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Anthocyanin plays an important role in wine color and quality. The anthocyanin concentration in grapes depends on the variety and is influenced by environmental factors, such as temperature, sunlight, soil, and grapevine practice. In this study, the anthocyanin profiles of two varieties, namely Cabernet Sauvignon and Merlot, from five regions (11 plots) in Xinjiang were examined. The climatic parameters performed noticeable difference between northern and southern of Xinjiang region. Result showed that northern of Xinjiang possessed the relatively lower humidity and higher average temperature in comparison with southern area. In addition, the total anthocyanin profiles of Cabernet sauvignon, which in Changji, Wushitala, Heshuo respectively, were higher than of other plots. This result might be caused by which those have relatively higher altitude than in other plots. For merlot, the higher anthocyanin concentrations performed in southern of Xinjiang, which could be contributed to the lower average temperature and higher relative humidity. Comparing Cabernet sauvignon and Merlot, the latter was easily affected by environment factors, and the anthocyanin composition and concentration of Merlot showed significant differences in different regions.

We report a facile and economical synthesis of α-fluoroacrylic acids via direct electrochemical defluorinative carboxylation of gem-difluoroalkenes with CO2. By using a platinum plate as the working cathode and a cheap nickel plate as the anode in a user-friendly undivided cell under constant current conditions, the reactions proceed smoothly under room temperature, without the use of expensive transition metal catalysts, ligands, external base or reductant, affording the desired adducts in up to 83% yield and 20:1 Z/E ratio, with good functional group tolerance. A cyclic voltammetry study was conducted and suggested a novel ECEC process.

Background Gibberellic acid (GA3 ), a plant-growth regulator, is often used to obtain enlarged table grape berries and induce seedlessness in them. However, the effects of GA3 on rachis elongation and bunch compactness have seldom been reported in wine-grape production. We assessed the effects of GA3 spraying on wine-grape inflorescences and bunches and their practical implications for viticulture in the Jiaodong Peninsula, China. Results Various GA3 concentrations were sprayed on field-grown Vitis vinifera L. 'Cabernet Franc' (CF) and 'Cabernet Sauvignon' (CS) grapevines before anthesis in the Jiaodong Peninsula, China, in 2015 and 2016. Inflorescence length during berry development was measured, and flavonoids and aroma compounds in the fruit were detected by high-performance liquid chromatography - mass spectrometry (HPLC-MS) and gas chromatography - mass spectrometry (GC-MS), respectively. For both cultivars, 50 and 100 mg L-1 GA3 caused significant elongation of the rachis, whereas there was no significant effect on inflorescence growth and berry seed number. Anthocyanin, flavonol, and flavan-3-ol levels in mature berries were not significantly influenced by GA3 spraying, whereas C13 -norisoprenoids were modified. Conclusion The application of 50-100 mg L-1 GA3 prior to grapevine anthesis caused elongation of inflorescences and bunches, and eased cluster compactness in CF and CS, and no negative effects were observed on the yield and seed numbers. The concentration and composition of flavonoids and most aroma compounds were not influenced, except that the norisoprenoids were increased by 50 mg L-1 GA3 applications. © 2020 Society of Chemical Industry.

An enantioselective carboxylative cyclization of propargylic alcohols and CO2 was realized under mild conditions, based on a kinetic resolution strategy, which enabled the synthesis of chiral cyclic carbonates and propargylic alcohols with promising yield and enantioselectivity simultaneously.

