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The isotopic compositions of samples returned from Cb-type asteroid Ryugu and Ivuna-type (CI) chondrites are distinct from other carbonaceous chondrites, which has led to the suggestion that Ryugu and CI chondrites formed in a different region of the accretion disk, possibly around the orbits of Uranus and Neptune. We show that, like for Fe, Ryugu and CI chondrites also have indistinguishable Ni isotope anomalies, which differ from those of other carbonaceous chondrites. We propose that this unique Fe and Ni isotopic composition reflects different accretion efficiencies of small FeNi metal grains among the carbonaceous chondrite parent bodies. The CI chondrites incorporated these grains more efficiently, possibly because they formed at the end of the disk's lifetime, when planetesimal formation was also triggered by photoevaporation of the disk. Isotopic variations among carbonaceous chondrites may thus reflect fractionation of distinct dust components from a common reservoir, implying CI chondrites and Ryugu may have formed in the same region of the accretion disk as other carbonaceous chondrites., Comment: Published open access in Science Advances

Super-Earths are highly irradiated, small planets with bulk densities approximately consistent with Earth. We construct combined interior-atmosphere models of super-Earths that trace the partitioning of water throughout a planet, including an iron-rich core, silicate-rich mantle, and steam atmosphere. We compare these models with exoplanet observations to infer a $1\sigma$ upper limit on total water mass fraction of $\lesssim 3\%$ at the population level. We consider end-member scenarios that may change this value, including the efficiency of mantle outgassing and escape of high mean-molecular weight atmospheres. Although our constraints are agnostic as to the origin of water, we show that our upper limits are consistent with its production via chemical reactions of primordial hydrogen-dominated atmospheres with magma oceans. This mechanism has also been hypothesised to explain Earth's water content, possibly pointing to a unified channel for the origins of water on small terrestrial planets., Comment: Submitted to ApJ

We investigate the consequences of non-ideal chemical interaction between silicate and overlying hydrogen-rich envelopes for rocky planets using basic tenets of phase equilibria. Based on our current understanding of the temperature and pressure conditions for complete miscibility of silicate and hydrogen, we find that the silicate-hydrogen binary solvus will dictate the nature of atmospheres and internal layering in rocky planets that garnered H$_2$-rich primary atmospheres. The temperatures at the surfaces of supercritical magma oceans will correspond to the silicate-hydrogen solvus. As a result, the radial positions of supercritical magma ocean-atmosphere interfaces, rather than their temperatures and pressures, should reflect the thermal states of these planets. The conditions prescribed by the solvus influence the structure of the atmosphere, and thus the transit radii of sub-Neptunes. Separation of iron-rich metal to form metal cores in sub-Neptunes and super-Earths is not assured due to prospects for neutral buoyancy of metal in silicate melt induced by dissolution of H, Si, and O in the metal at high temperatures., Comment: Corrected based on proof of paper to appear in PSJ

The relationship between stars and planets provides important information for understanding the interior composition, mineralogy, and overall classification of small planets (R $\lesssim$ 3.5R$_{\oplus}$). Since stars and planets are formed at the same time and from the same material, their compositions are inextricably linked to one another, especially with respect refractory elements like Mg, Si, and Fe. As a result, stellar elemental abundances can help break the degeneracy inherent to planetary mass-radius models and determine whether planets may be similar to the Earth in composition or if additional factors, such as formation near the host star or a giant impact, may have influenced the planet's make-up. To this end, we now have observations of the abundances of extrasolar rocks that were pulled onto the surfaces of a white dwarfs, whose compositions act as a direct insight into the interiors of small exoplanets. From measurements of $\sim$30 of these "polluted" white dwarfs, we have found that composition of the extrasolar rocks are similar to Solar System chondritic meteorites., Comment: accepted for publication as Ch. 154 in the Treatise on Geochemistry, 3rd Edition; 30 pages, 7 figures, and 8 figures

