1. Nucleation and growth of a quasicrystalline monolayer: Bi adsorption on the five-fold surface of i-Al70Pd21Mn9
- Author
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Smerdon, J. A., Parle, J. K., Wearing, L. H., Lograsso, T. A., Ross, A. R., and McGrath, R.
- Subjects
Condensed Matter - Other Condensed Matter - Abstract
Scanning tunnelling microscopy has been used to study the formation of a Bi monolayer deposited on the five-fold surface of i-Al70Pd21Mn9. Upon deposition of low sub-monolayer coverages, the nucleation of pentagonal clusters of Bi adatoms of edge length 4.9 A is observed. The clusters have a common orientation leading to a film with five-fold symmetry. By inspection of images where both the underlying surface and the Bi atoms are resolved, the pentagonal clusters are found to nucleate on pseudo-Mackay clusters truncated such that a Mn atom lies centrally in the surface plane. The density of these sites is sufficient to form a quasiperiodic framework, and subsequent adsorption of Bi atoms ultimately leads to the formation of a quasicrystalline monolayer. The initial nucleation site is different to that proposed on the basis of recent density functional theory calculations., Comment: 6 pages, 5 figures
- Published
- 2008
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