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Temperature-insensitive elastic modulus known as Elinvar effect is typically achievable in metastable titanium alloys only through thermomechanical processing. Here reports that a directly additively manufactured TiNb-based alloy exhibits Elinvar effect over a wide temperature range of 273 K. This is attributed to its α″+β dual-phase microstructure wherein both the elastic modulus and transition strain of the α″ phase increase monotonically with increasing temperature. The α″ phase was obtained by setting a base-plate temperature of 723 K to act as in-situ aging. This provides a new way to optimize mechanical and functional properties simultaneously by utilizing thermal fields of additive manufacturing.

Abstract Vascularization plays a significant role in promoting the expedited process of bone regeneration while also enhancing the stability and viability of artificial bone implants. Although titanium alloy scaffolds were designed to mimic the porous structure of human bone tissues to facilitate vascularization in bone repair, their biological inertness restricted their broader utilization. The unique attribute of Metal-organic framework (MOF) MIL-53(Fe), known as “breathing”, can facilitate the efficient adsorption of extracellular matrix proteins and thus provide the possibility for efficient interaction between scaffolds and cell adhesion molecules, which helps improve the bioactivity of the titanium alloy scaffolds. In this study, MIL-53(Fe) was synthesized in situ on the scaffold after hydrothermal treatment. The MIL-53(Fe) endowed the scaffold with superior protein absorption ability and preferable biocompatibility. The scaffolds have been shown to possess favorable osteogenesis and angiogenesis inducibility. It was indicated that MIL-53(Fe) modulated the mechanotransduction process of endothelial cells and induced increased cell stiffness by promoting the adsorption of adhesion-mediating extracellular matrix proteins to the scaffold, such as laminin, fibronectin, and perlecan et al., which contributed to the activation of the endothelial tip cell phenotype at sprouting angiogenesis. Therefore, this study effectively leveraged the intrinsic “breathing” properties of MIL-53 (Fe) to enhance the interaction between titanium alloy scaffolds and vascular endothelial cells, thereby facilitating the vascularization inducibility of the scaffold, particularly during the sprouting angiogenesis phase. This study indicates that MIL-53(Fe) coating represents a promising strategy to facilitate accelerated and sufficient vascularization and uncovers the scaffold-vessel interaction from a biomechanical perspective. Graphical Abstract

The ultra-fine grain Ti–6Al–4V alloy sheet was successfully achieved by friction stir processing (FSP). The low-temperature superplastic deformation mechanism of Ti–6Al–4V alloy under the strain rate of 3 × 10−4 s−1 at 600 °C was studied by scanning electron microscope, electron backscatter diffraction and superplastic tensile test. It is found that the grain size of Ti–6Al–4V alloy by FSP is refined from 7.48 μm to 0.82 μm, and there is no preferential crystallographic orientation of the uniform grain. After FSP, the β phase of the base material (BM) in the grain boundary is refined and homogenized. During the superplastic tensile processing, with the increase of strain, the grain is refined continuously, and the α→β phase transition is induced by the dislocations pile-up at the β grain boundary, and the content of β phase increases. The grain near the fracture was refined to 0.35 μm, and the stress concentration led to the formation of cavities near the β phase, which eventually caused the fracture. The dynamic recrystallization in superplastic tensile processing is mainly geometric dynamic recrystallization and discontinuous dynamic recrystallization. The elongation of superplastic tensile (1033%) is 19.7 times higher than that of BM (50%). The order of superplastic deformation mechanism in the low-temperature superplastic deformation of the ultra-fine grain Ti–6Al–4V alloy sheet is as follows: intragranular dislocation slip and diffusion, grain boundary sliding, and phase boundary sliding. Phase boundary sliding is the main deformation mechanism for low-temperature superplastic deformation.

Repair of large bone defects remains challenge for orthopedic clinical treatment. Porous titanium alloys have been widely fabricated by the additive manufacturing, which possess the elastic modulus close to that of human cortical bone, good osteoconductivity and osteointegration. However, insufficient bone regeneration and vascularization inside the porous titanium scaffolds severely limit their capability for repair of large-size bone defects. Therefore, it is crucially important to improve the osteogenic function and vascularization of the titanium scaffolds. Herein, methacrylated gelatin (GelMA) were incorporated with the porous Ti-24Nb-4Zr-8Sn (Ti2448) scaffolds prepared by the electron beam melting (EBM) method (Ti2448-GelMA). Besides, the deferoxamine (DFO) as an angiogenic agent was doped into the Ti2448-GelMA scaffold (Ti2448-GelMA/DFO), in order to promote vascularization. The results indicate that GelMA can fully infiltrate into the pores of Ti2448 scaffolds with porous cross-linked network (average pore size: 120.2 ± 25.1 μm). Ti2448-GelMA scaffolds facilitated the differentiation of MC3T3-E1 cells by promoting the ALP expression and mineralization, with the amount of calcium contents ∼2.5 times at day 14, compared with the Ti2448 scaffolds. Impressively, the number of vascular meshes for the Ti2448-GelMA/DFO group (∼7.2/mm2) was significantly higher than the control group (∼5.3/mm2) after cultivation for 9 h, demonstrating the excellent angiogenesis ability. The Ti2448-GelMA/DFO scaffolds also exhibited sustained release of DFO, with a cumulative release of 82.3% after 28 days. Therefore, Ti2448-GelMA/DFO scaffolds likely provide a new strategy to improve the osteogenesis and angiogenesis for repair of large bone defects.