A comprehensive measurement of green economic efficiency in the Yellow River Delta region can provide a reference basis for achieving ecological protection and high-quality development. We constructed an evaluation system of green economic efficiency in counties based on multi-source remote sensing data. We adopted the Super-EBM model that considered non-expected output to make a comprehensive measurement of green economic efficiency in Yellow River Delta counties, used the kernel density function estimation method to portray the characteristics of spatial and temporal evolution, and finally used the system generalized moment estimation method to identify influen-cing factors. The results showed that the comprehensive efficiency and pure technical efficiency of the green economy in the Yellow River Delta counties showed a fluctuating upward trend from 2000 to 2015. The scale efficiency showed a rapid increase and then stayed stable in a 'Γ' type trend, while the increase in comprehensive efficiency transformed from being driven by scale-technology to being led by technology. The comprehensive efficiency and pure technical efficiency of the green economy in the Yellow River Delta counties showed an evolutionary trend from 'club convergence' to 'overall convergence', with the low efficiency counties formed a 'catch-up effect' on the high efficiency counties and the scale efficiency toward a balanced and smooth development. The comprehensive efficiency of green economy and its decomposition efficiency spatially formed a 'mountain' pattern, which was high in the middle, low in the two wings, and the high value area concentrated in the headland of the Yellow River Delta and along the coast of Laizhou Bay. The high-value area showed the characteristics of a northwest-southeast shift, and the east and west wings of the Yellow River Delta formed low-value subsidence areas. Industrial structure, population concentration level, and fixed asset investment intensity had positive effects on green economic efficiency, while population urbanization rate had negative effects on green economic efficiency. There was an obvious 'environmental Kuznets' effect between green economic efficiency and economic development level.综合测度黄河三角洲地区的绿色经济效率,可为实现黄河三角洲地区生态保护和高质量发展提供参考依据。本研究依托多源遥感数据构建了县域绿色经济效率评价体系,采用考虑非期望产出的Super-EBM模型对黄河三角洲县域绿色经济效率进行了综合测度,运用核密度函数估计等方法刻画了时空演变特征,最后利用系统广义矩估计法识别其影响因素。结果表明: 2000—2015年黄河三角洲县域绿色经济综合效率和纯技术效率呈现波动上升态势,规模效率呈快速提升后保持平稳的类“Γ”型趋势,综合效率的提升由规模-技术驱动向技术主导转变;黄河三角洲县域绿色经济综合效率和纯技术效率呈现由“俱乐部收敛”向“整体收敛”演进趋势,低效率县区对高效率县区形成“追赶效应”,规模效率趋向均衡平稳发展;绿色经济综合效率及其分解效率空间上形成中部高、两翼低的“山”字型格局,高值区集中于黄河三角洲岬角处和莱州湾沿岸,且高值区呈西北-东南向偏移的特征,黄河三角洲东西两翼形成低值塌陷区;产业结构、人口集聚水平、固定资产投资强度对绿色经济效率具有正向影响,人口城镇化率对绿色经济效率具有负向作用,绿色经济效率与经济发展水平之间存在明显的“环境库兹涅茨”效应。.

An unprecedented γ-carboxylation of α-CF3 alkenes with CO2 is reported. This approach constitutes a rare example of using electrochemical methods to achieve regioselectivity complementary to conventional metal catalysis. Accordingly, using platinum plate as both a working cathode and a nonsacrificial anode in a user-friendly undivided cell under constant current conditions, the γ-carboxylation provides efficient access to vinylacetic acids bearing a gem-difluoroalkene moiety from a broad range of substrates. The synthetic utility is further demonstrated by gram-scale synthesis and elaboration to several value-added products. Cyclic voltammetry and density functional theory calculations were performed to provide mechanistic insights into the reaction.

The ripeness of a grape is critical to berry composition and to the resultant wine. For wineries with a single cultivar occupying an extensive area, the total soluble solid of grapes can range from 22°Brix to 28°Brix. Accordingly, the influence of different harvest dates (ripeness) on berry compositions and on the resultant wine profile was investigated for Vitis vinifera L. cv. ‘Cabernet Sauvignon.’ Berry dehydration was observed as berry weight and juice yields decreased. Berry anthocyanins were concentrated and methylated anthocyanin levels fluctuated with increasing delays in harvesting. Hexanal and 2-hexenal levels in must decreased significantly as berries ripened. In the resultant wines, 2,3-butanediol levels increased. Wines harvested earlier were lighter, presented lower color intensity (CI) values and higher yellow% levels, and exhibited richer aroma profiles (compounds). Through a principal component analysis and discriminant analysis, the compounds characterizing each harvest date were identified.

An unprecedented γ-carboxylation of α-CF3 alkenes with CO2 is reported. This approach constitutes a rare example of using electrochemical methods to achieve regioselectivity complementary to conventional metal catalysis. Accordingly, using platinum plate as both a working cathode and a nonsacrificial anode in a user-friendly undivided cell under constant current conditions, the γ-carboxylation provides efficient access to vinylacetic acids bearing a gem-difluoroalkene moiety from a broad range of substrates. The synthetic utility is further demonstrated by gram-scale synthesis and elaboration to several value-added products. Cyclic voltammetry and density functional theory calculations were performed to provide mechanistic insights into the reaction., A γ-carboxylation of α-CF3 alkenes with CO2 using platinum plate as both working cathode and nonsacrificial anode has been developed.

