1. Determination of 57 organic pollutants in edible vegetable oil by gas chromatography-triple quadrupole mass spectrometry
- Author
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LIU Yu-xing, YI Shou-fu, XU Wen-yang, TANG Wan-li, KANG Shao-ying, and WANG Xia-li
- Subjects
gas chromatography-triple quadrupole mass spectrometry ,edible vegetable oil ,polycyclic aromatic hydrocarbons ,polychlorinated biphenyls ,phthalates ,benzene hexachloride ,dichlorodiphenyltrichloroethane ,Food processing and manufacture ,TP368-456 - Abstract
Objective: Establish a high throughput method for the determination of 57 organic pollutants in edible vegetable oil. Methods: The target compounds were extracted by acetonitrile-hexane solution and purified by disperse solid phase extraction and solid phase extraction, after that the contents of 16 polycyclic aromatic hydrocarbons, 17 phthalates, 8 organochlorines and 16 polychlorinated biphenyls in edible oil were detected by gas chromatography triple quadrupole mass spectrometry. Results: All target components had an excellent linearity within the linear range of 0.001~0.1 μg/mL (r2>0.998), and the limits of detection was between 0.16~2.0 μg/kg, meanwhile the average recovery rate of matrix addition was between 71.0%~119.5%, and the relative standard deviation was below 12.6% (n=6). Furthermore, the method was used to analyze 24 baches of edible oils, and 25 types of target substances were founded. Conclusion: This method is high efficiency, accuracy, high sensitivity, which has great significance for the monitoring of persistent organic pollutants and phthalates in edible oil.
- Published
- 2023
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