Even though sub-Neptunes likely represent the most common outcome of planet formation, their natures remain poorly understood. In particular, planets near 1.5-2.5$\,R_\oplus$ often have bulk densities that can be explained equally well with widely different compositions and interior structures, resulting in grossly divergent implications for their formation. Here, we present the full 0.6-5.2$\,\mu \mathrm{m}$ JWST NIRISS/SOSS+NIRSpec/G395H transmission spectrum of the 2.2$\,R_\oplus$ TOI-270d ($4.78\,M_\oplus$, $T_\mathrm{eq}$=350-380 K), delivering unprecedented sensitivity for atmospheric characterization in the sub-Neptune regime. We detect five vibrational bands of CH$_4$ at 1.15, 1.4, 1.7, 2.3, and 3.3$\,\mu$m (9.4$\sigma$), the signature of CO$_2$ at 4.3$\,\mu$m (4.8$\sigma$), water vapor (2.5$\sigma$), and potential signatures of SO$_2$ at 4.0$\,\mu \mathrm{m}$ and CS$_2$ at 4.6$\,\mu\mathrm{m}$. Intriguingly, we find an overall highly metal-rich atmosphere, with a mean molecular weight of $5.47_{-1.14}^{+1.25}$. We infer an atmospheric metal mass fraction of $58_{-12}^{+8}\%$ and a C/O of $0.47_{-0.19}^{+0.16}$, indicating that approximately half the mass of the outer envelope is in high-molecular-weight volatiles (H$_2$O, CH$_4$, CO, CO$_2$) rather than H$_2$/He. We introduce a sub-Neptune classification scheme and identify TOI-270d as a "miscible-envelope sub-Neptune" in which H$_2$/He is well-mixed with the high-molecular-weight volatiles in a miscible supercritical metal-rich envelope. For a fully miscible envelope, we conclude that TOI-270d's interior is $90_{-4}^{+3}\,$wt$\,\%$ rock/iron, indicating that it formed as a rocky planet that accreted a few wt % of H$_2$/He, with the overall envelope metal content explained by magma-ocean/envelope reactions without the need for significant ice accretion. TOI-270d may well be an archetype of the overall population of sub-Neptunes., Comment: 25 pages, 12 figures

Small, close-in exoplanets are divided into two sub-populations: super-Earths and sub-Neptunes. Most super-Earths are thought to have lost their primordially accreted hydrogen-dominated atmospheres via thermally driven winds. We consider the global chemical equilibrium of super-Earths and the lasting impacts of their fleeting hydrogen atmospheres. We find that hydrogen is efficiently sequestered into the interior, oxidising iron and endogenously producing $\sim0.5-1.0\%$ water by mass. As the atmospheres of super-Earths are continuously sculpted by mass loss and chemical equilibration, they remain hydrogen-dominated by mole (number) fraction but become steam-dominated by mass, which may be observable with JWST for planets transitioning across the radius valley. One of the main effects of efficient sequestration of hydrogen into the interior is to produce an under-dense bulk interior compared to that of Earth. We predict bulk densities of super-Earths to be $\sim 5.0 \text{ g cm}^{-3}$ for a $1M_\oplus$ planet, which is consistent with high-precision mass measurements and also population-level inference analyses from atmospheric escape models., Comment: 16 pages, 4 figures. Accepted for publication in ApJ. Comments welcome

As the field of Zr stable isotopes is rapidly expanding from the study of mass-independent to that of mass-dependent isotope effects, a variety of Zr standards have appeared in the literature. While several of these standards have been proposed as the ideal isotope reference material (iRM) against which all data should be reported, none of them have been shown to meet the compositional and/or conflict-of-interest-free distribution requirements put forth by the community. To remedy this situation, we report on a community-led effort to develop and calibrate a scale defining iRM for Zr isotopes: NIST RM 8299. Developed in partnership with the National Institute of Standards and Technology (NIST) from the widely used SRM 3169 Zr Standard Solution, the candidate RM 8299 was calibrated through an inter-laboratory study involving three laboratories. Our data show that RM 8299 meets all requirements of an ideal iRM. It is an isotopically homogeneous, high-purity reference material, that is free of isotope anomalies, and whose composition is identical to that of a major geological reservoir (Ocean Island Basalts). Furthermore, RM 8299 will be curated and distributed by NIST, a neutral, conflict-of-interest free organization, and was produced in sufficient quantities to last multiple decades. We recommend that all Zr isotope data to be reported against RM 8299. Our results also show that SRM 3169 lots #130920 and #071226 have identical composition to RM 8299. Therefore, using RM 8299 as the scale defining iRM will enable direct comparison of all future data with the vast majority of the existing literature data, both for mass-independent and mass-dependent isotope effects. To facilitate conversion of d94/90Zr values reported against other Zr standards, we provide high-precision conversion factors to the RM 8299 scale obtained using the double-spike method.

