134 results on '"Whiteley, Mark W."'
Search Results
2. Synthesis of cyclopentadienyl iron alkoxycarbene complexes via vinylidene intermediates: X-ray structures of [Fe{C(OMe)Me}(dppe)Cp][I] and [Fe{C(CH2)3O}(dppe)Cp][PF6]
3. Electronic structure and spectroscopy of the cycloheptatrienyl molybdenum halide complexes [MoBrL2(η-C7H7)]n+ (L2 = 2CO, n = 0; L2 = 2,2′-bipyridyl, n = 0 or 1)
4. Synthesis and structure of the diynyl complexes [Mo(C [tbnd]CC [tbnd]CR)L 2(η-C 7H 7)], L 2 = chelate N- or P-donor ligand, R = SiMe 3 or H: X-ray crystal structures of [Mo(C [tbnd]CC [tbnd]CSiMe 3)(2,2′-bipyridine)(η-C 7H 7)] and [Mo(C [tbnd]CC [tbnd]CH)(Ph 2PCH 2CH 2PPh 2)(η-C 7H 7)]
5. Synthesis of the sterically crowded cycloheptatrienyl complexes [M(CO)(PPh 3) 2(η-C 7H 7)] + (M = Mo or W): X-ray crystal structures of [W(CO)(PPh 3) 2(η-C 7H 7)][BF 4] and [W(CO) 2(PPh 3)(η-C 7H 7)][BF 4] · CH 2Cl 2
6. Synthesis and reactions of cycloheptadienyl and cyclooctadienyl tungsten complexes: X-ray crystal structure of [W(CO) 2(PPh 3) 2(η 5-C 7H 9)][BF 4]
7. π-Complexes of Chromium, Molybdenum and Tungsten, Excluding those of Cyclopentadienyls and Arenes
8. Investigations on the trigonal twist process in the pseudooctahedral complexes [MX(CO) 2(PP)(η 3-R)] (M=Mo or W; X=halide or pseudohalide; PP=bidentate P-donor ligand; R=cycloheptatrienyl, cyclohexenyl or cyclooctenyl)
9. Iron versus Ruthenium: Clarifying the Electronic Differences between Prototypical Mixed-Valence Organometallic Butadiyndiyl Bridged Molecular Wires
10. Electronic structure and spectroscopy of the cycloheptatrienyl molybdenum halide complexes [MoBrL2(η-C7H7)]+ (L2= 2CO, n= 0; L2= 2,2′-bipyridyl, n= 0 or 1)
11. Synthesis and solvent induced halide exchange of the electron rich, half sandwich complexes [FeI(dppe)Cp] and [MoX(dppe)(η7-C7H7)] (X = Br, Cl; dppe = Ph2PCH2CH2PPh2)
12. Synthesis and redox chemistry of cycloheptatrienyl molybdenum carbon-chain complexes featuring diimine support ligands: [Mo{(CC)nCCR}(R′NCH–CHNR′)(η-C7H7)], (n = 0 or 1)
13. Synthesis, Redox Chemistry, and Electronic Structure of the Butadiynyl and Hexatriynyl Complexes [Mo{(C≡C)nC≡CR}(L2)(η-C7H7)]z+ (n = 1, 2; z = 0, 1; R = SiMe3, H; L2 = 2,2′-bipyridine, Ph2PCH2CH2PPh2)
14. Orbital Symmetry Control of Electronic Coupling in a Symmetrical, All-Carbon-Bridged “Mixed Valence” Compound: Synthesis, Spectroscopy, and Electronic Structure of [{Mo(dppe)(η-C7H7)}2(μ-C4)]n+ (n = 0, 1, or 2)
15. Spectroscopic Evidence for Redox Isomerism in the 1,4-Diethynylbenzene-Bridged Heterobimetallic Cation [{Fe(dppe)Cp*}(μ-C≡CC6H4C≡C){Mo(dppe)(η-C7H7)}]PF6
16. Synthesis, Redox Chemistry, and Electronic Structure of the Alkynyl Cyclopentadienyl Molybdenum Complexes [Mo(C≡CR)(CO)(L2)Cp′]n+ (n = 0 or 1; R = Ph or C6H4-4-Me, L2 = Ph2PCH2CH2PPh2 or 2PMe3, Cp′ = Cp or Cp*)
17. Synthesis, spectroscopy and electronic structure of the vinylidene and alkynyl complexes [W(CCHR)(dppe)(η-C7H7)]+and [W(CCR)(dppe)(η-C7H7)]n+(n = 0 or 1)