Abstract The rock mass in fault zones is frequently subjected to cyclic loading and unloading during deep resource exploitation and tunnel excavation. Research on the mechanical and hydraulic characteristics of fault rock during the cyclic loading and unloading is of great significance for revealing the formation mechanism of water-conducting pathways in fault and preventing water inrush disasters. In this study, the mechanical and seepage tests of fault rock under the multi-stage cyclic loading and unloading of axial compression were carried out by using the fluid–solid coupling triaxial experimental device. The hysteresis loop of the stress–strain curve, peak strain rate, secant Young's modulus, and permeability of fault rock were obtained, and the evolution law of the dissipated energy of fault rock with the cyclic number of load and unloading was discussed. The experimental results show that with an increase in the cyclic number of loading and unloading, several changes occur. The hysteresis loop of the stress–strain curve of the fault rock shifts towards higher levels of strain. Additionally, both the peak strain rate and the secant Young's modulus of the fault rock increase, resulting in an increase in the secant Young's modulus of the fault rock mass. However, the growth rate of the secant Young's modulus gradually slows down with the increase of cyclic number of loading and unloading. The permeability evolution of fault rock under the multi-stage cyclic loading and unloading of axial compression can be divided into three stages: steady increase stage, cyclic decrease stage, and rapid increase stage. Besides, the calculation model of dissipated energy of fault rock considering the effective stress was established. The calculation results show that the relationship between the dissipated energy of fault rock and the cyclic number of loading and unloading conforms to an exponential function.

In order to investigate the temporal-spatial evolution properties of the water inrush disaster process of weakly cemented fault rock mass, a creep-erosion coupling water inrush model of weakly cemented fault rock mass is established. This model expands the equivalent continuum seepage theory, and a creep submodel and an erosion submodel are established respectively. The proposed creep submodel fully considers the mass conversion among materials, stress-strain and strain-porosity relationships. The proposed erosion submodel fully considers the mass conservation, particle migration and non-Darcy flow laws. According to the superposition principle of the mass conservation equations and three influence relationships (i.e., porosity-effective stress, porosity-creep material coefficient and creep strain-porosity-permeability relationships), the coupling between the submodels is realized, and the governing equations of the one-dimensional radial seepage direction coupling model are given. The solution conditions of the water inrush model are set, and the numerical computation method of the model in the temporal-spatial domain is established based on the COMSOL Multiphysics. By comparing the laboratory experimental results and the model calculation results of porosity evolution, the validity of the creep-erosion coupling model of weakly cemented surrounding rock is verified. On this basis, the temporal-spatial evolution law of the creep-erosion characteristics of weakly cemented surrounding rocks of the roadway is solved and analyzed. The calculated results show that in terms of the creep characteristics evolution, the effective stress decreases and the creep strain increases with time, and the samples exhibit the accelerated creep characteristics. The inhomogeneity of the spatial distribution of effective stress and creep strain increases with the creep-erosion coupling process. As for the evolution of the erosion characteristics, in the initial stage of the creep-erosion coupling process, the fine rock particles migrate out continuously under the effect of water flow, the volume fraction of fluidized particles, the permeability and flow velocity continuously increase, and new water-conducting channels are constantly formed in the weakly cemented rock mass. Subsequently, the erosion effect is weakened and finally stagnates due to the increasing creep effect. The closer to the inner wall of the roadway, the stronger the erosion effect. The spatial distribution of porosity and permeability after the stagnation of erosion shows obvious inhomogeneous characteristics, and the spatial distribution of water pressure presents a nonlinear-linear-nonlinear trend in the creep-erosion coupling process.

The significance of the osteogenesis-angiogenesis relationship in the healing process of bone defects has been increasingly emphasized in recent academic research. Surface topography plays a crucial role in guiding cellular behaviors. Metal-organic framework (MOF) is an innovative biomaterial with nanoscale structural and topological features, enabling the modulation of scaffold physicochemical properties. This study involved the loading of varying quantities of UiO-66 nanocrystals onto alkali-heat treated 3D-printed titanium scaffolds, resulting in the formation of hierarchical micro/nano topography named UiO-66/AHTs. The physicochemical properties of these scaffolds were subsequently characterized. Furthermore, the impact of these scaffolds on the osteogenic potential of BMSCs, the angiogenic potential of HUVECs, and their intercellular communication were investigated. The findings of this study indicated that 1/2UiO-66/AHT outperformed other groups in terms of osteogenic and angiogenic induction, as well as in promoting intercellular crosstalk by enhancing paracrine effects. These results suggest a promising biomimetic hierarchical topography design that facilitates the coupling of osteogenesis and angiogenesis.

