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Mutations in the human AAA-ATPase VPS4 isoform, VPS4A, cause severe neurodevelopmental defects and congenital dyserythropoietic anemia (CDA). VPS4 is a crucial component of the endosomal sorting complex required for transport (ESCRT) system, which drives membrane remodeling in numerous cellular processes, including receptor degradation, cell division, and neural pruning. Notably, while most organisms encode for a single VPS4 gene, human cells have 2 VPS4 paralogs, namely VPS4A and VPS4B, but the functional differences between these paralogs is mostly unknown. Here, we set out to investigate the role of the human VPS4 paralogs in cytokinetic abscission using a series of knockout cell lines. We found that VPS4A and VPS4B hold both overlapping and distinct roles in abscission. VPS4A depletion resulted in a more severe abscission delay than VPS4B and was found to be involved in earlier stages of abscission. Moreover, VPS4A and a monomeric-locked VPS4A mutant bound the abscission checkpoint proteins CHMP4C and ANCHR, while VPS4B did not, indicating a regulatory role for the VPS4A isoform in abscission. Depletion of VTA1, a co-factor of VPS4, disrupted VPS4A-ANCHR interactions and accelerated abscission, suggesting that VTA1 is also involved in the abscission regulation. Our findings reveal a dual role for VPS4A in abscission, one that is canonical and can be compensated by VPS4B, and another that is regulatory and may be delivered by its monomeric form. These observations provide a potential mechanistic explanation for the neurodevelopmental defects and other related disorders reported in VPS4A-mutated patients with a fully functional VPS4B paralog.

Concentrated gypsum slurries used for wallboard production are studied using shear and elongational rheometers. It is shown that the rheological behavior of different slurry compositions can be sufficiently accurately described in the framework of the Ostwald-de Waele power law, which reproduces both shear and elongational experimemtal data with sufficiently close values of the consistency and flow behavior indexes for each slurry composition studied.

An efficient manufacturing of colorimetric nonwoven indicators represents a promising alternative to enable applications of such materials in food quality monitoring. The objective of this study is to use the solution blow spinning technique (SBS) to rapidly produce colorimetric nonwoven indicators based on polycaprolactone, incorporating natural or synthetic pH indicators to detect volatile amines, bacterial growth and monitor pH. Produced via the SBS method, these indicators were characterized aiming their physical, mechanical, thermal, and spectroscopic properties, evaluating their efficacy in detecting amines, monitoring bacterial growth, and pH, as well as assessing color stability during storage. The thermal stability and mechanical properties of the nonwovens practically always increased with the incorporation of natural and synthetic indicators. When exposed to volatile amines, the nonwoven indicators, particularly those embedded with bromophenol blue, displayed remarkable color change abilities in the presence of five volatile amines. These smart nonwovens in direct contact with E. coli K-12 or its volatiles in 24 h changed their color perceptible to the naked eye. The nanofiber nonwovens displayed visible color changes (ΔE ≥ 3) in response to buffer solutions (pH between 3 and 10). The smart nonwovens rapidly produced by the solution blow spinning method prove to be a promising tool for real-time monitoring of food freshness., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

In this study, the development of novel pH-responsive and dual thermo- and pH-responsive filter materials is described. The dual-responsive system combines poly(N-isopropylacrylamide) (PNIPAM) for temperature sensitivity and poly(acrylic acid) (PAA) for pH responsiveness, which offers dynamic filtration capabilities tailored to environmental changes. PNIPAM is a thermo-responsive polymer that undergoes significant conformational changes in response to temperature variations. The present work integrates PNIPAM's temperature sensitivity with the pH-responsive properties of PAA, a versatile polymer widely recognized for its ability to change its conformation in response to pH variations. The dual materials developed here undergo conformational changes at specific temperatures and pH levels, modifying their hydrophilicity, pore size, and permeability. In particular, when exposed to higher temperatures, PNIPAM transitions from a hydrated, expanded state to a dehydrated, collapsed state, directly influencing the flow rate and selectivity of the filter medium that comprises it. On the other hand, PAA responds to pH changes by ionizing or deprotonating, causing swelling or shrinkage that alters the filtration performance of the media with embedded PAA. This dual responsiveness allows for the development of advanced filtration systems that can adapt to varying environmental conditions, optimize the capture of specific contaminants, and reduce fouling., (© 2024 The Author(s). Macromolecular Rapid Communications published by Wiley‐VCH GmbH.)

In this study, a combination of ab initio modeling and experimental analysis is presented to investigate and elucidate the electronic conductivity of films composed of conducting polymer blend PEDOT:PSS-PEO. Detailed density functional theory (DFT) calculations, aligned with experimental data, aided at profound understanding of the chemical composition, band structure, and the mechanical behavior of these composite materials. Systematic evaluation across diverse ratios of PEDOT, PSS, and PEO revealed a pronounced transformation in electronic properties. Specifically, the addition of PEO into the polymer matrix remarkably changes the band gap, with a marked alteration observed near a PEO concentration of 52 wt-%. This adjustment led to a substantial enhancement in the electrical conductivity, exhibiting an increase by a factor of approximately 20, compared to the original PEDOT:PSS polymer. The present investigation determined the crucial role of the PEDOT to PSS ratio in band gap determination, emphasizing its significant impact on the material's electrical conductivity. Concurrently, the mechanical property analysis unveiled a consistent increase in Young's modulus, reaching up to 765.93 MPa with increased PEO content, signifying a notable mechanical stiffening of the blend. The obtained combined theoretical and experimental insights illustrate a detailed perspective on the conductivity anomalies observed in PEDOT:PSS-PEO systems, establishing a robust framework for designing highly conducting and mechanically stable polymer blends. This comprehensive approach elucidates the interplay between chemical composition and electronic behavior, offering a strategic pathway for extrusion-based manufacturing techniques such as Direct Ink Writing (DIW)., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

A light-weight actuator developed in this work belongs to a class of soft robots, and in a sense, resembles an octopus. Its main function is in the attachment or detachment to a solid surface driven by an electro-thermopneumatic mechanism. In this study, a suction cup similar to that of an octopus is manufactured from an elastomer, which is actuated by an electro-thermopneumatic system, mimicking the movement of the octopus' acetabular muscle. Accordingly, the adhesion force generated by such an actuator is regulated by releasing the inner air or adjusting the cup's elasticity. This actuator is designed to be an assistive device that facilitates the individual's physical strength in case of conditions related to aging or cerebellar disease, or a person who lost limbs. In this study, the actuator capabilities are demonstrated in the form of a grip-assisting glove and prosthetic attacher. Moreover, the adhesion mechanism is quantified by numerical simulations and verified experimentally.

