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We conventionally assume that ceramics are brittle. The risks induced by this structural behaviour do not cancel the undeniable need for ceramics in applications with extreme environmental demands. These constraints could be a high working temperature or wear, where metals cannot be used, or in contact with the human body, where the inherent chemical resistance of ceramics makes them more biocompatible and durable. While the first statement on brittleness still holds true for most ceramics, solutions have been found for some: damage-resistant Ceramic Matrix Composites (CMC) are now part of plane engines, and tough zirconia-based ceramics are routinely used in orthopaedic and dental implants. Because of the intrinsic brittleness of ceramics, the required toughness increase must be introduced by tailoring their microstructure. A lot of ground has been covered since the first descriptions of the toughening mechanisms in ceramics in the 1970s. The goal of this review is thus three-fold: summarise the necessary background in fracture mechanics to discuss complex fracture behaviours, provide a picture of the recent development on all the strategies to toughen ceramics, and finally extract lessons on the efficiency of these various toughening mechanisms. In terms of materials, this review will cover CMCs, zirconia-based ceramics, and bulk ceramics using microstructural engineering, which includes the combination of elongated grains with grain boundary engineering, using carbon allotropes, MAX phases, and bioinspired microstructures. For each we will discuss both the core toughening mechanisms and the most recent studies on it. By gathering all these research strands, we will provide in the final part a reflection on the link between toughness and pseudo-ductile behaviour and how it can help to hopefully reach uncharted territory in terms of structural properties in the future. [ABSTRACT FROM AUTHOR]

The study explores the mechanical behavior of bioinspired honeycomb sandwich structures against hail impact using Ls-Dyna. The hail model, based on experimental values, is created with smoothed particle hydrodynamics. The force-time graph aligns with the peak value from the impact test on a rigid bar, showing good agreement with literature. The sandwich model, impacted by a hemispherical-nosed impactor, exhibits post-impact damage images and collapse in the z-axis consistent with experimental results. Diversified honeycomb cell profiles include wavy, spider web, bamboo, and combinations. When subjected to hail impact, the wavy model excels in sEA, spider web-bamboo in specific deformation, and bamboo in sPCF. [ABSTRACT FROM AUTHOR]

Superhydrophobic sand (SHS) is a plastic-free mulching technology that re- duces surface evaporation of water from irrigated soils. Here, we present the results of two experimental field trials conducted in the 2019-20 and 2021-22 cropping seasons, comparing the efficacy of SHS with those of traditional plastic mulches on the growth and yield performance of sweet pepper (Capsicum annum L.) plants. The experiments were conducted at the King Abdulaziz University (KAU) agriculture research station at Hada Al-Sham (21°48′3″N, 39°43′25″E), Al-Jamoom, Saudi Arabia. The effects of bare soil (i.e., control treatment), 5 mm SHS thickness, and 10 mm SHS thickness, along with white and black plastic mulches (120-um-thick polyethylene) were recorded on the plants via a randomized complete block design with three replicate plots. We found significant benefits of all of the mulches during the 2021-22 season, as evidenced by 51% (P < 0.001), 31% (P 0.0102), and 32% (P = 0.0048) more fruits for the 10-mm SHS, white plastic, and black plastic mulches, respectively, compared with the unmulched con- trols. Consequently, the total fruit yield per plant increased by 112% (P=0.000), 71% (P<0.001), and 83% (P<0.001), under 10 mm SHS, white plastic, and black plastic mulches, respectively. Curiously, the field trial conducted in 2019 in an adjacent field did not reveal significant benefits of SHS, which we attribute partially to erratic rain showers and field heterogeneity. Taken together, this study and our previous work show that 10-mm-thick SHS mulch is optimal for boosting irrigation efficiency in regions where water is a limiting factor. Unlike plastic mulches, SHS biodegrades in <1 year and becomes a part of the sandy soil matrix, thereby obviating landfilling. Thus, the benefits of SHS exceed those of plastic mulches in terms of closing the yield gap and carbon footprint. These findings underscore the potential of SHS as a sustainable solution for growing plants in hot and dry arid regions in Saudi Arabia and globally. [ABSTRACT FROM AUTHOR]

