Search

The India-Asia collision reactivated the early Paleozoic Qilian orogen with an intense metamorphic belt that promoted the release of metamorphism-generated radiogenic Sr into the drainage systems on the NE Tibetan Plateau. This metamorphic impact on the regional dissolved Sr cycle is well observed at the recent−modern scale, but its onset and evolutionary histories are unclear. We present the first basin-scale 52−5 Ma regional dissolved Sr isotopic record in water on the NE Tibetan Plateau by analyzing well-dated basin fluvial-lacustrine sediments in the Xining, Linxia, and Tianshui Basins. The Xining Basin displays an increase in basin water 87Sr/86Sr ratio and a decrease in the sediment εNd values at ca. 25 Ma. This Sr-Nd isotope-deduced provenance change coincides with the reorganization of drainage and erosion regimes that is suggested by an evident rise in the youngest peak and the lag time of detrital apatite fission-track ages from Cenozoic sedimentary basins surrounding the Qilian orogen. The Qilian-sourced eolian dust during ca. 9−8 Ma significantly elevated the river and lake water 87Sr/86Sr ratios in the downwind Linxia and Tianshui Basins, which is consistent with the expansion of the Asian dust system. Our results suggest that large-scale denudation of the Qilian orogen in response to the India-Asia collision initiated in the late Oligocene. Given the remarkable hydrological impact of the Cenozoic reactivation of the Qilian orogen, our study highlights the potentially important role of continental collision−formed metamorphic belts in regulating past regional and even seawater Sr isotope evolution.

Tracing pedogenic processes is fundamental for reconstructing climatic and environmental changes using loess deposits. Lithium isotopes can serve as a sensitive tracer to unravel these processes, owing to its active behaviors without effect by redox and biological reactions. This study investigated the Li contents and δ7Li values of leachate and residue ([Li]leachate, [Li]residue, δ7Lileachate and δ7Liresidue) of the upper 12.5 m Luochuan loess-paleosol sediment (since the last interglacial) on the Chinese Loess Plateau, in order to better understand pedogenic processes in loess. The [Li]leachate, varying from 0.39 to 1.97 μg/g, is mainly derived from the adsorption phase, with a significant variation in δ7Lileachate, from −6.55‰ to +12.88‰. Both [Li]leachate and δ7Lileachate variations reflect weathering and adsorption processes during different periods. The [Li]residue vary from 34.4 to 46.3 μg/g (averaging 38.4 μg/g) and their δ7Liresidue vary from −3.66‰ to +2.44‰ (averaging −0.22 ± 1.68‰), both in agreement with the upper continental crust values. At initial stage after loess deposited (stage I), high [Li]leachate but low δ7Lileachate are results of preferential adsorption of 6Li by clays and migration of 7Li with soil solution during weathering and eluviation processes. When overlying loess was deposited and experienced pedogenesis as the stage I, 7Li migrated downward and was adsorbed by clays (stage II), resulting in high [Li]leachate and δ7Lileachate in underlying loess. When loess has superimposed pedogenic and adsorption processes as the stages I and II, loess became as paleosol with highest δ7Lileachate in underlying carbonate accumulation layer. A persistent increase in δ7Lileachate indicates dominant control of post-depositional adsorptions on Li fractionation along solution migrations during weathering and eluviation of overlying deposits, and vice versa. These results highlight that variations in [Li]leachate and δ7Lileachate can be used to trace soil water migration processes and the magnitude of pedogenic processes in loess-paleosol sediment at different periods.

For its greenhouse effects, atmospheric CO2 can critically influence the global climate on millennial and centennial timescales. Pleistocene atmospheric CO2 variations must involve changes in ocean storage of carbon, but the mechanisms and pathways of carbon transfer between the oceanic and atmospheric reservoirs are poorly understood due, in part, to complications associated with interpretation of carbonate system proxy data. Here we employ a recently developed approach to reconstruct upper Atlantic air–sea CO2 exchange signatures through the last deglaciation. Using this approach, proxy and model data each suggest that there was a net release of CO2 via the Atlantic sector of the Southern Ocean during the early deglaciation, which probably contributed to the millennial-scale atmospheric CO2 rise during Heinrich Stadial 1 at ~18.0–14.7 kyr ago. Moreover, our data reveal a previously unrecognized mechanism for the centennial-scale atmospheric CO2 rise at the onset of the Bølling warming event around 14.7 kyr ago, namely, the expansion of Antarctic Intermediate Water, a water mass that is especially inefficient at sequestering atmospheric CO2. Our findings highlight the role of the Southern Ocean outgassing and intermediate water-mass production and volume variations in governing millennial- and centennial-timescale atmospheric CO2 rises during the last deglaciation.

