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Understanding the thermal-fluid characteristics of boiling hydrogen is of great significance for applications of liquid hydrogen, such as alternative clean energy and space vehicles. The boiling temperature of liquid hydrogen under atmospheric pressure is 20.3 K; thus, it is easy to boil to form a gas–liquid two-phase flow. Fuel transfer under the boiling state has been avoided in the space industry because of its unstable flow characteristics; precise control of the fuel, including the boiling flow, is necessary to improve the space-vehicle performance. This study aims to understand the flow-regime transition characteristics of boiling hydrogen through experimental investigation. The experimental conditions were as follows: the flow direction was horizontal, the inner diameter of the heating pipe was 15 mm, the mass flux ranged from 50 to 110 kg/m2s, and the pressure ranged from 250 to 300 kPa A. The flow-regime transition characteristics were obtained by a high-speed camera. Fully liquid phase (LP), dispersed bubbly flow (DB), intermittent flow (IN), and annular flow (AN) were observed during the experiment. Each flow-regime boundary model is constructed using two dominant forces from the experimental result based on a Taitel–Dukler model. For the DB/IN boundary, a large-bubble sustainable condition is derived by the balance between the shear and buoyancy forces acting upon the bubble; for the IN/AN boundary, a droplet-sustainable condition is derived in terms of the force balance between the drag and gravity acting on the droplet. The semi-theoretical model predicts the experimental data with 96.7% accuracy.

Accepted: 2019-12-13, 資料番号: SA1190199000

Accepted: 2019-05-09, 資料番号: SA1190071000

Accepted: 2018-07-23, 資料番号: SA1180211000

Band gap opening in bilayer graphene (BLG) under a vertical electric field is important for the realization of high performance graphene-based semiconductor devices, and thus, the synthesis of uniform and large-area BLG is required. Here we demonstrate the synthesis of a highly uniform BLG film by chemical vapor deposition (CVD) over epitaxial Cu−Ni (111) binary alloy catalysts. The relative concentration of Ni and Cu as well as the growth temperature and cooling profile was found to strongly influence the uniformity of the BLG. In particular, a slow cooling process after switching off the carbon feedstock is important for obtaining a uniform second layer, covering more than 90% of the total area. Moreover, low-energy electron microscopy (LEEM) study revealed the second layer grows underneath the first layer. We also investigated the stacking order by Raman spectroscopy and LEEM and found that 70–80% of bilayer graphene has Bernal stacking. The metastable 30°-rotated orientations were also observed both i...

Chemical functionalisation is a promising method to tune the electronic structure of graphene, and the two-dimensional structure of graphene enables access to both of its faces for various types of functionalisation. Here, we present the effect of covalent functionalisation on the Raman spectrum in terms of monofacial (one-sided) and bifacial (two-sided) functionalisation using both monolayer and bilayer graphene. Asymmetrical or ‘Janus’ functionalisation is found to provide significantly increased levels of doping compared to other schemes allowing for control over graphene's electronic structure as well as control over surface functionality.