Hypothesis: Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) is an attractive conducting polymer, albeit its rheological properties are inappropriate for direct ink writing (DIW). Here it is hypothesized that a suspension of PEDOT:PSS with a non-conducting highly spinnable viscoelastic polymer, e.g., polyethylene oxide (PEO), will significantly facilitate printability and enhance the electrical conductivity (EC) of PEDOT:PSS-PEO. It is also hypothesized that high-humidity post-treatment will enhance the EC even further, and the application of the electric field can facilitate the DIW speed beyond the capabilities of current commercial 3D printers., Experiments: The rheological behavior of PEDOT:PSS suspensions with several non-conducting polymers was explored in the experiments. The EC of the suspensions was measured, including the effect of high-humidity post-treatment. High-speed DIW of the optimal suspension was experimentally demonstrated with the applied electric field., Findings: The findings revealed that PEO serves as a secondary dopant, and the suspension of 4.33 wt% PEDOT:PSS-52 wt% PEO possesses the EC > 15 times higher than that of PEDOT:PSS. Many 2D, 2.5D and 3D functional traces were printed at high resolution at the DIW speed up to 8.64 m/s (>10 times faster than current commercial printers), facilitated by the applied electric field. Post-treatment at 80-90% relative humidity enhanced the EC more than twice., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Inc. All rights reserved.)

High-entropy materials have received notable attention concern on account of their unique structure, tunable properties, and unprecedented potential applications in many fields. In this work, for the first time a NiCoMnZnMg-containing high-entropy glycerolate (HE-Gly) particles has been synthesized using a scalable solvothermal method. The HE-Gly particles were used as a precursor in design of porous high-entropy oxide (HEO) microparticles. The morphological and structural characterizations demonstrate that the temperature of the annealing process, and the composition of the metal ions in the HE-Gly precursors play important roles in determining porosity, crystallinity, and phase separation in HEOs. In fact, HE-Gly exhibited a porous structure of spinel HEOs with secreted MgO phase after annealing process at 800 °C, while the annealing process at 400 °C led to a low-crystallinity spinel phase without phase segregation. Overall, this work describes HE-Gly as a new precursor for altering the composition, crystallinity, and porosity of HEOs. This strategy is scalable for potential high mass productions, paving a new path toward industrial application of high-entropy materials., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Inc. All rights reserved.)

In this study, we fabricated a nanofiber-based electrothermo-pneumatic soft actuator (ETPSA) using electrospinning technique. The actuator uses liquid-vapor phase transition. The ETPSA developed in the present study goes beyond the limitations of the existing pneumatic soft actuators. The present ETPSA has a built-in source of heat (Joule heating from an embedded metal wire) and allows the smooth anthropomorphic movement of the actuator and, in particular, eliminates the use of external pumping systems that are indispensable in the existing pneumatic soft actuators and robots. In addition, since the present ETPSA can be operated effectively even using a portable miniature battery, it holds great promise as an adaptable soft actuator for various robotic applications with high energy efficiency and programmable motions.

Nonwoven fibrous filter membranes are widely used in filtration because of their low cost. They are less effective in intercepting airborne particles of the order of 100 nm, which is of the SARS-CoV-2 (COVID-19) virus's size. Many diseases, including COVID-19, predominantly spread by droplets released by breathing, coughing, sneezing, or medical procedures. It was shown that the smallest droplets can evaporate in air before settling, thus, making viruses airborne and easily penetrating even the best masks and filters. As a result, air-filtering membranes, which are capable of effective interception of ∼100 nm nanoparticles are highly desirable. A traditional way to improve filtration efficiency by overlapping several layers of nonwoven fabrics increases the required pressure drop, and thus, should be avoided as much as possible. Here, we propose and demonstrate an innovative approach to enhance performance of filtration membranes based on (i) a dramatic reduction in the fiber size, and (ii) metal coating of the fibers. The first component of this approach allows one to incorporate a novel physical mechanism of filtration, the short-range van der Waals forces, whereas the second one adds the long-range electric Coulomb forces if the oncoming nanoparticles are pre-charged and the metal-plated membrane grounded. In the present work, the ∼100 nm aluminum nanoparticles are filtered as a model of commensurate airborne single COVID-19 viruses, and Platinum is used as the sputter-coated material for the fiber coating. The resulting filtration efficiency enhanced by the electric Coulomb forces alone is increased by the factor of 1.77, while the filtration efficiency additionally facilitated by the van der Waals forces increased by the factor of 2.44. In comparison to the filter membranes with ∼500 nm fibers without the electric forces involved, the van-der-Waals-electric filter membrane with fibers ∼90 nm is 2.24 × 1.77 = 3.96 times more effective. The quality factor of a membrane which combines the van der Waals and Coulomb forces is 10.6 psi -1 , which is almost three times that of a comparable membrane without the electric Coulomb force (with only van der Waals forces being used)., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© 2021 Elsevier B.V. All rights reserved.)

To improve performance of thermopneumatic soft actuators, which have recently been developed for various industrial applications, we embedded different nanoscale materials into their elastomer bodies. This yields a significant enhancement in the actuator performance via improving the mechanical and thermal properties of the elastomer bodies. In addition, the use of nanoinclusions diminished losses of the working fluid from the actuators by decreasing vapor leaks through the elastomer body and thus improving longevity. Notably, when using different working fluids with low boiling temperatures, the operating temperature range of the actuators can be lowered and widened. The hybrid approach proposed in this study is expected to advance the industrial feasibility of thermopneumatic actuators.

The creeping-flow theory describing evolution and steady-state shape of two-dimensional ionic-conductor drops under the action of surface tension and the subcritical (in terms of the electric Bond number) electric field imposed in the substrate plane is developed. On the other hand, the experimental data are acquired for drops impacted or softly deposited on dielectric surfaces of different wettability and subjected to an in-plane subcritical electric field. Even though the experimental situation involves viscous friction of drops with the substrates and wettability-driven motion of the contact line, the comparison to the theory reveals that it can accurately describe the steady-state drop shape on a non-wettable substrate. In the latter case, the drop is sufficiently raised above the substrate, which diminishes the three-dimensional effects, making the two-dimensional description (lacking the no-slip condition at the substrate and wettability-driven motion of the contact line) relevant. Accordingly, it is demonstrated how the subcritical electric field deforms the initially circular drops until an elongated steady-state configuration is reached. In particular, the surface tension tends to round off the non-circular drops stretched by the electric Maxwell stresses imposed by the electrodes. A more pronounced substrate wettability leads to more elongated steady-state configurations observed experimentally than those predicted by the two-dimensional theory. The latter cases reveal significant three-dimensional effects in the electrically driven drop stretching. In the supercritical electric fields (corresponding to the supercritical electric Bond numbers), the electrical stretching of drops predicted by the present linearized two-dimensional theory results in splitting into two separate droplets. This scenario is corroborated by the predictions of the fully nonlinear results for similar electrically stretched bubbles in the creeping-flow regime available in the literature as well as by the present experimental results on a substrate with slip.

