1. Synergistic effects of N-doping and mesoporous structures in block copolymer-derived three-dimensionally ordered mesoporous carbon for PEMFC.
- Author
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Yang, Yi, Zhao, Chenglin, Wang, Zhida, Fan, Xiaokai, and Yan, Changfeng
- Subjects
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OXYGEN reduction , *PROTON exchange membrane fuel cells , *BLOCK copolymers - Abstract
Block copolymer (BCP) is a promising precursor to design ordered mesoporous carbon (OMC) materials for proton exchange membrane fuel cells due to its accessibility and controllability. However, enhancing the performance of OMCs through the integration of heteroatoms during the self-assembly process remains a challenging endeavor. Herein, an ammonia-assisted pyrolysis method is used to deposit N atoms in self-assembled OMC (N-OMC). The resulting N-OMC exhibits a well-ordered mesoporous structure with the N content up to 6.43 at.%. Upon PtCo nanoparticles loading (PtCo/N-OMC), the PtCo/N-OMC demonstrates exceptional electrocatalytic activity, evidenced by a half-wave potential of 0.876 V RHE and an electrochemical surface area of 98.19 m2·g−1. The single-cell test confirms the superiority of the N-OMC structure, revealing a current density of 1.53 A·cm−2 at 0.6 V and a peak power density of 1.17 W·cm−2. Theoretical calculations affirm that the pyridinic N-doping reduces oxygen binding energy, thereby enhancing oxygen reduction reaction activity. The confinement effect of the mesopores avoids aggregation of nanoparticles, while doping-N-induced defects further bolster their electrochemical activities. This work highlights the synergistic effect of N-doping defects and ordered mesoporous architectures, illustrating the exceptional potential of the BCP-derived OMC as an ideal support for electrocatalysis applications. [Display omitted] • Synthesis of efficient block copolymer-derived 3D ordered mesoporous carbon support for Pt-based electrocatalyst with synchronized ammonia-assisted pyrolysis. • Coordination environment and stability of N atoms in the block copolymer-derived carbon. • Synergistic enhancement of catalytic performance by N doping and confinement effect of ordered mesoporous structures. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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