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This paper presents the results of morphological and microclimatic surveys and speleothem analyses of ten karst caves located in different isles in Ha Long Bay, a famous tourist attraction in Vietnam. Characteristically, the caves have enormous entrances, roomy interiors, but short length, typical of karst caves in tropical climates. The cave microclimate was found to be significantly dependent on the outside atmosphere and human activities. There was a clear spatial variation in macro features and fabrics of speleothems from entrance (porous, microcrystalline) to rear (solid, macrocrystalline) of the caves. Microstructure analysis with the use of an environmental scanning electron microscope shows a gradual decrease of biological activity and microclimate instability from outside to the innermost parts of the caves are the causes for this spatial variation. Past and present deterioration of caves and speleothems directly due to tourist activities and vandalism has been observed. On the other hand, there are signs of speleothem regrowth in the caves where tourism has been stopped. This study has proved that caves and their speleothems in Ha Long Bay are highly dynamic and understanding of their environment requires immediate methodological attention. Based on the analytical results, it is recommended that regulation of visitor frequency and removal of lamp-flora are necessary for sustainable development of the show caves and their speleothems.

For the first time, the dual isotope approach was applied to trace the sources of impacts and to identify the governing biogeochemical processes in a river network in the tropical deltaic region of the Red River (Vietnam). Our long term surveys concluded that water in this river network was severely impacted by anthropogenic activities. Analysis has shown strong spatio-temporal variation of nitrate isotopes; ranges of δ15N– and δ18O– were from −5 to 15 ‰ and from −10 to 10 ‰, respectively. Average values of δ15N– and δ18O– in the dry season, when fertilizer is applied, were 3.54 and 3.15 ‰, respectively. In the rainy season, the values changed to 6.41 and −2.23 ‰, respectively. Denitrification and biological assimilation were active throughout the year, but were especially enhanced during fertilization time. Mineralization of domestic organic matter and consequent nitrification of mineralized were the dominant processes, particularly during the rainy period.

For the first time, the dual isotope approach was applied to trace the sources of impacts and to identify the governing biogeochemical processes in a river network in the tropical deltaic region of the Red River (Vietnam). Our long term surveys concluded that water in this river network was severely impacted by anthropogenic activities. Analysis has shown strong spatio-temporal variation of nitrate isotopes; ranges of δ15N– and δ18O– were from −5 to 15 ‰ and from −10 to 10 ‰, respectively. Average values of δ15N– and δ18O– in the dry season, when fertilizer is applied, were 3.54 and 3.15 ‰, respectively. In the rainy season, the values changed to 6.41 and −2.23 ‰, respectively. Denitrification and biological assimilation were active throughout the year, but were especially enhanced during fertilization time. Mineralization of domestic organic matter and consequent nitrification of mineralized were the dominant processes, particularly during the rainy period.

International audience; The export of dissolved organic carbon (DOC) from agricultural soils can represent an important pathway of soil organic carbon loss. However, despite its importance in terrestrial and downstream aquatic ecosystems, most work has focused on temperate agrosystems with tropical and sub-tropical ecosystems being ignored. Here we present the results of a series of rain simulation experiments aimed at examining DOC export from sloping lands in North Vietnam. Three regularly used agricultural practices were tested and compared with Bare soils. We also compared the impact of leaf litter in two planted forest sites. We found high rates of DOC export (0.03-0.25 g C m(-2)) during a 40 min rain episode with the lowest rates observed in the Bare soils and the highest in the planted Forest without leaf litter. This is equivalent to a loss of between 0.001 and 0.008% of the total soil organic carbon in the upper 10 cm during a single, intense rain event. This work highlights the impact of different agricultural practices (Bare soil, hoeing, mulching and fallow) and land use (planted Forest with or without leaf litter) on the export of DOC from upland, tropical soils and further underlines the importance of studying DOC fluxes from agricultural land as it represents an important and highly mobile component of ecosystem carbon fluxes.

A research program was established to identify the governing factors for the partition coefficient (K(D)) of heavy metals between suspended particulate and dissolved phases in the Day River system a tropical, highly alluvial aquatic system, in Vietnam. The targeted river system, draining an urbanized-industrialized catchment where discharged wastewater is mostly untreated, could be separated into the least impacted, pristine area, and the most impacted, polluted area. Organic matter degradation was shown to govern the variation of parameters like total organic carbon, biochemical oxygen demand, chemical oxygen demand, nutrients, conductivity, or redox potential. Heavy metals in both dissolved and particulate phases were enriched in severely polluted area because of wastewater inflow that contains concentrated metals and intensification of metal influx from sediment. Results show log K(D) in the order Mn < As < Zn < Hg < Ni < Cu < Cd < Co < Pb < Cr < Fe and As < Zn < Ni < Mn < Cr < Cu < Co < Fe in the polluted zone and the pristine zone, respectively. A decreasing tendency of partition coefficients of 11 heavy metals considered from the pristine to the impacted zones was observed. Three explanations for the difference are: (1) increase of solubility of most heavy metals in low redox potential, (2) competition for the binding sites with major and minor cations, and (3) complexation with dissolved organic matter concentrated in municipal waste impacted water. Apart from domestic waste impact, statistical analysis has contributed to identify the influence of climate condition and hydrological regime to the partition of heavy metals in the area.