Antimicrobial nonwovens for single use applications (e.g., diapers, sanitary napkins, medical gauze, etc.) are of utmost importance as the first line of defense against bacterial infections. However, the utilization of petrochemical nondegradable polymers in such nonwovens creates sustainability-related issues. Here, sustainable poly(hydroxybutyrate) (PHB) and ε-poly-l-lysine (ε-PLL) submicro- and microfiber-based antimicrobial nonwovens produced by a novel industrially scalable process, solution blowing, have been proposed. In such nonwovens, ε-PLL acts as an active material. In particular, it was found that most of ε-PLL is released within the first hour of deployment, as is desirable for the applications of interest. The submicro- and microfiber mat was tested against C. albicans and E. coli , and it was found that ε-PLL-releasing microfibers result in a significant reduction of bacterial colonies. It was also found that ε-PLL-releasing antimicrobial submicro- and microfiber nonwovens are safe for human cells in fibroblast culture. Mechanical characterization of these nonwovens revealed that, even though they are felt as soft and malleable, they possess sufficient strength, which is desirable in the end-user applications.

Wearable electronic textiles are used in sensors, energy-harvesting devices, healthcare monitoring, human-machine interfaces, and soft robotics to acquire real-time big data for machine learning and artificial intelligence. Wearability is essential while collecting data from a human, who should be able to wear the device with sufficient comfort. In this study, reduced graphene oxide (rGO) and silver nanowires (AgNWs) were supersonically sprayed onto a fabric to ensure good adhesiveness, resulting in a washable, stretchable, and wearable fabric without affecting the performance of the designed features. This rGO/AgNW-decorated fabric can be used to monitor external stimuli such as strain and temperature. In addition, it is used as a heater and as a supercapacitor and features an antibacterial hydrophobic surface that minimizes potential infection from external airborne viruses or virus-containing droplets. Herein, the wearability, stretchability, washability, mechanical durability, temperature-sensing capability, heating ability, wettability, and antibacterial features of this metallized fabric are explored. This multifunctionality is achieved in a single fabric coated with rGO/AgNWs via supersonic spraying.

COVID-19, caused by the SARS-CoV-2 (severe acute respiratory syndrome coronavirus 2) virus, has been rapidly spreading worldwide since December 2019, causing a public health crisis. Recent studies showed SARS-CoV-2's ability to infect humans via airborne routes. These motivated the study of aerosol and airborne droplet transmission in a variety of settings. This study performs a large-scale numerical simulation of a real-world dentistry clinic that contains aerosol-generating procedures. The simulation tracks the dispersion of evaporating droplets emitted during ultrasonic dental scaling procedures. The simulation considers 25 patient treatment cubicles in an open plan dentistry clinic. The droplets are modeled as having a volatile (evaporating) and nonvolatile fraction composed of virions, saliva, and impurities from the irrigant water supply. The simulated clinic's boundary and flow conditions are validated against experimental measurements of the real clinic. The results evaluate the behavior of large droplets and aerosols. We investigate droplet residence time and travel distance for different droplet diameters, surface contamination due to droplet settling and deposition, airborne aerosol mass concentration, and the quantity of droplets that escape through ventilation. The simulation results raise concerns due to the aerosols' long residence times (averaging up to 7.31 min) and travel distances (averaging up to 24.45 m) that exceed social distancing guidelines. Finally, the results show that contamination extends beyond the immediate patient treatment areas, requiring additional surface disinfection in the clinic. The results presented in this research may be used to establish safer dental clinic operating procedures, especially if paired with future supplementary material concerning the aerosol viral load generated by ultrasonic scaling and the viral load thresholds required to infect humans., (© 2021 Author(s).)

Numerous threats to human health and ecosystems on earth exist due to air pollution and the spread of fatal diseases. Airborne pollutants and particulate matter (PM) pose serious public health risks. In addition, the emergence and spread of bacterial and viral diseases constantly threaten public health and safety. Although various approaches have been implemented thus far to protect humans from air pollution and exposure to diseases, several challenges remain to be addressed. In this study, we developed a hybrid air filter consisting of filtration, heating, and thermal insulation layers. The air filtration layer can effectively capture airborne PM 1 particles (less than 1.0 μm in diameter). Furthermore, the heating layer enables the hybrid air filter to generate temperatures above 100 °C, and the insulation layer prevents the heat from being transferred to the other side (e.g., the human skin, if the hybrid air filter is used in a facemask). Since several bacteria and viruses are incapacitated under high temperatures, this hybrid air filter holds great promise for antibacterial and antiviral protection.

Multifunctional nanomaterials with the ability to respond to near-infrared (NIR) light stimulation are vital for the development of highly efficient biomedical nanoplatforms with a polytherapeutic approach. Inspired by the mesoglea structure of jellyfish bells, a biomimetic multifunctional nanostructured pillow with fast photothermal responsiveness for NIR light-controlled on-demand drug delivery is developed. We fabricate a nanoplatform with several hierarchical levels designed to generate a series of controlled, rapid, and reversible cascade-like structural changes upon NIR light irradiation. The mechanical contraction of the nanostructured platform, resulting from the increase of temperature to 42 °C due to plasmonic hydrogel-light interaction, causes a rapid expulsion of water from the inner structure, passing through an electrospun membrane anchored onto the hydrogel core. The mutual effects of the rise in temperature and water flow stimulate the release of molecules from the nanofibers. To expand the potential applications of the biomimetic platform, the photothermal responsiveness to reach the typical temperature level for performing photothermal therapy (PTT) is designed. The on-demand drug model penetration into pig tissue demonstrates the efficiency of the nanostructured platform in the rapid and controlled release of molecules, while the high biocompatibility confirms the pillow potential for biomedical applications based on the NIR light-driven multitherapy strategy.