The active sites of metalloenzymes involved in small molecules activation often contain pendant bases that act as proton relay promoting proton‐coupled electron‐transfer processes. Here we focus on hydrogenases and on the reactions they catalyze, i. e. the hydrogen evolution and oxidation reactions. After a short description of these enzymes, we review some of the various biomimetic and bioinspired molecular systems that contain proton relays. We then provide the formal electrochemical framework required to decipher the key role of such proton relay to enhance catalysis in a single direction and discuss the few systems active for H2 evolution for which quantitative kinetic data are available. We finally highlight key parameters required to reach bidirectional catalysis (both hydrogen evolution and hydrogen oxidation catalyzed) and then transition to reversible catalysis (both reactions catalyzed in a narrow potential range) as well as illustrate these features on few systems from the literature. [ABSTRACT FROM AUTHOR]

The development of positioning systems has been significantly advanced by a combination of technological innovations, such as improved sensors, signal processing, and computational power, alongside inspiration drawn from biological mechanisms. Although vision is the main means for positioning oneself—or elements relative to oneself—in the environment, other sensory mediums provide additional information, and may even take over when visibility is lacking, such as in the dark or in troubled waters. In particular, the auditory system in mammals greatly contributes to determining the location of sound sources, as well as navigating or identifying objects' texture and shape, when combined with echolocation behavior. Taking further inspiration from the neuronal processing in the brain, neuromorphic computing has been studied in the context of sound source localization and echolocation-based navigation, which aim at better understanding biological processes or reaching state-of-the-art performances in energy efficiency through the use of spike encoding. This paper sets out a review of these neuromorphic sound source localization, sonar- and radar-based navigation systems, from their earliest appearance to the latest published works. Current trends and possible future directions within this scope are discussed. [ABSTRACT FROM AUTHOR]

Abstract The discovery of natural slab photonic crystals in diatoms has sparked questions regarding their prevalence and functional role in nature. These advanced nanomaterials open so-called photonic stopbands in two dimensions, enabling precise light manipulation essential in technologies like quantum computing and photonics. However, the natural role of these advanced properties remains a mystery. In this study, we adopted a multidisciplinary approach, combining taxonomic, evolutionary, and photonic property analyses. Using scanning electron micrographs, we examined the girdle elements of the silicon dioxide shell from several hundred diatom species to explore the potential correlation between occurrence of slab photonic crystals and taxonomic relationship. Girdle slab photonic crystals emerged among the oldest diatom classes, with stopband properties covering the visible to mid-infrared spectral range. Square lattice formations emerged first, evolving from quasi-ordered templates, and later diverged into more efficiently packed hexagonal structures. This study shows how photonic nanomaterials developed from quasi order to order over evolutionary trajectories and provides a sustainable inventory of natural slab photonic crystals for application and deeper investigation. Understanding how diatoms utilize these structures can inspire innovative principles for smarter energy management systems as well serve as a model for the evolution of order and symmetry in cellular processes and organization.

Stinger-like structures in living organisms evolved convergently across taxa for both defensive and offensive purposes, with the main goal being penetration and damage. Our observations over a broad range of taxa and sizes, from microscopic radiolarians to narwhals, reveal a self-similar geometry of the stinger extremity: the diameter (d) increases along the distance from the tip (x) following a power law [Formula: see text] , with the tapering exponent varying universally between 2 and 3. We demonstrate, through analytical and experimental mechanics involving three-dimensional (3D) printing, that this geometry optimizes the stinger's performance; it represents a trade-off between the propensity to buckle, for n smaller than 2, and increased penetration force, for n greater than 3. Moreover, we find that this optimal tapering exponent does not depend on stinger size and aspect ratio (base diameter over length). We conclude that for Nature's stingers, composed of biological materials with moduli ranging from hundreds of megapascals to ten gigapascals, the necessity for a power-law contour increases with sharpness to ensure sufficient stability for penetration of skin-like tissues. Our results offer a solution to the puzzle underlying this universal geometric trait of biological stingers and may provide a new strategy to design needle-like structures for engineering or medical applications.

