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Although the mass production of synthetic plastics has transformed human lives, it has resulted in waste accumulation on the earth. Here, we report a low-temperature conversion of polyethylene into olefins. By mixing the polyethylene feed with rationally designed ZSM-5 zeolite nanosheets at 280 °C in flowing hydrogen as a carrier gas, light hydrocarbons (C

The fine-tuning of the pore structure of metal-organic frameworks (MOFs) is of critical importance to developing energy-efficient processes for the challenging separation of structurally similar molecules. Herein, we demonstrate a strategy to realize a quasi-three-dimensional refinement of the pore structure that utilizes the tunability of ring size and number in polycycloalkane-dicarboxylate ligands. Two hydrolytically stable MOFs with a confined aliphatic pore environment, ZUL-C1 and ZUL-C2, were, for the first time, synthesized and applied in separating low-concentration C2-C3 hydrocarbons from natural gas and ultralow-concentration Xe from used nuclear fuel (UNF) off-gas. Validated by X-ray diffraction and modeling, an expansion of the polycycloalkane moiety enables sub-angstrom contraction in specific directions and forms a pore surface with more alkyl sites, which affords stronger trapping of guest molecules with relatively higher polarizability. The resultant material exhibits record C

The separation and purification of xylene isomers is an industrially important but challenging process. Developing highly efficient adsorbents is crucial for the implementation of simulated moving bed technology for industrial separation of these isomers. Herein, we report a stacked one-dimensional coordination polymer {[Mn(dhbq)(H 2 O) 2 ], H 2 dhbq = 2,5-dihydroxy-1,4-benzoquinone} that exhibits an ideal molecular recognition and sieving of xylene isomers. Its distinct temperature-adsorbate–dependent adsorption behavior enables full separation of p -, m -, and o -xylene isomers in both vapor and liquid phases. The delicate stimuli-responsive swelling of the structure imparts this porous material with exceptionally high flexibility and stability, well-balanced adsorption capacity, high selectivity, and fast kinetics at conditions mimicking industrial settings. This study may offer an alternative approach for energy-efficient and adsorption-based industrial xylene separation and purification processes.

The development of adsorption-based separation processes alternative to the energy-intensive cryogenic distillation for a mixture of propylene and propane remains essential but challenging in gas industries. Molecular sieving separation of C

As a new class of porous crystalline materials, hydrogen-bonded organic frameworks (HOFs) assembled from building blocks via hydrogen bonds have gained increasing attention. HOFs benefit from advantages including mild synthesis, easy purification, and good recyclability. However, some HOFs transform into unstable frameworks after desolvation, which hinders their further applications. Nowadays, the main challenges of developing HOFs lie in stability improvement, porosity establishment, and functionalization. Recently, more and more stable and permanently porous HOFs have been reported. Among all these design strategies, stronger charge-assisted hydrogen bonds and coordination bonds have been proven to be effective for developing stable, porous, and functional solids called hybrid HOFs, including ionic and metallized HOFs. This review discusses the rational design synthesis principles of hybrid HOFs and their cutting-edge applications in selective inclusion, proton conduction, gas separation, catalysis and so forth.

This work reports novel hydrophobic paraffin-selective pillared-layer MOFs realizing efficient adsorption separation of paraffins from olefins.

It is challenging to obtain high-purity xenon (Xe) and krypton (Kr) from the by-products of the air separation process due to their similar atom size and physical properties. Adsorption using porou...

Hydrogen-bonded organic frameworks (HOFs) have emerged as rapidly growing porous materials while established permanent porosities are very fragile and difficult to stabilize due to weak hydrogen-bonding interactions among building units. Herein, we report a stable hydrogen-bonded metallotecton framework (termed as HOF-ZJU-102) that was constructed through hydrogen-bonding networks between cationic metal-organic complexes [Cu2 (Hade)4 (H2 O)2 ]4+ (Hade=adenine) and GeF62- anions. The framework not only shows permanent porosity, but also exhibits efficient separation performance of C2 H2 /C2 H4 at room temperature. More interestingly, its crystal structure could be irreversibly transformed into isostructural counterpart HOF-ZJU-101 by ion exchange in the SiF62- containing solution, evidenced by multiple characterization techniques including gas sorption measurements, 19 F NMR spectra, FTIR and EDS. Utilizing such an ion exchange mechanism, the collapsed HOF-ZJU-102 could be restored into HOF-ZJU-101 by simply soaking in the salt solution.