The aerosol transmissibility of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) has impacted the delivery of health care and essentially stopped the provision of medical and dental therapies. Dentistry uses rotary, ultrasonic, and laser-based instruments that produce water-based aerosols in the daily, routine treatment of patients. Abundant aerosols are generated, which reach health care workers and other patients. Viruses, including SARS-CoV-2 virus and related coronavirus disease (COVID-19) pandemic, continued expansion throughout the USA and the world. The virus is spread by both droplet (visible drops) and aerosol (practically invisible drops) transmission. The generation of aerosols in dentistry-an unavoidable part of most dental treatments-creates a high-risk situation. The US Centers for Disease Control and The Occupational Safety and Health Administration consider dental procedures to be of "highest risk" in the potential spreading of SARS-CoV-2 and other respiratory viruses. There are several ways to reduce or eliminate the virus: (i) cease or postpone dentistry (public and personal health risk), (ii) screen patients immediately prior to dental treatment (by appropriate testing, if any), (iii) block/remove the virus containing aerosol by engineering controls together with stringent personal protective equipment use. The present work takes a novel, fourth approach. By altering the physical response of water to the rotary or ultrasonic forces that are used in dentistry, the generation of aerosol particles and the distance any aerosol may spread beyond the point of generation can be markedly suppressed or completely eliminated in comparison to water for both the ultrasonic scaler and dental handpiece., (Copyright © 2020 Author(s).)

Air-quality control remains a major environmental concern as polluted air is a threat to public safety and health in major industrialized cities. To filter pollutants, fibrous filters employing electrostatic attraction have been widely used. However, such air filters suffer from some major disadvantages, including low recyclability and a significant pressure drop owing to clogging and a high packing density. Herein, we developed ionization-assisted electrostatic air filters consisting of nonwoven nanofibers. Ionization of particulate matter (PM) using air ionization enhanced the electrostatic attraction, thereby promoting efficient filtration. Metallization of the fibers facilitated strong electrical attraction and the consequent capture of PM of various sizes. The low packing density of the metallized fibers also facilitated efficient filtration of the PM, even at low driving pressures, which in turn reduced the energy consumption of the air-filtration device.

Here we aim at understanding and modeling of macroscopic interactions and sliding motion of curved filaments during muscles' isometric action in which tension is developed without overall contraction. A generic dynamic model of a curved elastic filament undergoing sliding, twisting, and unraveling around a cylindrical filament affected by the interfilament friction force is developed in full detail. In particular, the dynamic equations describing the general sliding motion of a curved filament wrapped around a cylindrical filament and pulled by a constant force applied to a free end are derived and solved numerically; the other end of the curved filament is considered to be fixed at the cylindrical one. The model predicts propagation of an elastic wave over the wrapped filament determined by the filament stiffness and the interfilament friction. The wrapped filament deformation and its ultimate arrest are predicted, and the final configurations of such filaments are revealed. Accordingly, the wrapped filament strain is predicted as a function of time for different values of the friction coefficient. The potential applications and possible biomechanical links of the proposed generic model are also discussed.

Solid state electrolytes (SSEs) offer great potential to enable high-performance and safe lithium (Li) batteries. However, the scale-up synthesis and processing of SSEs is a major challenge. In this work, three-dimensional networks of lithium lanthanum titanite (LLTO) nanofibers are produced through a scale-up technique based on solution blowing. Compared with the conventional electrospinning method, the solution blowing technique enables high-speed fabrication of SSEs (e.g., 15 times faster) with superior productivity and quality. Additionally, the room-temperature ionic conductivity of composite polymer electrolytes (CPEs) formed from solution-blown LLTO fibers is 70% higher than the ones formed from electrospun fibers (1.9 × 10 -4 vs 1.1 × 10 -4 S cm -1 for 10 wt % LLTO fibers). Furthermore, the cyclability of the CPEs made from solution-blown fibers in the symmetric Li cell is more than 2.5 times that of the CPEs made from electrospun fibers. These comparisons show that solution-blown ion-conductive fibers hold great promise for applications in Li metal batteries.

A multifunctional sensor capable of simultaneous sensing of temperature, pressure, and proximity has been developed. This transparent and body-attachable device is also capable of providing heat under low voltage. The multi-sensor consists of metal fibers fabricated by electrospinning and electroplating. The device comprises randomly deposited metal fibers, which not only provide heating but also perform as thermal and proximity sensors, and orderly aligned metal fibers that act as a pressure sensor. The sensor is fabricated by weaving straight rectangular electrodes on a transparent substrate (a matrix). The sensitivity is readily enhanced by installing numerous matrices that facilitate higher sensing resolution. The convective heat transfer coefficient of the heater is h = 0.014 W·cm -2 ·°C -1 . The temperature coefficient of resistivity (TCR) and pressure sensitivity (η P ) are 0.038 °C -1 and 5.3 × 10 -3 kPa -1 , respectively. The superior sensitivity of the device is confirmed via quantitative comparison with similar devices. This multifunctional device also has a superior convective heat transfer coefficient than do other heaters reported in the literature.

Supersonic cold spraying is an emerging technique for rapid deposition of films of materials including micrometer-size and sub-micrometer metal particles, nanoscale ceramic particles, clays, polymers, hybrid materials composed of polymers and particulates, reduced graphene oxide (rGO), and metal-organic frameworks. In this method, particles are accelerated to a high velocity and then impact a substrate at near ambient temperature, where dissipation of their kinetic energy produces strong adhesion. Here, recent progress in fundamentals and applications of cold spraying is reviewed. High-velocity impact with the substrate results in significant deformation, which not only produces adhesion, but can change the particles' internal structure. Cold-sprayed coatings can also exhibit micro- and nanotextured morphologies not achievable by other means. Suspending micro- or nanoparticles in a liquid and cold-spraying the suspension produces fine atomization and even deposition of materials that could not otherwise be processed. The scalability and low cost of this method and its compatibility with roll-to-roll processing make it promising for many applications, including ultrathin flexible materials, solar cells, touch-screen panels, nanotextured surfaces for enhanced heat transfer, thermal and electrical insulation films, transparent conductive films, materials for energy storage (e.g., Li-ion battery electrodes), heaters, sensors, photoelectrodes for water splitting, water purification membranes, and self-cleaning films., (© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Recently, endovascular coil embolization has been introduced to treat intracranial aneurysms because it has lower morbidity and mortality than surgical clipping. The endovascular coils prevent the extravasation of blood by decreasing the permeability of an aneurysm flow governed by Darcy's law. Here, we developed and explored Pt-coated micro-ropes for potential use as endovascular coils. Electrospinning with subsequent electroplating were employed to fabricate Pt-coated nanofibers, which were tightly twisted to form micro-ropes. The compatibility of Pt micro-ropes with commercial delivery catheters was verified and their performance was experimentally explored in an in vitro experimental model. The developed Pt-coated micro-ropes demonstrated feasibility as efficient and low-cost endovascular coils. STATEMENT OF SIGNIFICANCE: The use of Platinum (Pt)-coated polymer nanofibers to prevent blood extravasation has been demonstrated. These Pt nanofibers were installed within a microfluidic channel, and the resulting reduced permeability was evaluated using a fluid similar to blood. Based on the obtained results, these newly developed nanofibers are expected to decrease the operation cost for aneurysmal subarachnoid hemorrhage (SAH), owing their reduced size and low material cost. Overall, the use of this new material should reduce the operational risk associated with the multiple steps required to place the Pt coils at the SAH site. The compatibility of Pt micro-ropes with commercial delivery catheters was verified and their performance was experimentally explored in an in vitro experimental model. The developed Pt-coated micro-ropes demonstrated feasibility as efficient and low-cost endovascular coils., (Copyright © 2019 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.)