Polarimetric synthetic aperture radar (SAR) provides an effective way to understand the physical properties of planetary surfaces. Rocks are the products of specific geological events, recording the evolution of impact craters on airless bodies. Multiple-scattered radar echoes from the surface or near-surface rocks generally exhibit high circular polarization ratio (CPR). In this article, we systematically investigate the relationship between radar CPR and rock abundance of lunar regolith using miniature radio frequency (Mini-RF) SAR data. A total of 51 craters with diameters of 11.8–200 km are selected for analysis. The mean values of Mini-RF CPR and Diviner rock abundance are calculated for the interior and exterior of each crater. Statistical results show a close correlation between Mini-RF CPR and Diviner rock abundance, where high radar CPR and Diviner rock abundance are observed at the blocky ejecta. However, we find the difference of mean CPR value between crater interior and exterior is smaller than that of Diviner rock abundance. This may be attributed to the near-surface rocks that contribute to radar CPR but are not considered in the inversion of Diviner rock abundance. Therefore, the concept of volumetric rock abundance is introduced, indicating the proportion of rocks with diameters larger than one-tenth of the radar wavelength within the detection area. A three-component CPR model is then developed to link radar CPR to volumetric rock abundance. Furthermore, an inverse power-law relationship between volumetric rock abundance and crater ages is discovered, which further indicates the feasibility of using SAR data to estimate rock abundance of lunar regolith.

Rolled static cracking agent (RSCA) can solve the intractable problem of traditional bulk static cracking agent (BSCA) in engineering applications. This paper innovatively studies the rational water-cement ratio of BSCA and the immersion soaking time of RSCA under the condition of controlling temperature. Through the expansion and cracking performance experiments, the development characteristics of expansion pressure, the cracking effect of the single-hole specimen and the performance of hole spraying prevention under the action of BSCA and RSCA were compared and analyzed. The results show that: (1) The volume growth rate of static cracking agent decreases with the increase of water-cement ratio, and the fluidity increases with the increase of water-cement ratio. The rational water-cement ratio for BSCA application is 0.3, and the rational immersion time of RSCA is 2–2.5 min; (2) Under the bore diameters of 30, 35, 40 and 45 mm, the expansion pressure of BSCA with a water-cement ratio of 0.3 is 38.2, 52.3, 61.5 and 68 MPa, and the expansion pressure of RSCA immersed in water for 2.5 min is 43.5, 58.8, 69.5 and 75.1 MPa, respectively. Among them, the development speed of expansion pressure of BSCA is higher than that of RSCA, and the arrival time of the peak expansion pressure of RSCA is 1.7 times that of BSCA; (3) The crack initiation speed of single-hole specimen under the action of RSCA is 10.3% lower than that under the action of BSCA, but the cracking speed of the former is 72.6% higher than that of the latter; (4) The hole spraying occurs in BSCA under the bore diameter of 50, 55 and 60 mm, while the hole spraying occurs in RSCA under the bore diameter of 60 mm. In terms of bore diameter, the hole spraying prevention of the RSCA is better than that of BSCA. The research results enrich the static blasting technology and provide data support and theoretical reference for field application.

The paper investigates the effect of tool eccentricity on the strain rate and microtextures produced in rapid-quenched AA6061 friction stir welds. Thermocouples are embedded in the tool and the thermal cycle are recorded via a data acquisition system. Stir zone grain refinement is observed in all samples, with the eccentric sample having the finest grains (3.18 μm). The strain rate is measured to be between 0.17 and 51.94 s−1, with the eccentric sample experiencing the highest strain rate. The pole figures indicate crystallographic textures shifted approximately 90° when tool eccentricity is employed. The aligned samples have a strong {11-2} B simple shear texture component, while the eccentric sample shows morphological changes towards a strong {11-1} A simple shear texture component.

This paper presents a coding scheme based on bilayer low-density parity-check (LDPC) codes for multi-level cell (MLC) NAND flash memory. The main feature of the proposed scheme is that it exploits the asymmetric properties of an MLC flash channel and stores the extra parity-check bits in the lower page, which are activated only after the decoding failure of the upper page. To further improve the performance of the error correction, a perturbation process based on the genetic algorithm (GA) is incorporated into the decoding process of the proposed coding scheme, which can convert uncorrectable read sequences into error-correctable regions of the corresponding decoding space by introducing GA-trained noises. The perturbation decoding process is particularly efficient at low program-and-erase (P/E) cycle regions. The simulation results suggest that the proposed bilayer LDPC coding scheme can extend the lifetime of MLC NAND flash memory up to 10,000 P/E cycles. The proposed scheme can achieve a better balance between performance and complexity than traditional single LDPC coding schemes. All of these findings indicate that the proposed coding scheme is suitable for practical purposes in MLC NAND flash memory.

