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Recycling of valuable metals from spent catalysts in a green way is gaining extensive interest for economic and environment reasons. In this study, we developed novel hydrophobic deep eutectic solvents to extract Mo from spent catalysts. The hydrophobic DESs have been designed and synthesized by mixing one molar of the quaternary ammonium salt and two molars of various saturated fatty acids with different carbon chain lengths. The extraction ability and extraction mechanism of these DESs were studied, some factors influencing the extraction efficiency, including the structure of hydrogen bond acceptors and hydrogen bond donors, initial aqueous pH, reaction time and temperature, phase ratios were investigated. It is found that the synthesized hydrophobic DESs exhibit excellent extraction performance toward Mo, where the Mo distribution ratio is more than 2200 in the presence of other metals, corresponding to an extraction efficiency of 99% at optimal reaction conditions. This work reveals a distinct class of materials, guiding an effective and green way for spent catalyst treatment.Implications: Novel hydrophobic deep eutectic solvents have been developed to extract Mo from spent catalysts, the synthesized hydrophobic DESs possess several advantages, such as green, low price, low toxicity, and biodegradability. It exhibits excellent extraction performance under an optimized extraction condition. This work reveals a distinct class of materials, guiding a promising way for green and economical utilization of spent catalysts.

A web-based survey was conducted among 238 Chinse medical students to examine their acceptance and use of e-Health services. Chinese medical students are found to have limited experience and low satisfaction with current e-Health services, which indicates an urgent need to improve e-Health practice training based on a consumer-centered model of health care.

Metacognition is the ability to introspect and control ongoing cognitive processes. Despite the extensive investigation of the brain architectures supporting metacognition for perception and memory, little is known about the neural basis of metacognitive capacity for motor function, a vital aspect of human behavior. Here, using functional and structural magnetic resonance imaging (MRI), we examined the brain substrates underlying self-awareness of handwriting, a highly practiced visuomotor skill. Results showed that experienced adult writers generally overestimated their handwriting quality, and such overestimation was more pronounced in men relative to women. Individual variations in self-awareness of handwriting quality were positively correlated with gray matter volume in the left fusiform gyrus, right middle frontal gyrus and right precuneus. The left fusiform gyrus and right middle frontal gyrus are thought to represent domain-specific brain mechanisms for handwriting self-awareness, while the right precuneus that has been reported in other domains likely represents a domain-general brain mechanism for metacognition. Furthermore, the activity of these structurally related regions in a handwriting task was not correlated with self-awareness of handwriting, suggesting the correlation with metacognition was independent of task performance. Together, this study reveals that metacognition for practiced motor skills relies on both domain-general and domain-specific brain systems, extending our understanding about the neural basis of human metacognition.

The aim of this respective study was to assess the graft signal/noise quotient (SNQ) value and associated factors based on magnetic resonance imaging (MRI) after lateral meniscal allograft transplantation (LMAT). Patients with LMAT were included. The SNQ, width of the anterior horn (WAH), width of the midbody (WMB), width of the posterior horn (WPH) of each lateral meniscus, coronal graft extrusion (CGE), the anterior cartilage meniscus distance (ACMD) and the posterior cartilage meniscus distance (PCMD) were measured using MRI and tested by multivariate stepwise regression analysis. The relative percentage of extrusion (PRE) was calculated. Seventy-one male patients were examined, and 7 patients were lost to follow-up. The SNQ of the meniscus increased from immediately after surgery to 6 months postoperatively, decreased from 6 to 12 months, increased from 12 to 24 months, and increased from 24 to 36 months. The mean SNQ had a significant negative association with the WPH and CGE at 6 months (p