Vineyard row orientation plays a critical role in determining cluster microclimate. This study aimed to figure out how cluster positions determined by vineyard row orientation affect grape flavonoids and aroma profiles of Cabernet Sauvignon and Italian Riesling grapes. Three cluster positions (two canopy sides and the inner canopy) of NS and EW oriented row Cabernet Sauvignon and NS oriented row Italian Riesling were selected for the experiment. Microclimate data was monitored around clusters from both canopy sides of different row orientations. The south canopy side had higher daytime temperatures and PAR than the north canopy side in EW row orientation. Flavonoids of grape skins and seeds were separated and determined by LC-MS, and aroma compounds of grape must were determined by GC-MS. Results showed that flavanols were affected by orientations, and EW orientation had higher berries skin flavanol concentration than NS orientation. EW-IN berries had fewer glucuronide form flavonols and 3'-hydroxylated flavonols than the other two positions in EW orientation. Inner canopy berries had lower flavonol concentration than other positions in EW orientation of CS and NS orientation of IR. To aromas, C6/C9 were the main compounds significantly affected by row orientations. EW orientation berries had higher C6 alcohols concentration such as (E)-3-Hexen-1-ol, (E)-2-Hexen-1-ol and (Z)-3-Hexen-1-ol than NS orientation, while NS orientation berries had higher C6 aldehyde concentrations such as Hexanal and (E)-2-hexenal than EW orientation. EW-IN berries had more abundant C6/C9 compounds than the other two positions. The study provided preliminary scientific evidence for vineyard viticulture practice and harvest strategy.

In this study, black geotextile inter-row mulch, a weed control practice, was applied under a semi-arid climate to attenuate solar reflection in 2015-2017, and it concurrently increased soil temperature and fruit-zone high temperature duration and decreased low temperature duration. Inter-row mulch decreased anthocyanins concentrations in grapes in 2015-2016, and consistently inhibited flavonols accumulation in 2015-2017. Correlation analysis between microclimate parameters and flavonoids concentrations reflected the importance of solar reflection, fruit-zone high and low temperature duration, heat accumulation and soil temperature to flavonoids accumulation. Basal leaf removal, a widely applied practice to increase fruit-zone light exposure, was applied to mulch-treated grapevines to investigate if increasing incident light could mitigate the impact of inter-row mulch on flavonoids, and it had limited influence on anthocyanins whereas compensated the loss of flavonols in grapes caused by inter-row mulch. Notably, inter-row mulch wines showed less red and more yellow color than controls because of lower anthocyanins concentrations.

We report a facile and economical synthesis of α-fluoroacrylic acids via direct electrochemical defluorinative carboxylation of

Herein, we report that 1,3-diphenylguanidine (DPG) could be utilized for the carboxylative cyclization of homopropargyl amines with CO2 under ambient temperature and pressure, in combination with AgSbF6, which enabled the synthesis of both chiral and achiral 2-oxazinones efficiently. A mechanistic study revealed that the multi-functionality of DPG is critical to the success of the reaction.

We report the copper-catalyzed defluorinative carboxylation of gem-difluoroalkenes with CO2. Using cheap and easily available CuI as the catalyst and bis(pinacolatodiboron) as the stoichiometric reductant, the reaction efficiently converts the alkenyl C–F bond to a carboxyl group with complete retention of stereochemistry, thus providing fluoroalkenyl carboxylic acids in good to excellent yields.

