1. Self-doped (N/O/S) nanoarchitectonics of hierarchically porous carbon from palm flower for high-performance supercapacitors.
- Author
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Zhang, Pinghua, Li, Yangyang, Wang, Mengzhuo, Zhang, Dejin, Ouyang, Wenzhu, Liu, Lin, Wang, Mingli, Zhang, Keying, Wang, Hongyan, and Chen, Chong
- Subjects
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SUPERCAPACITORS , *SUPERCAPACITOR electrodes , *ENERGY density , *POROUS materials , *ENERGY storage , *RENEWABLE energy sources , *SURFACE area - Abstract
Based on the pyrolysis of palm flower, self-doped multi-heteroatoms nanoarchitectonics of hierarchically porous carbon materials have been designed and synthesized. The derived materials which co-doped with N, O, and S, exhibit an ultra-high specific surface area of 3362.51 m2 g−1 and an extra-large pore volume of 2.34 cm3 g−1 with interconnected macro-, meso- and micro-pores. The as-synthesized material shows satisfactory electrochemical properties, including high specific capacitance of 391.05 F g−1 (at 1 A g−1), good rate capability (85.70 % capacitance retention at 10 A g−1) and superior cycling performance in alkaline electrolyte. The as-fabricated symmetric supercapacitor, at a stable working voltage of 3.5 V, shows a high energy density of 128.63 Wh kg−1 and excellent cycle life of 94.93 % after 10,000 cycles in ionic liquids electrolyte. The porous carbon materials derived from nature materials can be good candidate materials for fabricating energy storage devices. [Display omitted] • PF-HPCs x with multi-heteroatoms self- and co-doped • The nanoarchitectonics hierarchically carbon possess ultra-large surface area. • The supercapacitors show good rate capability and high energy density. • A clear strategy of renewable resources selection for energy storage is provided. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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