1. Electrochemical properties of an all-solid-state lithium-ion battery with an in-situ formed electrode material grown from a lithium conductive glass ceramics sheet
- Author
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Tsukasa Hirayama, Fumihiro Sagane, Masao Sudoh, Kazuo Yamamoto, Munekazu Motoyama, Yasutoshi Iriyama, and Yuichi Amiki
- Subjects
Battery (electricity) ,Materials science ,Renewable Energy, Sustainability and the Environment ,Inorganic chemistry ,Energy Engineering and Power Technology ,chemistry.chemical_element ,Electrolyte ,Electrochemistry ,Lithium-ion battery ,chemistry ,Chemical engineering ,Electrode ,Lithium ,Electrical and Electronic Engineering ,Physical and Theoretical Chemistry ,Thin film ,Titanium - Abstract
A lithium insertion reaction in a Li + conductive glass ceramics solid electrolyte (lithium aluminum titanium phosphate: LATP) sheet produces an in-situ formed electrode active material, which operates at 2.35 V vs. Li/Li + in the vicinity of the LATP-sheet/current–collector interface. Electron energy loss spectroscopy clarifies that titanium in the LATP sheet in the vicinity of the current collector/LATP-sheet interface is preferentially reduced by this lithium insertion reaction. Charge transfer resistance between the in-situ-formed-electrode and the LATP-sheet is less than 100 Ω cm 2 , which is smaller than that of the common LiPON/LiCoO 2 interface. A thin film of LiCoO 2 is deposited on one side of the LATP-sheet as a Li + source for developing the in-situ formed electrode material. Eventually, a Pt/LATP-sheet/LiCoO 2 /Au multilayer is fabricated. The multilayer structure successfully works as an all-solid-state lithium-ion battery operating at 1.5 V. A redox peak of the battery is observed even at 100 mV s −1 in the potential sweep curve. Additionally, charge–discharge reactions are repeated stably even after 25 cycles.
- Published
- 2013
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