Titanium alloy scaffolds with a porous structure have attracted much attention in bone defect repair. However, which pore structure is more beneficial to bone defect repair is controversial. In the present research, the Ti6Al4V alloy porous scaffolds with gradient pore sizes were designed and fabricated. The microstructure characterization, tests of mechanical properties, and in vitro and in vivo experiments have been performed to systematically evaluate the effect of pore size on osteoinduction and osteogenesis. The results revealed that the contact angle with water, compressive strength, and elastic modulus of the Ti6Al4V alloy porous scaffolds decreased gradually with the increase of pore size. However, there were obvious drops when the pore size of the porous scaffold was around 600 μm. As the pore size increased, the proliferation and integrin β1 of RAW 264.7 macrophages seeded on Ti6Al4V alloy porous scaffolds increased at first, reaching a maximum value at a pore size of around 600 μm, and then decreased subsequently. The proliferation, integrin β1, and osteogenic gene-related expressions of Bone marrow mesenchymal stem cells (BMSCs) seeded on Ti6Al4V alloy porous scaffolds with different pore sizes all exhibited similar variations which rose with increased pore size firstly, obtaining the maximum value at pore size about 600 μm, and then declined. The in vivo experiments confirmed the in vitro results, and the Ti6Al4V alloy porous scaffold with a pore size of 600 μm possessed the better capability to induce new bone formation. Therefore, for the design of Ti6Al4V alloy with a regular porous scaffold, the surface morphology, porosity, strength, and elastic modulus should be considered systematically, which would determine the capability of osteoinduction and osteogenesis.

In the present work, duplex stainless steels (DSSs) SAF2507 were friction stir processed with flowing cryogenic medium mixed with liquid nitrogen and industrial ethanol. Homogeneous ultrafine grained (UFG) dual-phase structure with ferrite (α) and austenite (γ) grains with average size of around 1 μm was obtained due to the significantly lower peak temperature and shorter high-temperature duration. The developed UFG dual-phase structure enabled a dramatic enhancement of yield strength by about 22 %, while maintaining a high elongation of 55 % owing to the excellent strain hardening capacity. The grain refinement and increased number of α/γ interfaces were dominantly responsible for the significantly improved YS, while the massive development of geometrically necessary dislocations around the deformation incompatible α/γ interfaces primarily contributed to improving the strain hardening capacity. As a result, the enhanced strength-ductility synergy was achieved by cryogenic friction stir processing. Also, the obtained UFG dual-phase structure helps with enhancing corrosion resistance. This work provides a new strategy for preparing uniform UFG DSSs with outstanding mechanical properties and anticorrosion.

In the traditional teaching, the lack of emotional education for students leads to emotional indifference between teachers and students and low teaching quality. In this paper, from the perspective of emotional education. In college physical education teaching, information sharing through the Internet is compared with traditional education in terms of timeliness of communication, integrity of emotional education, teacher-student relationship, and teaching quality. The results show that the timeliness of communication has increased by 9.3%, the integrity of education has increased by 30%, and the relationship between teachers and students has also been significantly improved. In terms of teaching quality, students are more satisfied, and the teaching quality has also been improved. It also shows that emotional education in the Internet sharing information environment can better help students improve their learning, improve their learning efficiency, and learn better in happiness. Emotional education in a shared information environment can better enrich teaching content and enhance students’ enthusiasm, which is of great significance.

Abstract The current investigation of refill friction stir spot welding (refill FSSW) Al alloy to copper primarily involved plunging the tool into bottom copper sheet to achieve both metallurgical and mechanical interfacial bonding. Compared to conventional FSSW and pinless FSSW, weld strength can be significantly improved by using this method. Nevertheless, tool wear is a critical issue during refill FSSW. In this study, defect-free Al/copper dissimilar welds were successfully fabricated using refill FSSW by only plunging the tool into top Al alloy sheet. Overall, two types of continuous and ultra-thin intermetallic compounds (IMCs) layers were identified at the whole Al/copper interface. Also, strong evidence of melting and resolidification was observed in the localized region. The peak temperature obtained at the center of Al/copper interface was 591 °C, and the heating rate reached up to 916 °C/s during the sleeve penetration phase. A softened weld region was produced via refill FSSW process, the hardness profile exhibited a W-shaped appearance along middle thickness of top Al alloy. The weld lap shear load was insensitive to the welding condition, whose scatter was rather small. The fracture path exclusively propagated along the IMCs layer of Cu9Al4 under the external lap shear loadings, both CuAl2 and Cu9Al4 were detected on the fractured surface on the copper side. This research indicated that acceptable weld strength can be achieved via pure metallurgical joining mechanism, which has significant potential for the industrial applications.

