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Antimony sulfide (Sb2S3) is a promising candidate as an absorber layer for single-junction solar cells and the top subcell in tandem solar cells. However, the power conversion efficiency of Sb2S3-based solar cells has remained stagnant over the past decade, largely due to trap-assisted non-radiative recombination. Here we assess the trap-limited conversion efficiency of Sb2S3 by investigating non-radiative carrier capture rates for intrinsic point defects using first-principles calculations and Sah-Shockley statistics. Our results show that sulfur vacancies act as effective recombination centers, limiting the maximum efficiency of Sb2S3 to 16% light to electricity. The equilibrium concentrations of sulfur vacancies remain relatively high regardless of growth conditions, indicating the intrinsic limitations imposed by these vacancies on the performance of Sb2S3.

Pedestrian detection and tracking in crowded video sequences have a wide range of applications, including autonomous driving, robot navigation and pedestrian flow surveillance. However, detecting and tracking pedestrians in high-density crowds face many challenges, including intra-class occlusions, complex motions, and diverse poses. Although deep learning models have achieved remarkable progress in head detection, head tracking datasets and methods are extremely lacking. Existing head datasets have limited coverage of complex pedestrian flows and scenes (e.g., pedestrian interactions, occlusions, and object interference). It is of great importance to develop new head tracking datasets and methods. To address these challenges, we present a Chinese Large-scale Cross-scene Pedestrian Head Tracking dataset (Cchead) and a Multi-Source Information Fusion Network (MIFN). Our dataset has features that are of considerable interest, including 10 diverse scenes of 50,528 frames with over 2,366,249 heads and 2,358 tracks annotated. Our dataset contains diverse human moving speeds, directions, and complex crowd pedestrian flows with collision avoidance behaviors. We provide a comprehensive analysis and comparison with existing state-of-the-art (SOTA) algorithms. Moreover, our MIFN is the first end-to-end CNN-based head detection and tracking network that jointly trains RGB frames, pixel-level motion information (optical flow and frame difference maps), depth maps, and density maps in videos. Compared with SOTA pedestrian detection and tracking methods, MIFN achieves superior performance on our Cchead dataset. We believe our datasets and baseline will become valuable resources towards developing pedestrian tracking in dense crowds.

Antimony selenide (Sb2Se3) is at the forefront of an emerging class of sustainable photovoltaic materials. Despite notable developments over the past decade, the light-to-electricity conversion efficiency of Sb2Se3 has reached a plateau of ~10%. Is this an intrinsic limitation of the material or is there scope to rival the success of metal halide perovskite solar cells? Here we assess the trap-limited conversion efficiency of Sb2Se3. First-principles defect analysis of the hole and electron capture rates for point defects demonstrates the critical role of vacancies as active recombination centres. We predict an upper limit of 25% efficiency in Sb2Se3 grown under optimal equilibrium conditions where the concentrations of charged vacancies are minimised. We further reveal how the detrimental effect of Se vacancies can be reduced by extrinsic oxygen passivation, highlighting a pathway to achieve high-performance metal selenide solar cells close to the thermodynamic limit.

Balancing safety and efficiency when planning in crowded scenarios with uncertain dynamics is challenging where it is imperative to accomplish the robot's mission without incurring any safety violations. Typically, chance constraints are incorporated into the planning problem to provide probabilistic safety guarantees by imposing an upper bound on the collision probability of the planned trajectory. Yet, this results in overly conservative behavior on the grounds that the gap between the obtained risk and the specified upper limit is not explicitly restricted. To address this issue, we propose a real-time capable approach to quantify the risk associated with planned trajectories obtained from multiple probabilistic planners, running in parallel, with different upper bounds of the acceptable risk level. Based on the evaluated risk, the least conservative plan is selected provided that its associated risk is below a specified threshold. In such a way, the proposed approach provides probabilistic safety guarantees by attaining a closer bound to the specified risk, while being applicable to generic uncertainties of moving obstacles. We demonstrate the efficiency of our proposed approach, by improving the performance of a state-of-the-art probabilistic planner, in simulations and experiments using a mobile robot in an environment shared with humans., Comment: Accepted for presentation at the 2023 IEEE International Conference on Robotics and Automation (ICRA)