Background and Aims Yan73 and Kolor are Vitis vinifera grape cultivars with both red skin and red pulp. The aim of the present work was to determine the distribution of flavonoid compounds in the skin, pulp and seed, as well as the aromatic composition of the whole berry. Methods and Results Anthocyanin and flavonol were extracted from grape skin and pulp, while proanthocyanidin was isolated from skin, pulp and seeds; individual anthocyanins, flavonols and proanthocyanidins were then separated and determined by LC/MS. Anthocyanin was dominated by malvidin derivatives in the skin and by peonidin derivatives in the pulp. The distribution of flavonols in the skin and pulp of the two cultivars showed no consistent trend. Proanthocyanidins were unequally distributed in the skin, pulp and seeds. Proanthocyanidin content, composition and mean degree of polymerisation varied distinctly in the three tissues, especially the profile of the proanthocyanidin terminal and extension subunits. Yan73 and Kolor contained similar aroma compounds, both in free form and as glycosidically bound precursors, as determined by GC/MS, but their content varied significantly. Conclusions Flavonoid compounds were asymmetrically distributed in the skin, pulp and seeds. Epicatechin was the common predominant extension subunit in the three tissues, while epigallocatechin, catechin and epicatechin‐3‐O‐gallate were the characteristic extension subunits of the skin, pulp and seeds, respectively. Kolor accumulated more C6 aldehydes in the free fraction and more alcohols in bound fraction, while Yan73 was characterised by a higher content of terpenes. Significance of the Study The results define the distribution of flavonoid compounds in two teinturier cultivars.

We report a tandem asymmetric aldehyde–alkyne–amine (A3) coupling-carboxylative cyclization sequence for the highly enantioselective synthesis of chiral N-aryl 2-oxazolidinones. This is a rare example of a multicatalyst-promoted asymmetric tandem reaction using CO2 as a C1 synthon. Notably, the copper species and ligand from the upstream A3 reaction are internally reused to facilitate the downstream silver-catalyzed carboxylative cyclization.

We report a general and highly efficient Mukaiyama-aldol reaction of ketones and difluoroenoxysilanes. While the reaction of aryl ketones worked efficiently in the presence of Bi(OTf) 3 , that of aliphatic ketones required the use of Sc(OTf) 3 . In addition, Sc(OTf) 3 was capable of achieving excellent 1,2-selectivity in the corresponding reaction of α,β-unsaturated ketones. This method provides a facile access to differently substituted β-hydroxy α,α-difluoro ketones, versatile synthons for difluomethylated tertiary alcohols.

Firefighters often need to complete combat missions in dark environments, such as finding trapped people, exploring unknown rooms and forming corresponding internal fire maps. The judgment of spatial orientation is especially important in these tasks because it can be effectively optimized. Rescue strategy to improve the personal protection level of firefighters. Therefore. this study conducted a 2 × 2 × 2×3 inter-group experiment on the spatial orientation of firefighters in a dark environment based on posture, personnel composition, difficulty level of the scene and memory demand level. The subject needs to pass through the 5 × 14 rectangular space clockwise along the wall and stop at the measurement points on the other three sides except the side of the departure position. The direction judgment is performed by measuring the oral report angle of the subject and the actual arm pointing angle. The posture is divided into upright and half-turn. The composition of the personnel is divided into one person and two people. Scene difficulty is divided into simple and complex. A complicated and simple way to distinguish is to increase the edge of the scene by placing obstacles on the corners of the rectangle. The memory requirement level is divided into three levels: low, medium, and high. The experimental results show that the complexity of the scene significantly affects the azimuth backlash error of the subject, the complex scene error is higher, and the simple scene error is lower. The composition of the personnel greatly affected the azimuth adaptation error. In the case of a group of 2 people, the orientation judgment error is lower. The level of posture and memory requirements did not significantly affect the azimuth anaphora error. The results of this study can provide a reference for firefighters in space cognitive design.

Herein, we report that 1,3-diphenylguanidine (DPG) could be utilized for the carboxylative cyclization of homopropargyl amines with CO2 under ambient temperature and pressure, in combination with AgSbF6, which enabled the synthesis of both chiral and achiral 2-oxazinones efficiently. A mechanistic study revealed that the multi-functionality of DPG is critical to the success of the reaction.

Gibberellic acid (GAVarious GAThe application of 50-100 mg L

Sunlight conditions around grape clusters vary with their positions, and can have a significant effect on grape berry compounds. This study investigated the influence of cluster positions in the canopy (interior and two exterior canopy sides) and vineyard row orientation (north–south and east–west) on flavonoid and volatile compound profiles of Vitis vinifera L. cvs ‘Cabernet franc’ (CF) and ‘Chardonnay’ (CH) berries in two consecutive years. The experimental vineyard was located in Jiaodong Peninsula of China, which is characterized by a temperate monsoon-type climate and relatively short sunlight duration. Clusters located in the interior of the canopy received less sunlight irradiation than the exterior positions, and the average temperature around clusters located in different positions differed slightly. The results showed that over two years, the positions of clusters in the canopy had no consistent impact on cluster weight, berry weight, juice total soluble solids or titratable acidity for either cultivar. For both cultivars, the interior clusters had lower total flavonol concentrations than the exterior clusters, while the position of clusters in the canopy had no major impacts on the composition of anthocyanins and flavan-3-ols. The volatile compounds were somewhat influenced by the positions of clusters in the canopy, while some bound norisoprenoids and terpenoids had lower levels in interior clusters than in exterior clusters. These results will help winegrowers make decisions regarding harvest strategies.