The separation of C8 aromatics (xylenes and ethylbenzene) remains one of the most challenging industrial separations due to their similar structures and properties. Suitable adsorbents that can distinguish the small differences among isomers are urgently demanded. Herein, we demonstrate a strategy to realize the precise discrimination of C8 aromatics by constructing a nonaromatic confined pore environment with mixed polycycloalkane-type ligands. The nonaromatic low-polar pore environment avoids strong convergent interactions between the framework and the common phenyl rings while creating possibilities to amplify the difference between host-guest/guest-guest interactions regarding the different methyl (ethyl) group positions of isomers. The resultant metal-organic framework, ZUL-C3, with either tetragonal or monoclinic lattice, exhibits outstanding separation performance for C8 aromatics, not only realizing the simultaneous separation of four isomers from each other but also setting a benchmark for the dynamic separation performance of OX/PX and OX/MX.

Separation of C3 gases including propyne, propadiene and propylene is important for propylene purification. The absorption separation technology using ionic liquid as the separation medium can overcome the shortcomings of traditional organic solvents and is expected to be promising for the separation of C3 gases. The solubilities of C3 gases in strongly hydrogen-bonding basic carboxylate ionic liquids (ILs) have been measured in this work, and the results showed that these ILs had both high capacity and high selectivity in the separation of C3 gases. In particular, [P4442][C5COO] had a molar solubility of 0.3 mol/mol for propyne at 313.1 K, which reached the highest value. Meanwhile, the solubility of propadiene reached 0.14 mol/mol, significantly higher than that of propylene. The solubility of C3 gases in ILs with different anion lengths and different temperatures showed that the better C3 gas separation performance was achieved with a shorter anion and a lower temperature. Absorption-desorption recycling tests proved that these ILs had great recycling performance.

Selective elimination of sulfur dioxide is significant in flue gas desulfurization and natural gas purification, yet developing adsorbents with high capture capacity especially at low partial pressure as well as excellent cycling stability remains a challenge. Herein, a family of isostructural gallate-based MOFs with abundant hydrogen bond donors decorating the pore channel was reported for selective recognition and dense packing of sulfur dioxide via multiple hydrogen bonding interactions. Multiple O···H-O hydrogen bonds and O···H-C hydrogen bonds guarantee SO2 molecules are firmly grasped within the framework, and appropriate pore apertures afford dense packing of SO2 with high uptake and density up to 1.86 g cm-3, which is evidenced by dispersion-corrected density functional theory calculations and X-ray diffraction resolution of a SO2-loaded single crystal. Ultrahigh adsorption uptake of SO2 at extremely low pressure (0.002 bar) was achieved on Co-gallate (6.13 mmol cm-3), outperforming all reported state-of-the-art MOFs. Record-high IAST selectivity of SO2/CO2 (325 for Mg-gallate) and ultrahigh selectivity of SO2/N2 (>1.0 × 104) and SO2/CH4 (>1.0 × 104) were also realized. Breakthrough experiments further demonstrate the excellent removal performance of trace amounts of SO2 in a deep desulfurization process. More importantly, M-gallate shows almost unchanged breakthrough performance after five cycles, indicating the robust cycling stability of these MOFs.