A persistent question in exoplanet demographics is whether exoplanetary systems form from similar compositional building blocks to our own. Polluted white dwarf stars offer a unique way to address this question as they provide measurements of the bulk compositions of exoplanetary material. We present a statistical analysis of the rocks polluting oxygen-bearing white dwarfs and compare their compositions to rocks in the Solar System. We find that the majority of the extrasolar rocks are consistent with the composition of typical chondrites. Measurement uncertainties prevent distinguishing between chondrites and bulk Earth, but do permit detecting the differences between chondritic compositions and basaltic or continental crust. We find no evidence of crust amongst the polluted white dwarfs. We show that the chondritic nature of extrasolar rocks is also supported by the compositions of local stars. While galactic chemical evolution results in variations in the relative abundances of rock-forming elements spatially and temporally on galaxy-wide scales, the current sample of polluted white dwarfs are sufficiently young and close to Earth that they are not affected by this process. We conclude that exotic compositions are not required to explain the majority of observed rock types around polluted white dwarfs, and that variations between exoplanetary compositions in the stellar neighborhood are generally not due to significant differences in the initial composition of protoplanetary disks. Nonetheless, there is evidence from stellar observations that planets formed in the first several billion years in the Galaxy have lower metal core fractions compared with Earth on average., Comment: Accepted to PSJ

Earth's water, intrinsic oxidation state, and metal core density are fundamental chemical features of our planet. Studies of exoplanets provide a useful context for elucidating the source of these chemical traits. Planet formation and evolution models demonstrate that rocky exoplanets commonly formed with hydrogen-rich envelopes that were lost over time. These findings suggest that Earth may also have formed from bodies with H$_2$-rich primary atmospheres. Here we use a self-consistent thermodynamic model to show that Earth's water, core density, and overall oxidation state can all be sourced to equilibrium between H$_2$-rich primary atmospheres and underlying magma oceans in its progenitor planetary embryos. Water is produced from dry starting materials resembling enstatite chondrites as oxygen from magma oceans reacts with hydrogen. Hydrogen derived from the atmosphere enters the magma ocean and eventually the metal core at equilibrium, causing metal density deficits matching that of Earth. Oxidation of the silicate rocks from solar-like to Earth-like oxygen fugacities also ensues as Si, along with H and O, alloys with Fe in the cores. Reaction with hydrogen atmospheres and metal-silicate equilibrium thus provides a simple explanation for fundamental features of Earth's geochemistry that is consistent with rocky planet formation across the galaxy., Comment: 3 main figures, 5 auxiliary figures

Sub-Neptune exoplanets are commonly hypothesized to consist of a silicate-rich magma ocean topped by a hydrogen-rich atmosphere. Previous work studying the outgassing of silicate material has demonstrated that such atmosphere-interior interactions can affect the atmosphere's overall structure and extent. But these models only considered SiO in an atmosphere of hydrogen gas, without considering chemical reactions between them. Here we couple calculations of the chemical equilibrium between H, Si, and O species with an atmospheric structure model. We find that substantial amounts of silane, SiH$_4$, and water, H$_2$O, are produced by the interaction between the silicate-rich interior and hydrogen-rich atmosphere. These species extend high into the atmosphere, though their abundance is greatest at the hottest, deepest regions. For example, for a 4 $M_\oplus$ planet with an equilibrium temperature of 1000 K, a base temperature of 5000 K, and a 0.1 $M_\oplus$ hydrogen envelope, silicon species and water can comprise 30 percent of the atmosphere by number at the bottom of the atmosphere. Due to this abundance enhancement, we find that convection is inhibited at temperatures $\gtrsim 2500$ K. This temperature is lower, implying that the resultant non-convective region is thicker, than was found in previous models which did not account for atmospheric chemistry. Our findings show that significant endogenous water is produced by magma-hydrogen interactions alone, without the need to accrete ice-rich material. We discuss the observability of the signatures of atmosphere-interior interaction and directions for future work, including condensate lofting and more complex chemical networks., Comment: 13 pages, 12 figures, accepted for publication in MNRAS

