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Monitoring atmospheric concentrations of greenhouse gases (GHGs) like carbon dioxide and methane in near real time and with good spatial resolution is crucial for enhancing our understanding of the sources and sinks of these gases. A novel approach can be proposed using a constellation of small satellites equipped with miniaturized spectrometers having a spectral resolution of a few nanometers. The objective of this study is to describe expected results that can be obtained with a single satellite named Uvsq-Sat NG. The SolAtmos end-to-end simulator and its three tools (IRIS, OptiSpectra, and GHGRetrieval) were developed to evaluate the performance of the spectrometer of the Uvsq-Sat NG mission, which focuses on measuring the main GHGs. The IRIS tool was implemented to provide Top-Of-Atmosphere (TOA) spectral radiances. Four scenes were analyzed (pine forest, deciduous forest, ocean, snow) combined with different aerosol types (continental, desert, maritime, urban). Simulated radiance spectra were calculated based on the wavelength ranges of the Uvsq-Sat NG, which spans from 1200 to 2000 nm. The OptiSpectra tool was used to determine optimal observational settings for the spectrometer, including Signal-to-Noise Ratio (SNR) and integration time. Data derived from IRIS and OptiSpectra served as input for our GHGRetrieval simulation tool, developed to provide greenhouse gas concentrations. The Levenberg–Marquardt algorithm was applied iteratively to fine-tune gas concentrations and model inputs, aligning observed transmittance functions with simulated ones under given environmental conditions. To estimate gas concentrations (CO2, CH4, O2, H2O) and their uncertainties, the Monte Carlo method was used. Based on this analysis, this study demonstrates that a miniaturized spectrometer onboard Uvsq-Sat NG is capable of observing different scenes by adjusting its integration time according to the wavelength. The expected precision for each measurement is of the order of a few ppm for carbon dioxide and less than 25 ppb for methane. [ABSTRACT FROM AUTHOR]

The solar spectrum at the top of the atmosphere contains crucial data for solar physics, astronomy, and geophysics. Accurately determining high-resolution solar reference spectra, whether they are disk-integrated, disk-center, or intermediate cases, represents a new challenge and is of primary importance for all applications where spectral solar radiation needs to be evaluated. These spectra are also essential for interpreting remote sensing measurements that rely on sunlight, such as those obtained by Earth observation satellites or spacecraft exploring other planets. This paper lays a foundation for the implementation of multiple new solar irradiance reference spectra that have high resolution and are representative of solar minimum conditions. We developed the SOLAR high-resolution extraterrestrial reference spectra (SOLAR-HRS disk-integrated spectra) by normalizing high-spectral-resolution solar line data to the absolute irradiance scale of the SOLAR-ISS reference spectrum. The resulting one-of-a-kind SOLAR-HRS disk-integrated spectrum has a spectral resolution varying between 0.001 and 1 nm in the 0.5–4400 nm wavelength range. We also implemented a new high-resolution solar spectrum at the disk-center, covering a range of 650–4400 nm with a spectral resolution of 0.001 to 0.02 nm. We further expanded our analysis by producing several solar spectra for ten different solar view angles ranging from μ = 0.9 to μ = 0.05 (SOLAR-HRS intermediate cases). Finally, we developed new Merged Parallelised Simplified ATLAS spectra (MPS-ATLAS) based on solar modeling with Kurucz and Vald3 solar linelists for both the disk-integrated and disk-center spectra. One of the objectives of implementing all these new solar spectra is to fulfill the requirements of the MicroCarb space mission, which focuses on measuring greenhouse gas emissions. The solar data of this study are openly available. [ABSTRACT FROM AUTHOR]