Disposal of spent catalyst in an economical and green way has become a great concern for industrial production. We developed a process including acid leaching, solvent extraction and stripping in order to recycle spent catalyst. In this study, we conducted selective recovery of molybdenum through focus on finding an optimized extraction and stripping process by comparing different extractants and stripping agents. To separate molybdenum from other metals efficiently and figure out the mechanism of extraction process, the five different extractants of methyl trioctyl ammonium chloride, tri-n-octylamine, tris (2-ethylhexyl) amine, bis (2-ethylhexyl) phosphate, and tributyl phosphate with different functional groups were examined; the extraction ability and extraction mechanism of these five extractants were systematically studied under the same system for the first time. It was found that more than 98% of the molybdenum could be extracted with an organic phase consisting of tri-n-octylamine or methyl trioctyl ammonium chloride under the optimal conditions. The result indicated that the tri-n-octylamine and methyl trioctyl ammonium chloride possess excellent molybdenum extraction ability, the extraction capacity of the rest extractants was in the order of bis (2-ethylhexyl) phosphate > tris (2-ethylhexyl) amine > tributyl phosphate. In the stripping process, NH4OH, NaOH, and H2SO4 were chosen as stripping agent to strip the molybdenum from the loaded tri-n-octylamine organic phase. The stripping ability of the three studied stripping agents was in the order NaOH > NH4OH > H2SO4. The Fourier transform infrared (FTIR) spectra showed that the structure of the tri-n-octylamine organic phase was stable during the extraction and stripping process. Results showed that molybdenum could be highly and efficiently recovered by optimized extraction and stripping process. Implications: A series of different extractants and stripping agent have been systematically studied in order to compare their extraction and stripping ability under the same system. Based on the obtained results, an optimized extraction and stripping process was proposed to recycle molybdenum from spent catalyst efficiently. It is possible to dispose spent catalysts in an economic and environmental way by this developed metal recovery process.

One of the most important questions concerning language processing in the bilingual brain is whether the two languages share the same neural structure for comprehension [1-3].

Using functional magnetic resonance imaging (fMRI) or positron emission tomography (PET), much knowledge has been gained in understanding how the brain is activated during controlled experiments of language tasks in educated healthy subjects and in uneducated healthy subjects. While previous studies have compared performance between alphabetic subjects, few data were about Chinese-speaking individuals. In alphabetic subjects, studies indicate that the literates surpass the illiterates, especially in tasks involving phonological processing, and that different activation regions in fMRI are located between Broca’s area and the inferior parietal cortex, as well as the posterior-mid-insula bridge between Wernicke’s and Broca’s area. In Chinese subjects, the results were shown in silent word recognition tasks (the left inferior/middle frontal gyrus and bilateral superior temporal gyri) and in silent picture-naming tasks (the bilateral inferior/middle fontal gyri and left limbic cingulated gyrus). In this study, the authors use some recent fMRI data to investigate language processing in the human brain of literate and illiterate subjects.

Previous neuroimaging studies used functional magnetic resonance imaging (fMRI) to clarify the different brain activities when bilingual speaker comprehend their first language (Ll) compared with their second language (L2). Many studies show the different activation patterns of alphabetic language and logographic language. It is unclear that if bilinguals`Ll and L2 language are all logographic language (e.g. Chinese and Japanese), whether Japanese (L2) processing is different from Chinese (Ll) for bilinguals- brain activity. To study the underlying mechanisms, we used functional magnetic resonance imaging (fMRI) to visualize Chinese-Japanese bilinguals- brain activity in both of Chinese character and Japanese Kanji. Precuneus were activated by morphology judgment in Chinese word contrast with Japanese word. The results with Chinese and Japanese logographs suggested precuneus were played an important role in Chinese morphology processing for Chinese-Japanese bilingual speakers.

Using functional magnetic resonance imaging (fMRI) or positron emission tomography (PET), much knowledge has been gained in understanding how the brain is activated during controlled experiments of language tasks in alphabetic subjects and in Chinese subjects. While previous studies have compared performance between alphabetic and Chinese subjects, few data were about Japanese-speaking individuals. In this study, we used fMRI to investigate brain activations in processing Japanese phonological and orthographic by visual tasks in six Japanese subjects. Different activation patterns were observed between phonological and orthographic processing. We conclude that constellation of neural substrates was different for phonological processing.