We present observations and analyses of eight white dwarf stars that have accreted rocky material from their surrounding planetary systems. The spectra of these helium-atmosphere white dwarfs contain detectable optical lines of all four major rock-forming elements (O, Mg, Si, Fe). This work increases the sample of oxygen-bearing white dwarfs with parent body composition analyses by roughly thirty-three percent. To first order, the parent bodies that have been accreted by the eight white dwarfs are similar to those of chondritic meteorites in relative elemental abundances and oxidation states. Seventy-five percent of the white dwarfs in this study have observed oxygen excesses implying volatiles in the parent bodies with abundances similar to those of chondritic meteorites. Three white dwarfs have oxidation states that imply more reduced material than found in CI chondrites, indicating the possible detection of Mercury-like parent bodies, but are less constrained. These results contribute to the recurring conclusion that extrasolar rocky bodies closely resemble those in our solar system, and do not, as a whole, yield unusual or unique compositions., Comment: Accepted for publication in ApJ. 7 Figures, 7 Tables

We have conducted a NanoSIMS-based search for presolar material in samples recently returned from C-type asteroid Ryugu as part of JAXA's Hayabusa2 mission. We report the detection of all major presolar grain types with O- and C-anomalous isotopic compositions typically identified in carbonaceous chondrite meteorites: 1 silicate, 1 oxide, 1 O-anomalous supernova grain of ambiguous phase, 38 SiC, and 16 carbonaceous grains. At least two of the carbonaceous grains are presolar graphites, whereas several grains with moderate C isotopic anomalies are probably organics. The presolar silicate was located in a clast with a less altered lithology than the typical extensively aqueously altered Ryugu matrix. The matrix-normalized presolar grain abundances in Ryugu are 4.8$^{+4.7}_{-2.6}$ ppm for O-anomalous grains, 25$^{+6}_{-5}$ ppm for SiC grains and 11$^{+5}_{-3}$ ppm for carbonaceous grains. Ryugu is isotopically and petrologically similar to carbonaceous Ivuna-type (CI) chondrites. To compare the in situ presolar grain abundances of Ryugu with CI chondrites, we also mapped Ivuna and Orgueil samples and found a total of SiC grains and 6 carbonaceous grains. No O-anomalous grains were detected. The matrix-normalized presolar grain abundances in the CI chondrites are similar to those in Ryugu: 23 $^{+7}_{-6}$ ppm SiC and 9.0$^{+5.3}_{-4.6}$ ppm carbonaceous grains. Thus, our results provide further evidence in support of the Ryugu-CI connection. They also reveal intriguing hints of small-scale heterogeneities in the Ryugu samples, such as locally distinct degrees of alteration that allowed the preservation of delicate presolar material., Comment: 12 pages, 3 figures, 2 tables. Published in ApJL

Polluted white dwarfs offer a unique way to study the bulk compositions of exoplanetary material, but it is not always clear if this material originates from comets, asteroids, moons, or planets. We combine N-body simulations with an analytical model to assess the prevalence of extrasolar moons as white dwarf (WD) polluters. Using a sample of observed polluted white dwarfs we find that the extrapolated parent body masses of the polluters are often more consistent with those of many solar system moons, rather than solar-like asteroids. We provide a framework for estimating the fraction of white dwarfs currently undergoing observable moon accretion based on results from simulated white dwarf planetary and moon systems. Focusing on a three-planet white dwarf system of Super-Earth to Neptune-mass bodies, we find that we could expect about one percent of such systems to be currently undergoing moon accretions as opposed to asteroid accretion., Comment: Submitted to AAS journals, comments welcome

We use new experiments and a theoretical analysis of the results to show that the isotopic fractionation associated with laser-heating aerodynamic levitation experiments is consistent with the velocity of flowing gas as the primary control on the fractionation. The new Fe and Mg isotope data are well explained where the gas is treated as a low-viscosity fluid that flows around the molten spheres with high Reynolds numbers and minimal drag. A relationship between the ratio of headwind velocity to thermal velocity and saturation is obtained on the basis of this analysis. The recognition that it is the ratio of flow velocity to thermal velocity that controls fractionation allows for extrapolation to other environments in which molten rock encounters gas with appreciable headwinds. In this way, in some circumstances, the degree of isotope fractionation attending evaporation is as much a velocimeter as it is a barometer., Comment: Accepted for publication in Earth and Planetary Science Letters

