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The ExoMol database (www.exomol.com) provides molecular data for spectroscopic studies of hot atmospheres. These data are widely used to model atmospheres of exoplanets, cool stars and other astronomical objects, as well as a variety of terrestrial applications. The 2024 data release reports the current status of the database which contains recommended line lists for 91 molecules and 224 isotopologues giving a total of almost 10$^{12}$ individual transitions. New features of the database include extensive "MARVELization" of line lists to allow them to be used for high resolutions studies, extension of several line lists to ultraviolet wavelengths, provision of photodissociation cross sections and extended provision of broadening parameters. Some of the in-house data specifications have been rewritten in JSON and moved to conformity with other international standards. Data products, including specific heats, a database of lifetimes for plasma studies, and the ExoMolHR web app which allows exclusively high resolution data to be extracted, are discussed.

A new silicon monoxide ($^{28}$Si$^{16}$O) line list covering infrared, visible and ultraviolet regions called SiOUVenIR is presented. This line list extends the infrared EBJT ExoMol line list by including vibronic transitions to the $A\,{}^{1}\Pi$ and $E\,{}^{1}\Sigma^{+}$ electronic states. Strong perturbations to the $A\,{}^{1}\Pi$ band system are accurately modelled through the treatment of 6 dark electronic states: $C\,{}^{1}\Sigma^{-}$, $D\,{}^{1}\Delta$, $a\,{}^{3}\Sigma^{+}$, $b\,{}^{3}\Pi$, $e\,{}^{3}\Sigma^{-}$ and $d\,{}^{3}\Delta$. Along with the $X\,{}^{1}\Sigma^{+}$ ground state, these 9 electronic states were used to build a comprehensive spectroscopic model of SiO using a combination of empirical and ab initio curves, including the potential energy (PE), spin-orbit (SO), electronic angular momentum (EAM) and (transition) dipole moment curves. The ab initio PE and coupling curves, computed at the multireference configuration interaction (MRCI) level of theory, were refined by fitting their analytical representations to 2617 experimentally derived SiO energy levels determined from 97 vibronic bands belonging to the $X$-$X$, $E$-$X$ and $A$-$X$ electronic systems through the MARVEL procedure. 112 observed forbidden transitions from the $C$-$X$, $D$-$X$, $e$-$X$, and $d$-$X$ bands were assigned using our predictions, and these could be fed back into the MARVEL procedure. The SiOUVenIR line list was computed using published ab initio transition dipole moments for the $E$-$X$ and $A$-$X$ bands; the line list is suitable for temperatures up to 10,000 K and for wavelengths longer than 140 nm. SiOUVenIR is available from www.exomol.com and the CDS database.

The ExoMol database (www.exomol.com) provides molecular data for spectroscopic studies of hot atmospheres. While the data is intended for studies of exoplanets and other astronomical bodies, the dataset is widely applicable. The basic form of the database is extensive line lists; these are supplemented with partition functions, state lifetimes, cooling functions, Land\'e g-factors, temperature-dependent cross sections, opacities, pressure broadening parameters, $k$-coefficients and dipoles. This paper presents the latest release of the database which has been expanded to consider 80 molecules and 190 isotopologues totaling over 700 billion transitions. While the spectroscopic data is concentrated at infrared and visible wavelengths, ultraviolet transitions are being increasingly considered in response to requests from observers. The core of the database comes from the ExoMol project which primarily uses theoretical methods, albeit usually fine-tuned to reproduce laboratory spectra, to generate very extensive line lists for studies of hot bodies. The data has recently been supplemented by line lists deriving from direct laboratory observations, albeit usually with the use of ab initio transition intensities. A major push in the new release is towards accurate characterisation of transition frequencies for use in high resolution studies of exoplanets and other bodies.

Theoretical calculations are contributing a significantly higher proportion of data to contemporary spectroscopic databases, which have traditionally relied on experimental observations and semi-empirical models. It is now a common procedure to extend calculated line lists to include ro-vibrational transitions between all bound states of the ground electronic state up to the dissociation limit. Advanced ab initio methods are utilized to calculate the potential energy and dipole moment surfaces (PESs and DMSs), and semi-empirical PESs are then obtained by combining ab initio and experimental data. The objective is to reach high accuracy in the calculated transition intensities for all parts of spectrum, i.e. to increase the predictive power of the model. We show that in order to perform this task, one needs, in addition to the standard improvements of the PES and DMS in the spectroscopically accessible regions, to extend the ab initio calculations of the PES towards the united-atom limit along the stretching coordinates. The argument is based on the correlation between the intensities of high-overtone transitions and the repulsive potential wall that has previously been theoretically established for diatomic molecules and is empirically extended here to linear and nonlinear triatomic molecules. We generate partial line lists for water and ozone, and together with an already available line list for carbon dioxide, we derive the normal intensity distribution, which is a direct consequence of this correlation. The normal distribution is not an instrument to compute highly accurate intensities, rather it is a means to analyze the intensities computed by the traditional methods.

SiS has long been observed in the circumstellar medium of the carbon-rich star IRC+10216 CW Leo. Comprehensive and accurate rotation-vibrational line lists and partition functions are computed for 12 isotopologues of silicon sulphide ($^{28}$Si$^{32}$S, $^{28}$Si$^{34}$S, $^{29}$Si$^{32}$S, $^{28}$Si$^{33}$S, $^{30}$Si$^{32}$S, $^{29}$Si$^{34}$S, $^{30}$Si$^{34}$S, $^{28}$Si$^{36}$S, $^{29}$Si$^{33}$S, $^{29}$Si$^{36}$S, $^{30}$Si$^{33}$S, $^{30}$Si$^{36}$S) in its ground (X $^1\Sigma^+$) electronic state. The calculations employ an existing spectroscopically accurate potential energy curve (PEC) derived from experimental measurements and a newly-computed ab initio dipole moment curve (DMC). The $^{28}$Si$^{32}$S line list includes 10104 states and 91715 transitions. These line lists are available from the ExoMol website www.exomol.com and the CDS database.