Significance Reconstructing past extreme weather events, such as tropical cyclones and cold surges, using natural paleoclimate archives can lengthen the instrumental data and help us have a broader understanding of the range of weather variability not evident in instrumental record. However, the time resolution of current paleoarchives, from millennial to monthly at best, is usually too low to explore past weather events. Here we found that the Tridacna shells from South China Sea, western Pacific, have continuous daily growth bands, and several daily to hourly resolution biogeochemical proxy records were developed. Our results demonstrate that these records can record nearby tropical cyclones and cold surges, indicating that Tridacna shells have the potential to be an unprecedented ultra-high-resolution archive for paleoweather reconstructions., Paleoclimate research has built a framework for Earth’s climate changes over the past 65 million years or even longer. However, our knowledge of weather-timescale extreme events (WEEs, also named paleoweather), which usually occur over several days or hours, under different climate regimes is almost blank because current paleoclimatic records rarely provide information with temporal resolution shorter than monthly scale. Here we show that giant clam shells (Tridacna spp.) from the tropical western Pacific have clear daily growth bands, and several 2-y-long (from January 29, 2012 to December 9, 2013) daily to hourly resolution biological and geochemical records, including daily growth rate, hourly elements/Ca ratios, and fluorescence intensity, were obtained. We found that the pulsed changes of these ultra-high-resolution proxy records clearly matched with the typical instrumental WEEs, for example, tropical cyclones during the summer−autumn and cold surges during the winter. When a tropical cyclone passes through or approaches the sampling site, the growth rate of Tridacna shell decreases abruptly due to the bad weather. Meanwhile, enhanced vertical mixing brings nutrient-enriched subsurface water to the surface, resulting in a high Fe/Ca ratio and strong fluorescence intensity (induced by phytoplankton bloom) in the shell. Our results demonstrate that Tridacna shell has the potential to be used as an ultra-high-resolution archive for paleoweather reconstructions. The fossil shells living in different geological times can be built as a Geological Weather Station network to lengthen the modern instrumental data and investigate the WEEs under various climate conditions.

Across the Miocene–Pliocene boundary (MPB; 5.3 million years ago, Ma), late Miocene cooling gave way to the early-to-middle Pliocene Warm Period. This transition, across which atmospheric CO2 concentrations increased to levels similar to present, holds potential for deciphering regional climate responses in Asia—currently home to more than half of the world’s population— to global climate change. Here we find that CO2-induced MPB warming both increased summer monsoon moisture transport over East Asia, and enhanced aridification over large parts of Central Asia by increasing evaporation, based on integration of our ~1–2-thousand-year (kyr) resolution summer monsoon records from the Chinese Loess Plateau aeolian red clay with existing terrestrial records, land-sea correlations, and climate model simulations. Our results offer palaeoclimate-based support for ‘wet-gets-wetter and dry-gets-drier’ projections of future regional hydroclimate responses to sustained anthropogenic forcing. Moreover, our high-resolution monsoon records reveal a dynamic response to eccentricity modulation of solar insolation, with predominant 405-kyr and ~100-kyr periodicities between 8.1 and 3.4 Ma., Global warming drove ‘wet gets wetter and dry gets drier’ climate shifts in Asia ~5.3 million years ago with monsoon pacing by ~400,000 and ~ 100,000 year cycles. This could be a template for future Asian climate response to anthropogenic warming.

Reconstructing the long-term Hg history in major emission countries is important for understanding the global Hg cycle and controlling Hg pollution. In this study, the atmospheric Hg history was reconstructed over the last three centuries based on three lacustrine sediment records from southeastern Inner Mongolia in North China, and its relationship with global and regional Hg emissions was revealed. These records show little Hg pollution in the 18th and 19th centuries. This implies a limited influence of Hg emitted from Europe and North America in this region, which is confirmed by their different Hg trends during the two World Wars and the post-1970s. Atmospheric Hg in the region had increased gradually since the 1900s, primarily contributed by emissions from the former Soviet Union in Lake Dalihu (DLH) and Lake Zhagesitai (ZGST) and from the Beijing-Tianjin-Hebei region in Lake Kulunnao (KLN). In the last century, two decreases in Hg fluxes occurred in the KLN core due to the economic recession in the 1960s-1970s and reduced energy consumption and industrial production in the 1990s. In the DLH and ZGST cores, only one decrease occurred, corresponded with the dissolution of the Soviet Union in the 1990s. Although atmospheric Hg emissions in China had stabilized or even decreased in the last decade, atmospheric Hg continued to increase, particularly in KLN, because of emissions from small cities in the region. This study can help understand Hg sources and control Hg pollution in North China and supplement the understanding of the global Hg cycling.