A novel approach presented in this work allows one to calculate the potential drop across the compact layer in electrostatic atomization with high voltages applied at the electrode. Ionic conductor liquids employed in electrostatic atomization have a low dielectric constant, which causes almost all of the potential drop across the double layer to occur inside the compact layer. In the previous article of this group (Sankarn, A., et al. Langmuir 2017 , 33 , 1375-1384), it was shown that faradaic reactions in the kinetics-limited regime are responsible for liquid electrification in electrostatic atomization. Here, we apply the Frumkin slow discharge theory to calculate the electric potential at the interface of the compact and diffuse layers. The electric potential value at the interface of the compact and diffuse layers is required in computational models accounting for the discharge of counterions due to faradaic reactions when solving the ionic transport equations. The activation energy of the electron transfer reaction is calculated through the Marcus theory. Knowing the counterion flux value at the electrode surface from the concurrent experimental measurements, the ionic concentration and net charge distribution across the polarized diffuse layer are also found from the numerical simulations. Considering canola oil to be the ionic conductor liquid, two different examples are used to demonstrate the application of this approach to calculate the electric potential at the interface of compact and diffuse layers.

The demand for wearable, stretchable soft electronics for human-machine interface applications continues to grow given the potential of these devices in humanoid robotics, prosthetics, and health-monitoring devices. We demonstrate fabrication of multifunctional sensors with simultaneous temperature-, pressure-, proximity-, and strain (or bending)-sensing capabilities, combined with heating and UV-protection features. These multifunctional sensors are flexible, light, and transparent and are thus body-attachable. Silver nanowires are supersonically sprayed on a large-scale transparent and flexible roll-to-roll substrate. The junctions between nanowires are physically fused by a strong impact resulting from supersonic spraying, which promotes adhesion and efficient deposition of the nanowire network. Accordingly, nanowires are strongly interconnected, facilitating efficient propagation of electric signals through the fused nanowire network, which allows simultaneous operation of such sensors while maintaining significant transparency. These multifunctional sensors are mechanically durable and retain long-term stability. A theoretical discussion is provided to explain the respective mechanisms of heating and proximity, pressure, and strain sensing.

A novel approach is developed to predict the thickness of the equivalent one-dimensional Stern layer near conducting electrodes subjected to high voltage and carrying electric current. The nonspecific (nonelectric) ion adsorption responsible for the formation of the Stern compact layer at the electrode surface is attributed to the Langmuir-Brunauer-Emmett-Teller mechanism. The compact Stern layer is implied to be intrinsically two-dimensional and forming on the oxide or impurity islands on the electrode surface, which prevents electron transfer to or from the adsorbed ions. On the other hand, electrons are transferred through the open parts of the metallic electrode surface by electron transfer faradaic reactions characterized by the Frumkin-Butler-Volmer kinetics. Then, the one-dimensional Stern layer appears to be an approximation of the abovementioned two-dimensional model. In the framework of this model, the equivalent one-dimensional Stern layer thickness is predicted, rather than used as an adjustable parameter, as frequently done in the literature.

Here, we investigate the feasibility and effectiveness of electrowetting in the motion control of droplets of different liquids, which are widely used as inks in direct writing (DW)-based three-dimensional (3D) printing processes for various applications. To control the movement of DW ink droplets on dielectric substrates, the electrodes were embedded in the substrate. It is demonstrated that droplets of pure liquid inks, aqueous polymer solution inks, and carbon fiber suspension inks can be moved on multi-angled surfaces. Also, experimental results reveal that droplets of a commercial hydrogel, agar-agar, alginate, xanthan gum, and gum arabic can be moved by electrowetting. Droplets of sizes 200 μm-3 mm were manipulated and moved by the electric field on different dielectric substrates accurately and repeatedly. Effective electrowetting-based control and movement of droplets were observed on horizontal, vertical, and even inverted substrates. These findings imply the feasibility and potential application of electrowetting as a flexible, rapid, and new method for ink droplet control in 3D printing processes.

Bloodstain pattern analysis (BPA) is an integral part of crime scene investigation. For violent crimes involving gunshots, standard practice in police departments worldwide have some physical limitations. For instance, the effect of gravity and air drag on trajectories of blood droplets are neglected using current reconstruction methods, which results in a well-known overestimation of the height of the source of blood. As a consequence, more sophisticated models for blood spatter trajectory reconstruction are being developed, two of which are highlighted in the present work. They allow the prediction of bloodstain patterns produced from backward spattered blood droplets from blunt and sharp bullets. Our recent models attribute the splashing of blood to the Rayleigh-Taylor instability which arises when blood is accelerated towards lighter air. This physically-based description comes with the powerful predictive capability to correlate features of bloodstain patterns with the specific bullet and gun that produced them, as well as with the body position. The results of the numerical models were compared with four experiments simulating blood spatter deposition on a vertical wall through the number of stains produced, average stain area, and average impact angle at the surface, and the agreement found is fairly good. Moreover, further insight is obtained by probing and explaining the influence of observable parameters on the resulting spatter pattern, with the goal of aiding BPA experts evaluating a crime scene., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Particulate matter (PM) from ever-increasing industrialization poses a great public health risk. Although fiber-based filters are used effectively to block PM, filters with high packing densities suffer from excessive pressure drops. Electret filters bypass intermediate- or large-sized particles and thus capture only small particles, the motion of which can be influenced by weak electrostatic fields. In this study, we demonstrate the fabrication of metallized fibers that produce intense electric fields, thereby enabling capture of PMs of a variety of sizes produced by burning incense. The filter consisting of these metallized fibers effectively removes moving particles from air. An electricity-driven filter is relatively thin and has a low packing density, making it light, portable, transparent, and inexpensive. The sizes of the pores between the metallized fibers are readily controlled by manipulating the electrospinning and electroplating times. Sufficiently large pores permit efficient airflow and thus increase permeability without risking an excessive pressure drop. The metallized fiber filter is washable and thus reusable. In this study, a PM removal rate of >97% was recorded using a filter designed under optimal conditions.

