequency of detection varied; however, perfluorooctanoic acid (PFOA) and linear perfluorooctanesulfonic acid (PFOS lin ) were the two PFAS that were detected the most frequently. This study documents the first-time detection of hexadecafluorosebacic acid and perfluoro-3,6,9-trioxaundecane-1,11-dioic acid within environmental samples.

Municipal solid waste incineration (MSWI) ash is often managed through co-disposal with unburned wastes in landfills, a practice previously reported to result in enhanced leaching of pollutants (e.g., heavy metals) in landfill leachate. The objective of this study was to evaluate the effect of co-disposed unburned wastes on per- and polyfluoroalkyl substances (PFAS) in MSWI ash landfill leachate. Leachate was collected from four landfills containing MSWI ash, either as a sole waste stream or co-disposed of with sewage sludge and MSW screenings. Samples of ash and unburned materials were collected and assessed separately for leachable PFAS in the laboratory. All samples were analyzed for 26 PFAS. Results showed that greater ash content was associated with lower leachate PFAS concentrations. The pure ash monofill exhibited the lowest PFAS in landfill leachate (290 ng L -1 ) while the landfill contained a large amount of unburned waste had the highest PFAS (11,000 ng L -1 ). For laboratory leaching tests, average ∑ 26 PFAS concentration in lab ash leachate (310 ng L -1 ) was 10 and 24 times lower than observed in lab sewage sludge leachate (3,200 ng L -1 ) and lab MSW screenings leachate (7,500 ng L -1 ), respectively. Leachate from the ash-only landfill had ∑ 26 PFAS concentration similar to what was measured in the ash itself. On the contrary, ∑ 26 PFAS concentration in co-disposal landfill leachates were similar to those in PFAS-rich unburned waste itself, regardless of the percentages of landfilled unburned wastes. We hypothesize that leachate generated in co-disposal scenarios preferentially flows through PFAS-rich unburned materials and that biotransformation of precursors enhanced by unburned waste degradation further contributes to higher concentrations of terminal PFAS in ash co-disposal sites. Landfill operators should expect PFAS in leachates to be higher when PFAS-rich unburned wastes are disposed of alongside MSWI ash, even if the unburned fraction is small., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

From a GHG perspective, most LCA studies find incineration (MSWI) to be preferred over landfilling because of high energy recovery offsets. In some studies, however, landfilling results in less greenhouse gases (GHG) emissions than MSWI. We investigated using LCA, the landfill gas (LFG) collection efficiencies and waste composition that led to landfills resulting in less GHG emissions. Then, we explored what theoretical minimum lifetime gas collection efficiencies can be expected when following US LFG regulations. Only landfills with high LFG collection efficiencies (at least 81%) and recovery of methane for energy resulted in less GHG emissions compared to the management of the same waste stream in MSWI; required efficiency increased to 93% without LFG energy recovery. Expected theoretical lifetime LFG collection efficiencies were modeled in the range of 30-80%, with the lower rates associated with landfills having smaller input masses, high decay rates, and low concentrations of nonmethane organic compounds (C NMOC) . Our modeling found that only under a limited combination of conditions (e.g., high C NMOC , high waste input rate, low decay rate) could a landfill expect to achieve a LFG collection efficiency as high as 80%, and that this value falls just under the 81-93% collection efficiency threshold needed for a landfill to result in less GHG emissions than MSWI. When exploring the influence of higher oxidation rates, changing decay rates, varying electricity grids, and inclusion of nonferrous metals recovery offsets the collection effciency range needed increased in nearly all cases; the electricity grid and nonferrous metals offsets had the greatest influence., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

A common perception of plasma arc treatment systems for municipal solid waste incineration ash is that the resulting vitrified slag is inert from an environmental perspective. Research was conducted to examine this hypothesis and to assess whether reduced pollutant release results from pollutant depletion during the process of the ash with plasma, or encapsulation in the glassy vitrified matrix. The concentrations of four discrete municipal solid waste incineration ash samples before and after plasma arc vitrification in a bench-scale unit were compared. Slag and untreated ash samples were leached using several standardized approaches and mobility among the four metals of interest (e.g. As, Cd, Pb and Sb) varied across samples, but was generally high (as high as 100% for Cd). Comparison across methods did not indicate substantial encapsulation in the vitrified slag, which suggests that reduced pollutant release from plasma arc vitrified slag is due to pollutant depletion by volatilization, not encapsulation. This has significant implications for the management of air pollution control residues from waste-to-energy facilities using plasma arc vitrification.