The Qinghai-Tibetan Plateau (QTP) is one of the amplifiers of global climate change. The headwater area of the Yellow River Basin (HYRB) on the QTP is the dominant water source region for the whole Yellow River Basin (YRB). However, the sensitive responses of hydrological processes to the intensifying climate change are exerting high uncertainties to the water cycle in the HYRB. The aim of this study was to investigate the potential climate change under three Representative Concentration Pathways (RCP 2.6, 4.5, and 8.5) and their hydrological impacts in this region using the ensemble climate data from eight general circulation models (GCMs) and the Soil and Water Assessment Tool (SWAT). Compared to the baseline (1976–2015), the projected climate indicated a rise of 7.3–7.8% in annual precipitation, 1.3–1.9°C in maximum air temperature, and 1.2–1.8°C in minimum air temperature during the near future period (2020–2059), and an increment of 9.0–17.9%, 1.5–4.5°C, and 1.3–4.5°C in precipitation, maximum and minimum temperature, respectively, during the far future period (2060–2099). The well-simulated SWAT modeling results suggested that due to a wetter and warmer climate, annual average actual evapotranspiration (AET) would increase obviously in the future (31.9–35.3% during the near future and 33.5–54.3% during the far future), which might cause a slight decrease in soil water. Water yield would decrease by 16.5–20.1% during the near future period, implying a worsening water crisis in the future. Till the end of this century, driven by the increased precipitation, water yield would no longer continue to decrease, with a decline by 15–19.5%. Overall, this study can not only provide scientific understanding of the hydrological responses to the future climate in both semi-arid and alpine areas, but also contribute to the decision support for sustainable development of water resources and protection of eco-environment in the HYRB.

The widespread aeolian deposits on the Chinese Loess Plateau (CLP) have been investigated intensively as an outstanding archive of information on past variations of the East Asian Monsoon (EAM). However, differentiating the impacts of precipitation and temperature on loess-based proxies is difficult and complex, which hampers our ability to understand the variability and dynamics of the EAM. In this study, we investigated the Mg isotope composition (δ26Mg) of the secondary carbonates in fine-grained loess samples from ten Holocene profiles and a loess-paleosol sequence, as well as in the primary carbonates of nine loess-source samples from the Asian inland deserts. Our aim was to explore the potential of the δ26Mg values of secondary carbonates in tracing precipitation changes. The results demonstrate that δ26Mg values are homogeneous (−2.07‰) in primary carbonates from different loess-sources, but display large variations in secondary carbonates of loess, increasing from −3.33‰ in the northwest CLP to −1.80‰ in the southeast CLP, and from −3.58‰ during the last glacial to −1.65‰ during the last interglacial. The variations were mainly controlled by EAM precipitation via the migration of isotopically light Mg, because Mg isotope fractionation during the formation of secondary carbonates is temperature insensitive, and the primary carbonate in different loess-sources has relatively constant δ26Mg values. This conclusion is further supported by high correlation (r2 = 0.84) between modern mean annual precipitation (MAP) and δ26Mg in the secondary carbonates of spatial loess samples. Based on this δ26Mg-MAP relationship, temporal variations in MAP were quantitatively estimated, ranging from 670 mm during the last interglacial to 270 mm during the last glacial at the southern CLP. Compared with previous estimates, our MAP exhibits a larger amplitude of glacial-interglacial fluctuations (∼400 mm) with a less uncertainty (53–76 mm), implying that δ26Mg values in secondary carbonates of loess can serve as a novel precipitation proxy to infer EAM variability and dynamics.

