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The feasibility of the autothermic pyrolysis in situ conversion (ATS) process for low-grade oil shale (OS) has not been determined. In this research, the pyrolysis and combustion properties of Tongchuan OS, with a 4.04% oil yield, were systematically analyzed. The findings revealed that temperatures between 350 and 425 °C favored oil production, while temperatures from 450 to 520 °C resulted in a higher rate of gaseous generation. At 300 °C, the volume expansion and ignition coking caused by the large amount of bitumen generated resulted in severe pore plugging, which significantly increased the combustion activation energy of the residue, while the presence of substantial flammable bitumen also significantly decreased the ignition and combustion temperatures. From 300 to 520 °C, the combustion performance of residue decreases continuously. In addition, pyrolysis residues of Tongchuan exhibited a slightly higher calorific value, between 425 and 520 °C, owing to its higher fixed carbon content (10.79%). Based on the ideal temperature screening method outlined for Tongchuan OS, the recommended preheating temperature for Tongchuan OS was 425 °C, while the optimum temperature for the retorting zone should be 510 °C, considering a heat utilization rate of 40%. These findings contribute valuable insights for the application of the ATS process to low-grade OS. [ABSTRACT FROM AUTHOR]

Electrochemical nitrate reduction (NO3−RR) has been recognized as a promising strategy for sustainable ammonia (NH3) production due to its environmental friendliness and economical nature. However, the NO3−RR reaction involves an eight-electron coupled proton transfer process with many by-products and low Faraday efficiency. In this work, a molybdenum oxide (MoOx)-decorated titanium dioxide nanotube on Ti foil (Mo/TiO2) was prepared by means of an electrodeposition and calcination process. The structure of MoOx can be controlled by regulating the concentration of molybdate during the electrodeposition process, which can further influence the electron transfer from Ti to Mo atoms, and enhance the binding energy of intermediate species in NO3−RR. The optimized Mo/TiO2-M with more Mo(IV) sites exhibited a better activity for NO3−RR. The Mo/TiO2-M electrode delivered a NH3 yield of 5.18 mg h−1 cm−2 at −1.7 V vs. Ag/AgCl, and exhibited a Faraday efficiency of 88.05% at −1.4 V vs. Ag/AgCl. In addition, the cycling test demonstrated that the Mo/TiO2-M electrode possessed a good stability. This work not only provides an attractive electrode material, but also offers new insights into the rational design of catalysts for NO3−RR. [ABSTRACT FROM AUTHOR]

Soil microorganisms in tropical forests can adapt to phosphorus (P)-poor conditions by changing the activity ratios of different types of phosphatases. We tested whether microorganisms in P-poor tropical forest soils increased the phosphomonoesterase (PME) to phosphodiesterase (PDE) activity ratio, because a one-step enzymatic reaction of monoester P degradation might be more adaptive for microbial P acquisition than a two-step reaction of diester P degradation. A continuous 10-year P addition experiment was performed in three tropical forests. The activities of PME and PDE, and their ratio in soil, were determined under the hypothesis that the P-fertilized plots where P shortage is relieved would have lower PME:PDE ratios than the unfertilized controls. We demonstrated that long-term P addition in tropical forest soil did not alter the PME:PDE ratio in primary and secondary forests, whereas P fertilization elevated the PME:PDE ratio in planted forest. These results were in contrast to previous results. The long-term, large-scale P fertilization in our study may have reduced litter- and/or throughfall-derived PDE, which negated the lowered PME:PDE ratio via exogenous P inputs. [ABSTRACT FROM AUTHOR]

Soil enzyme activity can be affected by both production and degradation processes, as enzymes can be degraded by proteases. However, the impact of nutrient addition on enzyme activity is often solely attributed to changes in enzyme production without fully considering degradation. In this study, we demonstrate that the activities of β-1,4-glucosidase (BG), β-D-cellobiohydrolase (CBH), β-1,4-xylosidase (BX), and β-1,4-N-acetyl-glucosaminidase (NAG) in two tropical plantations exhibited comparable levels between nitrogen (N)- and phosphorus (P)-fertilized soils and the unfertilized control under field conditions. However, it was observed that the reduction in enzymatic activity was significantly higher in the fertilized soils during short-term laboratory incubation in the acacia plantation. Additionally, the eucalyptus plantation exhibited a similar tendency, although statistical significance was not achieved due to the high variance of the data. The results show that the interruption of the natural, continuous supply of organic matter or non-soil microbial-derived enzymes, which typically occurs under field conditions, leads to a more significant reduction in soil enzyme activities in fertilized soils compared to unfertilized control. This may be attributed to the higher abundance of protease in fertilized soils, resulting in faster enzyme degradation. Interestingly, P fertilization alone did not have a similar effect, indicating that N fertilization is likely the main cause of the larger decreases in enzyme activity during incubation in fertilized soils compared to unfertilized control soils, despite our study site being poor in P and rich in N. These findings highlight the importance of considering enzyme degradation when investigating material dynamics in forest ecosystems, including the impact of nutrient addition on enzyme activity, as enzyme production alone may not fully explain changes in soil enzyme activity. [ABSTRACT FROM AUTHOR]