Abstract Bionanotechnology research has surged to the forefront of scientific innovation, propelling the exploration of cutting-edge technologies and interdisciplinary collaboration. Biomimicry, which harnesses nature's ingenuity, drives the development of novel research-based solutions in diverse fields such as vaccines, medicine, and biomedical devices. Nature's role is becoming increasingly pivotal in addressing complex challenges related to environmental conservation, human health, and pandemic preparedness, including those posed by SARS-CoV-2 and other emerging pathogens. Progress in this domain encompasses understanding nature´s mechanisms to develop advanced materials inspired by biological structures. Biomimetic innovations have the potential to revolutionize industries, reduce environmental impacts, and facilitate a more harmonious relationship between humans and nature while considering bioethics, underlining the necessity of conducting responsible research and implementing biomimetic advancements conscientiously. As biomimicry continues to grow, integrating ethical guidelines and policies will ensure these nature-inspired technologies' sustainable development and application, ultimately contributing to a more resilient and adaptive society. This mini-review article broadly overviews bionanotechnology applications based on natural examples. Graphical Abstract

Bionanotechnology research has surged to the forefront of scientific innovation, propelling the exploration of cutting-edge technologies and interdisciplinary collaboration. Biomimicry, which harnesses nature's ingenuity, drives the development of novel research-based solutions in diverse fields such as vaccines, medicine, and biomedical devices. Nature's role is becoming increasingly pivotal in addressing complex challenges related to environmental conservation, human health, and pandemic preparedness, including those posed by SARS-CoV-2 and other emerging pathogens. Progress in this domain encompasses understanding nature´s mechanisms to develop advanced materials inspired by biological structures. Biomimetic innovations have the potential to revolutionize industries, reduce environmental impacts, and facilitate a more harmonious relationship between humans and nature while considering bioethics, underlining the necessity of conducting responsible research and implementing biomimetic advancements conscientiously. As biomimicry continues to grow, integrating ethical guidelines and policies will ensure these nature-inspired technologies' sustainable development and application, ultimately contributing to a more resilient and adaptive society. This mini-review article broadly overviews bionanotechnology applications based on natural examples. [ABSTRACT FROM AUTHOR]

Gastropod mucus, a complex and versatile substance produced by snails and slugs, plays a critical role in their biology, and holds promise for various applications. This review offers a comprehensive and insightful overview of the current state of knowledge on gastropod mucus, encompassing its composition, biological roles, and potential applications. We delve into the multiple intricate mechanisms by which snails and slugs employ mucus to achieve their various biological goals such as locomotion, defense against predators, protection from environmental threats, communication, mating, homing behavior, nutrient recycling, and regulating population density. The focus then shifts to an examination of the practical applications of gastropod mucus such as antipathogen properties, skincare and antiaging, surgical adhesive and drug delivery, dental and orthopedic application, engineering, and biomimicry, as revealed through various studies. We also critically assess the results and identify areas for further research. This critical review helps to refine our understanding of the true potential of gastropod mucus and guides future investigations. Finally, we discuss the challenges of studying gastropod mucus. [ABSTRACT FROM AUTHOR]

Materials with structural coloration capable of multimode color manipulation are gaining growing significance for advanced encryption and high‐security anti‐counterfeiting applications. Among the most promising candidates are naturally derived biomaterials, owing to their renewable, biocompatible, and biodegradable features for developing sustainable, bio‐interfaced photonic platforms. Nevertheless, structural color encryption strategies developed from biological materials usually exhibit limited optical operation modes, lowering their encryption capability and security level. Here, an all‐biomass‐based photonic crystal platform is reported that hierarchically integrates chiral nematic and inverse opal structures through a combination of colloidal assembly, silk protein self‐assembly, and chiral self‐assembly of cellulose nanocrystals, enabling multiplex structural color manipulation in 2D and 3D spaces. The platform's Janus‐style integration brings specular and diffuse reflection, direction‐dependent reflection, circular dichroism, and birefringence into a single form, thereby facilitating multimode structural color tuning in a 2D plane by altering the illumination‐viewing modes. The inherent shape plasticity of silk proteins allows the subsequent creation of 3D photonic platforms with diverse configurations, offering additional spatial flexibility for color encoding. It is demonstrated that this all‐biomass‐based photonic framework exhibits versatile, multilevel, and high‐capacity encryption capability in 2D and 3D spaces, representing an innovative solution to bolster security measures against counterfeiting for future technologies. [ABSTRACT FROM AUTHOR]