As one of the largest dust sources on the Earth's surface, dryland in Central Asia gives rise to thick eolian deposits over East Asia (e.g., the Chinese Loess Plateau, CLP) and significantly influences the regional hydrochemistry in the downwind drainage areas. However, the formation of thick eolian dust deposits requires not only climatic prerequisites for dust emission and transport but also climatic and topographic conditions favourable for deposition and accumulation. The scarcity of widespread eolian deposition around the CLP before 7-8 Ma hinders a full understanding of the processes and mechanisms of Central Asian aridification. The deposition of eolian dust also impacts the hydrogeochemistry of fluvial systems and the precipitation of authigenic phases in continental sedimentary systems could be an archive for studying eolian dust dynamics when pure eolian deposits are scarce. Here, we present the Ca-Mg-Sr concentrations and 87Sr/86Sr isotope compositions of bulk carbonates in a new fluvial sequence (12.7-4.8 Ma) of the Xining Basin. The Mg/Ca and Sr/Ca ratios of the carbonate describe a power law relationship with a power coefficient of ∼0.8, lower than the coefficient characteristic of prior calcite precipitation (PCP). An input of eolian dust with the dissolution of Mg-rich carbonate is likely responsible for the deviation from a pure PCP process. The bulk carbonates also show a general decrease of 87Sr/86Sr ratios from 12.7 to 4.8 Ma, with a transition around 8.6 Ma revealed by lower Sr/Mg ratios. The comparison of these proxies to a previously reported fluvial section (12.2-5.1 Ma) in the Linxia Basin, ∼200 km to the southeast, shows that the 87Sr/86Sr ratios of the bulk carbonates and water-soluble salts in the Linxia Basin are around 0.7098, which is 0.0018 lower than those in the Xining Basin before 8.6 Ma, but shows a significant rise between 8.6 and 7.0 Ma. The two basins share the same range of carbonate 87Sr/86Sr ratios when sediments are younger than 7 Ma. For the last 7 Myrs, the evolution of the 87Sr/86Sr ratios in bulk carbonates of fluvial sediments and Pliocene-Quaternary eolian deposits found in the Xining Basin are similar to those in typical eolian red clays/loess-palaeosol sequences on the CLP. These results suggest a transition of the hydrochemical regime at 8.6 Ma in the Linxia Basin from a catchment only influenced by the weathering of its bedrock to one significantly impacted by eolian dust input. In the Xining Basin, the carbonate elemental and 87Sr/86Sr ratios are consistent with a hydrochemistry more impacted by the presence of the eolian dust. There, the dust input occurred earlier, at ≥12.7 Ma, though it has strengthened since 8.6 Ma. The eolian dust impact on fluvial systems in the Xining Basin was much earlier than in the Linxia Basin and also preceded the initial accumulation of widespread eolian red clays on the CLP (7-8 Ma), suggesting a temporally propagating and spatially stepwise expansion of eolian dust delivery across the Asian inland during the late Cenozoic.

The deposition couplets within the check dams and landslide-dammed reservoirs on the Chinese Loess Plateau (CLP) document the processes and histories of watershed soil erosion, transportation and deposition, related to floods, eco-environment and land use changes, and human activities. Previously, dating the couplets was dominantly dependent on multiple intercomparisons among specific sediment yields of visible couplets, 137Cs activities distributions and erosive rainfall events by meteorological records. However, inter-annual division of the deposition couplets and dating historical sequence beyond meteorological records in the landslide-dammed reservoir are little known. Based on high-resolution XRF core scanning on a 22.75 m sediment sequence in Jingbian (JB) landslide-dammed reservoir on the central hilly-gully area of the CLP, and cross checking of multiple dating methods, this study tried to propose a new method to build the accurate chronology sequence based on inter-annual division by annual freeze-thaw layer and to further date the sediment without rainfall records. The results showed that a total of 126 deposition couplets and 78 annual freeze-thaw layers were identified in the JB sequence. Multimethod cross-dating, including 137Cs activities, annual freeze-thaw layers, couplet specific sediment yield and modern rainfall records, was the most accurate method of dating the JB sediment sequences since 1960s with detail meteorological records. Furthermore, the correspondence between annual freeze-thaw layers and the historical grades of flood index from literature was the valid method to date the JB historical sequences without rainfall records. Consequently, the JB sequence was deposited during the period between 1855 and 2014. High-resolution dating of the JB sequence provides the chronology for recovering natural and anthropogenic information on the central hilly-gully area of CLP since 1850s. The proposed methods will also shed new light on the accurate dating of the sediment sequences within other check dams and landslide-dammed reservoirs on the central and northern CLP.

