Search

Polaritons are a hybrid class of quasiparticles originating from the strong and resonant coupling between light and matter excitations. Recent years have witnessed a surge of interest in novel polariton types, arising from directional, long-lived material resonances, and leading to extreme optical anisotropy that enables novel regimes of nanoscale, highly confined light propagation. While such exotic propagation features may also be in principle achieved using carefully designed metamaterials, it has been recently realized that they can naturally emerge when coupling infrared light to directional lattice vibrations, i.e., phonons, in polar crystals. Interestingly, a reduction in crystal symmetry increases the directionality of optical phonons and the resulting anisotropy of the response, which in turn enables new polaritonic phenomena, such as hyperbolic polaritons with highly directional propagation, ghost polaritons with complex-valued wave vectors, and shear polaritons with strongly asymmetric propagation features. In this Review, we develop a critical overview of recent advances in the discovery of phonon polaritons in low-symmetry crystals, highlighting the role of broken symmetries in dictating the polariton response and associated nanoscale-light propagation features. We also discuss emerging opportunities for polaritons in lower-symmetry materials and metamaterials, with connections to topological physics and the possibility of leveraging anisotropic nonlinearities and optical pumping to further control their nanoscale response.

Following the discovery of moir\'e-driven superconductivity in twisted graphene multilayers, twistronics has spurred a surge of interest in tailored broken symmetries through angular rotations, enabling new properties from electronics to photonics and phononics. Analogously, in monoclinic polar crystals a nontrivial angle between non-degenerate dipolar phonon resonances can naturally emerge due to asymmetries in their crystal lattice, and its variations are associated with intriguing polaritonic phenomena, including axial dispersion, i.e., a rotation of the optical axis with frequency, and microscopic shear effects that result in asymmetric loss distributions. So far these phenomena were restricted to specific mid-infrared frequencies, difficult to access with conventional lasers, and fundamentally limited by the degree of asymmetry and the strength of light-matter interactions available in natural crystals. Here, we leverage twistronics to demonstrate giant axial dispersion and loss asymmetry of hyperbolic waves in elastic metasurfaces, by tailoring the angle between coupled pairs of anisotropic metasurfaces. We show extreme control over elastic wave dispersion via the twist angle, and leverage the resulting phenomena to demonstrate reflection-free negative refraction, as well as the application of axial dispersion to achieve diffraction-free non-destructive testing, whereby the angular direction of a hyperbolic probe wave is encoded into its frequency. Our work welds the concepts of twistronics, non-Hermiticity and extreme anisotropy, demonstrating the powerful opportunities enabled by metasurfaces for tunable, highly directional surface acoustic wave propagation, of great interest for applications ranging from seismic mitigation to on-chip phononics and wireless communications, paving the way towards their translation into emerging photonic and polaritonic metasurface technologies.

Abbe diffraction limit fundamentally bounds the resolution of conventional optical imaging and spectroscopic systems. Along the years, several schemes have been introduced to overcome this limit, each offering opportunities and trade-offs. Metamaterials have been proposed as a promising platform in this context, in principle enabling superlenses capable of drastic resolution enhancements. However, their performance is severely hindered by material loss and nonlocal phenomena, which become increasingly more detrimental as we attempt to image more subwavelength details. Active metamaterials have been explored to overcome these challenges, however material gain introduces other obstacles, e.g., instabilities, nonlinearities and noise. Here, we demonstrate that the temporal excitation of passive superlenses using signals oscillating at complex frequencies compensates material loss, leading to resolution enhancement. Our results demonstrate that virtual gain stemming from tailored forms of excitation can tackle the impact of loss in superlenses. More broadly, our work opens promising avenues for loss compensation in metamaterials, with a broad range of applications extendable to optics and nanophotonic systems., Comment: 19 pages, 4 figures

