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Observing the vibrational/rotational lines in a comet's optical spectrum requires high-resolution spectroscopy, as they are otherwise seen as a blended feature. To achieve this, we have obtained medium and high-resolution (R ($\lambda/\Delta \lambda$) = 30000 and 60000) spectra of several comets, including C/2015 V2 (Johnson), 46P/Wirtanen, 41P/Tuttle-Giacobini-Kres\'ak and 38P/Stephan-Oterma, using the Hanle Echelle Spectrograph (HESP) mounted on the 2-m Himalayan Chandra Telescope (HCT) in India. The spectra effectively cover the wavelength range 3700 - 10,000 {\AA}, allowing us to probe the various vibrational bands and band sequences to identify the rotational lines in the cometary molecular emission. We were also able to separate the cometary Oxygen lines from the telluric lines and analyse the green-to-red (G/R) forbidden oxygen [OI] ratios in a few comets. For comets C/2015 V2, 46P, and 41P, the computed G/R ratios, 0.04$\pm$0.01, 0.04$\pm$0.01, and 0.08$\pm$0.02 respectively, point to H$_2$O being a major source of Oxygen emissions. Notably, in the second fibre pointing at a location 1000 km away from the photocenter of comet 46P, the G/R ratio reduced by more than half the value observed in the first fibre, indicating the effects of quenching within the inner coma. We also measured the NH$_2$ ortho-to-para ratio of comet 46P to be about 3.41$\pm$0.05 and derived an ammonia ratio of 1.21$\pm$0.03 corresponding to a spin temperature of $\sim$26 K. With these, we present the results of the study of four comets from different cometary reservoirs using medium and high-resolution optical spectroscopy, emphasising the capabilities of the instrument for future cometary studies., Comment: 12 pages, 21 figures, 6 tables, Accepted for publication in MNRAS

Jupiter Family Comets (JFCs), having orbital period less than 20 years, provide us with an opportunity to observe their activity and analyse the homogeneity in their coma composition over multiple apparitions. Comet 46P/Wirtanen with its exceptionally close approach to Earth during its 2018 apparition offered the possibility for a long-term spectroscopic observations. We used a 1.2 m telescope equipped with a low-resolution spectrograph to monitor the comet's activity and compute the relative abundances in the coma, as a function of heliocentric distance. We report the production rates of four molecules CN, C$_2$, C$_3$ and NH$_2$, and Af$\rho$ parameter, a proxy to the dust production, before and after perihelion. We found that 46P has a typical coma composition with almost constant abundance ratios with respect to CN across the epochs of observation. Comparing the coma composition of comet 46P during the current and previous apparitions, we conclude the comet has a highly homogeneous chemical composition in the nucleus with an enhancement in ammonia abundance compared to the average abundance in comets., Comment: 11 pages, 6 figures, 2 tables, accepted for publication in JOAA

Two papers recently reported the detection of gaseous nickel and iron in the comae of over 20 comets from observations collected over two decades, including interstellar comet 2I/Borisov. To evaluate the state of the laboratory data in support of these identifications, we re-analyzed archived spectra of comet C/1996 B2 (Hyakutake), one of the nearest and brightest comets of the last century, using a combined experimental and computational approach. We developed a new, many-level fluorescence model that indicates that the fluorescence emission of Fe I and Ni I vary greatly with heliocentric velocity. Combining this model with laboratory spectra of an Fe-Ni plasma, we identified 22 lines of Fe I and 14 lines of Ni I in the spectrum of Hyakutake. Using Haser models, we estimate the nickel and iron production rates as Q(Ni) = 2.6 - 4.1 x 10^22 s^-1 and Q(Fe) = 0.4 - 2.8 x 10^23 s^-1. From derived column densities, the Ni/Fe abundance ratio log10[Ni/Fe] = -0.15 +/- 0.07 deviates significantly from solar abundance ratios, and it is consistent with the ratios observed in solar system comets. Possible production and emission mechanisms are analyzed in context of existing laboratory measurements. Based on the observed spatial distributions, excellent fluorescence model agreement, and Ni/Fe ratio, our findings support an origin consisting of a short-lived unknown parent followed by fluorescence emission. Our models suggest that the strong heliocentric velocity dependence of the fluorescence efficiencies can provide a meaningful test of the physical process responsible for the Fe I and Ni I emission., Comment: 23 pages, 11 figures

Comet 2I/Borisov is the first true interstellar comet discovered. Here we present results from observational programs at two Indian observatories, 2 m Himalayan Chandra Telescope at the Indian Astronomical Observatory, Hanle (HCT) and 1.2 m telescope at the Mount Abu Infrared Observatory (MIRO). Two epochs of imaging and spectroscopy were carried out at the HCT and three epochs of imaging at MIRO. We found CN to be the dominant molecular emission on both epochs, 31/11/2019 and 22/12/2019, at distances of r$_H$ = 2.013 and 2.031 AU respectively. The comet was inferred to be relatively depleted in Carbon bearing molecules on the basis of low $C_2$ and $C_3$ abundances. We find the production rate ratio, Q($C_2$)/Q(CN) = 0.54 $\pm$ 0.18, pre-perihelion and Q($C_2$)/Q(CN) = 0.34 $\pm$ 0.12 post-perihelion. This classifies the comet as being moderately depleted in carbon chain molecules. Using the results from spectroscopic observations, we believe the comet to have a chemically heterogeneous surface having variation in abundance of carbon chain molecules. From imaging observations we infer a dust-to-gas ratio similar to carbon chain depleted comets of the Solar system. We also compute the nucleus size to be in the range $0.18\leq r \leq 3.1$ Km. Our observations show that 2I/Borisov's behaviour is analogous to that of the Solar system comets., Comment: Accepted for publication in MNRAS, 10 pages, 8 figures

