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Three coordination polymers [ZnL4Cl2]n(1), [(AgL2·NO3)2]n(2), [CuL4·2NO3]n(3) (L = uniconazole) have been synthesised and structurally characterized by element analysis, infrared spectra and X-ray crystal diffraction. Complex 1 is the triclinic system, space group P-1 with a = 8.9407(10) A, b = 13.2994(15) A, c = 14.9242(17) A, α = 93.8180(10)°, β = 99.0250(10)°, γ = 104.7690(10)°, V = 1684.1(3) A3. Complex 2 is the Triclinic system, space group P-1 with a = 8.997(3) A, b = 16.941(5) A, c = 24.113(7) A, α = 89.182(4)°, β = 86.440(4)°, γ = 86.440(4)°, V = 3483.0(19) A3. Complex 3 is the triclinic system, space group P-1 with a = 8.7387(5) A, b = 13.4087(8) A, c = 15.4353(9) A, α = 87.8870(10)°, β = 80.7150(10)°, γ = 71.3930(10)°, V = 1691.42(17) A3. In 1 and 3, Each six-coordinated Zn(II), Cu(II) ions adopts a distorted octahedral geometry. 1 and 3 was linked into a one dimensional chain by intermolecular hydrogen bonds. But in 2, each Ag(I) ion is two-coordinated in a linear mode. Althought there is many intermolecular hydrogen bonds, but the complex is zero dimensional. Three new coordination polymers [ZnL4Cl2]n(1), [(AgL2·NO3)2]n(2), [CuL4·2NO3]n(3) (L = uniconazole) have been synthesised and structurally characterized by element analysis, infrared spectra and X-ray crystal diffraction.

Two coordination polymers [Ag(HIMPAA)(IMPAA)] n (1), [Cu(HIMPAA)(IMPAA)Cl] n (2), (HIMPAA = (2E)-3-[4-(1H-imidazol-1-ylmethyl)phenyl]acrylic acid) have been synthesised with ozagrel and structurally characterized by element analysis, infrared spectra (IR), PXRD and X-ray crystal diffraction. Complex 1 is the monoclinic system, space group P21/c with a = 10.897(3) A, b = 6.1624(14) A, c = 19.274(4) A, α = 90.00°, β = 113.13°, γ = 90.00°, V = 1190.2(5) A3, Z = 2. In complex 1, the Ag(I) atom is two-coordinated in a linear mode. Intermolecular O–H···O hydrogen bonds links 1 to generate one-dimensional hydrogen bonds chain. Complex 2 is the monoclinic system, space group C2/c with a = 22.742(7) A, b = 13.829(4) A, c = 7.918(2) A, α = 90.00°, β = 97.10°, γ = 90.00°, V = 2471.1(12) A3, Z = 4. In complex 2, four HIMPAA and four Cu(II) ions forms a novel 52-membered macrocycle [Cu4(IMPAA)4]4+. The 52-membered macrocycle is further briged by HIMPAA to form a two-dimensional network. A one-dimensional coordination polymers [Ag(HIMPAA)(IMPAA)] n (1) and a two-dimensional network [Cu(HIMPAA)(IMPAA)Cl] n (2), (HIMPAA = (2E)-3-[4-(1H-imidazol-1-ylmethyl)phenyl] acrylic acid) were synthesised with ozagrel and structurally characterized by element analysis, IR, PXRD and X-ray crystal diffraction.

C15H15NO3, triclinic, P1 (no. 2), a = 10.428(1) A, b = 11.996(1) A, c = 22.421(2) A, & = 82.167(2)°, % = 81.538(2)°, ! = 74.196(2)°, V = 2655.7 A, Z = 8, Rgt(F) = 0.0640, wRref(F ) = 0.1529, T = 298 K.

C37H52O4, orthorhombic, P212121 (no. 19), a = 11.1018(9) A, b = 12.434(1) A, c = 22.860(2) A, V = 3155.7 A, Z = 4, Rgt(F) = 0.0351, wRref(F ) = 0.0922, T = 296 K.

This study is to investigate the effect of diet and gene on blood-fat trait of the individual mouse. One hundred and twenty mice were fed with high fat emulsion for 4 weeks. Then the genotypes of Glut-4 were analyzed by PCR-SSCP to investigate the effect on blood-fat traits and some organ performance of mice. After fed with high fat emulsion for 4 weeks, 98 mice suffered from hyperlipidemia, while 22 mice did not. And a T/A mutation was found in 188 targeted fragments we amplified at 8,521 site, and association analysis showed that the mice carried BB genotype had higher TC, TG and LW/BW level than those of the mice with AA genotype (P0.05). Different Glut-4 genotypes show different sensitivities to high fat emulsion on mice.