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Garnet amphibolite and semi-pelitic gneiss preserving three stages of metamorphic mineral assemblages, i.e., the prograde metamorphic inclusion assemblage (M1) preserved in the garnet porphyroblast, metamorphic peak assemblage (M2) and retrograde symplectic assemblage (M3), have been recognized in the Aketashitage area, northwestern China. Geothermobarometric computation shows that the M1, M2 and M3 assemblages record the metamorphic P-T conditions of 600–700 °C/4.2–5.3 kbar, 730–790 °C/6.3–7.1 kbar, and 770 °C/5.6 kbar, respectively. These three metamorphic stages define clockwise P-T paths including nearly isothermal decompression (ITD) process, indicating typical orogenic metamorphism. The peak metamorphic P-T conditions reach the transition zone between the high amphibolite facies and granulite facies, and belong to intermediate P/T facies series. The SHRIMP and LA-ICP-MS U-Pb dating of metamorphic zircon implies that the subduction might occur as early as ∼1.97 Ga and last as late as 1.84 Ga. Combined with literature data, it is concluded that the Aketashitage area was a Paleoproterozoic orogenic belt, which is possibly related to the assembly of the basements of the Columbia supercontinent.

Garnet-bearing mafic granulites occur as lenses within TTG gneiss or metapelite in the Fuping Complex, middle Palaeoproterozoic Trans-North China Orogen. They are composed mainly of garnet, clinopyroxene, orthopyroxene, hornblende, plagioclase, quartz and accessary zircon and titanite. Four stages of metamorphic mineral assemblages have been found in these mafic granulites: (a) the prograde assemblages (M1) are inclusions preserved in the garnet porphyroblasts, including clinopyroxene, hornblende, plagioclase and quartz; (b) the metamorphic peak assemblages (M2) consist of garnet porphyroblasts plus matrix minerals clinopyroxene + orthopyroxene + hornblende + plagioclase + quartz + zircon + titanite; (c) the first retrograde assemblages (M3) are represented by clinopyroxene + orthopyroxene + plagioclase + quartz symplectites rimming the garnets; and (4) the final retrograde assemblages (M4) are hornblende + plagioclase + quartz symplectites rimming or adjacent to the garnets. The retrieved metamorphic P-T paths pass from 530–600 °C/6.5–7.0 kbar (M1) through 680–820 °C/7.2–11.7 kbar (M2) to 730–760 °C/3.2–3.9 kbar (M3) and finally to 600–640 °C/3.2–3.7 kbar (M4). All the P-T paths of the mafic granulites are clockwise, two of these even contain near isothermal decompression (ITD) and subsequent near isobaric cooling (IBC) segments. SHRIMP U-Pb dating of metamorphic zircons of the mafic granulites yields a mean weighted age of ∼1849 ± 9Ma, which is consistent with the metamorphic time of surrounding TTG gneisses. Therefore, the Fuping Complex records the collision event between the Eastern and Western Blocks of the North China Craton that led to the final assembly of this craton during the late Paleoproterozoic.

Mafic and felsic granulite from the Miyun metamorphic complex, northeast Beijing, North China Craton, occur as either interlayers or lenses within the Late Archean TTG gneiss. In the mafic granulite, the metamorphic peak assemblages (M1) are represented by porphyroblast minerals plus matrix minerals (orthopyroxene + clinopyroxene + plagioclase + quartz ± K-feldspar ± hornblende ± biotite) as well as accessory minerals of zircon + apatite + ilmenite ± magnetite, the post-peak assemblages (M2) are characterized by “red-eye socket” symplectites (garnet + clinopyroxene + plagioclase + quartz) rimming the orthopyroxene or clinopyroxene porphyroblast as well as accessory minerals of rutile, and the final retrograde assemblages (M3) are marked by the hornblende-biotite intergrowth. As for the felsic granulite, the peak assemblages (M1) are represented by the porphyroblast and matrix minerals (garnet + orthopyroxene + biotite + plagioclase + quartz ± K-feldspar) as well as accessory minerals in the matrix (zircon + monazite + apatite + pyrite), the post-peak assemblages (M2) are characterized by “red-eye socket” symplectites (garnet + plagioclase + quartz) rimming the orthopyroxene porphyroblast, and the final retrograde assemblages (M3) are marked by the biotite-calcite intergrowth. Geothermobarometric computation suggests that the M1, M2 and M3 assemblages of the mafic granulite were formed under P-T conditions of ∼800 to 860 °C/∼6 to 10 kbar, ∼620 to 700 °C/11 to 12 kbar and ∼590 to 660 °C/4 to 6 kbar, respectively, suggesting that these granulites record anticlockwise P-T paths including final nearly isothermal decompression (ITD) segments, indicative of orogenic process. For the felsic granulite, metamorphic P-T conditions of the M1 and M3 assemblages were estimated to be ∼680 to 750 °C/6–8 kbar and ∼670 to 680 °C/5 kbar, respectively, also including ITD process. The widely penetrative gneissosity of the granulite and these P-T paths, suggest a collisional event of cold nappes overthrusting on hot ones or hot nappes being buried/subducted into cold ones and finally experienced fast tectonic exhumation. High-precision SIMS and LA-ICP-MS U-Pb dating of metamorphic zircon of the granulite suggest that the metamorphism occurred at ∼2.5 Ga. These data confirm that the Miyun metamorphic complex experienced a Neoarchean collisional event within the Eastern Block of the North China Craton.