One of the most significant breakthroughs in physics of the last decade has been the discovery that materials with non-trivial topological properties for electronic, electromagnetic, acoustic and mechanical responses can be designed and manufactured at our will through engineered metamaterials (MMs). Here, we review the foundation and the state-of-the-art advances of topological photonics, acoustics and mechanical MMs. We discuss how topological MMs enable nontrivial wave phenomena in physics, engineering, of great interest for a broad range of interdisciplinary science disciplines such as classical and quantum chemistry. We first introduce the foundations of topological materials and the main concepts behind their peculiar features, including the concepts of topological charge and geometric phase. We then discuss the topology of electronic band structures in natural topological materials, like topological insulators and gapless Dirac and Weyl semimetals. Based on these concepts, we review the concept, design and response of topologically nontrivial MMs in photonics and phononics, including topological phases in 2D MMs with and without time-reversal symmetry, Floquet TIs based on spatial and temporal modulation, topological phases in 3D MMs, higher-order topological phases in MMs, non-Hermitian and nonlinear topological MMs and the topological features of scattering anomalies. We also discuss the topological properties emerging in other related contexts, such as the topological aspects of chemical reactions and polaritons. This survey aims at connecting the recent advances in a broad range of scientific areas associated with topological concepts, and highlights opportunities offered by topological MMs for the chemistry community at large.

Recently, the domain of topological insulators in condensed matter physics has been teeming with intriguing and very exciting discoveries. Notably, the capacity of guiding currents towards specific directions according to the spin of the travelling electrons has a great potential for electronic devices. This new phenomenon has been transposed to the classical domain in electromagnetics and acoustics, unveiling the pseudo-spin locking of guided waves. However, these macroscopic analogues are photonic/phononic crystals which are intrinsically wavelength scaled. In this work, we realize a genuine acoustic analogue of the valley-Hall effect in the audible regime using a lattice of soda cans. The crystalline description of this very simple metamaterial allows us to demonstrate experimentally the unidirectional excitation of sound guided at a scale much smaller than the wavelength of operation. These results not only open the tantalizing valley-topological phenomena to the audible regime but also allow to envision compact applications for acoustic manipulation.

The exciting discovery of bi-dimensional systems in condensed matter physics has triggered the search of their photonic analogues. In this letter, we describe a general scheme to reproduce some of the systems ruled by a tight-binding Hamiltonian in a locally resonant metamaterial: by specifically controlling the structure and the composition it is possible to engineer the band structure at will. We numerically and experimentally demonstrate this assertion in the microwave domain by reproducing the band structure of graphene, the most famous example of those 2D-systems, and by accurately extracting the Dirac cones. This is a direct evidence that opting for a crystalline description of those sub-wavelength scaled systems, as opposed to the usual description in terms of effective parameters, makes them a really convenient tabletop platform to investigate the tantalizing challenges that solid-state physics offer.

Wave propagation control is of fundamental interest in many areas of Physics. It can be achieved with wavelength-scaled photonic crystals, hence avoiding low frequency applications. By contrast, metamaterials are structured on a deep-subwavelength scale, and therefore usually described through homogenization, neglecting the unit-cell structuration. Here, we show with microwaves that, by considering their inherent crystallinity, we can induce wave propagation carrying angular momenta within a subwavelength-scaled collection of wires. Then, inspired by the Quantum Valley-Hall Effect in condensed matter physics, we exploit this bulk circular polarization to create modes propagating along particular interfaces. The latter also carry an edge angular momentum whose conservation during the propagation allows wave routing by design in specific directions. This experimental study not only evidences that crystalline metamaterials are a straightforward tabletop platform to emulate exciting solid-state physics phenomena at the macroscopic scale, but it also opens the door to crystalline polarized subwavelength waveguides., Comment: 5 figures

Due to the deep sub-wavelength unit cell in metamaterials, the quasi-static approximation is usually employed to describe the propagation. By making pairs of resonators, we highlight that multiple scattering also occurs at this scale and results in the existence of a dipolar resonance, which leads to a negative index of refraction when we consider several resonators. We experimentally verify the possibility of obtaining a negative index of refraction in periodic metamaterials in two different ways, and eventually demonstrates a superlensing effect in both cases.

The exciting discovery of topological condensed matter systems has lately triggered a search for their photonic analogs, motivated by the possibility of robust backscattering-immune light transport. However, topological photonic phases have so far only been observed in photonic crystals and waveguide arrays, which are inherently physically wavelength scaled, hindering their application in compact subwavelength systems. In this letter, we tackle this problem by patterning the deep subwavelength resonant elements of metamaterials onto specific lattices, and create crystalline metamaterials that can develop complex nonlocal properties due to multiple scattering, despite their very subwavelength spatial scale that usually implies to disregard their structure. These spatially dispersive systems can support subwavelength topological phases, as we demonstrate at microwaves by direct field mapping. Our approach gives a straightforward tabletop platform for the study of photonic topological phases, and allows to envision applications benefiting the compactness of metamaterials and the amazing potential of topological insulators.