We report the activation of (salen)CoI complex 3g by a phosphorane to form a bifunctional catalyst for the reaction of carbon dioxide with terminal epoxides or aziridines at ambient temperature and 1 bar carbon dioxide pressure. Only 1.0 mol% of both (salen)CoI 3g and phosphorane 4d are required for cyclic carbonate synthesis, and the catalyst loading could even be lowered down to 0.1 mol%. Under these conditions, no polycarbonate formation is detected by NMR analysis. It is proposed that the high efficiency originates from the activation of (salen)CoI by a phosphorane to form a phosphorane–salen Co(III) complex with enhanced Lewis acidity for the electrophilic activation while generating an iodide anion as a Lewis base co-catalyst to facilitate the ring-opening of epoxides. Further investigation revealed that the phosphorane–(salen)CoI complex could also successfully catalyze the coupling of CO2 with aziridines under ambient conditions at a catalyst loading of 2.5 mol%.

In this study, fruit-zone microclimate was modified by three treatments, including inter-row mulch (M), the combination of leaf removal applied at the onset of veraison and inter-row mulch (MLR-BV), and the combination of leaf removal applied at complete veraison and inter-row mulch (MLR-EV), in a semi-arid climate in three consecutive years (2015–2017). M decreased fruit-zone reflected solar radiation from vineyard floor and low temperature (10–20 °C) duration, whereas it increased soil temperature and high temperature (> 30 °C) duration. MLR-BV and MLR-EV increased fruit-zone incident photosynthetically active radiation while decreased the duration of 20–25 °C compared to M. Notably, M significantly decreased grape total norisoprenoid concentrations in 2015–2017, and total terpenoid concentrations in 2015–2016. Applying leaf removal applied at the onset of veraison could compensate the decreases of total norisoprenoids and terpenoids caused by M when two treatments were applied together. Besides, M significantly increased grape total C6/C9 compound concentrations, besides, (Z)-3-hexen-1-ol concentrations were significantly higher in grapes of M than those of MLR-BV in 2015–2017. Light exposure and high temperature duration after veraison had strong positive correlations with total norisoprenoids and terpenoids, besides, low temperature duration was positively correlated with total norisoprenoids. In addition, light exposure after veraison had strong negative correlations with total C6/C9 compounds. With respect to the volatile compounds in wines, M significantly decreased the concentrations of isopentanol and ethyl acetate, and the concentrations of ethyl cinnamate, phenylacetaldehyde, phenylethyl alcohol and 3-methylthio-1-propanol were significantly lower in MLR-BV and MLR-EV than in M. The outcome of this study can assist winegrowers to properly adjust vineyard managements to optimize the concentrations of desired volatile compounds in grapes and wines.

Differences in key odor-active volatile compounds among the head, heart, and tail fractions of freshly distilled spirits from Spine grape (Vitis davidii Foex) wine were identified for the first time by gas chromatography–olfactometry and gas chromatography-mass spectrometry. Results from aroma extract dilution analysis (AEDA) showed that there were 34, 45, and 37 odor-active compounds in the head, heart and tail fractions, respectively. Besides, 20, 22, and 17 quantified compounds, respectively, showed odor activity values (OAVs) > 1. The head fraction was characterized by fruity, fusel/solvent notes owing to higher concentrations of higher alcohols and esters, while the tail fraction had more intense smoky/animal, sweaty/fatty attributes due to higher concentrations of volatile phenols and fatty acids. Finally, the heart fraction was characterized by ethyl octanoate, ethyl hexanoate, ethyl 3-phenylpropanoate, ethyl cinnamate, isoamyl alcohol, guaiacol, 4-ethylguaiacol, 4-vinylguaiacol, 2,3-butanedione, and (E)-β-damascenone. Furthermore, observation of the distillation progress indicated that different volatiles with various boiling points and solubilities followed diverse distillation patterns: concentrations of most esters, higher alcohols, terpenes and C13-norisoprenoids decreased, while concentrations of volatile phenols, fatty acids and some aromatic compounds increased during distillation. As a result, their final concentrations in the three distillate fractions varied significantly.