Far ultraviolet observations of comets yield information about the energetic processes that dissociate the sublimated gases from their primitive surfaces. Understanding which emission processes are dominant, their effects on the observed cometary spectrum, and how to properly invert the spectrum back to composition of the presumably pristine surface ices of a comet nuclei are all critical components for proper interpretation and analysis of comets. The close approach of comet 46P/Wirtanen in 2018-2019 provided a unique opportunity to study the inner most parts of a cometary coma with the Hubble Space Telescope Cosmic Origins Spectrograph, rarely accessible with remote observations, at length scales (100's of km) and wavelengths (900-1430 Angstroms) previously probed only by the European Space Agency's Rosetta spacecraft. Our observations show a complex picture for the inner coma; atomic production rates for H and O that show water is the dominant source of both, an abundance of atomic sulfur that is difficult to explain with the lifetimes of common sulfur parent molecules, and a density distribution that is poorly fit with both Haser and vectorial models., Comment: 16 pages, 9 figures. Accepted in A'Hearn Special Issue of Planetary Science Journal

We carried out observations of a peculiar comet, C/2016 R2 (Pan-STARRS), using a low resolution spectrograph mounted on the 1.2m telescope at Mount Abu Infrared Observatory, India. The comet was observed on two dates in January 2018, when it was at a heliocentric distance of 2.8 AU. Study based on our observations revealed that the optical spectrum of this comet is quite unusual as compared to general cometary spectra. Most of the major cometary emissions like C$_{2}$, C$_{3}$ and CN were absent in comet C/2016 R2. However, the comet spectrum showed very strong emission bands from ionic species like CO$^{+}$ and N$_{2}^{+}$. A mean N$_{2}$/CO ratio of 0.09 $\pm$ 0.02 was derived from the spectra and an extremely low depletion factor of 1.6 $\pm$ 0.4 has been estimated for this ratio as compared to the solar nebula. We have also detected minor emission features beyond 5400 Angstroms, albeit marginally. The column densities of CO$^{+}$ and N$_{2}^{+}$ were calculated from their emission bands. The optical spectrum suggests that the cometary ice is dominated by CO. The low depletion factor of N$_{2}$/CO ratio in this comet, as compared to the solar nebula and the unusual spectrum of the comet are consequences of distinctive processing at the location of its formation in the early solar nebula., Comment: Accepted for Publication in MNRAS

The asteroid 2014 JO25, considered to be "potentially hazardous" by the Minor Planet Center, was spectroscopically followed during its close-Earth encounter on 19th and 20th of April 2017. The spectra of the asteroid were taken with the low resolution spectrograph (LISA), mounted on the 1.2-m telescope at the Mount Abu Infrared Observatory, India. Coming from a region close to the Hungaria population of asteroids, this asteroid follows a comet-like orbit with a relatively high inclination and large eccentricity. Hence, we carried out optical spectroscopic observations of the asteroid to look for comet-like molecular emissions or outbursts. However, the asteroid showed a featureless spectrum, devoid of any comet-like features. The asteroid's light curve was analyzed using V band magnitudes derived from the spectra and the most likely solution for the rotation of the asteroid was obtained. The absolute magnitude $H$ and the slope parameter $G$ were determined for the asteroid in V filter band using the IAU accepted standard two parameter H-G model. A peculiar, rarely found result from these observations is its phase bluing trend. The relative B-V color index seems to decrease with increasing phase angle, which indicates a phase bluing trend. Such trends have seldom been reported in literature. However, phase reddening in asteroids is very common. The asymmetry parameter $g$ and the single scattering albedo $w$ were estimated for the asteroid by fitting the Hapke phase function to the observed data. The asteroid shows relatively large value for the single scattering albedo and a highly back scattering surface., Comment: Accepted for publication in The Astronomical Journal

Spectra of comet C/2014 Q2 (Lovejoy) were taken with a low resolution spectrograph mounted on the 0.5 m telescope at the Mount Abu Infrared Observatory (MIRO), India during January to May 2015 covering the perihelion and post-perihelion periods. The spectra showed strong molecular emission bands (C2, C3 and CN) in January, close to perihelion. We have obtained the scale lengths for these molecules by fitting the Haser model to the observed column densities. The variation of gas production rates and production rate ratios with heliocentric distance were studied. The extent of the dust continuum using the Af-rho parameter and its variation with the heliocentric distance were also investigated. The comet is seen to become more active in the post-perihelion phase, thereby showing an asymmetric behaviour about the perihelion., Comment: Accepted for publication in MNRAS