18. Molybdenum Complexes of C,C-Bis(ethynyl)carboranes: Design, Synthesis, and Study of a Weakly Coupled Mixed-Valence Compound
19. Spectroscopic Properties and Electronic Structure of the Cycloheptatrienyl Molybdenum Alkynyl Complexes [Mo(C≡CR)(Ph2PCH2CH2PPh2)(η-C7H7)]n+(n= 0 or 1; R =But, Fc, CO2Me, or C6H4-4-X, X = NH2, OMe, Me, H, CHO, CO2Me)
20. Metal-stabilised diynyl radicals: structure and reactivity of [Mo(CC–CCSiMe3)L2(η-C7H7)]˙+ (L2 = 2,2′-bipyridine or dppe)
21. Experimental observation of spin delocalisation onto the aryl-alkynyl ligand in the complexes [Mo(CCAr)(Ph2PCH2CH2PPh2)(η-C7H7)]+ (Ar = C6H5, C6H4-4-F; C7H7 = cycloheptatrienyl): an EPR and ENDOR investigation
22. Metallacumulenylidene Complexes in the Cycloheptatrienyl Molybdenum Series [Mo{(C)n═CR2}L2(η-C7H7)]+ (n = 0−2; L2 = P-Donor Ligand). X-ray Crystal Structures of [Mo{C═C(H)Ph}{P(OMe)3}2(η-C7H7)][BF4] and [Mo(C═C═CPh2)(dppe)(η-C7H7)][PF6] and DFT Investigation of Cumulenylidene Ligand Orientations
23. Synthesis and structure of the diynyl complexes [Mo(CCCCR)L2(η-C7H7)], L2=chelate N- or P-donor ligand, R=SiMe3 or H: X-ray crystal structures of [Mo(CCCCSiMe3)(2,2′-bipyridine)(η-C7H7)] and [Mo(CCCCH)(Ph2PCH2CH2PPh2)(η-C7H7)]
24. Synthesis of the sterically crowded cycloheptatrienyl complexes [M(CO)(PPh3)2(η-C7H7)]+ (M=Mo or W): X-ray crystal structures of [W(CO)(PPh3)2(η-C7H7)][BF4] and [W(CO)2(PPh3)(η-C7H7)][BF4]·CH2Cl2
25. Synthese eines Pentadecker-Sandwichkomplexes
26. Synthesis and reactions of cycloheptadienyl and cyclooctadienyl tungsten complexes: X-ray crystal structure of [W(CO)2(PPh3)2(η5-C7H9)][BF4]
27. Synthesis, structure and hapticity interconversion reactions of pentahapto-bonded cyclooctadienyl complexes of molybdenumElectronic supplementary information (ESI) available: 1H and 13C NMR data for [Mo(CO)2(L′)(L2)(η3-C8H11) 8a, 9a 11a, 12a, 3b, 8b, 9b, 10b, 11b, 12b. See http://www.rsc.org/suppdata/dt/b2/b209975f/
28. Synthesis and reactions of the cyclooctadienylmolybdenum complexes [MoBr(CO)2(NCMe)2(η3-C8H11)] (η3-C8H11 = 1–3-η:4,5-C8H11 or 1–3-η:5,6-C8H11)
29. Investigations on the trigonal twist process in the pseudooctahedral complexes [MX(CO)2(PP)(η3-R)] (M=Mo or W; X=halide or pseudohalide; PP=bidentate P-donor ligand; R=cycloheptatrienyl, cyclohexenyl or cyclooctenyl)
30. Synthesis, redox chemistry and EPR spectroscopy of the mixed-sandwich complexes (η-arene)(η-cycloheptatrienyl)metal(z+) (M = Cr or Mo; z = 1 or 2): crystal structures of the redox pair [Cr(η-C6H5Me)(η-C7H6C6H4Me-4)][PF6]n (n = 1 or 2)
31. Synthesis, redox properties, EPR and ENDOR spectroscopy of the 17-electron cycloheptatrienylmolybdenum complexes [MoX(Ph2PCH2CH2PPh2)(η-C7H7)]z+ (z = 1, X = I, Br, Cl, F, NCO, NCS, CN, 13CN, Me, CCPh; z = 2, X = NCMe, CNMe, 13CNMe, oxacyclopentylidene)
32. Reactions of the cycloheptatrienyl complexes [MX(CO)2(η-C7H7)] (M=Mo, X=Br; M=W, X=I) with CNBut: X-ray crystal structure of [WI(CO)2(CNBut)2(η3-C7H7)]