Objective: The objective of this paper is to review the literature on the processes by which individuals respond to fires in order to identify the decision-making process between fire risk perception and evacuation behaviors.

In view of the needs of personnel behavior research in fire scenarios, a virtual experimental platform is set up to conduct research on personnel behavior in fire sites. The fire scenario is divided into two aspects: static and dynamic. In static aspect, the artistry and repeatability of the building are constructed by modeling software. In the aspect of dynamics, the change of building structure is realized by unity3D software, and the influence of structural change on Wayfinding Behavior is shown. It is intended to pave the way for the experimental platform for the study of personnel behavior in the subsequent fire field.

To investigate the microRNA (miRNA) expression in plasma of patients with aGVHD and without aGVHD after allo-hematopoietic stem cell transplantation (allo-HSCT).The miRNAs (miR-423, mirR199a-3p, miR93*, miR377) expression levels in peripheral blood plasma of 25 patients before and after allo-HSCT were detected by real-time PCR.miR-423, miR199a-3p and miR-93* in aGVHD group were significantly upregulated (P0.05); miR-377 expression was not significantly different between aGVHD and non-aGVHD (P0.05).The expression of miR-423, miR-199a-3p, miR-93* are upregulated in aGVHD group, which can be used as biomarkes to monitor and to diagnose aGVHD.

Physical and chemical insult-induced bone marrow (BM) damage often leads to lethality resulting from the depletion of hematopoietic stem and progenitor cells (HSPCs) and/or a deteriorated BM stroma. Notch signaling plays an important role in hematopoiesis, but whether it is involved in BM damage remains unclear. In this study, we found that conditional disruption of RBP-J, the transcription factor of canonical Notch signaling, increased irradiation sensitivity in mice. Activation of Notch signaling with the endothelial cell (EC)-targeted soluble Dll1 Notch ligand mD1R promoted BM recovery after irradiation. mD1R treatment resulted in a significant increase in myeloid progenitors and monocytes in the BM, spleen and peripheral blood after irradiation. mD1R also enhanced hematopoiesis in mice treated with cyclophosphamide, a chemotherapeutic drug that induces BM suppression. Mechanistically, mD1R increased the proliferation and reduced the apoptosis of myeloid cells in the BM after irradiation. The β chain cytokine receptor Csf2rb2 was identified as a downstream molecule of Notch signaling in hematopoietic cells. mD1R improved hematopoietic recovery through up-regulation of the hematopoietic expression of Csf2rb2. Our findings reveal the role of Notch signaling in irradiation- and drug-induced BM suppression and establish a new potential therapy of BM- and myelo-suppression induced by radiotherapy and chemotherapy.

Rootstocks are widely used in viticulture due to their resistance to biotic and abiotic stress. Additionally, rootstocks can affect vine growth and berry quality. This study evaluated the effects of eight rootstocks (101-14, 110R, 5A, 5BB, Ganzin 1, Harmony, Riparia Gloire, and SO4) on the vine growth, berry ripening, and flavonoids and aromatic profiles of Cabernet Sauvignon in two consecutive seasons (2015&ndash, 2016). With few exceptions, minor differences were observed among grafted and own-rooted vines. Own-rooted vines produced the least pruning weight but the highest yield. 101-14, 5BB, and SO4 slightly reduced total soluble solids, but increased acidity, showing tendencies for retarding maturation. Ganzin 1 inhibited the accumulation of flavan-3-ols in berry skins. Furthermore, concentrations and proportions of epicatechin-3-O-galate were decreased by rootstocks, except for 110R. 5A, Harmony, and Riparia Gloire enhanced flavonol concentrations. SO4 slightly decreased most of the individual anthocyanin concentrations. With respect to volatile compounds, 110R, Riparia Gloire, and SO4 induced reductions in concentrations of total esters, whilst 101-14, Ganzin 1, 110R, and 5BB led to increases in the concentrations of C13-norisoprenoids. Therefore, with respect to the negative effects of SO4 on berry ripening and the accumulation of anthocyanin and volatile esters, SO4 is not recommended in practice.