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Carbonation treatment is a promising option to enhance recycled concrete aggregate (RCA) quality and eventually improve concrete performance. This study investigated the multi-scale mechanical properties of calcium silicate hydrates (C-S-H) in a mature alite paste subjected to accelerated carbonation treatment by testing macro compressive strength, microhardness and nanoindentation. The results show that, carbonation treatment resulted in a heterogeneous distribution of carbonation products in the alite sample. Reinforcement of C-S-H by the randomly precipitated calcite and vaterite crystals prevailed over the nano-structural and compositional alteration of C-S-H induced by carbonation, leading to an increase of nano-indentation modulus at the edge of the sample. Also, the microhardness at the edge zone was markedly higher than that at the core of the carbonated sample. The carbonated peripheral zone with improved nano-scale modulus and microhardness was likely serving as a "hard shell", contributing to the improved macro compressive strength. The new insights into the multi-scale mechanical properties of carbonated C-S-H contribute to further understanding of the enhanced properties of RCA after carbonation treatment.

Treatment by accelerated carbonation has been widely studied to enhance the quality of recycled concrete aggregates (RCA) and hence the performance of new concrete produced with the RCA. This is often ascribed to the densification of RCA. This study investigated the influence of carbonation treatment of modeled RCA on the interface between the carbonated RCA and new cement mortar/paste using frictional (shear) and tensile bond tests, microhardness, X-ray diffraction (XRD), thermal analysis (TGA), and scanning electron microscope (SEM). It was found that carbonation treatment resulted in massive calcite precipitating on the surface of RCA, which further reacted with the aluminate species of the new cement to form the monocarbonate (Mc), and served as nucleation sites for the grow of C-S-H on the surface of RCA. These led to local densification around the surface of the carbonated RCA, resulting in a slight reduction of the porosity at the innermost part of ITZ and improved microhardness of ITZ. Moreover, the chemical bonds provided a superior adhesion of the carbonated RCA with the new cement pastes. This improved the bond strengths between the carbonated RCA and the new cement mortar.