International audience; For the first time in Vietnam, excess carbon dioxide partial pressure (EpCO2) was used to assess the trophic state of surface waters. Among five methods evaluated, that which takes into account the effect of temperature, salinity and of dissolved organic carbon content was selected, owing to the high temperature fluctuation (about 20°C) during the year, the strong tidal influence causing backwater in the downstream region, and the concentrated organic matter (OM) (up to 34.4 mg C/l in the polluted area). These three variables altogether can lead to a 20% difference in calculated EpCO2. The high EpCO2 values clearly indicated a deterioration of water quality at least as far as 60 km downstream from Hanoi, due largely to the impact of domestic wastewater from the city.

This study focused on the prediction of a 22 km meandering channel migration of the Sabine River between the states of Texas and Louisiana. The meander characteristics of 12 bends, identified from seven orthophotos taken between 1974 and 2004, were acquired in a GIS environment. Based on that earlier years' data acquisition, channel prediction was performed for the two years 1996 and 2004 using least squares estimation and linear extrapolations, yielding a satisfactory agreement with the observations (the median predicted and observed migration rates were 3.1 and 3.6 [m/year], respectively). The best-predicted migration rate was found to be associated with the longest orthophoto-recorded interval. The study confirmed that channel migration is strongly correlated with bend curvature and that the maximum migration rate of the bend corresponded to a radius of curvature [bend radius (R(C))/channel width (W(C))] of 2.5. In tight bends of a smaller radius of curvature than 1.6, secondary flow scouring near the bend apex increases bend curvature. The stability index of the dimensionless bend radius was determined to be 2.45. Overall, this study proves the effectiveness of least squares estimation with historical orthophotography for characterization of meandering channel migration.

International audience; Analyses of water quality and flow regime in combination with laboratory studies and ecological modelling were used to assess the water quality impact of pollution from to To Lich River that drains through Hanoi City and greatly contaminates the Nhue River. With an average discharge of 26.2 m3/s, the Nhue River receives about 5.8 m3/s of untreated domestic water from the city?s main open-air-sewer the To Lich River. The studies during 2002 2003 showed high concentrations of BOD (70 mg O2/l), DOC (15 mg C/l), coliform (2.4e6 MNP/100 ml), total phosphorus (3.5 mg P/l), and total nitrogen (31.6 mg N/l) in the To Lich, while DO level was less than 1 mg O2/l. Such high loads of untreated wastewater impacted water quality in the Nhue River where DO decreased at times to as low as 1 mg O2/l. The accumulation of particulate organic matter and micro-organisms in the sediments of the Nhue represented substantial sources of nutrients and sinks for DO. They are also considerable production of dissolved carbon dioxide at concentrations up to two orders of magnitude higher than pressure. Such pressures (EpCO2) are expected in polluted environments, but the results presented here are new for Vietnam and much of developing countries. A number of factors linked to field monitoring and laboratory measurements clearly indicate the importance of autotrophic over heterotrophic biological processes and sediments. An ecological model for management purposes has been developed that reliably estimates of the pollutant loads. An opportunity was taken to examine the changing impacts and processes when the To Lich was diverted from the Nhue. The monitoring and modelling of this opportunity showed low dissolved oxygen levels even if the impact from the To Lich was lessened. Alternatives are proposed to alleviate problems of water quality in the Nhue. It is concluded that the treatment of the To Lich River?s water is highly recommended; otherwise a reduction to one third of current wastewater discharge is needed to bring water quality back to the environmental standard.

Tropical rivers are dynamic CO2 sources. Regional patterns in the partial pressure of CO2 (pCO2) and relationships with other a/biotic factors in densely populated and rapidly developing river delta regions of Southeast Asia are still poorly constrained. Over one year, at 21 sites across the river system in the Red River Delta (RRD), Vietnam, we calculated pCO2 levels from temperature, pH, and total alkalinity and inter-linkages between pCO2 and phytoplankton, water chemistry and seasonality were then assessed. The smaller, more urbanized, and polluted Day River had an annual median pCO2 of 5000 ± 3300 µatm and the larger Red River of 2675 ± 2271 µatm. pCO2 was 1.6 and 3.2 times higher during the dry season in the Day and Red rivers respectively than the rainy season. Elevated pCO2 levels in the Day River during the dry season were also 2.4-fold higher than the median value (2811 ± 3577 µatm) of calculated and direct pCO2 measurements in >20 sub/tropical rivers. By further categorizing the river data into Hanoi City vs. other less urban-populated provinces, we found significantly higher nutrients, organic matter content, and riverine cyanobacteria during the dry season in the Day River across Hanoi City. Forward selection also identified riverine cyanobacteria and river discharge as the main predictors explaining pCO2 variation in the RRD. After accounting for the shared effects (14%), river discharge alone significantly explained 12% of the pCO2 variation, cyanobacteria uniquely a further 21%, while 53% of the pCO2 variance was unexplained by either. We show that the urbanization of rivers deltas could result in increased sources of riverine pCO2, water pollution, and harmful cyanobacterial blooms. Such risks could be mitigated through water management to increase water flows in problem areas during the dry season.