Vapor bubble nucleation during subcooled boiling on thin strip wire heaters and the resultant vibrations are studied experimentally. The results show how the subcooled boiling-induced vibrations (SBIV) are intrinsically related to the hydrodynamic flow induced near the heated wires. It is shown that the dominant force responsible for the vibrations in this case is imposed by a localized strong hydrodynamic flow rather than by the vapor recoil force. The dominant frequency of SBIV is the fundamental frequency of the wire, regardless of the individual departure frequencies of the nucleating vapor bubbles. The recorded wire vibrations are used to quantify the hydrodynamic flow. It is shown experimentally and theoretically that the flow fades exponentially with distance from the wire., Competing Interests: Conflict of interest None declared.

Trajectory reconstruction in bloodstain pattern analysis is currently performed by assuming that blood drop trajectories are straight along directions inferred from stain inspection. Recently, several attempts have been made at reconstructing ballistic trajectories backwards, considering the effects of gravity and drag forces. Here, we propose a method to reconstruct the region of origin of impact blood spatter patterns that considers fluid dynamics and statistical uncertainties. The fluid dynamics relies on defining for each stain a range of physically possible trajectories, based on known physics of how drops deform, both in flight and upon slanted impact. Statistical uncertainties are estimated and propagated along the calculations, and a probabilistic approach is used to determine the region of origin as a volume most compatible with the backward trajectories. A publicly available data set of impact spatter patterns on a vertical wall with various impactor velocities and distances to target is used to test the model and evaluate its robustness, precision, and accuracy. Results show that the proposed method allows reconstruction of bloodletting events with distances between the wall and blood source larger than ∼1 m. The uncertainty of the method is determined, and its dependency on the distance between the blood source and the wall is characterized. Causes of error and uncertainty are discussed. The proposed method allows the consideration of stains indicating impact velocities that point downwards, which are typically not used for determining the height of the origin. Based on the proposed method, two practical recommendations on crime scene documentation are drawn., (Copyright © 2019. Published by Elsevier B.V.)

Soft robotic systems are increasingly emerging as robust alternatives to conventional robotics. Here, we demonstrate the development of programmable soft actuators based on volume expansion/retraction accompanying liquid-vapor phase transition of a phase-change material confined within an elastomer matrix. The combination of a soft matrix (a silicone-based elastomer) and an embedded ethanol-impregnated polyacrylonitrile nanofiber (PAN NF) mat makes it possible to form a sealed compound device that can be operated by changing the actuator temperature above/below the boiling point of ethanol. The thermo-responsive actuators based on this principle demonstrate excellent bending ability at a sufficiently high temperature (>90 °C) - comparable with compressed air-based soft actuators. The actuator using the mechanism presented here is easy to manufacture and automate and is recyclable. Finally, the actuation mechanism can be incorporated into a wide variety of shapes and configurations, making it possible to obtain tunable and programmable soft robots that could have a wide variety of industrial applications.

This is a review article on the basic and the latest achievements on superspreading. The complete and fast spreading of droplets on many surfaces in the nature is a special phenomenon discovered in 1960-ies Intensive studies on this phenomenon have been conducted since that time, but the mechanism of superspreading remained in completely unveiled till nowadays. Here we scrutinized the basic literature on superspreading from the last 25 years and also present results related to superspreaders acquired in the present work. The literature in superspreading can be divided to the following groups: (i) works on the properties of the trisiloxane surfactants; (ii) works on the mechanisms of superspreading; (iii) MD simulations; (iv) works on the effect of the trisiloxane surfactants on thin liquid films. There is a number of review articles published in the last decade related to mainly works from groups (i) and (ii). The works on MD simulations (iii) and the effects on trisiloxane surfactants on thin liquid films (iv) are still few despite they are important from the scientific view point. We conducted our own study on the effect of the superspreaders on foam films in rectangular frame and confirmed that the superspreaders cause powerful Marangoni effect within the foam films. Such a strong Marangoni effect has been never observed with the ordinary surfactants. We scrutinized and discussed the basic works from the groups (i)-(iv) on the superspreading and added our own investigation on the distinguishable effects of superspreaders and non-superspreaders on thin foam films. The work could be useful to both beginners and specialists in the field of wetting/de-wetting and superspreading., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Pool boiling of ethanol and self-rewetting fluids on bare copper surface and copper surface with polymer nanofibers were studied experimentally. No significant effect of the depths of ethanol layer on the heat removal rate was found. That indicates that only the heat transfer in the liquid microlayer near the heater surface is a dominant factor. As a result, one can expect that self-rewetting fluids can significantly affect boiling performance. Accordingly, several alcohol solutions including the self-rewetting ones were investigated as working fluids in the boiling chamber. It was found that at the 0.1% (v/v) concentration, only the high carbon-alcohol, n-heptanol in aqueous solution, improved boiling heat transfer considerably. Furthermore, the experimental study of the effect of surface nano-texture on boiling characteristics was undertaken. For that aim, polyacrylonitrile (PAN) nanofibers were deposited onto the copper heater surface. Measurements of the boiling curve revealed a detrimental effect of such nano-texture in the case of such working fluids as ethanol and self-rewetting n-heptanol solutions. On the other hand, when polystyrene (PS) nanofibers were deposited onto the copper heater surface instead of PAN nanofibers, a significant improvement in boiling heat transfer was observed. The more hydrophobic nature of PS compared to copper is responsible for this effect, i.e. is the reason of the heat transfer enhancement on such a nano-textured surface compared to the pure copper one. In addition, the critical heat flux in the case of n-heptanol solution was found to be reduced considerably on the PS nano-textured surface compared to the pure copper one. This stems from the increased propensity of the heater surface to be covered by vapor, while the rewetting is insufficiently effective at high heat fluxes in presence of PS nanofibers., Competing Interests: Conflicts of interest The authors certify that this project has no conflict of interest.