Recently, local governments experienced unprecedented challenges to their recycling programs and are looking to alternative forms to meet their sustainability goals. Traditionally, waste management policies focus on using a mass-based recycling rate to promote and measure sustainability, however that metric inadvertently promotes recycling over source reduction. Here, we present a metric which measures a community's greenhouse gas (GHG) and energy use footprints for their consumed and end-of-life material streams. Using materials and waste statistics for Florida as an example, we estimated the consumed and discarded masses of 24 materials in 2018. We developed methods and used existing (i.e., WARM, literature) lifecycle assessment data to measure upstream and end-of-life environmental footprints of these materials. The total upstream footprints were approximately 12 and 10 times larger than the end-of-life GHG emissions and energy use footprints, respectively, indicating the need for sustainable materials management application. Mixed paper, cardboard, mixed construction and demolition (C&D) materials had the largest lifecycle footprints. We then use these data to illustrate a method for local governments to apply the alternative metric referred to as the lifecycle footprint reduction target. We demonstrate this target's application in Florida using a hypothetical 20% footprint reduction and provide approaches which focus on increasing the source reduction and recycling potentials of key materials to meet the target. The approaches included a junk mail ban, food donation mandate, cardboard takeback mandate, and building deconstruction mandate and were evaluated for their feasibility in meeting the target; the building deconstruction and the food donation mandate resulted in the greatest and least progress, respectively, toward meeting the target. These approaches provide local government a baseline for continued progress toward SMM application. Implications : Consumer consumption of manufactured products - the packaging for our food and beverages, the products in our homes and offices, the vehicles we drive, and the buildings we live and work in - ultimately must be discarded at the end of their useful life. It is through the management of residential and commercial solid waste that local governments face the consequences of society's materials consumption. Thus, not surprisingly, materials conservation efforts at the government level focus primarily on efforts to recycle waste and divert these materials from landfill disposal. Here we examine a concept whereby local governments - normally charged with collecting and managing residential and commercial waste, and thus setting waste recycling targets - expand their thinking to include all life cycle phases for the materials consumed and discarded in their jurisdiction. In doing so, local governments can now shift from a waste management to a lifecycle-oriented perspective and expand beyond just managing waste to managing materials.

Specific aspects of previously reported extraction workflows, for measurement of per- and polyfluoroalkyl substances (PFAS) in solid matrices, have not been adequately interrogated. The objective of this study was to explore the importance of each workflow step in providing the most appropriate extraction for a comprehensive set of PFAS (51 different species) in soil. We compared different procedures, including two pre-extraction set ups (overnight handling of samples prior to extraction), two extraction solvents (methanol (MeOH), and acetonitrile (ACN)), two extraction solvent volumes (10 mL and 8.5 mL), and two post-extraction cleanup strategies (ENVI-Carb and ion-pair). Of the 51 species targeted, 21 were at quantifiable levels in soil samples collected adjacent to a landfill, of which 13 PFAS were consistently detected among the different extraction workflows. Overall, results showed no significant difference in PFAS concentration between different extraction solvents and cleanup strategies. Perfluoropentanoic acid, perfluorohexanoic acid, and perfluorooctanoic acid had the highest concentrations in all extraction workflows, accounting for nearly 13%, 38%, and 17% of the total monitored PFAS (ΣPFAS), respectively. While final concentration values were similar across methods, recovery and accuracy studies showed that MeOH had the best recovery, with 88% of the isotopically labeled PFAS standards showing extraction recovery within the acceptable range of 80% to 120% (compared to 14% of isotopically labeled PFAS standards in workflows using ACN). Upon examination of additional cleanup steps, 67% of monitored PFAS (out of 51 total PFAS monitored), on average, exhibited higher accuracy (relative error ≤20%) using ENVI-Carb clean up (in comparison with 51% in workflows using ion pair clean up). Results also demonstrated that larger volumes of MeOH (and subsequent re-extractions) did not yield a better recovery, enabling a reduction in overall analysis time and cost in comparison to many published methods., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