During the process of the airborne synthetic aperture radar (SAR) system platform in space, platform attitude deflection is inevitable. However, large attitude deflection angles are unacceptable for polarimetric calibration using point targets, especially the dihedral, which is very sensitive to the pointing angle of the radar. To mitigate the impact of attitude angles on calibration accuracy, attitude compensation of the corner reflector is necessary during the calibration process. The conventional approach to attitude compensation typically maps the three-dimensional attitude angle information to the one-dimensional polarimetric orientation angle (POA) information. However, the reduction of dimension inevitably results in information loss, leading to errors that affect calibration performance when the attitude angle is large. In order to ensure the accuracy of point target calibration, this paper proposes a novel point target compensation method based on the reflection theory of electromagnetic waves. This method is based on three-dimensional attitude angle information and has higher reliability than the POA method. Finally, this paper calculates the distance between the scattering matrices obtained after compensation based on the proposed method and the POA method to obtain the difference in the performance of the two methods. Through a simulation, this paper finds that when the attitude angle is small, the results of the two schemes are approximately the same, but as the attitude angle increases, the error between the two gradually increases. This suggests that the proposed method has greater advantages in the case of attitude deflection. Furthermore, the proposed method does not require additional information supplementation compared with the equivalent POA method, making it highly practical.

Polarimetric decomposition is an effective way for synthetic aperture radar (SAR) data interpretation. As for hybrid compact polarimetric (HCP) SAR, there are mainly two different types of decomposition methods, including wave-dichotomy-theorem-based and model-based. However, the existing methods are not universal because they cannot estimate volume scattering component accurately in different scenes. In order to solve this problem, a general two-stage model-based three-component HCP decomposition method (GTM) is proposed by involving Arii volume scattering model. In the first stage, a method is designed to identify the dominant scattering mechanism (surface, dihedral, and volume scattering mechanism) of each pixel according to the characteristics of the three scattering models. Then, the GTM method is solved when the three basic scattering mechanisms are dominant, respectively, in the second stage. Two simulated HCP datasets are used to verify the performance of the decomposition method. The results show that GTM can more accurately identify the dominant scattering mechanism in different regions than existing methods, and it can obtain closer results to the quad-polarimetric method.

In this article, five-component model-based decomposition methods of polarimetric synthetic aperture radar (PolSAR) (P5SD) and polarimetric synthetic aperture radar interferometry (PolInSAR) (PI5SD) using coupling scattering mechanisms are proposed. The target of these methods is to overcome the overestimation of volume scattering and to mitigate the mixed ambiguity of the scattering mechanism. First, coupling scattering models are proposed to decompose the coherency matrix into five submatrices. According to the traditional seven-component decomposition method proposed by Singh et al., the helix and mixed dipole can be merged into a coupling component, while the oriented dipole and compound dipole can also be generated in a general form. Then, the refined volume scattering models of PolSAR are introduced to characterize the volume scattering power of various land covers. The polarimetric interferometric similarity parameter (PISP) is introduced to modify the refined volume scattering models, and it can be used to further reduce the volume scattering contribution of building areas with large orientation angles. In addition, a feature named $\theta _{dv}$, total power, and PISP are embedded in the building area identification, and the building extraction results are used as the branch condition of the volume scattering model selection. In this article, the validity of P5SD and PI5SD can be demonstrated using airborne $L$-band E-SAR PolInSAR datasets and airborne $C$-band PolInSAR data collected by the Aerospace Information Research Institute, Chinese Academy of Sciences. The experimental results demonstrate that the P5SD and PI5SD can be used to effectively interpret the scattering characteristics of the ambiguous regions.

For large segmental bone defects, porous titanium scaffolds have some advantages, however, they lack electrical activity which hinders their further use. In this study, a barium titanate (BaTiO3) piezoelectric ceramic was used to modify the surface of a porous Ti6Al4V scaffold (pTi), which was characterized by scanning electron microscopy, energy dispersive spectroscopy, X-ray photoelectron spectroscopy, and roughness and water contact angle analyses. Low intensity pulsed ultrasound (LIPUS) was applied in vitro and in vivo study. The activity of bone marrow mesenchymal stem cells, including adhesion, proliferation, and gene expression, was significantly superior in the BaTiO3/pTi, pTi + LIPUS, and BaTiO3/pTi + LIPUS groups than in the pTi group. The activity was also higher in the BaTiO3/pTi + LIPUS group than in the BaTiO3/pTi and pTi + LIPUS groups. Additionally, micro-computed tomography, the mineral apposition rate, histomorphology, and the peak pull-out load showed that these scaffold conditions significantly enhanced osteogenesis and osseointegration 6 and 12 weeks after implantation in large segmental bone defects in the radius of rabbits compared with those resulting from the pTi condition. Consequently, the improved osteogenesis and osseointegration make the BaTiO3/pTi + LIPUS a promising method to promote bone regeneration in large segmental bone defects for clinical application.

