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Relevance of the research topic. Blockchain technology has become a new paradigm for building decentralized systems that do not require the creation of a central governing body to organize the cooperation and coordination of participants with different characteristics. The possibilities of blockchain applications have already begun to go beyond digital finance and are increasingly being used for the decentralized organization of communities and participants in digital partnerships. Decentralized autonomous organizations (DAOs) built on blockchain technology represent a new form of collective management in which communities are organized based on the decentralized infrastructure of the third generation of the Internet (Web 3.0). In this context, as an innovative form of economic cooperation, decentralized autonomous organizations have become an object of research interest. Problem statement. The use of decentralized autonomous organizations as a form of cooperation is a new and relatively unexplored area in economics. The role of DAOs in the system of economic relations and their possibilities for digital partnerships remain unexplored. In addition, the use of DAOs poses a number of opportunities and risks that can be identified through analysis and evaluation. Objective and tasks of the research. The aim of the research is to determine the possibilities of using decentralized autonomous organizations as an innovative form of economic cooperation in the digital society. The tasks of the research include analyzing the mechanisms of DAO functioning, comparing them with traditional organizational forms, and determining their possibilities for application in different fields. Methodology of the research. The research methodology consists of analyzing scientific sources and practical experience in the use of decentralized autonomous organizations. The research was conducted by analyzing the main principles of DAO operation, their advantages and disadvantages compared to traditional forms of economic cooperation. A comparative analysis was also conducted to identify the differences between DAOs and traditional organizations. Finally, the possibilities of using DAOs in different fields were assessed, taking into account the potential risks associated with their use. Presentation of the main findings of the study. The results of the research demonstrate that DAO can be an effective form of organizing economic cooperation in the digital society. They provide decentralization and autonomy, which allows avoiding many problems of traditional forms of cooperation, such as management, power, and profit distribution issues. In addition, the application of blockchain technology enables a high level of security and trust among participants. Application fields of the results. DAO can be applied in various economic fields, such as finance, logistics, agriculture, and others. This technology can also find its application in public projects, such as charity and ecology. The digital nature of such an organization allows integrating any modern technological advancements, including tools of artificial intelligence and decentralized finance. With such characteristics, DAO is defined as one of the most interesting organizational innovations of the 21st century. Conclusions of the article. Based on the analysis results, we propose to consider the DAO concept as an innovative technology of organizing economic cooperation, capable of responding to new challenges through fast and remote organization of economic interaction, regardless of the geographic location of partnership participants, based on trust and modern tools using distributed ledger technology. This new form of cooperation, based on decentralization and autonomy, offers DAO technology as a competing form that replaces standard forms of cooperation and Web 2.0 internet organization. The unique feature of this form of economic cooperation is the absence of intermediaries, as the terms of interaction are recorded in the program code and executed automatically, significantly reducing costs and time for interaction realization.

Relevance of the research topic. Blockchain technology has become a new paradigm for building decentralized systems that do not require the creation of a central governing body to organize the cooperation and coordination of participants with different characteristics. The possibilities of blockchain applications have already begun to go beyond digital finance and are increasingly being used for the decentralized organization of communities and participants in digital partnerships. Decentralized autonomous organizations (DAOs) built on blockchain technology represent a new form of collective management in which communities are organized based on the decentralized infrastructure of the third generation of the Internet (Web 3.0). In this context, as an innovative form of economic cooperation, decentralized autonomous organizations have become an object of research interest. Problem statement. The use of decentralized autonomous organizations as a form of cooperation is a new and relatively unexplored area in economics. The role of DAOs in the system of economic relations and their possibilities for digital partnerships remain unexplored. In addition, the use of DAOs poses a number of opportunities and risks that can be identified through analysis and evaluation. Objective and tasks of the research. The aim of the research is to determine the possibilities of using decentralized autonomous organizations as an innovative form of economic cooperation in the digital society. The tasks of the research include analyzing the mechanisms of DAO functioning, comparing them with traditional organizational forms, and determining their possibilities for application in different fields. Methodology of the research. The research methodology consists of analyzing scientific sources and practical experience in the use of decentralized autonomous organizations. The research was conducted by analyzing the main principles of DAO operation, their advantages and disadvantages compared to traditional forms of economic cooperation. A comparative analysis was also conducted to identify the differences between DAOs and traditional organizations. Finally, the possibilities of using DAOs in different fields were assessed, taking into account the potential risks associated with their use. Presentation of the main findings of the study. The results of the research demonstrate that DAO can be an effective form of organizing economic cooperation in the digital society. They provide decentralization and autonomy, which allows avoiding many problems of traditional forms of cooperation, such as management, power, and profit distribution issues. In addition, the application of blockchain technology enables a high level of security and trust among participants. Application fields of the results. DAO can be applied in various economic fields, such as finance, logistics, agriculture, and others. This technology can also find its application in public projects, such as charity and ecology. The digital nature of such an organization allows integrating any modern technological advancements, including tools of artificial intelligence and decentralized finance. With such characteristics, DAO is defined as one of the most interesting organizational innovations of the 21st century. Conclusions of the article. Based on the analysis results, we propose to consider the DAO concept as an innovative technology of organizing economic cooperation, capable of responding to new challenges through fast and remote organization of economic interaction, regardless of the geographic location of partnership participants, based on trust and modern tools using distributed ledger technology. This new form of cooperation, based on decentralization and autonomy, offers DAO technology as a competing form that replaces standard forms of cooperation and Web 2.0 internet organization. The unique feature of this form of economic cooperation is the absence of intermediaries, as the terms of interaction are recorded in the program code and executed automatically, significantly reducing costs and time for interaction realization.

Chemistry - a European journal 29(22), e202203963 (2023). doi:10.1002/chem.202203963, Pentaphosphaferrocenes [Cp$^R$Fe(η$^5$-P$_5$)] (Cp*=η$^5$-C$_5$Me$_5$) (A), Cp’’=η$^5$-C$_5$H$_3$tBu$_2$-1,3 (B)) are excellent building blocks for polymeric assemblies in supramolecular chemistryin combination with coinage metal salts of weakly coordinating anions such as AgSbF$_6$. Adding rigid aromatic dinitriles ortho/meta/para-(NC)$_2$C$_6$H$_4$ in a one-pot reaction between [Cp$^R$Fe(η$^5$-P$_5$)] and AgSbF$_6$ leads to various coordination polymers (CPs) by a three-component self-assembly. The sterical demand of the differently substituted cyclopentadiene ligands as well as the rigid constitution of the isomeric dinitriles (NC)$_2$C$_6$H$_4$ play a key role in the formation of the isolated CPs. All CPs were characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single-crystal X-ray diffraction., Published by Wiley-VCH, Weinheim