Search

Kinetic calcium isotope effects can be used as growth-rate proxies for volcanic and subvolcanic minerals. Here, we analyze Ca isotopic compositions in experimental and natural samples and confirm that large kinetic effects (>2‰) can occur during magmatic plagioclase crystallization. Experiments confirm theoretical predictions that disequilibrium isotope effects depend mainly on the rates for crystal growth relative to liquid phase Ca diffusivity (R/D). Plagioclase phenocrysts from the 1915 Mount Lassen rhyodacite eruption, the ∼650-y-old Deadman Creek Dome eruption, and several mafic subvolcanic orbicules and plagioclase comb layers from Northern California have disequilibrium Ca isotopic compositions that suggest rapid crystal growth rates (>1 cm/y to 15 cm/y). The Ca isotope results, combined with complementary crystal-size distribution analyses, suggest that magmatic rejuvenation (and eruption) events, as reflected in crystal growth times, can be as short as ∼10-3 y. Although mafic systems are predicted to have shorter magmatic rejuvenation periods, we find similarly short timescales in both mafic and silicic systems. These results are consistent with a growing body of evidence suggesting that dominantly crystalline volcanic magma reservoirs can be rapidly reactivated by the injection of fresh magma prior to eruption. By focusing on a common mineral such as plagioclase, this approach can be applied across all major magmatic compositions, suggesting that Ca isotopes can be used as a tool for investigating the dynamics and timing of volcanic eruptions.

Crystals and bubbles nucleate and grow in a magma that experiences a range of temperatures, pressures and strain-rates. We have a good conceptual and sometimes quantitative understanding of how crystallization and bubble nucleation are controlled by decompression and cooling. Here we explore the effect of strain-rate on the crystallization kinetics of magmas. In order to understand the interaction between deformation and crystallization, samples of basalt were deformed during their crystallization. We made measurements at subliquidus conditions (1160°C) and deformed samples in compression at strain-rates varying from 0 to 2 × 10–4 s–1 for a total strain of 0.31. We simultaneously imaged the samples using X-ray micro-tomography. Without deformation, no crystallization was observed over the course of a 260 min experiment. Once deformation was applied, crystallization initiated. Deformation increased the nucleation rate, increased crystal growth rates, and decreased the incubation time. Increasing the strain-rate, however, does not show a discernable effect of crystallization kinetics. We hypothesize that deformation may have an effect on the parameters that govern the crystallization kinetics of magmas, such as activation energy and diffusion by changing chemical potentials.