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Due to strong irradiation, hot rocky exoplanets are able to sustain lava oceans. Direct interaction between these oceans and overlying atmospheres can provide insight into planetary interiors. In order to fully understand how the composition of the atmosphere of such planets are affected by the properties of the oceans, comprehensive chemical equilibrium models are required. Thus far, most models have only taken non-volatile species into account when calculating lava vaporisation. We investigate the effect of including C-, H-, N-, S-, and P-bearing species in the equilibrium lava vaporisation calculations on the overall atmospheric composition of hot rocky exoplanets by expanding our LavAtmos code. In LavAtmos 2.0 we integrate the chemical equilibrium code FastChem to expand the considered gas phase species to 523. We apply this new approach to calculate the composition of "pure" atmospheres which contain only a single volatile element and more complex atmospheres which contain C, H, N, S, and P. We also test two proposed compositions for the atmosphere of 55-Cnc e. We find that the inclusion of volatile elements in vaporisation calculations increases the partial pressures of vaporised species for all tested atmospheric compositions. Our models indicate that the tested volatile atmospheres above a lava ocean have a relatively low C-O ratio. This demonstrates the utility of complex chemical models that better describe the chemical behavior of atmospheres across a wide range of pressures and temperatures. Volatile elements must be taken into account for comprehensive modeling of vaporisation from a surface lava ocean into a volatile atmosphere. Vaporised species such as SiO, TiO, and Na may be present in greater abundances than previously estimated. A low atmospheric C/O ratio may be able to function as a new tracer for the presence of surface lava oceans on hot rocky exoplanets., Comment: In rev. A&A (16 pages, 14 figures)

Characterizing rocky exoplanets is a central endeavor of astronomy, and yet the search for atmospheres on rocky exoplanets has hitherto resulted in either tight upper limits on the atmospheric mass or inconclusive results. The 1.95-REarth and 8.8-MEarth planet 55 Cnc e, with a predominantly rocky composition and an equilibrium temperature of ~2000 K, may have a volatile envelope (containing molecules made from a combination of C, H, O, N, S, and P elements) that accounts for up to a few percent of its radius. The planet has been observed extensively with transmission spectroscopy, and its thermal emission has been measured in broad photometric bands. These observations disfavor a primordial H2/He-dominated atmosphere but cannot conclusively determine whether the planet has a secondary atmosphere. Here we report a thermal emission spectrum of the planet obtained by JWST's NIRCam and MIRI instruments from 4 to 12 {\mu}m. The measurements rule out the scenario where the planet is a lava world shrouded by a tenuous atmosphere made of vaporized rock, and indicate a bona fide volatile atmosphere likely rich in CO2 or CO. This atmosphere can be outgassed from and sustained by a magma ocean., Comment: Published online in Nature on May 8, 2024. https://www.nature.com/articles/s41586-024-07432-x. Authors' preprint

Many of the confirmed short period super-Earths and smaller sub-Neptunes are sufficiently irradiated for the surface silicates to be sustained in a long-lasting molten state. While there is no direct evidence of magma ocean influence on exoplanets, theory suggests that due to outgassing and diverse evolution paths, a wide range of resulting atmospheric compositions should be possible. Atmospheric contamination caused by the outgassing of the underlying magma ocean is potentially detectable using low resolution spectroscopy. The James Webb Space Telescope provides the necessary spectral coverage and sensitivity to characterise smaller planets, including lava worlds. In this light, we assess observability of outgassed silicates submerged in volatile atmospheres on the edge of the evaporation valley. By placing a hypothetical 2 R${_\oplus}$ planet around a Sun-like star, we self-consistently model, in 1-D, a wide range of potential atmospheric compositions, including thermal structure and outgassing. We focus on atmospheres rich in H, C and N. We assess diverse chemistry of silicates and volatiles, and what features of outgassed species could be detected via emission spectroscopy using MIRI LRS. Results indicate that even for substantial volatile envelopes, strong in infrared opacity, the presence of silicates causes deep thermal inversions, affecting emission. Similar to pure lava worlds, SiO remains the only outgassed species with major infrared, 5 and 9 \textmu m, bands. However, even a small amount of volatiles, especially of H2O and H-, may hinder its observability. We also find that the C/O ratio plays a large role in determining the abundance of SiO. Detecting SiO on a strongly irradiated planet could indicate an atmosphere with high metallicity and a low C/O ratio, which may be a result of efficient interaction between the atmosphere and the underlying melt., Comment: Accepted for publication at Astronomy & Astrophysics

To date, over 500 short-period rocky planets with equilibrium temperatures above 1500 K have been discovered. Such planets are expected to support magma oceans, providing a direct interface between the interior and the atmosphere. This provides a unique opportunity to gain insight into their interior compositions through atmospheric observations. A key process in doing such work is the vapor outgassing from the lava surface. LavAtmos is an open-source code that calculates the equilibrium chemical composition of vapor above a dry melt for a given composition and temperature. Results show that the produced output is in good agreement with the partial pressures obtained from experimental laboratory data as well as with other similar codes from literature. LavAtmos allows for the modeling of vaporization of a wide range of different mantle compositions of hot rocky exoplanets. In combination with atmospheric chemistry codes, this enables the characterization of interior compositions through atmospheric signatures., Comment: 13 pages, 6 figures, published in Meteoritics & Planetary Science