Owing to rapid socio-economic development and climate warming, lakes even in remote areas have experienced marked changes in the last century. However, there are few studies revealing the multi-faceted biogeochemical changes and disentangling impacts of human and climate in relatively remote lakes in China. In this study we reconstructed historical changes of geochemistry, nutrition, primary production, ecology, and pollution in an alpine lake (Gonghai) in central North China, and revealed coherent changes and drivers in relatively remote Chinese lakes by compiling other records. Results show that Lake Gonghai has experienced considerably biogeochemical changes since the 1980s induced mainly by increased regional human activities, with detected human-related changes occurring in the 1950s-70s. The most important change is a shift of diatom primary producers in the 1980s, caused mainly by an increase of regional atmospheric N and P deposition associated with rapid socio-economic development. Another remarkable change is the increase of pollution levels since the 1980s, represented by heavy metals, also caused by atmospheric deposition. Compiled sediment records demonstrate similar biogeochemical changes in most lakes from relatively remote areas of China since the 1970s-80s, associated closely with increased inputs of human-induced atmospheric N, P and pollutants, whereas the influence of climate warming is likely limited. This study highlights markedly human-related biogeochemical changes in relatively remote Chinese lakes during the Anthropocene epoch.

Water resources and water quality are restrictive factors in the Chinese Loess Plateau (CLP), a unique area with most severe soil erosion, fragile ecology and water shortage. River and well water samples were firstly analyzed, and multiple methods and indexes, including principal component analysis (PCA), correlation analysis (CA), sodium adsorption ratio (SAR), water quality index (WQI), hazard quotient (HQ), and hazard index (HI), were used to investigate characteristics, water quality and health risk assessment of trace elements in CLP. The average trace elements concentrations were higher than the world average with a slightly alkaline characteristic. PCA and CA showed that Al, Fe, Li, B, As, and F had natural origins from loess weathering and leaching; Cr, Pb, Cd, Cu, Ag, and Tl were mainly from anthropogenic input; Co, Ni, and Mn were dominated by both anthropogenic and natural sources. The poor river water quality was mainly related with high sodium (alkalinity) and salinity hazard. The poor well water quality samples with high WQI values, especially for As, Cr, and B, were distributed in the northwest and the Fenhe River sub-basin. The pollution level of trace elements in rivers in CLP was in medium level compared with other rivers worldwide. Arsenic pollution was the worst in well water and was the potential pollutant in river water especially for children. Arid climate together with anthropogenic input and special water characteristics (high Na, pH, and low Ca) aggravated As pollution. More work should be done to monitor the secular variation and remove As in the high As areas. The results of this study can provide the basic data for efficient water management and human health protection in CLP.

RATIONALE High-precision determination of magnesium (Mg) isotopes can now be routinely achieved by multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). The analytical sensitivity and instrumental mass discrimination behavior of this method are, however, sensitive to the types of sample and skimmer cones used in these measurements, so it is important that these parameters should be investigated. METHODS Using the sample-standard-bracketing method in the wet-plasma mode, four available combinations of sample and skimmer cones [Jet sample cone + H skimmer cone (Jet + H), standard sample cone + H skimmer cone (Standard + H), standard sample cone + X skimmer cone (Standard + X), and Jet sample cone + X skimmer cone (Jet + X)] were systematically investigated for peak shape, sensitivity, mass discrimination, accuracy, and precision in Mg-isotopic ratio determination using a Neptune plus MC-ICP mass spectrometer. RESULTS The results showed that different cone combinations do not affect peak shapes but would significantly change the sensitivities for Mg-isotopic determinations. Compared with using the Standard + H, the sensitivities of Mg-isotopic determinations were enhanced by approximately a factor of 1.3, 1.4, and 1.9 by using the Standard + X, the Jet + H, and the Jet + X combinations, with the most stable mass discrimination behaviors obtained by the Jet + H. The instrumental mass fractionation slope for any combination of a modified cone geometry (i.e. Standard + X, Jet + X, and Jet + H) is 0.500, while it is 0.510 for the Standard + H. In addition, the mass discrimination behavior is related to Mg concentrations once the combination is set, indicating the necessity of concentration match during Mg-isotopic determination. CONCLUSIONS The precision and accuracy of the Jet + H combination are better than those of the other combinations, and this is further supported by the validation of the Mg-isotope data for four international reference materials: Cambridge-1, NASS-6, AGV-2, and BHVO-2. As the Jet + H combination also provides a high signal, this combination gives the most robust strategy for the highly precise and accurate determination of Mg isotopes.

