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Environmental concerns regarding the disposal of seawater reverse osmosis brines require the development of new valorization strategies. Electrodialysis with bipolar membrane (EDBM) technology enables the production of acid and base from a salty waste stream. In this study, an EDBM pilot plant with a membrane area of 19.2 m 2 was tested. This total membrane area results much larger (i.e., more than 16 times larger) than those reported in the literature so far for the production of HCl and NaOH aqueous solutions, starting from NaCl brines. The pilot unit was tested both in continuous and discontinuous operation modes, at different current densities (200-500 A m -2 ). Particularly, three different process configurations were evaluated, namely, closed-loop, feed and bleed, and fed-batch. At lower applied current density (200 A m -2 ), the closed-loop had a lower specific energy consumption (SEC) (1.4 kWh kg -1 ) and a higher current efficiency (CE) (80%). When the current density was increased (300-500 A m -2 ), the feed and bleed mode was more appropriate due to its low values of SEC (1.9-2.6 kWh kg -1 ) as well as high values of specific production (SP) (0.82-1.3 ton year -1 m -2 ) and current efficiency (63-67%). These results showed the effect of various process configurations on the performance of the EDBM, thereby guiding the selection of the most suitable process configuration when varying the operating conditions and representing a first important step toward the implementation of this technology at industrial scale., Competing Interests: The authors declare no competing financial interest., (© 2023 The Authors. Published by American Chemical Society.)

In agreement with the Water Framework Directive, Circular Economy and European Union (EU) Green Deal packages, the EU-funded WATER-MINING project aims to validate next-generation water resource solutions at the pre-commercial demonstration scale in order to provide water management and recovery of valuable materials from alternative sources. In the framework of the WATER-MINING project, desalination brines from the Lampedusa (Italy) seawater reverse osmosis (SWRO) plant will be used to produce freshwater and recover valuable salts by integrating different technologies. In particular, electrodialysis with bipolar membranes (EDBM) will be used to produce chemicals (NaOH and HCl). A novel EDBM pilot plant (6.4 m 2 , FuMa-Tech) has been installed and operated. The performance of EDBM for single pass under different flowrates (2-8 L·min -1 ) for acid, base and saline channels, and two current densities (200 and 400 A·m -2 ), has been analyzed in terms of specific energy consumption (SEC) and current efficiency (CE). Results showed that by increasing the flowrates, generation of HCl and NaOH slightly increased. For example, ΔOH - shifted from 0.76 to 0.79 mol·min -1 when the flowrate increased from 2 to 7.5 L·min -1 at 200 A·m -2 . Moreover, SEC decreased (1.18-1.05 kWh·kg -1 ) while CE increased (87.0-93.4%), achieving minimum (1.02 kWh·kg -1 ) and maximum (99.4%) values, respectively, at 6 L·min -1 .