The solar nebula contained a number of short-lived radionuclides (SLRs) with half-lives of tens of Myr or less, comparable to the timescales for formation of protostars and protoplanetary disks. Therefore, determining the origins of SLRs would provide insights into star formation and the Sun's astrophysical birth environment. In this chapter, we review how isotopic studies of meteorites reveal the existence and abundances of these now-extinct radionuclides; and the evidence that the SLR ${}^{10}{\rm Be}$, which uniquely among the SLRs is not produced during typical stellar nucleosynthesis, was distributed homogeneously in the solar nebula. We review the evidence that the SLRs ${}^{26}{\rm Al}$, ${}^{53}{\rm Mn}$, and ${}^{182}{\rm Hf}$, and other radionuclides, were also homogeneously distributed and can be used to date events during the Solar System's planet-forming epoch. The homogeneity of the SLRs, especially ${}^{10}{\rm Be}$, strongly suggests they were all inherited from the Sun's molecular cloud, and that production by irradiation within the solar nebula was very limited, except for ${}^{36}{\rm Cl}$. We review astrophysical models for the origin of ${}^{10}{\rm Be}$, showing that it requires that the Sun formed in a spiral arm of the Galaxy with higher star formation rate than the Galaxy-wide average. Likewise, we review the astrophysical models for the origins of the other SLRs and show that they likely arose from contamination of the Sun's molecular cloud by massive stars over tens of Myr, most likely dominated by ejecta from Wolf-Rayet stars. The other SLRs also demand formation of the Sun in a spiral arm of the Galaxy with a star formation rate as high as demanded by the Solar System initial ${}^{10}{\rm Be}$ abundance. We discuss the astrophysical implications, and suggest further tests of these models and future directions for the field., Comment: 37 pages, 8 figures. Submitted as a chapter to Protostars and Planets VII

We investigate equilibrium chemistry between molten metal and silicate, and a hydrogen-rich envelope using 18 independent reactions among 25 phase components for sub-Neptune-like exoplanets. Both reactive metal and unreactive metal sequestered in an isolated core are modeled. The overarching effects of equilibration are oxidation of the envelope and reduction of the mantle and core. Hydrogen and oxygen typically comprise significant fractions of metal cores at chemical equilibrium, leading to density deficits that offer a possible alternative explanation for the low densities of the Trappist-1 planets. Reactions with the magma ocean produce significant amounts of SiO and H$_2$O in the envelopes directly above the magma ocean. Molar concentrations in the envelopes of planets with reactive metal are H$_2>\rm{SiO}>CO\sim\rm{Na}\sim\rm{Mg}>\rm{H}_2\rm{O}>>\rm{CO}_2\sim\rm{CH}_4>>\rm{O}_2$ while for the unreactive metal case H$_2$O becomes the second most abundant species, after H$_2$, providing an arbiter for the two scenarios amenable to observation. The water abundances in the atmospheres exceed those in the mantles by at least an order of magnitude in both scenarios. The water concentrations in the silicate mantles are $\sim 0.01$ wt\% and $\sim 0.1$ wt\% in the reactive and unreactive metal core cases, respectively, limiting the H$_2$O that might be outgassed in a future super-Earth. Less dissolved water in the reactive core case is due to sequestration of H and O in the Fe-rich metal. The total hydrogen budget of most sub-Neptunes can be, to first order, estimated from their atmospheres alone, as the atmospheres typically contain more than 90\% of all H., Comment: Submitted to PSJ, 25 pages, 18 figures

We present evidence that excesses in Be in polluted white dwarfs (WDs) are the result of accretion of icy exomoons that formed in the radiation belts of giant exoplanets. Here we use excess Be in the white dwarf GALEX J2339-0424 as an example. We constrain the parent body abundances of rock-forming elements in GALEX J2339-0424 and show that the overabundance of beryllium in this WD cannot be accounted for by differences in diffusive fluxes through the WD outer envelope nor by chemical fractionations during typical rock-forming processes. We argue instead that the Be was produced by energetic proton irradiation of ice mixed with rock. We demonstrate that the MeV proton fluence required to form the high Be/O ratio in the accreted parent body is consistent with irradiation of ice in the rings of a giant planet within its radiation belt, followed by accretion of the ices to form a moon that is later accreted by the WD. The icy moons of Saturn serve as useful analogs. Our results provide an estimate of spallogenic nuclide excesses in icy moons formed by rings around giant planets in general, including those in the solar system. While excesses in Be have been detected in two polluted WDs to date, including the WD described here, we predict that excesses in the other spallogenic elements Li and B, although more difficult to detect, should also be observed, and that such detections would also indicate pollution by icy exomoons formed in the ring systems of giant planets., Comment: 13 pages, 4 figures, 1 table

