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Achieving efficient catalytic conversion over a heterogeneous catalyst with excellent resistance against leaching is still a grand challenge for sustainable chemical synthesis in aqueous solution. Herein, we devised a single‐atom Pt1/hydroxyapatite (HAP) catalyst via a simple hydrothermal strategy. Gratifyingly, this robust Pt1/HAP catalyst exhibits remarkable catalytic selectivity and catalyst stability for the selective oxidation of C2–C4 polyols to corresponding primary hydroxy acids. It is found that the Pt−(O−P) linkages with strong electron‐withdrawing function of PO43− (Pt1−OPO43− pair active site) not only realize the activation of the C−H bond, but also destabilize the transition state from adsorbed hydroxy acids toward the C−C cleavage, resulting in the sharply increased selectivity of hydroxy acids. Moreover, the strong PO43−‐coordination effect provides electrostatic stabilization for single‐atom Pt, ensuring the highly efficient catalysis of Pt1/HAP for over 160 hours with superior leaching resistance. [ABSTRACT FROM AUTHOR]

Background: The recent experimental discovery of drip-line nucleus 39Na has attracted great interest in theoretical studies of exotic nuclear structures in this mass region. Methods: We solve the Skyrme–Hartree–Fock–Bogoliubov (Skyrme-HFB) equation within deformed coordinate-spaces. The present approach is suitable for descriptions of weakly bound deformed nuclei with continuum effects and deformed halo structures. Results: The systematical two-neutron separation energies are obtained with the SkM ext 1 * and UNEDF0 ext 1 forces for Na and Mg isotopes close to the neutron drip line. The density distributions show that 39 Na and 42 Mg have deformed halo structures. Furthermore, there are significant influences of various pairing interactions on halo shapes at large distances. Conclusions: Both 39 Na and 42 Mg are very weakly bound with well prolate deformed cores. However, their surface halo structures are dependent on the choices of pairing interactions. The volume-type pairing interaction tends to predict a prolate deformed halo, while the halo deformations at large distances are reduced by adopting the surface pairing. We demonstrate that 39 Na and 42 Mg are promising candidates for two-neutron deformed halo nuclei. [ABSTRACT FROM AUTHOR]