Boron isotopes are useful tracers for fluid–rock interactions and subduction processes, as well as a proxy for paleo-ocean pH. However, the strong B memory effect presents a great challenge in precisely measuring B isotope ratios and accurately using multi-collector inductively coupled plasma mass spectrometry. In this study, we present the first systematic study to examine the effectiveness of eliminating the B memory effect by using different rinse solutions. The results demonstrate that F-based rinse solutions (HF and NaF) are the most effective. However, using HF as a rinse solution will require a high content of HF (more than 0.3 M) or a low content of HF with the samples also in an HF medium, and requires special care because HF is highly toxic. By contrast, NaF (0.6 mg g−1 NaF in 1% HNO3 solution) is equally effective regardless of the sample acid matrix. In addition, high concentration Na solution does not affect the stability of plasma, or result in unexpected mass bias during the analytical courses. It only takes less than 4 min to reduce the B signal to blank levels using NaF rinse solution. The long-term analysis of B reference materials over a year yields great reproducibility using acidified NaF as a rinse solution, with NIST SRM 951a, ERM-AE121, and GSB07-1979-2005 (in-house standard) with δ11B = 0.01 ± 0.11, 20.29 ± 0.48 and −13.32 ± 0.40‰ (2SD, n = 27), respectively, which indicates that excellent precision can be achieved for boron isotope measurement. A series of natural samples with diverse matrices covering a large range of δ11B variations in the natural environment were measured using this protocol and yielded better results. Therefore, our protocol is applicable to a wide field of B isotope research that requires high precision and accuracy.

In this data article, a dataset of paleoclimatic records ranging from 22 to 9 thousand years before present is reported, which is related to the research article entitled "Breakpoint lead-lag analysis of the last deglacial climate change and atmospheric CO2 concentration on global and hemispheric scales" published in the journal of Quaternary International by Liu et al. (2018). In the dataset, 4 delta O-18 records derived from Greenlandic ice cores, 2 delta D records and 7 delta O-18 records derived from Antarctic ice cores, 32 U-37(K') records and 26 Mg/Ca records derived from marine deposits, and 17 delta O-18 records derived from cave stalagmites were collected and collated. General and statistical characteristics of these 88 proxy records are showed here. All of the data are stored in separate Microsoft Excel spreadsheets that are available for researchers.

The Qinghai-Tibetan Plateau (QTP) is one of the amplifiers of global climate change. The headwater area of the Yellow River Basin (HYRB) on the QTP is the dominant water source region for the whole Yellow River Basin (YRB). However, the sensitive responses of hydrological processes to the intensifying climate change are exerting high uncertainties to the water cycle in the HYRB. The aim of this study was to investigate the potential climate change under three Representative Concentration Pathways (RCP 2.6, 4.5, and 8.5) and their hydrological impacts in this region using the ensemble climate data from eight general circulation models (GCMs) and the Soil and Water Assessment Tool (SWAT). Compared to the baseline (1976–2015), the projected climate indicated a rise of 7.3–7.8% in annual precipitation, 1.3–1.9°C in maximum air temperature, and 1.2–1.8°C in minimum air temperature during the near future period (2020–2059), and an increment of 9.0–17.9%, 1.5–4.5°C, and 1.3–4.5°C in precipitation, maximum and minimum temperature, respectively, during the far future period (2060–2099). The well-simulated SWAT modeling results suggested that due to a wetter and warmer climate, annual average actual evapotranspiration (AET) would increase obviously in the future (31.9–35.3% during the near future and 33.5–54.3% during the far future), which might cause a slight decrease in soil water. Water yield would decrease by 16.5–20.1% during the near future period, implying a worsening water crisis in the future. Till the end of this century, driven by the increased precipitation, water yield would no longer continue to decrease, with a decline by 15–19.5%. Overall, this study can not only provide scientific understanding of the hydrological responses to the future climate in both semi-arid and alpine areas, but also contribute to the decision support for sustainable development of water resources and protection of eco-environment in the HYRB.

