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A novel photocatalytic [4+2] cyclization strategy was developed for the transformation of biomass furan into a unique and cage-like oxabicyclo[2.2.1]heptene molecular skeleton. This strategy also enabled a significant and efficient cyclization of furan with acrylate. It provides access to the common core shared by a range of biologically active natural products and medicines, such as cantharidin, palasonin, and OBHSA. [ABSTRACT FROM AUTHOR]

The Fourier–Merlin transform method, multi-scale optical flow method, and Weibull distribution are used to integrate the GRAPES_3 km model and Radar Extrapolation Forecast (REF) both developed independently by China. Taking GRAPES_3 km, Wuhan Rapid Update Cycle (WHRUC), and the REF as examples, the prediction performance of the Blending forecast is evaluated comprehensively by the traditional point-to-point method. A new spatial test method is introduced to evaluate the applicability and difference of high-resolution model evaluation. The area, position, shape, and intensity of the precipitation area are matched through the target object test method. The potential forecast information of the spatial field is obtained and the related results are compared and analyzed. The results show that: (1) the comprehensive application of various evaluation methods can evaluate the convective storm forecast more comprehensively. The Blending forecast effect is obviously better than those of other models by using the point-to-point scoring method, especially in the heavy precipitation forecast. The shorter the prediction time is, the better the effect is. (2) The new spatial test method can evaluate the prediction effect of convective storm characteristics, and the target recognition hit rate of the Blending forecast is highest. The scores of target area, position, shape, and median intensity of precipitation are better than those of other forecasts. The variation in the east–west direction is less than that in the north–south direction, which is basically consistent with the actual observation. The variation range of the forecast grid before and after translation is the closest to the reality. (3) The Blending forecast method combines the advantages and disadvantages of the numerical model and REF, which can not only grasp the precipitation area but also improve the prediction ability of rainfall intensity. The traditional point-to-point scoring method and the new spatial test method have the same conclusion as the convective storm forecast of the high-resolution model, which has a certain reference value, and the new spatial test method can provide more detailed evaluation information. [ABSTRACT FROM AUTHOR]