Search

The first palladium‐catalyzed allylation of isocyanoacetates with vinyl aziridines has been developed. The reaction conditions were suitable for a variety of α‐aryl isocyanoacetates as well as N‐substituted vinyl aziridines, affording the corresponding allylation products in moderate to high yields (up to 98 %) along with excellent stereoselectivity and regioselectivity. Transformations of the allylation products into trans‐4,5‐dehydrolysine analogues and a highly functionalized proline ester derivative were further demonstrated, and a preliminary asymmetric version of the reaction has also been evaluated. [ABSTRACT FROM AUTHOR]

Abstract Researchers face difficulties in studying the effects of driveline efficiency on car fuel economy via bench and road tests because of long working periods, high costs, and heavy workloads. To simplify the study process and shorten test cycles, a car fuel economy simulation forecast method for combining computer simulation forecasting with bench tests is proposed. Taking a continuously variable transmission (CVT) as the research object, a transmission efficiency model based on a bench test is constructed. An optimal economic variogram based on the original CVT variogram, the boundary conditions of vehicle performance, the road conditions and the driving behavior of the driver is generated in the Gear Shift Program (GSP)-Generation module in AVL Cruise. And on this basis a driveline simulation model that can calculate the fuel consumption based on the driveline data of a test car is built. The model is used to forecast fuel consumption and calculate real-time CVT efficiency under different conditions. Contrastive analyses on simulation results and real car drum test results are made. The largest error between simulation results and drum test results in driving cycles is 4.099%, which is 5.449% under constant velocity condition in driver control mode and 4.2% under constant velocity condition in automatic cruise mode. The results confirm the feasibility of the method and the good performance of the driveline simulation model in accurately forecasting fuel consumption. The method can efficiently investigate the effects of driveline efficiency on car fuel economy. Moreover, this research provides instruction for accurately forecasting fuel economy as well as references for studies on the effects of drivelines on car fuel economy.