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We present the set-up and performances of the TOP-IMPLART accelerator as a proton source for radiation testing of space components. The TOP-IMPLART proton accelerator is a pulsed fully linear machine aimed at active intensity modulated proton therapy with a final energy of 150 MeV under development at ENEA Frascati Research Centre. Presently the machine offers a beam extraction point on the horizontal line at 35 MeV, with a current up to 50 µA in a 3 µs long pulse and maximum repetition frequency of 50 Hz. An in-air irradiation set-up 1.8 m downstream the accelerator exit window is available with an effective beam energy of about 30 MeV, ±5% transverse homogeneity on a 40 mm diameter beam spot, and intensity repeatability within ±5%. While the proton beams main characteristics (energy, intensity, average fluence) are the same of conventional cyclotron-based cancer treatment facilities, already used for space components qualification, its time structure is significantly different, with high instantaneous dose rate. This research aims at demonstrating the possibility to use an accelerator with these characteristics for radiation hardness assurance testing. A commercial 6-axis integrated MEMS inertial navigation system (accelerometer, gyroscope) was selected as device under test. These devices could be used for example as sensors for attitude determination in University Cubesat missions. Irradiation with proton beams allows simultaneous exploration of total dose, displacement damage and some single-event effect of such components. The results of experimental tests aimed to define an operational procedure are reported: the irradiation set-up is described in detail and the characterization of radiation effect on the component is reported highlighting the consequence of the device performance degradation in terms of the overall navigation system accuracy. These results are considered a first step towards the use of the TOP-IMPLART linear accelerator as a meaningful alternative to traditional cyclotron for proper space qualification of electronic components.

Irradiation of lithium fluoride with protons causes the formation of electronic defects, known as colour centres, in the crystal lattice. Two stable defects among them, the F2 and F3+ aggregate ones, under blue light simultaneous excitation show broad photoluminescence in the red and green visible spectral ranges, respectively, their peculiar characteristics being well known for applications in optically-pumped tuneable lasers, broad-band miniaturized light-emitting photonic devices and passive radiation imaging detectors. Recently, exploitation of their radiophotoluminescence has been successfully proposed for proton-beam advanced diagnostics and dosimetry, even at low dose values typical of radiotherapy. In the present study, lithium fluoride crystals were irradiated with 2.3 MeV protons in the dose range from ∼104 to ∼107 Gy and their dynamic range, that is the capability of detecting the widest possible range of radiophotoluminescence intensity emitted by the colour centres, was found to be 114 dB at the F2 peak emission wavelength of 675 nm under continuous-wave laser excitation at 445 nm. Moreover, after including in the analysis a set of lithium fluoride crystals irradiated with 26.1 MeV protons in the dose range from 0.5 to 48 Gy at a much lower dose-rate, it was found that the radiophotoluminescence intensity of the F2 colour centres shows a linear dependence with dose from 0.5 to ∼2 × 105 Gy.

Solid-state radiation detectors based on the visible photoluminescence of radiation-induced F2 and F3+ color centers in lithium fluoride crystals have been used for advanced diagnostics of 18 and 27 MeV proton beams, produced by the TOP-IMPLART linear accelerator, which is under development for protontherapy applications at ENEA C.R. Frascati, Italy. Visible fluorescence microscopy was successfully used to read the latent proton beam images stored in the lithium fluoride crystals, thanks to high emission efficiency of the F2 and F3+ color centers obtained by simultaneous optical excitation in the blue spectral range. High intrinsic spatial resolution and wide dynamic range of these novel LiF detectors allow obtaining two-dimensional images of both the beam transverse intensity distribution and of the Bragg curve. By using a simple defect formation model that takes into account the energy released in the material and the saturation of defect concentration, not only the two-dimensional dose map was obtained from the beam transverse intensity distribution image, but also the full Bragg curve was reconstructed, allowing the thorough characterization of proton beams produced by the accelerator.

We present the first results of a novel collaboration activity between ENEA Frascati Particle Accelerator Laboratory and University La Sapienza Guidance and Navigation Laboratory in the field of Radiation Hardness Assurance (RHA) for space applications. The aim of this research is twofold: (a) demonstrating the possibility to use the TOP-IMPLART proton accelerator for radiation hardness assurance testing, developing ad hoc dosimetric and operational procedures for RHA irradiations; (b) investigating system level radiation testing strategies for Commercial Off The Shelf (COTS) components of interest for SmallSats space missions, with focus on devices and sensors of interest for guidance, navigation and control, through simultaneous exploration of Total Ionizing Dose (TID), Displacement Damage (DD) dose and Single-Event Effects (SEE) with proton beams. A commercial 6-axis integrated Micro Electro-Mechanical Systems (MEMS) inertial navigation system (accelerometer, gyroscope) was selected as first Device Under Test (DUT). The results of experimental tests aimed to define an operational procedure and the characterization of radiation effects on the component are reported, highlighting the consequence of the device performance degradation in terms of the overall navigation system accuracy. Doses up to 50 krad(Si) were probed and cross sections for Single-Event Functional Interrupt (SEFI) evaluated at a proton energy of 30 MeV.