Alumina-forming austenitic (AFA) steel is considered as a promising candidate used for advanced energy systems. Fusion welding of austenitic steels usually requires the introduction of a certain delta (δ) ferrite to avoid thermal cracking, but for the AFA steel, the presence of δ ferrite will greatly accelerate the precipitation of hard and brittle sigma (σ) phase at its target service temperature. In this work, for the AFA steel with a typical composition, we demonstrated a superior capability of friction stir welding (FSW) in avoiding the formation of δ and σ phases, and developing the favorable weld microstructures under various welding conditions. The microstructure evolution of AFA steel during FSW with various rotational speeds (300–700 rpm) was studied in detail. The resulting FSW joints all exhibit higher yield strength (YS) and ultimate tensile strength (UTS) than the base metal, especially at low rotational speed, while retaining reasonable ductility, despite decreasing with reducing rotational speed. The associated relationship between the microstructure and mechanical properties of the resulting FSW joints was well correlated. This work provides an effective method to obtain the fully-austenitic welded joints of AFA steel with excellent strength-ductility synergy.

In this work, a new technique of self-consumption friction plug spot welding (SFPSW) was introduced to spot welding of Ti–6Al–4V alloy sheets using a semi-consumable welding tool, and defect-free joints were successfully produced. The semi-consumable welding tool consists of a nickel-based superalloy shoulder and a titanium alloy plug. The spot welding parameters were discussed, and the effect of welding parameters on the microstructure and mechanical properties of the joints was investigated. The cross-section of the welding zone was divided into five regions: base metal (BM), heat-affected zone (HAZ), thermo-mechanically affected zone (TMAZ), stir zone (SZ), and filled zone (FZ). The final joint interface has a basket-weave structure. The maximum tensile-shear load of the joint was up to 69.5 kN and the hardness value of the welding region was lower than that of base metal. The failure mode of the tensile-shear test was a typical quasi-cleavage fracture.

The insufficient osteogenesis and osseointegration of porous titanium based scaffold limit its further application. Early angiogenesis is important for scaffold survival. It is necessary to develop a multifunctional surface on titanium scaffold with both osteogenic and angiogenic properties. In this study, a biofunctional magnesium coating is deposited on porous Ti6Al4V scaffold. For osseointegration and osteogenesis analysis, in vitro studies reveal that magnesium-coated Ti6Al4V co-culture with MC3T3-E1 cells can improve cell proliferation, adhesion, extracellular matrix (ECM) mineralization and ALP activity compared with bare Ti6Al4V cocultivation. Additionally, MC3T3-E1 cells cultured with magnesium-coated Ti6Al4V show significantly higher osteogenesis-related genes expression. In vivo studies including fluorochrome labeling, micro-computerized tomography and histological examination of magnesium-coated Ti6Al4V scaffold reveal that new bone regeneration is significantly increased in rabbits after implantation. For angiogenesis studies, magnesium-coated Ti6Al4V improve HUVECs proliferation, adhesion, tube formation, wound-healing and Transwell abilities. HUVECs cultured with magnesium-coated Ti6Al4V display significantly higher angiogenesis-related genes (HIF-1α and VEGF) expression. Microangiography analysis reveal that magnesium-coated Ti6Al4V scaffold can significantly enhance the blood vessel formation. This study enlarges the application scope of magnesium and provides an optional choice to the conventional porous Ti6Al4V scaffold with enhanced osteogenesis and angiogenesis for further orthopedic applications.

Abstract Cemented paste backfill (CPB), which is prepared by mixing tailings, binder and water, is widely used in underground mines for waste management and ground control. Since the CPB is delivered into mined-out areas in the form of fluid, a barricade needs to be constructed for retaining it during the process of its filling and hardening. Therefore, the barricade should have enough mechanical stability to ensure the safety of the backfill operation. The behavior of CPB, which is influenced by the thermal, hydraulic, mechanical and chemical (THMC) coupled processes, acts on the barricade and thus affects its mechanical response. In the present study, a numerical model is developed to predict and analyze the barricade mechanical performance in response to the coupled THMC behavior of CPB. The validity of the proposed model is then verified against two field case studies. Acceptable agreement between the model prediction results and in situ monitoring data proves the capability of the developed model in simulating the barricade pressure and displacement. Then, the validated model is used to investigate the effect of filling strategy on the barricade displacement. The obtained results can contribute to a better understanding of the barricade performance under various backfill conditions.