Adhesives can intimately connect humans to machines, seamlessly bond diverse tissues in the human body, and manage various diseases. However, the precise spatial control of wet and tough adhesion of biocompatible hydrogels on biological tissues remains a major challenge. Inspired by the bioglue secreted by sandcastle worms, the design of printable tough adhesives (PTAs) is proposed, a supramolecular hydrogel that can be printed into defined structures, in situ mechanically reinforced into a tough matrix with physiologically relevant benign triggers, and strongly adhere to diverse substrates. With carefully selected polymer components and ratios, it is discovered that the 3D printed PTAs can achieve a marked increase in toughness, tensile strength, and stiffness after being immersed in water/saline solution or attached to biological tissues. To assess the robust toughening mechanism triggered by the supramolecular interactions, the effects of polymer content and pH on the mechanical performance of PTAs and the kinetics of their triggered reinforcement are thoroughly investigated. The potential of PTAs is further demonstrated for manufacturing tough connective tissue mimetics, controlling patterned bioadhesion, and designing programmable 4D soft robotics. The bioinspired, printable, benignly triggerable, and adhesive supramolecular PTAs are expected to find broad applications in engineering and medicine. [ABSTRACT FROM AUTHOR]

Sustainable development is increasingly driving the trend toward the application of biomimicry as a strategy to generate environmentally friendly solutions in the design of industrial products. Nature-inspired design can contribute to the achievement of the Sustainable Development Goals by improving efficiency and minimizing the environmental impact of each design. This research conducted an analysis of available biomimetic knowledge, highlighting the most applied tools and methodologies in each industrial sector. The primary objective was to identify sectors that have experienced greater adoption of biomimicry and those where its application is still in its early stages. Additionally, by applying the available procedures and tools to a selected case study (technologies in marine environments), the advantages and challenges of the methodologies and procedures were determined, along with potential gaps and future research directions necessary for widespread implementation of biomimetics in the industry. These results provide a comprehensive approach to biomimicry applied to more sustainable practices in product design and development. [ABSTRACT FROM AUTHOR]

With the increasing popularity of vertical axis turbines (VATs), researchers are now focusing on their performance improvement. Instead of adopting conventional means of performance improvements such as augmentation techniques and exhaustive parametric design optimization, the bio-inspired turbine designs have become a center of attraction, especially during the last decade. This review article attempts to compile the bio-inspired designs belonging to the VATs. Bio-inspired designs implemented in Savonius, Darrieus, Nautilus, and Seed-inspired turbines are elaborated besides giving a detailed explanation of the corresponding bio-organism and natural phenomenon. How the working principles of bio-organisms emulated in the form of fluid dynamic design are explained thoroughly in this paper. The bio-inspired designs for VATs are then classified pragmatically for the future designs. Research gaps are highlighted for the aspiring researchers, and this is followed by the important strategies and allied challenges. [ABSTRACT FROM AUTHOR]

Photothermal conversion technology presents a promising approach for harnessing solar energy to facilitate seawater desalination. However, salts will accumulate on the surface of the photothermal conversion structure during seawater desalination, which hinders solar energy absorption. Meanwhile, the photothermal conversion structure directly immersing in a large water body results in a large heat dissipation loss. Both factors impair solar energy conversion and water steam generation. To address the issues, inspired by a ginseng plant (with a trunk‐to‐branch water supply system), a 3D cotton‐based photothermal evaporator with tunable water supply is facilely designed herein via simple cloak‐weaving of a porphyrin‐based conjugated microporous polymer (PPCMP) as the photothermal conversion material. The as‐designed 3D cloak‐like photothermal evaporator achieves an equilibrium between the water supply flux and evaporation rate via optimizing PPCMP weaving and the water path. As a result, a high evaporation rate of 2.81 kg m−2 h−1 and photothermal conversion efficiency of 155% are obtained under 1 sun illumination. The findings underline the importance of 3D porous organic polymer‐based fabrics as effective media for harnessing solar energy and highlight their potential for seawater desalination. [ABSTRACT FROM AUTHOR]

Copyright of Cuadernos del Centro de Estudios de Diseño y Comunicación is the property of Cuadernos del Centro de Estudios de Diseno y Comunicacion and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Cuadernos del Centro de Estudios de Diseño y Comunicación is the property of Cuadernos del Centro de Estudios de Diseno y Comunicacion and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Cuadernos del Centro de Estudios de Diseño y Comunicación is the property of Cuadernos del Centro de Estudios de Diseno y Comunicacion and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Cuadernos del Centro de Estudios de Diseño y Comunicación is the property of Cuadernos del Centro de Estudios de Diseno y Comunicacion and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Bio‐inspired by natural species and previous research works, nanotubes are prepared by soft‐template electropolymerization in micellar solution. Various thiophene‐based and carbazole‐based monomers are designed from a triphenylamine core. With one of the carbazole‐based monomers, which is fully conjugated and with a star‐like structure, gecko‐like surface structures are obtained even if the structure is not perfectly planar. Extremely long and densely packed‐microtubes are reached especially at constant potential. However, the surfaces are not both highly hydrophobic and with strong water adhesion, but are superhydrophilic. These wetting properties can be explained by a high surface energy (γSV)=41.9 mN m−1 compared to gecko foot even if the natural gecko feet are also chemically inhomogeneous, or by differences in the arrangement of the surface structures. [ABSTRACT FROM AUTHOR]