Risk assessment is a crucial component of collision warning and avoidance systems in intelligent vehicles. To accurately detect potential vehicle collisions, reachability-based formal approaches have been developed to ensure driving safety, but suffer from over-conservatism, potentially leading to false-positive risk events in complicated real-world applications. In this work, we combine two reachability analysis techniques, i.e., backward reachable set (BRS) and stochastic forward reachable set (FRS), and propose an integrated probabilistic collision detection framework in highway driving. Within the framework, we can firstly use a BRS to formally check whether a two-vehicle interaction is safe; otherwise, a prediction-based stochastic FRS is employed to estimate a collision probability at each future time step. In doing so, the framework can not only identify non-risky events with guaranteed safety, but also provide accurate collision risk estimation in safety-critical events. To construct the stochastic FRS, we develop a neural network-based acceleration model for surrounding vehicles, and further incorporate confidence-aware dynamic belief to improve the prediction accuracy. Extensive experiments are conducted to validate the performance of the acceleration prediction model based on naturalistic highway driving data, and the efficiency and effectiveness of the framework with the infused confidence belief are tested both in naturalistic and simulated highway scenarios. The proposed risk assessment framework is promising in real-world applications., Comment: Under review at Engineering. arXiv admin note: text overlap with arXiv:2205.01357

The phenomenon of negative-U behavior, where a defect traps a second charge carrier more strongly than the first, has been established in many host crystals. Here we report the case of four-carrier transitions for both vacancy defects in Sb2Se3. A global structure searching strategy is employed to explore the defect energy landscape from first-principles, revealing previously-unrealized configurations which facilitate a major charge redistribution. Thermodynamic analysis of the accessible charge states reveals a four-electron negative-U transition (delta q = 4) for both V_Se and V_Sb and, by consequence, amphoteric behavior for all intrinsic defects in Sb2Se3, with impact on its usage in solar cells. To the best of our knowledge, four-electron negative-U behavior has not been previously explored in this or other compounds. The unusual behavior is facilitated by valence alternation, a reconfiguration of the local bonding environments, characteristic of both Se and Sb.

In recent years, novel materials supporting in-plane anisotropic polaritons have attracted a lot of research interest due to their capability of shaping nanoscale field distributions and controlling nanophotonic energy flows. Here we report a nano-optical imaging study of waveguide exciton polaritons (EPs) in tin sulfide (SnS) in the near-infrared (IR) region using the scattering-type scanning near-field optical microscopy (s-SNOM). With s-SNOM, we mapped in real space the propagative EPs in SnS, which show sensitive dependence on the excitation energy and sample thickness. Moreover, we found that both the polariton wavelength and propagation length are anisotropic in the sample plane. In particular, in a narrow spectral range from 1.32 to 1.44 eV, the EPs demonstrate quasi-one-dimensional propagation, which is rarely seen in natural polaritonic materials. Further analysis indicates that the observed polariton anisotropy is originated from the different optical bandgaps and exciton binding energies along the two principal crystal axes of SnS., Comment: 21 pages

Developing autonomous vehicles (AVs) helps improve the road safety and traffic efficiency of intelligent transportation systems (ITS). Accurately predicting the trajectories of traffic participants is essential to the decision-making and motion planning of AVs in interactive scenarios. Recently, learning-based trajectory predictors have shown state-of-the-art performance in highway or urban areas. However, most existing learning-based models trained with fixed datasets may perform poorly in continuously changing scenarios. Specifically, they may not perform well in learned scenarios after learning the new one. This phenomenon is called "catastrophic forgetting". Few studies investigate trajectory predictions in continuous scenarios, where catastrophic forgetting may happen. To handle this problem, first, a novel continual learning (CL) approach for vehicle trajectory prediction is proposed in this paper. Then, inspired by brain science, a dynamic memory mechanism is developed by utilizing the measurement of traffic divergence between scenarios, which balances the performance and training efficiency of the proposed CL approach. Finally, datasets collected from different locations are used to design continual training and testing methods in experiments. Experimental results show that the proposed approach achieves consistently high prediction accuracy in continuous scenarios without re-training, which mitigates catastrophic forgetting compared to non-CL approaches. The implementation of the proposed approach is publicly available at https://github.com/BIT-Jack/D-GSM

