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Cellulose based nanomaterials have the great potential to be applied to paper as bulk additive or coating material to improve overall final properties, especially in secondary fiber. In the present work, the effect of applying different kinds of cellulose nanofibrils (CNF) to papers obtained from recycled fibers using size press on physical, mechanical and barrier properties was investigated and compared with the sole use of starch as coating material. The coating process of CNF was carried out by the addition of size press grade starch to coating suspension. As a cellulose source, wheat straw was evaluated and CNF was obtained through oxidative and enzymatic pretreatments. Results indicate that starch/CNF suspension improves the overall paper properties. As a result of the deposition of coating suspension contains of 4 % wt. periodate-oxidized CNF onto paper surface, tensile and burst indices of papersheets increased as 52.2 % and 194.4 %. Significant decreases were observed in air permeability as 69.8 %. Compression tests also have been conducted to evaluate papersheets end-use properties. In comparison to the other pretreated CNF, due to is lower viscosity, applying periodate-oxidized CNF as size press significantly increased the mechanical properties of the papers fabricated from the recycled pulps. TUBITAK-TEYDEBTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [1505]; Scientific and Technological Research Council of Turkey, Technology and Innovation Funding Programs Directorate [1505, 5180044] This work was supported by TUBITAK-TEYDEB 1505 (The Scientific and Technological Research Council of Turkey, Technology and Innovation Funding Programs Directorate 1505), Project No. 5180044. WOS:000703585400013 2-s2.0-85108063350

This study aimed to evaluate eggshell wastes, which have the potential to turn into high value-added products in paper industry. Membrane-removed eggshell wastes were subjected to certain processes of washing, drying, grinding, and sieving. The final product of eggshell calcium carbonate (ECC) was used in office paper production as filler, and its possible effect on physical and optical properties of papers was investigated. Mixed office wastes were turned pulp using as raw material of office paper production. Moreover, the effects of ECC was compared with the use of industrial calcium carbonates of ground (GCC) and precipitated (PCC) forms as filler. Breaking lengths of the papers were shown to reduce up to 65.2, 76.6, and 64.1% by a 30% usage of GCC, PCC, and ECC fillers, respectively. PCC and GCC were more effective in improved optical properties of papers than ECC. The brightness values were measured to be 96.8, 98.4, and 93.1 ISO% with a 30% dosage of GCC, PCC, and ECC fillers, respectively. These results suggested that ECC can be used as filler in paper industry.