Previous studies have found that the novel low-elastic-modulus Ti2448 alloy can significantly reduce stress shielding and contribute to better bone repair than the conventional Ti6Al4V alloy. In this study, the promotion of osteogenesis and angiogenesis by three-dimensionally printed Ti2448 were also observed in vivo. However, these were not significant in a series of in vitro tests. The stiffness of materials has been reported to greatly affect the response of macrophages, and the immunological regulation mediated by macrophages directly determines the fate of bone implants. Therefore, we designed more experiments to explore the role of three-dimensionally printed Ti2448 in macrophage activation and related osteogenesis and angiogenesis. As expected, we found a significant increase in the number of M2 macrophages around Ti2448 implants, as well as better osteogenesis and angiogenesis in vivo. In vitro studies also showed that macrophages pre-treated with Ti2448 alloy significantly promoted angiogenesis and osteogenic differentiation through increased PDGF-BB and BMP-2 secretion, and the polarization of M2 macrophages was enhanced. We deduced that Ti2448 promotes angiogenesis and osteogenesis through Piezo1/YAP signaling axis-mediated macrophage polarization and related cytokine secretion. This research might provide insight into the biological properties of Ti2448 and provide a powerful theoretical supplement for the future application of three-dimensionally printed Ti2448 implants in orthopaedic surgery.

The Wishart mixture model is an effective tool for characterizing the statistical distribution of polarimetric synthetic aperture radar (PolSAR) data. However, due to the difficulty in determining the equivalent number of looks, the Wishart mixture model has some problems in terms of practicality. In addition, the flexibility of the Wishart mixture model needs to be improved for complicated scenes. To improve the practicality and flexibility, a new mixture model named the relaxed Wishart mixture model (RWMM) is proposed. In RWMM, the equivalent number of looks is no longer considered a constant for the whole PolSAR image but a variable that varies between different clusters. Next, an innovative algorithm named RWMM-Markov random field (RWMM-MRFt) for supervised classification is proposed. A new selection criterion for adaptive neighborhood systems is proposed in the algorithm to improve the classification performance. The new criterion makes effective use of PolSAR scattering information to select the most suitable neighborhood for each center pixel in PolSAR images. Three datasets, including one simulated image and two real PolSAR images, are utilized in the experiment. The maximum likelihood classification results demonstrate the flexibility of the proposed RWMM for modeling PolSAR data. The proposed selection criterion shows superior performance than the span-based selection criterion. Among the mixture model-based MRF classification algorithms, the proposed RWMM-MRFt algorithm has the highest classification accuracy, and the corresponding classification maps have better anti-noise performance.

This paper presents an online perturbed and directed neural-evolutionary (Online-PDNE) decoding algorithm for polar codes, in which the perturbation noise and online directed neuro-evolutionary noise sequences are sequentially added to the received sequence for re-decoding if the standard polar decoding fails. The new decoding algorithm converts uncorrectable received sequences into error-correcting regions of their decoding space for correct decoding by adding specific noises. To reduce the decoding complexity and delay, the PDNE decoding algorithm and sole neural-evolutionary (SNE) decoding algorithm for polar codes are further proposed, which provide a considerable tradeoff between the decoding performance and complexity by acquiring the neural-evolutionary noise in an offline manner. Numerical results suggest that our proposed decoding algorithms outperform the other conventional decoding algorithms. At high signal-to-noise ratio (SNR) region, the Online-PDNE decoding algorithm improves bit error rate (BER) performance by more than four orders of magnitude compared with the conventional simplified successive cancellation (SSC) decoding algorithm. Furthermore, in the mid-high SNR region, the average normalized complexity of the proposed algorithm is almost the same as that of the SSC decoding algorithm, while preserving the decoding performance gain.

Calibration using corner reflectors is an effective way to estimate the distortion parameters of hybrid compact polarimetric (HCP) synthetic aperture radar (SAR) systems. However, the existing literature lacks a discussion on the inconsistency of the amplitude and phase coefficients between measured scattering vectors of different corner reflectors. In response to this problem, this paper first proves that this inconsistency will seriously deteriorate the estimation accuracy of polarimetric distortion parameters. Based on the optimization algorithm, two calibration schemes for simultaneously estimating the traditional distortion parameters and the amplitude/phase coefficients are proposed while ignoring crosstalk (ICT) and considering crosstalk (CCT). In the process of distortion parameter estimation, the idea of “optimizing while compensating” is adopted to eliminate the problem of uneven echo intensity. Simulation results show that both schemes can eliminate the influence of the inconsistency of amplitude and phase coefficients, and estimate distortion parameters accurately. When the received crosstalk level is lower than −30 dB, the ICT scheme can accurately estimate polarimetric distortion parameters. The CCT scheme has a wider application range of crosstalk and can work well when the crosstalk level is lower than −20 dB, but it also has a higher requirement for the signal-to-clutter ratio (SCR). When SCR is greater than 35 dB, the CCT scheme yields higher estimation accuracy than the ICT scheme. In addition, the effectiveness of the calibration schemes is verified based on the L-band measured data acquired by the Aerospace Information Research Institute, Chinese Academy of Sciences.