Lava worlds belong to a class of short orbital period planets reaching dayside temperatures high enough to melt their silicate crust. Theory predicts that the resulting lava oceans outgas their volatile components, attaining equilibrium with the overlying vapour. This creates a tenuous, silicate-rich atmosphere that may be confined to the permanent dayside of the planet. The launch of JWST will provide the much needed sensitivity and spectral coverage to characterise these worlds. In this paper, we assess the observability of characterisable spectral features by self-consistently modelling silicate atmospheres for all the currently confirmed targets having sufficient substellar temperatures (> 1500 K). To achieve this we use outgassed equilibrium chemistry and radiative transfer methods to compute temperature-pressure profiles, atmospheric chemical compositions and emission spectra. We explore varying melt compositions, free of highly-volatile elements, accounting for possible atmospheric evolution. Our models include a large number of neutral and ionic species, as well as all up-to-date opacities. The results indicate that SiO and SiO2 infrared features are the best, unique identifiers of silicate atmospheres, detectable using MIRI instrument of JWST. Detection of these two species in emission would allow for strong constraints on atmospheric thermal structure and possibly the composition of the melt. We also propose that certain species, e.g., TiO, may be directly tied to different classes of melts, possibly revealing surface and interior dynamics. Currently, there are nearly a dozen confirmed lava planets ideal for characterisation of silicate atmospheres using JWST, with two of these already accepted for the initial General Observers program., Comment: Accepted for publication in A&A Preprint: https://doi.org/10.1051/0004-6361/202142984

Ariel, the Atmospheric Remote-sensing Infrared Exoplanet Large-survey, was adopted as the fourth medium-class mission in ESA's Cosmic Vision programme to be launched in 2029. During its 4-year mission, Ariel will study what exoplanets are made of, how they formed and how they evolve, by surveying a diverse sample of about 1000 extrasolar planets, simultaneously in visible and infrared wavelengths. It is the first mission dedicated to measuring the chemical composition and thermal structures of hundreds of transiting exoplanets, enabling planetary science far beyond the boundaries of the Solar System. The payload consists of an off-axis Cassegrain telescope (primary mirror 1100 mm x 730 mm ellipse) and two separate instruments (FGS and AIRS) covering simultaneously 0.5-7.8 micron spectral range. The satellite is best placed into an L2 orbit to maximise the thermal stability and the field of regard. The payload module is passively cooled via a series of V-Groove radiators; the detectors for the AIRS are the only items that require active cooling via an active Ne JT cooler. The Ariel payload is developed by a consortium of more than 50 institutes from 16 ESA countries, which include the UK, France, Italy, Belgium, Poland, Spain, Austria, Denmark, Ireland, Portugal, Czech Republic, Hungary, the Netherlands, Sweden, Norway, Estonia, and a NASA contribution., Comment: Ariel Definition Study Report, 147 pages. Reviewed by ESA Science Advisory Structure in November 2020. Original document available at: https://www.cosmos.esa.int/documents/1783156/3267291/Ariel_RedBook_Nov2020.pdf/

We show that in extremely irradiated atmospheres of hot super-Earths shortwave absorption of CN can cause strong temperature inversions. We base this study on previous observations of 55 Cancri e, which lead us to believe that ultra-short-period super-Earths can sustain volatile atmospheres, rich in nitrogen and/or carbon. We compute our model atmospheres in a radiative-convective equilibrium for a variety of nitrogen-rich cases and orbital parameters. We demonstrate the effects caused by thermal inversions on the chemistry and compute low resolution synthetic emission spectra for a range of 0.5 - 28 micron. Our results indicate that dueto shortwave absorption of CN, atmospheres with temperatures above 2000 K and C/O $\geq$ 1.0 are prone to thermal inversions. CN is one of the few molecules that is extremely stable at large temperatures occurring on the day side of short period super-Earths. The emission spectrum of such atmospheres will differ substantially from non-inverted cases. In the case of inversions, absorption features become inverted, showing higher than expected flux. We propose that inversions in hot atmospheres should be the expected norm. Hot super-Earths are some of the most extreme natural laboratories for testing predictions of atmospheric chemistry and structure. They are frequently occurring, bright in emission and have short orbital periods. All these factors make them perfect candidates to be observed with JWST and ARIEL missions., Comment: Accepted for publication MNRAS. A video presentation of this work can be found at https://exoplanet-talks.org/talk/199

We explore the chemistry and observability of nitrogen dominated atmospheres for ultra-short-period super-Earths. We base the assumption, that super-Earths could have nitrogen filled atmospheres, on observations of 55 Cnc e that favour a scenario with a high-mean-molecular-weight atmosphere. We take Titan's elemental budget as our starting point and using chemical kinetics compute a large range of possible compositions for a hot super-Earth. We use analytical temperature profiles and explore a parameter space spanning orders of magnitude in C/O \& N/O ratios, while always keeping nitrogen the dominant component. We generate synthetic transmission and emission spectra and assess their potential observability with the future James Webb Space Telescope and ARIEL. Our results suggest that HCN is a strong indicator of a high C/O ratio, which is similar to what is found for H-dominated atmospheres. We find that these worlds are likely to possess C/O > 1.0, and that HCN, CN, CO should be the primary molecules to be searched for in thermal emission. For lower temperatures (T < 1500 K), we additionally find NH3 in high N/O ratio cases, and C2H4, CH4 in low N/O ratio cases to be strong absorbers. Depletion of hydrogen in such atmospheres would make CN, CO and NO exceptionally prominent molecules to look for in the 0.6 - 5.0 $\mu$m range. Our models show that the upcoming JWST and ARIEL missions will be able to distinguish atmospheric compositions of ultra-short period super-Earths with unprecedented confidence., Comment: Accepted for publication MNRAS