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We describe the properties of a continuous-wave room-temperature quantum cascade laser operating at the long wavelength of 17 $\mu$m. Long wavelength mid-infrared quantum cascade lasers offer new opportunities for chemical detection, vibrational spectroscopy and metrological measurements using molecular species. In particular, probing low energy vibrational transitions would be beneficial to the spectroscopy of large and complex molecules, reducing intramolecular vibrational energy redistribution which acts as a decoherence channel. By performing linear absorption spectroscopy of the v2 fundamental vibrational mode of N2O molecules, we have demonstrated the spectral range and spectroscopic potential of this laser, and characterized its free-running frequency noise properties. Finally, we also discuss the potential application of this specific laser in an experiment to test fundamental physics with ultra-cold molecules.

We demonstrate a trap that confines polarizable particles around the antinode of a standing-wave microwave field. The trap relies only on the polarizability of the particles far from any resonances, so can trap a wide variety of atoms and molecules in a wide range of internal states, including the ground state. The trap has a volume of about 10 cm$^3$, and a depth approaching 1 K for many polar molecules. We measure the trap properties using $^{7}$Li atoms, showing that when the input microwave power is 610 W, the atoms remain trapped with a $1/e$ lifetime of 1.76(12) s, oscillating with an axial frequency of 28.55(5) Hz and a radial frequency of 8.81(8) Hz. The trap could be loaded with slow molecules from a range of available sources, and is particularly well suited to sympathetic cooling and evaporative cooling of molecules., Comment: 7 pages, 6 figures. Modified figure 5, added figure 6, added further discussion of applications

We present the properties and advantages of a new magneto-optical trap (MOT) where blue-detuned light drives `type-II' transitions that have dark ground states. Using $^{87}$Rb, we reach a radiation-pressure-limited density exceeding $10^{11}$cm$^{-3}$ and a temperature below 30$\mu$K. The phase-space density is higher than in normal atomic MOTs, and a million times higher than comparable red-detuned type-II MOTs, making it particularly attractive for molecular MOTs which rely on type-II transitions. The loss of atoms from the trap is dominated by ultracold collisions between Rb atoms. For typical trapping conditions, we measure a loss rate of $1.8(4)\times10^{-10}$cm$^{3}$s$^{-1}$.

Using frequency-chirped radiation pressure slowing, we precisely control the velocity of a pulsed CaF molecular beam down to a few m/s, compressing its velocity spread by a factor of 10 while retaining high intensity: at a velocity of 15~m/s the flux, measured 1.3~m from the source, is 7$\times$10$^{5}$ molecules per cm$^{2}$ per shot in a single rovibrational state. The beam is suitable for loading a magneto-optical trap or, when combined with transverse laser cooling, improving the precision of spectroscopic measurements that test fundamental physics. We compare the frequency-chirped slowing method with the more commonly used frequency-broadened slowing method., Comment: 19 pages, 8 figures. Extension of earlier version to include detailed comparison of slowing methods

Rydberg states of atomic helium with principal quantum numbers ranging from n=20 to n=100 have been prepared by non-resonance-enhanced single-color two-photon excitation from the metastable 2 {^3}S{_1} state. Photoexcitation was carried out using linearly and circularly polarized pulsed laser radiation. In the case of excitation with circularly polarized radiation, Rydberg states with azimuthal quantum number |m_{\ell}|=2 were prepared in zero electric field, and in homogeneous electric fields oriented parallel to the propagation axis of the laser radiation. In sufficiently strong electric fields, individual Rydberg-Stark states were resolved spectroscopically, highlighting the suitability of non-resonance-enhanced multiphoton excitation schemes for the preparation of long-lived high-|m_{\ell}| hydrogenic Rydberg states for deceleration and trapping experiments. Applications of similar schemes for Doppler-free excitation of positronium atoms to Rydberg states are also discussed.

We demonstrate slowing and longitudinal cooling of a supersonic beam of CaF molecules using counter-propagating laser light resonant with a closed rotational and almost closed vibrational transition. A group of molecules are decelerated by about 20 m/s by applying light of a fixed frequency for 1.8 ms. Their velocity spread is reduced, corresponding to a final temperature of about 300 mK. The velocity is further reduced by chirping the frequency of the light to keep it in resonance as the molecules slow down., Comment: 6 pages, 6 figures

We report the Stark deceleration of CaF molecules in the strong-field seeking ground state and in a weak-field seeking component of a rotationally-excited state. We use two types of decelerator, a conventional Stark decelerator for the weak-field seekers, and an alternating gradient decelerator for the strong-field seekers, and we compare their relative merits. We also consider the application of laser cooling to increase the phase-space density of decelerated molecules., Comment: 10 pages, 8 figures

In a Stark decelerator, polar molecules are slowed down and focussed by an inhomogeneous electric field which switches between two configurations. For the decelerator to work, it is essential that the molecules follow the changing electric field adiabatically. When the decelerator switches from one configuration to the other, the electric field changes in magnitude and direction, and this can cause molecules to change state. In places where the field is weak, the rotation of the electric field vector during the switch may be too rapid for the molecules to maintain their orientation relative to the field. Molecules that are at these places when the field switches may be lost from the decelerator as they are transferred into states that are not focussed. We calculate the probability of nonadiabatic transitions as a function of position in the periodic decelerator structure and find that for the decelerated group of molecules the loss is typically small, while for the un-decelerated group of molecules the loss can be very high. This loss can be eliminated using a bias field to ensure that the electric field magnitude is always large enough. We demonstrate our findings by comparing the results of experiments and simulations for the Stark deceleration of LiH and CaF molecules. We present a simple method for calculating the transition probabilities which can easily be applied to other molecules of interest., Comment: 12 pages, 9 figures, minor revisions following referee suggestions

An alternating gradient electric guide provides a way to transport a wide variety of polar molecules, including those in high-field seeking states. We investigate the motion of polar molecules in such a guide by measuring the transmission of CaF molecules in their high-field seeking ground state, with the guide operating at a variety of switching frequencies and voltages. We model the guide using analytical and numerical techniques and compare the predictions of these models to the experimental results and to one another. The analytical results are approximate, but provide simple and useful estimates for the maximum phase-space acceptance of the guide and for the switching frequency required. The numerical methods provide more accurate results over the full range of switching frequencies. Our investigation shows that, even when the fields are static, some high-field seeking molecules are able to pass through the guide on metastable trajectories. We show that the maximum possible transmission requires accurate alignment within the guide and between the guide and detector., Comment: 10 pages, 5 figures; revised following referee suggestions

We describe a method for determining the radiative decay properties of a molecule by studying the saturation of laser-induced fluorescence and the associated power broadening of spectral lines. The fluorescence saturates because the molecules decay to states that are not resonant with the laser. The amplitudes and widths of two hyperfine components of a spectral line are measured over a range of laser intensities and the results compared to a model of the laser-molecule interaction. Using this method we measure the lifetime of the A(v'=0) state of CaF to be tau=19.2 \pm 0.7 ns, and the Franck-Condon factor for the transition to the X(v=0) state to be Z=0.987 (+0.013 || -0.019). In addition, our analysis provides a measure of the hyperfine interval in the lowest-lying state of A(v'=0), Delta_e=4.8 \pm 1.1 MHz., Comment: 10 pages, 6 figures. Minor revisions following referee suggestions