A critical examination of the US Environmental Protection Agency's (US EPA's) Greenhouse Gas Reporting Program (GHGRP) database provided an opportunity for the largest evaluation to date of landfilled waste decomposition kinetics with respect to different US climate regimes. In this paper, 5-8 years of annual methane collection data from 114 closed landfills located in 29 states were used to estimate site-specific waste decay rates (k) and methane collection potentials (Lc). These sites account for approximately 9% of all landfills required to report GHG emissions to the US EPA annually. The mean methane collection potential (Lc) for the sites located in regions with less than 635 mm (25 in) annual rainfall was significantly (p<0.002) lower than the mean methane collection potential of the sites located in regions with more than 635 mm (25 in) annual precipitation (49 and 73 m3 methane Mg-1 waste, respectively). This finding suggests that a fraction of the in-place biodegradable waste may not be decomposing, potentially due to a lack of adequate moisture content of landfills located in arid regions. The results of this evaluation offer insight that challenges assumptions of the traditional landfill methane estimation approach, especially in arid climates, that all methane corresponding to the total methane generation potential of the buried solid waste will be produced. Decay rates showed a significant correlation with annual precipitation, with an average k of 0.043 year-1 for arid regions (< 508 mm (20 in) year-1), 0.074 year-1 for regions with 508-1,016 mm (20-40 in) annual precipitation, and 0.09 year-1 in wet regions (> 1,016 mm (40 in) year-1). The data suggest that waste is decaying faster than the model default values, which in turn suggests that a larger fraction of methane is produced during a landfill's operating life (relative to post-closure)., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. The employment of Pradeep Jain and James Wally with Innovative Waste Consulting Services LLC does not alter our adherence to PLOS ONE policies on sharing data and materials.

Municipal solid waste contain diverse and significant amounts of per- and polyfluoroalkyl substances (PFAS), and these compounds may transform throughout the "landfilling" process from transport through landfill degradation. Fresh vehicle leachates, from commercial and residential waste collection vehicles at a transfer station, were measured for 51 PFAS. Results were compared to PFAS levels obtained from aged landfill leachate at the disposal facility. The landfill leachate was dominated by perfluoroalkyl acids (PFAAs, including perfluoroalkyl carboxylic acids (PFCAs) and perfluoroalkyl sulfonic acids (PFSAs); 86% of the total PFAS, by median mass concentration), while the majority of PFAS present in commercial and residential waste vehicle leachate were PFAA-precursors (70% and 56% of the total PFAS, by median mass concentration, respectively), suggesting precursor transformation to PFAAs during the course of landfill disposal. In addition, several PFAS, which are not routinely monitored-perfluoropropane sulfonic acid (PFPrS), 8-chloro-perfluoro-1-octane sulfonic acid (8Cl-PFOS), chlorinated polyfluoroether sulfonic acids (6:2, 8:2 Cl-PFESAs), sodium dodecafluoro-3H-4,8-dioxanonanoate (NaDONA), and perfluoro-4-ethylcyclohexanesulfonate (PFECHS)-were detected. Potential degradation pathways were proposed based on published studies: transformation of polyfluoroalkyl phosphate diester (diPAPs) and fluorotelomer sulfonic acids (FTS) to form PFCAs via formation of intermediate products such as fluorotelomer carboxylic acids (FTCAs)., Competing Interests: The authors declare no competing financial interest.