33. Investigations on the synthesis and stability of ν3-bonded cycloheptadienyl complexes of molybdenum
34. Synthesis and properties of the alkynyl-bridged heterobimetallics [Mo(CCFc)(Ph2PCH2CH2PPh2)(η-C7H7)]z(Fc = ferrocenyl, z = 0 or + 1)
35. Synthesis and X-ray crystal structures of the cyclic oxacarbene complexes (n = 1 or 2): boat conformation of the 2-oxacyclohexylidene ligand
36. Synthesis and reactivity of the cycloheptatrienyl-bridged bimetallic complexes [M(CO)3(μ-η6: η1-C7H7)M'(CO)2(η-C5R5)](M = Cr, Mo or W; M' = Fe or Ru; R = H or Me)
37. Cyclic oxacarbene complexes of the cycloheptatrienylmolybdenum auxiliary MoL2(η-C7H7), L = CO or P-donor ligand: isolation and subsequent cyclisation of a hydroxyvinylidene intermediate
38. η7→η3Hapticity interconversion in cycloheptatrienyl complexes of molybdenum and tungsten. Crystal structures of [Mo(NCS)(CO)2(C10H8N2)(η3-C7H7)] and [MoCl(CO)2(Ph2PCH2CH2PPh2)(η3-C7H6C6H4F-4)]
39. New class of mixed sandwich cycloheptatrienylchromium complex: crystal structures of the redox pair [Cr(η-C6H5Me)(η-C7H6C6H4Me-4)][PF6]n(n= 1 or 2)
40. Synthesis, structure and reactivity of bicycloheptatrienyl-bridged dimolybdenum complexes: crystal structure of [Mo2(CO)4(µ-I)(µ-η7: η7-C14H12)][PF6]
41. Dalton communications. Cyclooctadienyl complexes of molybdenum: synthesis and η5→η3hapticity interconversion
42. Vinylidene complexes of the molybdenum auxiliary Mo(Ph2PCH2CH2PPh2)(C7H7). Structural and spectroscopic investigations on vinylidene ligand orientation
43. η5↔η3Hapticity interconversion in cycloheptadienyl molybdenum complexes
44. Alkyl, aryl, vinyl, alkynyl and carbene derivatives of cycloheptatrienylmolybdenum complexes
45. Synthesis, Redox Chemistry,and Electronic Structure of the Butadiynyl and Hexatriynyl Complexes[Mo{(Cî¼C)nCî¼CR}(L2)(η-C7H7)]z(n= 1, 2; z= 0, 1; R= SiMe3, H; L2=...
46. The synthesis of ring-substituted cycloheptatrienyl complexes [M(CO)3(η7-C7H6R)]+ (M = Cr, Mo or W; R = Me, tBu, C6H4F-p or CCPh)
47. Synthesis, structure and reactivity of tri- and penta-hapto-bonded cycloheptadienyl complexes of molybdenum
48. Spectroscopic Properties and Electronic Structure of the Cycloheptatrienyl Molybdenum Alkynyl Complexes [Mo(CCR)(Ph2PCH2CH2PPh2)(η-C7H7)]n+ (n = 0 or 1; R =...
49. Heterometallic analogues of [{M(CO)2(η-C5H5)}2] (M = Fe, Ru, Os). The synthesis of the tetracarbonylcyclopentadienylcycloheptatrienyl complexes [M(CO)2(η-C5H5)M′(CO)2(η-C7H7)] (M = Fe, Ru; M′ = Mo, W). Crystal structures of [Ru(CO)2(η-C5H5Mo(CO)2(η-C7H7)] (RuMo) and [Mo(CO)3(μ-η6, η1-C7H7)Ru(CO)2(η-C5Me5)]
50. The chemistry of cycloheptatrienyl complexes of molybdenum and tungsten: ligand substitution via a ring slipped intermediate in cationic carbonylisonitrile derivatives
Catalog
Books, media, physical & digital resources
Discovery Service for Jio Institute Digital Library
For full access to our library's resources, please sign in.