This is a data set of blood spatter patterns scanned at high resolution, generated in controlled experiments. The spatter patterns were generated with a rifle or a handgun with varying ammunition. The resulting atomized blood droplets travelled opposite to the bullet direction, generating a gunshot backspatter on a poster board target sheet. Fresh blood with anticoagulants was used; its hematocrit and temperature were measured. The main parameters of the study were the bullet shape, size and speed, and the distance between the blood source and target sheet. Several other parameters were explored in a less systematic way. This new and original data set is suitable for training or research purposes in the forensic discipline of bloodstain pattern analysis.

Electrospun metal-plated nanofibers and supersonically sprayed nanowires were used to fabricate hybrid films exhibiting a superior low sheet resistance of 0.18 Ω sq-1, a transparency of 91.1%, and a figure-of-merit of 2.315 Ω-1. The films are suitable to serve as thermal sensors and heaters. Such hybrid transparent conducting films are highly flexible and thus wearable. They can be used as body-temperature monitors and heaters. The employed hybrid approach improved the sheet resistance diminishing it to a minimum, while maintaining transparency. In addition, the low sheet resistance of the films facilitates their powering with a low-voltage battery and thus, portability. The thermal sensing and heating capabilities were demonstrated for such films with various sheet resistances and degrees of transparency. The temperature sensing was achieved by the resistance change of the film; the resistance value was converted back to temperature. The sensing performance increased with the improvement in the sheet resistance. The temperature coefficient of resistivity was TCR = 0.0783 K-1. The uniform distribution of the metal-plated nanofibers and nanowires resulted in a uniform Joule heating contributing to an efficient convection heat transfer from the heaters to the surrounding, demonstrated by an improved convective heat transfer coefficient.

Here we study the inception and propagation of vaporization fronts and transition to the critical heat flux (CHF) and film-boiling regime triggered by a steep, almost instantaneous increase in the heat release from a strip heater submerged in Novec 7300 liquid. The propagation path of the resulting vaporization front along the strip heater is measured and shown to be exponentially increasing in time, in distinction from the previous reports in literature claiming that the increase is only linear. Since the previous experiments employed such liquids as water, refrigerants, acetone, ethanol, and alkali metals, which possess relatively high latent heat of evaporation and thus require a relatively high power to be supplied, the heater burnout at the inception of the CHF and film boiling was too fast to allow for longer-time observations. Accordingly, the previous works observed only an extremely short-time asymptotics of the propagation process, which means the short-time expansion of the exponential function, which is linear. On the other hand, in the experiments with Novec 7300 liquid, the heater burnout is delayed due to a much lower latent heat of evaporation, thus allowing for a much longer observation of the propagation path, which appears to be exponentially increasing in time. The experiments were preceded by our theoretical prediction of such a behavior, and this theory is also described in the present work. Due to the fact that this theory has been corroborated by the experimental data, the theory yields an adequate explanation and description of the CHF trigger and film boiling inception.

Here, we fabricated nanofiber (NF)-based triboelectric nanogenerators (TENGs) from natural biopolymers using the industrially scalable solution blowing. This technique eliminates severe restrictions on solutions to be used and allows one to achieve biocompatible devices. Here, solutions of soy protein and lignin were blown into continuous monolithic NFs of hundreds of nanometers in diameter. The technique we employed yields large-area NF mats within tens of minutes and has never been employed to form TENGs. Furthermore, in contrast to electrospun and meltblown fiber mats, solution-blown NF mats are much fluffier/porous, which is beneficial for achieving higher voltages by means of triboelectricity. In particular, triboelectricity generated by our biopolymer-based TENGs revealed that they hold great promise as sustainable and environmentally friendly self-powered devices for biomedical applications with the highest efficiency in their class. Moreover, these are the first nanotextured plant-derived biopolymer-made TENGs.

Here, model blister-like soft thermo-pneumatic artificial muscles with the embedded nanofibers impregnated with ethanol are developed. The muscles are essentially blister-like thermo-pneumatic soft actuators (BTSAs), which deflect in response to heat supplied to their bottom. The resulting deflections are on the scale of 1 cm, and the BTSAs are operational for several cycles. They are able to raise the artificial rigid scales, spines or fur/thin fibers attached to them emulating animals such as pangolin, hedgehog and porcupine. They are also capable of removing the stickiest adhesive tapes attached to them, and thus hold great promise for biomedical applications where artificially grown skin patches should be removed from an underlying substrate without being damaged. The theory of the BTSA proposed in this work is in reasonable agreement with the acquired experimental data.

This paper is concerned with simulation of the droplet impact on a dielectric surface, referred to as the dynamic electrowetting-on-dielectric (DEWOD). In particular, we seek to shed more light on the fundamental processes occurring during the impact of an electrically conducting droplet onto a dielectric surface with and without an applied voltage. The liquid in the droplet is an ionic conductor (a leaky dielectric). This work employs an approach based on Cahn-Hilliard-Navier-Stokes (CHNS) modeling. The simulations are validated by predicting the equilibrium contact angle, droplet oscillations, and charge density estimation. Then, four cases of droplet impact are studied, namely, the impact onto a surface with no voltage applied and the impacts onto the surfaces with 2, 4, and 6 kV applied. The modeling results of water droplet impact allow for direct comparison with the experimental results reported by Lee et al. [ Langmuir 2013, 29, 7758]. The results reveal the electric field, the body forces acting on the droplet, the velocity and pressure fields inside and outside the droplet, as well as the free charge density and the electric energy density. The model predicts the droplet shape evolution (e.g., the spreading distance over the surface and the rebound height) under different conditions that are consistent with the experimental observations. Thus, our findings provide new qualitative and quantitative insights into the droplet manipulation that can be used in novel applications of the DEWOD phenomenon.

Aneurysmal subarachnoid hemorrhage (SAH) is the extravasation of blood into the subarachnoid space and is fatal in most cases. Platinum coils have been used to fill the hemorrhage site and prevent the extravasation of blood. Here we explored the use of Pt-coated polymer nanofibers (NF) to prevent blood extravasation and were able to achieve improved results in vitro. The polymer nanofibers were produced via electrospinning and were subsequently electroplated with Pt, resulting in metalized nanofibers. These nanofibers were installed within a microfluidic channel, and the resulting reduction in the permeability was evaluated using a fluid similar to blood. Based on the obtained results, these newly developed nanofibers are expected to decrease the operation cost for SAH, owing to their reduced size and low material cost. Furthermore, it is expected that these nanofibers will be used in a smaller amount during SAH operation while having the same preventive effect. This should reduce the operational risk associated with the multiple steps required to place the Pt coils at the SAH site. Finally, the underlying hydrodynamic mechanism responsible for the reduced permeability of the synthesized nanofibers is described.