Trace metals concentrations of 25 elements were determined for 22 subcomponents of biodegradable and non-biodegradable waste samples representing the United States municipal solid waste (MSW) stream collected during three separate waste sorts. The subcomponent trace metal concentrations and estimated composition results were used to predict trace metal concentrations present in the overall MSW stream along with MSW compost and waste to energy (WTE) ash, which were compared to health-based standards (i.e., US EPA regional screening levels) and to values previously reported in the literature. These estimates for potentially problematic elements like As and Sb could be attributed to abundant base materials in MSW, while other elements, such as Pb, were calculated at much lower concentrations than other published studies. This suggests that trace metals measured in actual MSW compost and WTE ash could originate not only from MSW base components but also from other sources, such as highly concentrated low-mass wastes (e.g., e-waste). While the removal of small quantity components with high metal concentrations may reduce concentrations of some potentially problematic metals (e.g., Pb), others (e.g., As and Sb) are likely to persist in quantities that impede reuse and recycling since they are present in the more abundant base MSW components (e.g., papers, plastics, organics). Promoting meaningful reductions in potentially problematic trace metals in MSW-derived materials may require reevaluating their presence in higher-volume, lower-concentrated MSW components such as paper, plastics, and organics., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Large volumes of per- and polyfluoroalkyl substances (PFAS)-contaminated wastewaters, such as municipal solid waste landfill leachates, pose a challenge for PFAS treatment technologies in practice today. In this study, the surfactant properties of PFAS were exploited to concentrate the compounds in foam produced via the bubble aeration of landfill leachate. The effectiveness of the foaming technique for concentrating PFAS varied by compound, with a mean removal percentage (the percent difference between PFAS in leachate before and after foam removal) of 69% and a median removal percentage of 92% among the 10 replicate foaming experiments. This technique appears to be similarly effective at sequestering sulfonates and carboxylate PFAS compounds and is less effective at concentrating the smallest and largest PFAS molecules. The results of this study suggest that for the pretreatment or preconcentration of landfill leachates, foaming to sequester PFAS may provide a practical approach that could be strategically coupled to high-energy PFAS-destructive treatment technologies. The process described herein is simple and could feasibly be applied at a relatively low cost at most landfills, where leachate aeration is already commonplace.

Thousands of per- and polyfluoroalkyl substances (PFAS) exist in the environment and pose a potential health hazard. Suspect and nontarget screening with liquid chromatography (LC)-high-resolution tandem mass spectrometry (HRMS/MS) can be used for comprehensive characterization of PFAS. To date, no automated open source PFAS data analysis software exists to mine these extensive data sets. We introduce FluoroMatch, which automates file conversion, chromatographic peak picking, blank feature filtering, PFAS annotation based on precursor and fragment masses, and annotation ranking. The software library currently contains ∼7 000 PFAS fragmentation patterns based on rules derived from standards and literature, and the software automates a process for users to add additional compounds. The use of intelligent data-acquisition methods (iterative exclusion) nearly doubled the number of annotations. The software application is demonstrated by characterizing PFAS in landfill leachate as well as in leachate foam generated to concentrate the compounds for remediation purposes. FluoroMatch had wide coverage, returning 27 PFAS annotations for landfill leachate samples, explaining 71% of the all-ion fragmentation (CF 2 ) n related fragments. By improving the throughput and coverage of PFAS annotation, FluoroMatch will accelerate the discovery of PFAS posing significant human risk.

This work examines polycyclic aromatic hydrocarbon (PAH) concentrations in yard trash at various stages of the yard trash management cycle of collection, stockpiling, grinding and screening into mulch, and composting. Total extractable PAH concentrations were measured in yard trash at various management stages from 10 locations in Florida. The concentrations of 16 PAH compounds in processed yard trash ranged from 0.38 to 14 mg kg -1 . PAH concentrations were detected in vegetative material harvested from a residential neighborhood, but were below the United States Environmental Protection Agency residential regional screening levels (RSLs). PAH concentrations near or above the RSLs were common in both unprocessed and processed yard trash collected at waste management facilities. PAH concentrations were amongst the highest in newly ground yard trash samples and were amongst the lowest in composted yard trash samples. These findings are important because land application of some waste materials, such as construction and demolition debris fines and street sweepings, are sometimes limited due to PAH. If processed yard trash, which is commonly land applied in residential settings, possesses similar PAH concentrations, evaluation of current risk assessment practices for land-applied wastes may require further examination.

Ash products from coal and municipal solid waste combustion constitute a waste stream with characteristics that, unless recycled, require specific disposal practices. Although traditional disposal involves ash placement in a cell dedicated solely for the ash (monofill), new regulations for the management of coal combustion residues in the US might lead to more co-disposal of these residues with unburned municipal solid waste (MSW) that has not been combusted or otherwise processed. Both monofill and co-disposal practices are currently utilized for MSW incineration ash in the US. Column tests were performed using landfill leachate as a leaching solution to simulate co-disposal conditions of ash with MSW, while DI water was used to simulate monofilling. Mobility of As, B and V from coal fly ash was enhanced in the presence of landfill leachate in both batch and column tests, and a similar trend was observed for Cd and Mo release from MSW incineration ash. For several elements, release was greater with the column procedure relative to the batch procedure. The results suggest that long-term implications of co-disposal should be factored into decisions regarding which disposal scenario to pursue., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020. Published by Elsevier Ltd.)