The element beryllium is detected for the first time in white dwarf stars. This discovery in the spectra of two helium-atmosphere white dwarfs was made possible only because of the remarkable overabundance of Be relative to all other elements, heavier than He, observed in these stars. The measured Be abundances, relative to chondritic, are by far the largest ever seen in any astronomical object. We anticipate that the Be in these accreted planetary bodies was produced by spallation of one or more of O, C, and N in a region of high fluence of particles of MeV or greater energy., Comment: 23 pages, 11 figures, 9 tables, v2: revised, accepted for publication in ApJ

We utilize observations of 16 white dwarf stars to calculate and analyze the oxidation states of the parent bodies accreting onto the stars. Oxygen fugacity, a measure of overall oxidation state for rocks, is as important as pressure and temperature in determining the structure of a planet. We find that most of the extrasolar rocky bodies formed under oxidizing conditions, but approximately 1/4 of the polluted white dwarfs have compositions consistent with more reduced parent bodies. The difficulty in constraining the oxidation states of relatively reduced bodies is discussed and a model for the time-dependent evolution of the apparent oxygen fugacity for a hypothetical reduced body engulfed by a WD is investigated. Differences in diffusive fluxes of various elements through the WD envelope yield spurious inferred bulk elemental compositions and oxidation states of the accreting parent bodies under certain conditions. The worst case for biasing against detection of reduced bodies occurs for high effective temperatures. For moderate and low effective temperatures, evidence for relatively reduced parent bodies is preserved under most circumstances for at least several characteristic lifetimes of the debris disk., Comment: 22 pages, 13 figures; accepted for publication in ApJ

Oxygen fugacity is a measure of rock oxidation that influences planetary structure and evolution. Most rocky bodies in the Solar System formed at oxygen fugacities approximately five orders of magnitude higher than a hydrogen-rich gas of solar composition. It is unclear whether this oxidation of rocks in the Solar System is typical among other planetary systems. We exploit the elemental abundances observed in six white dwarfs polluted by the accretion of rocky bodies to determine the fraction of oxidized iron in those extrasolar rocky bodies and therefore their oxygen fugacities. The results are consistent with the oxygen fugacities of Earth, Mars, and typical asteroids in the Solar System, suggesting that at least some rocky exoplanets are geophysically and geochemically similar to Earth., Comment: 12 pages of main text, 3 figures in the main text

The photospheres of some white dwarfs are "polluted" by accretion of material from their surrounding planetary debris. White dwarfs with dust disks are often heavily polluted and high-resolution spectroscopic observations of these systems can be used to infer the chemical compositions of extrasolar planetary material. Here, we report spectroscopic observation and analysis of 19 white dwarfs with dust disks or candidate disks. The overall abundance pattern very much resembles that of bulk Earth and we are starting to build a large enough sample to probe a wide range of planetary compositions. We found evidence for accretion of Fe-rich material onto two white dwarfs as well as O-rich but H-poor planetary debris onto one white dwarf. In addition, there is a spread in Mg/Ca and Si/Ca ratios and it cannot be explained by differential settling or igneous differentiation. The ratios appear to follow an evaporation sequence. In this scenario, we can constrain the mass and number of evaporating bodies surrounding polluted white dwarfs., Comment: 22 pages, 13 figures, 7 tables, AJ, in press

Water content and the internal evolution of terrestrial planets and icy bodies are closely linked. The distribution of water in planetary systems is controlled by the temperature structure in the protoplanetary disk and dynamics and migration of planetesimals and planetary embryos. This results in the formation of planetesimals and planetary embryos with a great variety of compositions, water contents and degrees of oxidation. The internal evolution and especially the formation time of planetesimals relative to the timescale of radiogenic heating by short-lived 26Al decay may govern the amount of hydrous silicates and leftover rock-ice mixtures available in the late stages of their evolution. In turn, water content may affect the early internal evolution of the planetesimals and in particular metal-silicate separation processes. Moreover, water content may contribute to an increase of oxygen fugacity and thus affect the concentrations of siderophile elements within the silicate reservoirs of Solar System objects. Finally, the water content strongly influences the differentiation rate of the icy moons, controls their internal evolution and governs the alteration processes occurring in their deep interiors., Comment: 45 pages, 13 figures, accepted in Space Sci. Rev