Separation of xenon/krypton gas mixtures is one of the valuable but challenging processes in the gas industries due to their close molecular size and similar physical properties. Here, we report a novel ultramicroporous hydrogen-bonded organic framework (termed as

Owing to the similar physicochemical properties between ethane (C2H6) and ethylene (C2H4), obtaining polymerization-grade C2H4 (≥99.95% pure) is still tricky problem in the petrochemical industry. Here, we report a robust scandium-based metal-organic framework (ScBPDC), which is connected by oxygen-rich phenyl ligand with exceptionally high thermal stability (up to 873 K) and capacity of C2H6 (4.94 mmol/g at 100 kPa and 283 K), exhibiting superior separation performance of C2H6/C2H4 mixture (the IAST selectivity is up to 1.7 at 283 K). Importantly, ScBPDC can produce 8.96 L/kg C2H4 with ≥99.99% purity while the C2H4/C2H6 (50:50, v/v) as the mixture injection and the low isosteric heat of ScBPDC (16.4 kJ/mol for C2H6) validates the facility of adsorbent regeneration. Furthermore, theoretical calculations demonstrate the C2H6 molecules are trapped in the nonpolar pore surface via C-H⋯π and C-H⋯O interactions between multiple hydrogen atoms of C2H6 and the host framework.

The study of the reaction mechanism and complex network for heterogeneously catalyzed tandem reactions is challenging but can guide reaction design and optimization. Here, we describe a case study using bifunctional metal–organic framework supported Pd nanoparticles (Pd/UiO-66(HCl)) for the one-pot tandem synthesis of substituted tetrahydroquinolines via the Claisen–Schmidt condensation and reductive intramolecular cyclization. The directly observed evolution of intermediates and products, including reactive species containing hydroxylamine group and unstable intermediate 2-phenyl-3,4-dihydroquinoline, was enabled by operando magic angle spinning nuclear magnetic resonance studies under 50 bar H2. The reaction network of the tandem reaction is deduced based on reaction kinetic information obtained from the operando study. The optimized procedure was applied to various acetophenone and nitrobenzaldehyde derivatives carrying different functional groups, and eight valuable substituted tetrahydroquinolines were obtained in moderate to good yields. This work provides a molecular-level understanding of the catalytic system and brings up new opportunities for efficient and sustainable synthesis of medicinally relevant building blocks.

Separation of Xe and Kr is one of the greatest challenges in the gas industries owing to their close molecular structure and similar properties. Energy-effective adsorption-based separation using chemically stable carbon adsorbents is a promising technology. We propose a strategy for Xe/Kr separation using MOF-derived metallic carbon adsorbents. M-Gallate (M=Ni, Co) were used as precursors to fabricate CoNi alloy nanoparticles embedded carbon adsorbents by one-step auto-reduction pyrolysis. The optimal NiCo@C-700 exhibits record-high IAST selectivity (24.1) and Henry's selectivity (20.1) of Xe/Kr among reported carbon adsorbents. DFT calculations, local density of states calculation, charge density difference, and Bader charge analysis reveal the great affinity with Xe benefits from the presence of Ni or CoNi nanoparticles as a result of more charge transfer from Xe than Kr to metal, thus providing higher binding energy. Breakthrough experiments further verify NiCo@C-700 a promising candidate for Xe/Kr separation.

Adsorptive separation of xenon (Xe) and krypton (Kr) is a promising technique but remains a daunting challenge since they are atomic gases without dipole or quadruple moments. Herein we report a strategy for fabricating angular anion-pillared materials featuring shell-like Xe nano-traps, which provide a cooperative effect conferred by the pore confinement and multiple specific interactions. The perfect permanent pore channel (4-5 Å) of Ni(4-DPDS)

Xe/Kr separation is an industrially important but challenging process owing to their inert properties and low concentrations in the air. Energy-effective adsorption-based separation is a promising technology. Herein, two isostructural hydrogen-bonded metal-nucleobase frameworks (HOF-ZJU-201 and HOF-ZJU-202) are capable of separating Xe/Kr under ambient conditions and strike an excellent balance between capacity and selectivity. The Xe capacity of HOF-ZJU-201a reaches 3.01 mmol g