Amphibolites in the Shuixiakou area of the southern Dunhuang Orogenic Belt, southernmost Central Asian Orogenic Belt (CAOB), occur as lenses within hornblende-biotite-plagioclase gneiss or pelitic schist, exhibiting block-in-matrix feature of tectonic mélange. Three generations of metamorphic mineral assemblages (M1, M2, and M3) have been recognized in the garnet-bearing amphibolite lenses. The metamorphic prograde assemblage (M1) is documented with inclusion trails (hornblende + plagioclase + quartz) within garnet porphyroblasts, and are estimated to be formed under 610–690 °C and 6.5–10.2 kbar. The metamorphic peak assemblage (M2) consists of garnet + hornblende + clinopyroxene + plagioclase + quartz in the matrix and records metamorphic peak P-T conditions of 720–750 °C and 13.4–14.7 kbar. The retrograde assemblage (M3) is represented by the symplectic assemblage (hornblende + plagioclase + quartz ± biotite ± magnetite) rimming the garnet porphyroblast, formed in the decompression stage under P-T conditions of 630–730 °C and 3.8–7.2 kbar. The derived metamorphic P-T paths show similar tight clockwise loops including nearly isothermal decompression processes, typical of orogenic metamorphism. SIMS dating of metamorphic zircons from the amphibolites confirm that the high-pressure metamorphism (M2) occurred at ca. 438–398 Ma.

Metamorphic evolution and geochronology of pelitic granulites were reported for the first time in the Taihua metamorphic complex, Mts. Huashan area, southern segment of the trans-North China Orogen (TNCO). Three generations of metamorphic mineral assemblages are recognized: (1) the prograde metamorphic mineral assemblages (M1) are represented by mineral inclusions within the garnet porphyroblasts; (2) the metamorphic peak assemblage (M2) are the garnet porphyroblasts and minerals in the matrix (biotite + orthopyroxene + plagioclase + quartz + K-feldspar + ilmenite + zircon + magnetite); and (3) the retrograde metamorphic mineral assemblages (M3) are represented by the symplectic assemblages around the garnet porphyroblasts, resulted from decomposition reactions between garnet rims and neighboring minerals in the matrix. Calculated by both conventional thermobarometry and pseudosection modeling in the NCKFMASHT system using the Perple_X technique, the P–T conditions of these three metamorphic stages are constrained to be of 4–5 kbar/520–530 °C for the M1 stage, 6.8–8.6 kbar/730–810 °C for the M2 stage and 4.1–6.4 kbar/570–740 °C for the M3 stage, respectively. The derived clockwise P–T paths imply that the Mts. Huashan terrane involved in the subduction and subsequent collision between the Eastern and Western Blocks of the North China Craton (NCC) along the Palaeoproterozoic Trans-North China Orogen (TNCO). High resolution SIMS U–Pb dating of metamorphic zircons reveals the metamorphic ages of 1.85–1.82 Ga. Combined with geochronological data from the literature, it is concluded that the tectonothermal evolution between the Eastern and Western Blocks started as early as ∼1.97 Ga and lasted as late as 1.80 Ga. Furthermore, the eastern Taihua complex records older metamorphic ages and higher peak metamorphic pressures than those of the western Taihua complex, possibly suggesting an eastward subduction model for the TNCO.

Golgi protein 73 (GP73) is a potential serum biomarker used in diagnosing human hepatocellular carcinoma (HCC). Compared to alpha-fetoprotein, detection of GP73 is expected to give better sensitivity and specificity and thus offers a better method for diagnosis of HCC at an early stage. In this paper, silicon nitride microcantilever was used to detect GP73. The cantilever was modified through many steps to contain antibody of GP73. The result shows that the cantilever can be used as a label-free sensor to detect this kind of biomarker.