We report the relative abundances of the three stable isotopes of silicon, $^{28}$Si, $^{29}$Si and $^{30}$Si, across the Galaxy using the $v = 0, J = 1 \to 0$ transition of silicon monoxide. The chosen sources represent a range in Galactocentric radii ($R_{\rm GC}$) from 0 to 9.8 kpc. The high spectral resolution and sensitivity afforded by the GBT permit isotope ratios to be corrected for optical depths. The optical-depth-corrected data indicate that the secondary-to-primary silicon isotope ratios $^{29}{\rm Si}/^{28}{\rm Si}$ and $^{30}{\rm Si}/^{28}{\rm Si}$ vary much less than predicted on the basis of other stable isotope ratio gradients across the Galaxy. Indeed, there is no detectable variation in Si isotope ratios with $R_{\rm GC}$. This lack of an isotope ratio gradient stands in stark contrast to the monotonically decreasing trend with $R_{\rm GC}$ exhibited by published secondary-to-primary oxygen isotope ratios. These results, when considered in the context of the expectations for chemical evolution, suggest that the reported oxygen isotope ratio trends, and perhaps that for carbon as well, require further investigation. The methods developed in this study for SiO isotopologue ratio measurements are equally applicable to Galactic oxygen, carbon and nitrogen isotope ratio measurements, and should prove useful for future observations of these isotope systems., Comment: 18 pages, 12 figures, 2 tables. Published in The Astrophysical Journal, Volume 839, Issue 2

The presence of excesses of short-lived radionuclides in the early solar system evidenced in meteorites has been taken as testament to close encounters with exotic nucleosynthetic sources, including supernovae or AGB stars. An analysis of the likelihoods associated with different sources of these extinct nuclides in the early solar system indicates that rather than being exotic, their abundances were typical of star-forming regions like those observed today in the Galaxy. The radiochemistry of the early solar system is therefore unexceptional, being the consequence of extensive averaging of molecular cloud solids., Comment: In press, ApJ

Earth and Moon are shown here to be composed of oxygen isotope reservoirs that are indistinguishable, with a difference in {\Delta}"17O of -1 +/- 5ppm (2se). Based on these data and our new planet formation simulations that include a realistic model for oxygen isotopic reservoirs, our results favor vigorous mixing during the giant impact and therefore a high-energy high- angular-momentum impact. The results indicate that the late veneer impactors had an average {\Delta}"17O within approximately 1 per mil of the terrestrial value, suggesting that these impactors were water rich.

This study reports an unusual heterogeneity in [$^{12}$C$^{16}$O]/[$^{13}$C$^{16}$O] abundance ratios of carbon monoxide observed in the gas phase toward seven ~ solar-mass YSOs and three dense foreground clouds in the nearby star-forming regions, Ophiuchus, Corona Australis, Orion, Vela and an isolated core, L43. Robust isotope ratios were derived using infrared absorption spectroscopy of the 4.7 $\mu$m fundamental and 2.3 $\mu$m overtone rovibrational bands of CO at very high resolution ($\lambda$/$\Delta$$\lambda\approx 95,000$), observed with the CRIRES spectrograph on the Very Large Telescope. We find [$^{12}$C$^{16}$O]/[$^{13}$C$^{16}$O] values ranging from ~ 85 to 165, significantly higher than those of the local interstellar medium (~ 65 to 69). These observations are evidence for isotopic heterogeneity in carbon reservoirs in solar-type YSO environments, and encourage the need for refined Galactic chemical evolution models to explain the $^{12}$C/$^{13}$C discrepancy between the solar system and local ISM. The oxygen isotope ratios are consistent with isotopologue-specific photodissociation by CO self-shielding toward the disks, VV CrA N and HL Tau, further substantiating models predicting CO self-shielding on disk surfaces. However, we find that CO self-shielding is an unlikely general explanation for the high [$^{12}$C$^{16}$O]/[$^{13}$C$^{16}$O] ratios observed in this study. Comparison of the solid CO against gas-phase [$^{12}$C$^{16}$O]/[$^{13}$C$^{16}$O] suggests that interactions between CO ice and gas reservoirs need to be further investigated as at least a partial explanation for the unusually high [$^{12}$C$^{16}$O]/[$^{13}$C$^{16}$O] observed., Comment: 16 pages, 14 figures, 7 tables. Accepted for publication in The Astrophysical Journal