The first major build-up of Antarctic glaciation occurred in two consecutive stages across the Eocene–Oligocene transition (EOT): the EOT-1 cooling event at ~34.1–33.9 Ma and the Oi-1 glaciation event at ~33.8–33.6 Ma. Detailed orbital-scale terrestrial environmental responses to these events remain poorly known. Here we present magnetic and geochemical climate records from the northeastern Tibetan Plateau margin that are dated precisely from ~35.5 to 31 Ma by combined magneto- and astro-chronology. These records suggest a hydroclimate transition at ~33.7 Ma from eccentricity dominated cycles to oscillations paced by a combination of eccentricity, obliquity, and precession, and confirm that major Asian aridification and cooling occurred at Oi-1. We conclude that this terrestrial orbital response transition coincided with a similar transition in the marine benthic δ18O record for global ice volume and deep-sea temperature variations. The dramatic reorganization of the Asian climate system coincident with Oi-1 was, thus, a response to coeval atmospheric CO2 decline and continental-scale Antarctic glaciation., Marine records indicate a greenhouse to icehouse climate transition at ~34 million years ago, but how the climate changed within continental interiors at this time is less well known. Here, the authors show an orbital climate response shift with aridification on the northeastern Tibetan Plateau during this time.

Groundwater is essential for regional ecological-economic system and is an important resource of drinking water, especially in the Chinese Loess Plateau (CLP), where is a typical water-limited ecosystem. Groundwater quality deterioration will affect water security and exacerbate the water shortages. Groundwater hydrochemistry, pollution source apportionment, quality and health risks were evaluated based on analysis of major ions and selected trace elements in seasonal samples of the Fen River Basin (FRB) in the eastern CLP. Groundwaters in the FRB were mainly HCO3−-Ca2+-Na+ water type with low dissolved solutes in upstream samples, high values in midstream samples and medium values in downstream samples. Solutes in upstream samples were mainly derived from carbonate weathering, while those in midstream and downstream samples came from silicate weathering, evaporites dissolution and anthropogenic sources. Self-organizing map (SOM) showed the hydrochemistry remained unchanged from dry to wet season for most sampling points. The seasonal variations of Ag, Cd, Ni, Pb, and Tl were significant due to anthropogenic input. High NO3− in upstream and downstream samples resulted primarily from sewage discharge, and high SO42− in midstream and downstream samples was from gypsum- and coal-related industries. In addition, anthropogenic input related to coal industries significantly aggravates pollution of As, Ni, Ag, Fe, and Mn. Influenced by evaporites and anthropogenic input, midstream samples had high salinity, total hardness and water quality indices (WQIs) and were unsuitable for irrigation or drinking purposes. Seasonal variation of WQI in the FRB was unsignificant except Jiaokou River sub-basin, where groundwater quality was worse in the wet season than the dry season due to coal mining. Great attention should be paid to the high non-carcinogenic risks of exposure to F, V, Mn, and Cr via dermal absorption, particularly for children. Overall, groundwater quality in the FRB was best in upstream, medium in midstream and worst in midstream based on different index. Groundwater quality is deteriorated by anthropogenic input and the sewage discharge in the FRB should be strictly controlled. Our report provides a reference for groundwater pollution evaluation and source identification in similar areas.

Fen River Basin (FRB) is water-deficient and strongly influenced by human activities in the eastern Chinese Loess Plateau. The spatio-temporal variation and controlling factors of hyrochemistry and quality, sources of high boron, sulfate, and nitrate of surface waters in FRB were unclear. Major ions, δ

Global warming and intensified climate variability have greatly affected Earth’s surface processes and continental sediment evacuation. River suspended sediment is a sensitive indicator for tracing seasonal surface erosion, but details of the rates of sediment generation and evacuation, and their connections with nowadays warming climate are not entirely clear, particularly in Tibet and other high–altitude areas where field observations remain scarce. Here, we investigate daily to seasonal river sediment transport dynamics between the cold, permafrost–dominated northeastern Tibetan Plateau and warm, non–permafrost Sichuan and Taiwan regions. Our results show that at a given river water discharge, greater river suspended sediment was evacuated during the pre–monsoon season (April–Mid June) relative to other seasons in the cold NE Tibetan catchments. In contrast, no such phenomenon was observed in the warm, non–permafrost regions. These comparisons likely indicate a center role of freeze–thaw processes on loose sediment generation, which enhanced sediment output. Hydrometeorological records show up to ∼2 °C warming in the NE Tibetan Plateau since the past 30 years, coupled with an 8-fold increase in sediment transport. We suggest that continuous warming climate may further accelerate sediment and soil carbon release in the Tibetan Plateau and other global permafrost–dominated areas, which in turn influences climate feedback.