Along with device miniaturization, severe heat accumulation at unexpected nanoscale hotspots attracts wide attentions and urges efficient thermal management. Heat convection is one of the important heat dissipating paths but its mechanism at nanoscale hotspots is still unclear. Here shows the first experimental investigation of the convective heat transfer coefficient at size-controllable nanoscale hotspots. A specially designed structure of a single layer graphene supported by gold nanorods (AuNRs) is proposed, in which the AuNRs generate plasmonic heating sources of the order of hundreds of nanometers under laser irradiation and the graphene layer works as a temperature probe in Raman thermometry. The determined convective heat transfer coefficient is found to be about three orders of magnitude higher than that of nature convection, when the simultaneous interfacial heat conduction and radiation are carefully evaluated. Heat convection thus accounts to more than half of the total energy transferred across the graphene/AuNRs interface. Both the plasmonic heating induced nanoscale hotspots and ballistic convection of gas molecules contribute to the enhanced heat convection. This work reveals the importance of heat convection at nanoscale hotspots to the accurate thermal design of miniaturized electronics, and further offers a new way to evaluate the convective heat transfer coefficient at nanoscale hotspots.

The performance and radiation tolerance of the proton detector based on MAPbBr3 perovskite single crystal are investigated here with 3MeV protons. The detector can monitor fluence rate and dose quantificationally at a low applied bias electric field(0.01$V/{\mu}m$) within a dose range of 45 kGy. The detector can also be worked at zero bias due to the Dember effect. The dark current of the detector reduced to 20% of the initial value after being irradiated with protons to a total fluence of $7.3\times 10^{13} p/cm^2$ (1 MGy), however, it can be recovered at room temperature within hours. These results suggest that this kind of detector has a promising application in proton therapy and proton imaging etc., Comment: 19 pages, 7 figures

Antimony sulfide (Sb2S3) and selenide (Sb2Se3) are emerging earth-abundant absorbers for photovoltaic applications. Solar cell performance depends strongly on charge carrier transport properties but these remain poorly understood in Sb2X3. Here we report band-like transport in Sb2X3 by investigating the electron-lattice interaction and theoretical limits of carrier mobility using first-principles density functional theory and Boltzmann transport calculations. We demonstrate that transport in Sb2X3 is governed by large polarons with moderate Fr\"ohlich coupling constants (~ 2), large polaron radii (extending over several unit cells) and high carrier mobility (an isotropic average of > 10 for both electrons and holes). The room temperature mobility is intrinsically limited by scattering from polar phonon modes and is further reduced in highly defective samples. Our study confirms that the performance of the Sb2X3 solar cells is not limited by intrinsic self-trapping.

The last decades have witnessed a rapid increase of Earth observation satellites (EOSs), leading to the increasing complexity of EOSs scheduling. On account of the widespread applications of large region observation, this paper aims to address the EOSs observation scheduling problem for large region targets. A rapid coverage calculation method employing a projection reference plane and a polygon clipping technique is first developed. We then formulate a nonlinear integer programming model for the scheduling problem, where the objective function is calculated based on the developed coverage calculation method. A greedy initialization-based resampling particle swarm optimization (GI-RPSO) algorithm is proposed to solve the model. The adopted greedy initialization strategy and particle resampling method contribute to generating efficient and effective solutions during the evolution process. In the end, extensive experiments are conducted to illustrate the effectiveness and reliability of the proposed method. Compared to the traditional particle swarm optimization and the widely used greedy algorithm, the proposed GI-RPSO can improve the scheduling result by 5.42% and 15.86%, respectively., Comment: This work has been submitted to IEEE TAES