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The soluble solids content (SSC) of pears is mainly composed of sugars, organic acids, and other soluble substances and is one of the important indices used to measure the sweetness and quality of pear juice. The SSC of pears is mainly composed of sugars, organic acids, amino acids, esters, alcohols, phenols, flavonoids, and other compounds, and different groups within these compounds have different characteristic absorption peaks corresponding to different characteristic wavelengths. Traditional methods such as genetic algorithm (GA) and competitive adaptive reweighted sampling (CARS) models used for screening characteristic wavelengths are mainly based on statistical methods, and characteristic wavelengths are selected by finding the wavelengths related to the changes in the concentration of the target analytes. By ignoring the molecular structure and chemical properties of the target analytes and disregarding the influence of the groups of the compounds in the target analytes on the spectral characteristics, wavelengths that are not related to the target analytes may be selected, thus affecting the accuracy of the analytical results. In this paper, a partial least squares (PLS) model was established based on the characteristic wavelengths of CARS, GA, and LASSO algorithms, and the best least absolute shrinkage and selection operator (LASSO) was selected and compared with the characteristic wavelengths selected by group weighted fusion (GWF). The LASSO regression was validated by 10-fold cross-validation to select the appropriate regularization parameter, and the 33 characteristic wavelengths correlated with the SSC of pears were selected in the full spectral range, and the 9 characteristic wavelengths corresponding to the group response were weighted and fused and input into the PLS regression model. Using an established model, the coefficient of determination (R2) and the root mean square error (RMSE) of the calibration set were 0.992 and 0.177%, respectively, and the R2 and RMSE of the test set were 0.998 and 0.128%, respectively. The R2 of our LASSO–GWF–PLS prediction model was improved from 0.975 to 0.998, indicating that the LASSO–GWF–PLS method has very good prediction ability for detection of SSC in pears. [ABSTRACT FROM AUTHOR]

Molybdenum diselenide and cobalt diselenide have been commonly implemented in electrocatalytic hydrogen evolution reaction (HER). However, there have been few research on the creation of their three‐phase heterojunctions and the associated HER process. Herein, we constructed a three‐phase heterostructure sample consisting of orthorhombic CoSe2, cubic CoSe2 and MoSe2 and we investigated its HER performance. The sample shows microsphere morphology composed of nanosheets with interfacial interactions between the components. It possesses an overpotential of −136 mV at −10 mA cm−2 in acid medium, which is superior to that of single component and most two‐phase heterostructures. Especially, the overpotential at −200 mA cm−2 is smaller than that of Pt/C. The excellent performance can be attributed to the d‐orbital upshift of the Co active sites due to charge redistribution between the three‐phase heterojunction and the optimization of the hydrogen free energy. This work provides inspiration for exploring the application of other multi‐component heterojunctions in electrocatalytic hydrogen evolution. [ABSTRACT FROM AUTHOR]

Molybdenum diselenide and cobalt diselenide have been commonly implemented in electrocatalytic hydrogen evolution reaction (HER). However, there have been few research on the creation of their three-phase heterojunctions and the associated HER process. Herein, we constructed a three-phase heterostructure sample consisting of orthorhombic CoSe 2 , cubic CoSe 2 and MoSe 2 and we investigated its HER performance. The sample shows microsphere morphology composed of nanosheets with interfacial interactions between the components. It possesses an overpotential of -136 mV at -10 mA cm -2 in acid medium, which is superior to that of single component and most two-phase heterostructures. Especially, the overpotential at -200 mA cm -2 is smaller than that of Pt/C. The excellent performance can be attributed to the d-orbital upshift of the Co active sites due to charge redistribution between the three-phase heterojunction and the optimization of the hydrogen free energy. This work provides inspiration for exploring the application of other multi-component heterojunctions in electrocatalytic hydrogen evolution., (© 2022 Wiley-VCH GmbH.)