Here, we review the state-of-the-art in the field of engineered self-healing materials. These materials mimic the functionalities of various natural materials found in the human body (e.g., the healing of skin and bones by the vascular system). The fabrication methods used to produce these "vascular-system-like" engineered self-healing materials, such as electrospinning (including co-electrospinning and emulsion spinning) and solution blowing (including coaxial solution blowing and emulsion blowing) are discussed in detail. Further, a few other approaches involving the use of hollow fibers are also described. In addition, various currently used healing materials/agents, such as dicyclopentadiene and Grubbs' catalyst, poly(dimethyl siloxane), and bisphenol-A-based epoxy, are described. We also review the characterization methods employed to verify the physical and chemical aspects of self-healing, that is, the methods used to confirm that the healing agent has been released and that it has resulted in healing, as well as the morphological changes induced in the damaged material by the healing agent. These characterization methods include different visualization and spectroscopy techniques and thermal analysis methods. Special attention is paid to the characterization of the mechanical consequences of self-healing. The effects of self-healing on the mechanical properties such as stiffness and adhesion of the damaged material are evaluated using the tensile test, double cantilever beam test, plane strip test, bending test, and adhesion test (e.g., blister test). Finally, the future direction of the development of these systems is discussed., (Copyright © 2017 Elsevier B.V. All rights reserved.)

We have sequentially deposited layers of silver nanowires (AgNWs), silicon dioxide (SiO 2 ) nanoparticles, and polystyrene (PS) nanoparticles on uncoated glass by a rapid low-cost supersonic spraying method to create antifrosting, anticondensation, and self-cleaning glass. The conductive silver nanowire network embedded in the coating allows electrical heating of the glass surface. Supersonic spraying is a single-step coating technique that does not require vacuum. The fabricated multifunctional glass was characterized by X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), ultraviolet-visible spectroscopy, and transmission electron microscopy (TEM). The thermal insulation and antifrosting performance were demonstrated using infrared thermal imaging. The reliability of the electrical heating function was tested through extensive cycling. This transparent multifunctional coating holds great promise for use in various smart window designs.

Here we study experimentally the behavior of liquid healing agents released in vascular core-shell nanofiber mats used in self-healing engineered materials. It is shown that wettability-driven spreading of liquid drops is accompanied by the imbibition into the nanofiber matrix, and its laws deviate from those known for spreading on an intact surface. We also explore coalescence of the released drops on nanofiber mats, in particular, coalescence of drops of resin monomer and cure important for self-healing. The coalescence process is also affected by the imbibition into the pores of an underlying nanofiber mat. A theoretical model is developed to account for the imbibition effect on drop coalescence.

Here, we investigate crack propagation initiated from an initial notch in a self-healing material. The crack propagation in the core-shell nanofiber mats formed by coelectrospinning and the composites reinforced by them is in focus. All samples are observed from the crack initiation until complete failure. Due to the short-time experiments done on purpose, the resin and cure released from the cores of the core-shell nanofibers could not achieve a complete curing and stop crack growth, especially given the fact that no heating was used. The aim is to elucidate their effect on the rate of crack propagation. The crack propagation speed in polyacrylonitrile (PAN)-resin-cure nanofiber mats (with PAN being the polymer in the shell) was remarkably lower than that in the corresponding monolithic PAN nanofiber mat, down to 10%. The nanofiber mats were also encased in polydimethylsiloxane (PDMS) matrix to form composites. The crack shape and propagation in the composite samples were studied experimentally and analyzed theoretically, and the theoretical results revealed agreement with the experimental data.

Bioluminescent jellyfish has a unique structure derived from fiber/polymer interfaces that is advantageous for effective light scattering in the dark, deep sea water. Herein, we demonstrate the fabrication of bio-inspired hybrid films by mimicry of the jellyfish's structure, leading to excellent light-scattering performance and defrosting capability. A haze value reaching 59.3% and a heating temperature of up to 292 °C were achieved with the films. Accordingly, the developed surface constitutes an attractive optical device for lighting applications, especially for street or vehicle luminaries for freezing Arctic-climate countries. The morphological details of the hybrid films were revealed by scanning electron microscopy. The light-scattering properties of these films were examined by ultraviolet-visible-infrared spectrophotometry and anti-glare effect analyses. The defrosting performance of the hybrid films was evaluated via heating tests and infra-red observations.

High-speed videos of blood spatter due to a gunshot taken by the Ames Laboratory Midwest Forensics Resource Center (MFRC) [1] are analyzed. The videos used in this analysis were focused on a variety of targets hit by a bullet which caused either forward, backward, or both types of blood spatter. The analysis process utilized particle image velocimetry (PIV) and particle analysis software to measure drop velocities as well as the distributions of the number of droplets and their respective side view area. The results of this analysis revealed that the maximal velocity in the forward spatter can be about 47±5m/s and for the backward spatter - about 24±8m/s. Moreover, our measurements indicate that the number of droplets produced is larger in forward spatter than it is in backward spatter. In the forward and backward spatter the droplet area in the side-view images is approximately the same. The upper angles of the close-to-cone domain in which droplets are issued in forward and backward spatter are, 27±9° and 57±7°, respectively, whereas the lower angles of the close-to-cone domain are 28±12° and 30±18°, respectively. The inclination angle of the bullet as it penetrates the target is seen to play a large role in the directional preference of the spattered blood. Also, muzzle gases, bullet impact angle, as well as the aerodynamic wake of the bullet are seen to greatly influence the flight of the droplets. The intent of this investigation is to provide a quantitative basis for current and future research on bloodstain pattern analysis (BPA) of either forward or backward blood spatter due to a gunshot., (Published by Elsevier B.V.)

A microfluidic chip-like setup consisting of a vascular system of microchannels alternatingly filled with either a resin monomer or a curing agent is used to study the intrinsic physical healing mechanism in self-healing materials. It is observed that, as a prenotched crack propagates across the chip, the resin and curing agent are released from the damaged channels. Subsequently, both the resin and the curing agent wet the surrounding polydimethylsiloxane (PDMS) matrix and spread over the crack banks until the two blobs come in contact, mix, and polymerize through an organometallic cross-linking reaction. Moreover, the polymerized domains form a system of pillars, which span the crack banks on the opposite side. This "stitching" phenomenon prevents further propagation of the crack.