Passive solid-state radiation detectors, based on the radiophotoluminescence of stable color centers in nominally pure lithium fluoride (LiF) crystals, have been used for advanced diagnostics of the segment up to 35 MeV of the TOP-IMPLART proton linear accelerator for protontherapy applications, under development at ENEA Frascati. In LiF, proton beams generate a spatial distribution of F2 and F3+ aggregate color centers, which efficiently emit radiophotoluminescence in the red-green spectral range under optical pumping around 450 nm. LiF crystals were irradiated with 35 MeV nominal energy protons at several doses of interest for protontherapy (from 0.5 to 50 Gy). For the first time is shown here the possibility of measuring the radiophotoluminescence spectra of proton irradiated LiF even at such low doses and how the signal showed a linear behavior with dose with a good signal-to-noise ratio. A Bragg-curve image, stored as color-center distribution in a LiF crystal after a 50 Gy-dose irradiation in a particular geometry, was acquired in a conventional fluorescence microscope. After appropriate image processing, the signal intensity resulted to be proportional to the linear energy transfer along the whole Bragg curve. By best-fitting it with an ad-hoc analytical formula, the depth-dose distribution was reconstructed and the proton beam energy and energy spread were estimated.

The thermal behavior and pyrolytic kinetic analysis of main waste polymers (polypropylene (PP), polyethylene film (PE), poly(ethylene terephthalate) (PET), polystyrene (PS)) and three synthetic mixtures representing commingled postconsumer plastics wastes (CPCPWs) output from material recovery facilities were studied. Thermogravimetry (TG) pyrolysis experiments revealed that the thermal degradation of single polymers and the synthetic mixture enriched in PP occurred in one single step. The other two mixtures underwent a two-consecutive, partially overlapping degradation steps, whose peaks related to the first-order derivative of TG were deconvoluted into two distinct processes. Further TG experiments carried out on binary mixtures (PS/PP, PET/PP, PET/PEfilm and PP/PEfilm) showed a thermal degradation reliance on composition, structure and temperatures of single polymer components. A kinetic analysis was made for each step using the Kissinger-Akahira-Sunose (KAS) method, thus determining almost constant activation energy (Ea) for pyrolysis of PS, PET, PP and PE film in the range 0.25

The first proton linear accelerator for tumor therapy based on an actively scanned beam up to the energy of 150 MeV, is under development and construction by ENEA-Frascati, ISS and IFO, under the Italian TOP-IMPLART project. Protons up to the energy of 7 MeV are generated by a customized commercial injector operating at 425 MHz; currently three accelerating modules allow proton delivery with energy up to 27 MeV. Beam homogeneity and reproducibility were studied using a 2D ionizing chamber, EBT3 films, a silicon diode, MOSFETs, LiF crystals and alanine dosimetry systems. Measurements were taken in air with the detectors at ~1 m from the beam line exit window. The maximum energy impinging on the detectors surface was 24.1 MeV, an energy suitable for radiobiological studies. Results showed beam reproducibility within 5% and homogeneity within 4%, on a circular surface of 16mm in diameter. © The Author(s) 2018.

Solid-state radiation detectors based on the photoluminescence of stable point defects in lithium fluoride crystals have been used for advanced diagnostics during the commissioning of the segment up to 27 MeV of the TOP-IMPLART proton linear accelerator for proton therapy applications, under development at ENEA C.R. Frascati, Italy. The LiF detectors high intrinsic spatial resolution and wide dynamic range allow obtaining two-dimensional images of the beam transverse intensity distribution and also identifying the Bragg peak position with micrometric precision by using a conventional optical fluorescence microscope. Results of the proton beam characterization, among which, the estimation of beam energy components and dynamics, are reported and discussed for different operating conditions of the accelerator. © 2017 Elsevier B.V.

Seven waste thermoplastic polymers (polypropylene, polyethylene film, polyethylene terephthalate, polystyrene, acrylonitrile-butadiene-styrene, high-impact polystyrene and polybutadiene terephthalate, denoted as PP, PE (film), PET, PS, ABS, HIPS and PBT, respectively) and four synthetic mixtures thereof with different compositions representing commingled postconsumer plastic waste and waste of electrical and electronic equipment were studied by means of simultaneous thermogravimetry/differential scanning calorimetry coupled with Fourier transform infrared spectroscopy (TG/DSC-FTIR) under pyrolytic conditions (inert atmosphere). By summing all the heat change contributions due to physical and/or chemical processes occurring (i.e., melting, decomposition), an overall energy, defined as the degradation heat, was determined for both single component and their mixtures. It was found to be about 4-5 % of the exploitable energy of the input material. Vapors evolved during the pyrolysis of single-component polymers and their mixtures, analyzed using the FTIR apparatus, allowed identifying the main reaction products as monomers or fragments of the polymeric chain. Results from TG/DSC runs and FTIR analysis show that there is no interaction among the plastic components of the mixtures during the occurrence of pyrolysis. © 2015 Akadémiai Kiadó, Budapest, Hungary.

The increasing diffusion of Hi-tech complex products has raised the attention of scientific community towards their End of Life (EoL) treatment, both in terms of assuring an appropriate disposal, to avoid the dispersion of harmful substances, and at the aim of their exploitation as valuable sources of raw materials. Within this study an integrated approach for waste electrical and electronic equipment (WEEE) end of life treatment is proposed based on the integration of hydrometallurgy for metal recovery and pyrolysis for plastic fraction valorization, with a particular focus on EoL personal computers. An innovative hydrometallurgical process with limited environmental impact for the recycling of added value metals (Au, Ag, Cu, Sn, Pb) from printed circuit boards was developed and thermal technologies were investigated for the valorization of mixed plastic components. The results show metal recovery rates up to 99% and purity grade up to 99%. With reference to plastic valorization, the maximized production up to 95% w/w of both a liquid and gaseous hydrocarbon-based stream to be exploited as a fuel or as source of chemicals was achieved from WEEE plastic fractions. © 2015, Gh. Asachi Technical University of Iasi. All rights reserved.