The ash was removed before or after carbonization of potassium humate to investigate the effect of ash removal methods on pore structure and electrochemical performance of activated carbons for supercapacitors. The activated carbons were prepared by direct carbonization of potassium humate at 700 ℃ for 1 hour under N2 atmosphere with different de-ashing strategies. It was found that ash removal before carbonization was an effective strategy to reduce the ash content of the corresponding activated carbon. When de-ashing treatment was adopted after carbonization, part of the ash in activated carbon was coated with carbon and could not be removed through acid soaking. Moreover, ash removal before carbonization could better contribute to creating the micropores and the ash removed after carbonization performed as templates to mainly generate mesopores. The activated carbon with ash removed before carbonization as electrodes delivered a specific capacitance of 164.84 F/g at a current density of 50 mA/g, and exhibited typical electric double layer capacitive performance as well as lower leakage current of 15.3 µA.DOI: http://dx.doi.org/10.5755/j01.ms.24.3.18505

With the memory device is required to be widely used in more complex environment, the exploration of new memory device have become a focus of research. Herein, a resistive switching memory device based on BiFeO3(BFO)/Cu2ZnSnSe4(CZTSe) heterostructure is demonstrated, further the resistive switching characteristics of as-prepared device are characterized under different testing environments, suggesting an environmental factors controlled memory behavior is observed. Finally, we propose a new mechanism to explain the resistive switching effect based on the tunneling of interfacial carriers induced filament formation. This work demonstrates that the resistive switching memory device constructed by advanced semiconductor heterostructure display superior application value because they can work in complex environments. Keywords: Resistance switching, Heterojunction, BiFeO3, Cu2ZnSnSe4, Environmental factors, Memory device

Al/Mg dissimilar welds were successfully fabricated by refill friction stir spot welding using a grooved sleeve tool. Influences of sleeve penetration depth and rotational speed on the weld formation and mechanical performance were systematically evaluated in terms of welding parameter optimization, interfacial bonding mechanism, hardness distribution and welded joint strength. The results indicated that the success of joining Al alloy to Mg alloy significantly depends on tool sleeve penetration depth. The interfacial bonding mechanism compromised both metallurgical bonding and mechanical inter-locking. Intermetallic compound layers of Al3Mg2 and Al12Mg17 were formed at the Al/Mg interface. The thickness of the intermetallic compound (IMC) layer at the weld center increased from 20–30 μm to 40 μm when the rotational speed increased from 1000 to 2000 rpm. The minimum hardness was 80 HV in Al 7075 and 52 HV in ZEK 100; both were measured in the heat affected zone. The welded joint lap shear strength decreased, and the scatter increased with the increasing of rotation speed, whose maximum was 3.6 kN when the rotational speed was 1000 rpm. In addition, the failure mechanism was determined by tool rotational speed, and found to be interfacial failure under a rotational speed of 1000 rpm and nugget pullout under a rotational speed of 2000 rpm.

Soil salinization is a global problem, which seriously damages the ecological environment and considerably reduces agricultural productivity, especially in arid regions. Synthetic aperture radar (SAR) has been widely used in remote sensing due to its weather and sunlight independence. Polarimetric SAR has great potential for large-scale mapping and monitoring salt-affected soils. In this study, we investigate the characteristics of saline soil in extremely arid regions using dual-band quadrature-polarimetric (quad-pol) SAR images acquired by GF-3 (C-band) and ALOS-2 (L-band). Firstly, the effectiveness of the modified dielectric mixing model and integral equation model (IEM) in describing saline soil is evaluated. Secondly, the potential relationships between polarimetric parameters and salinity are discussed in both the C- and L-band, respectively, such as co-polarization ratio, scattering entropy H, and scattering angle α. Finally, a linear regression model for monitoring salt content is established. The main contributions of this article are as follows: (1) Simulation results suggest that the radar backscattering coefficient is a weak function of salinity at low water content, but our experimental data show that soil salinity significantly contributes to the radar backscattering coefficient, which indicates the modified dielectric mixing model and IEM model is not applicable in extremely arid areas. (2) A negative correlation between the co-polarization ratio and salinity is observed, and the correlation coefficients are 0.64 (C-band) and 0.71 (L-band). Besides, scattering entropy and scattering angle exhibit a positive correlation with salinity in the C-band with correlation coefficients 0.686 and 0.669, respectively, whereas a negative correlation is found in the L-band with correlation coefficients 0.682 and 0.680, respectively. This can be attributed to the different penetration depths and sensitivity to the surface roughness of the electromagnetic waves at two frequencies. (3) A regression model for salinity estimating based on radar backscattering coefficient, co-polarization ratio, and scattering entropy is established, with a determination coefficient (R2) of 0.79 and a root mean square error (RMSE) of 6.56%, allowing us to determine soil salinity from quad-pol SAR images without using backscattering models. Therefore, our results can be a reference for future soil salinity monitoring and inversion.