1. A general thermodynamic model for the long-period stacking ordered phases in magnesium alloys
- Author
-
Kai Xu, Shuhong Liu, Keke Chang, Yongpeng Liang, Yong Du, and Zhanpeng Jin
- Subjects
LPSOs ,Thermodynamic model ,Formation enthalpy ,CALPHAD ,Solidification ,Mining engineering. Metallurgy ,TN1-997 - Abstract
A thermodynamic model Mgx(Xs, Mg)6(Xl, Mg)8 (Xs and Xl are elements smaller and larger than Mg) for long-period stacking ordered phases (LPSOs) was proposed based on two key factors: the Xs6Xl8-type L12 clusters and the variation of chemical compositions. In general, all available LPSOs can be described with this model. As a representative system, Mg-Y-Zn with three LPSOs was investigated using the CALPHAD (calculation of phase diagram) approach aided with first-principles calculations. Two new three-phase equilibria were predicted and were validated by key experiments. The model-based descriptions will be the basis for the research and development of magnesium alloys.
- Published
- 2021
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