Understanding the densities of individual waste materials in landfills as a function of landfill overburden pressure can provide a means to estimate the space occupied by these materials when they are landfilled. A compression device was used to simulate the overburden pressures in a landfill to determine the densities associated with 14 material categories. The materials with the greatest density were food waste, yard waste, and glass, ranging from 1302 to 1865 kg m -3 . The lowest density was associated with aluminum and steel/tin cans at 206 and 389 kg m -3 , respectively. Some materials did not exhibit a large variation in density when the load increased, indicating that their density was mostly independent of the overburden pressure. The data gathered from this research can be used as lifecycle assessment impact categories, where the functional unit of interest is 1 tonne of a material and the impact is measured as m 3 of landfill space occupied.

Despite evidence that racial and ethnic characteristics influence the impact of traumatic exposure on psychological health, little is known about how race and ethnic identity can alter, and possibly protect against, the effects of trauma on the psychiatric diagnoses of women. Therefore, the present study examined the moderating role of race/ethnicity and ethnic identity in the link between trauma exposure and psychiatric diagnosis for African American and Caucasian college women. Participants were a sample of 242 women from the Mid-Atlantic region of the United States who self-identified as African American or Black (31%) and European American or Caucasian (69%; M age = 19.5 years). Interviews were conducted over the phone to screen for trauma, followed by longer in-person interviews. Each of the interviewers was supervised, and interviews were reviewed to control for quality. Regression analyses revealed that the number of traumatic events was a stronger predictor of lifetime psychiatric diagnoses for Caucasian women. In addition, ethnic identity served as a protective factor against trauma exposure among participants. The findings suggest that ethnic identity is a relevant buffer against potential psychiatric diagnoses as result of exposure to traumatic events for both Caucasian and African American women.

Elevated boron concentrations above the regulatory standard were inadvertently discovered in downgradient groundwater monitoring wells at 22 construction and demolition (C&D) debris landfills in Florida, US. This created a unique opportunity to evaluate whether C&D debris can be considered a plausible source of boron at unlined landfills. Approximately 1200 historical landfill-leachate and groundwater records were surveyed from semi-annual and annual monitoring reports covering a 9-year period. Laboratory leaching experiments were conducted on soils from each of these sites to determine if the source could have been boron mobilized from naturally occurring soils. Historical leachate quality data from lined landfills near four of the unlined C&D debris landfills were examined to determine if leachate from the unlined landfills could be the boron source. The US Environmental Protection Agency (EPA) Method 1312, or Synthetic Precipitation Leaching Procedure (SPLP), and the EPA Method 1316 were performed on materials commonly found in C&D debris to see if these products have the potential to leach appreciable levels of boron. The results of this work indicate leachate from unlined C&D debris landfills as the most plausible source of elevated boron concentrations in downgradient monitoring wells., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

In the US, the toxicity characteristic leaching procedure (TCLP) determines if a waste is toxicity characteristic (TC) hazardous based on leached concentrations of specific chemicals. The TC limits were originally derived from drinking water standards (DWS) adjusted by a dilution attenuation factor of 100. The TC limits have not been updated along with DWS revisions. This research examines potential implications of updating the TC limits to account for new DWS thresholds and elements, as well as tap-water risk thresholds; this allows a further expanded evaluation of elements that might be regulated as drinking water standards in the future. Fossil fuel combustion residues, batteries, electronic wastes, municipal solid waste incineration (MSWI) ashes, and treated wood were examined with TCLP and the leached metal concentrations were compared to revised TC thresholds. The two wastes most affected by updated TC limits would be batteries and MSWI ashes. Thallium and antimony, which were not included on the original TC list, exceeded the TC thresholds for batteries and MSWI ash, respectively. Copper, a chemical used in current preserved wood formulations, did not cause currently marketed treated wood to be hazardous waste, but arsenic did for older wood products., (Copyright © 2019 Elsevier B.V. All rights reserved.)