Robotic burrowing holds promise for applications in agriculture, resource extraction, and infrastructure development, but current approaches are ineffective, inefficient, or cause significant environmental disruption. In contrast, natural burrowers penetrate substrates with minimal disturbance, providing biomechanical principles that could inspire more efficient and sustainable mechanisms. A notable feature of many natural burrowers is their reliance on soft body compositions, raising the question of whether softness contributes to their burrowing success. This review explores the role of soft materials in biological burrowing and their implications for robotic design. We examine the mechanisms that soft-bodied organisms and soft robots employ for submerging and subterranean locomotion, focusing on how softness enhances efficiency and adaptability in granular media. We analyze the gaps between the capabilities of natural burrowers and soft robotic burrowers, identify grand challenges, and propose opportunities to enhance robotic burrowing performance. By bridging biological principles with engineering innovation, this review aims to inform the development of next-generation burrowing robots capable of operating with the efficiency and efficacy seen in nature.

Abstract The surge in modern civil technologies demands a transformation in cement composites to surpass traditional roles and integrate smart functionalities. In this regard, enhancing the electrical conductivity of cement composites is a critical challenge. This study introduces a novel strategy for the self‐propagating formation of expandable graphite‐based high‐conductivity cement composites through a simple thermal treatment with 3 wt.% expandable graphite and 1 wt.%carbon fiber as conductive fillers. Inspired by the popcorn effect, this method leverages the rapid expansion of graphite at high temperatures, promoting contact between conductive fillers and forming new conductive networks. The obtained composites demonstrate a remarkable reduction of 60% in electrical resistance after heat treatment compared to the electrical resistance of standard cement composites, and the enhancing mechanisms is explored. The conductive properties endow the material with excellent electrothermal (>100 °C at 10 V), electrothermochromic (response time of 2 s), and electromagnetic interference shielding (42 dB at 12.4 GHz) performance. This innovative approach provides vast opportunities for developing smart infrastructure with enhanced electrical properties, regarded as a promising candidate for promoting next‐generation buildings and infrastructures.

Soft and tensegrity structures are two configurations that have appeared as robots continue to draw inspiration from nature and diversify beyond rigid machines toward compliant systems. One artificial manifestation of a biological attribute that is an active research topic is the body's capacity to calibrate its stiffness for adapting its behavior to a given task. This study brings together these designs spaces and presents a soft tensile element named FlexiStiff for tensegrity structures to enable transitioning between flexible and stiff states for variable load‐bearing capability and compliance. The device's tensile stiffness constant can be increased by 4400% with a change in pressure. It can provide a high blocking force of 535.5 N and can endure elongation up to 184%. It is assembled using four commercially available materials and a two‐step fabrication method consisting of 3D printing and elastomer curing. As opposed to classical tensegrities for which shape change is inexpensive in terms of energy, this work betokens a new stage in their design wherein the arrangement can radically alter the magnitude of its demand for external energy for shape morphing, a crucial characteristic for operation in partially mapped environments that present diverse terrains and disturbances of varying intensities prompting adaptability. [ABSTRACT FROM AUTHOR]

Soil nails and tieback anchors are used extensively for excavation support and slope stabilization; however, their performance can be complicated by limited pullout capacity or installation challenges. This paper presents the results of field load tests performed on anchorage elements with snakeskin-inspired surfaces that do not require grout and that can reduce the force required for installation. These tests evaluated the effects of the asperity geometry, soil type, and embedment depth on the anchor load transfer behavior and pullout capacity. The tests consisted of jacked installation and pullout loading in sites consisting of dense sand and structured silt. The test results in sand indicate that the installation force and pullout skin friction increase as the asperity height is increased and the asperity length is decreased. The pullout capacity of the snakeskin-inspired anchors in sand was between 1.2 and 4.2 times greater than the capacity of a reference rough anchor. In the structured silt site, disturbance during installation influenced the pullout behavior, resulting in a decrease in anchor capacity as the asperity height was increased. However, the anchor capacity with small asperity heights was greater than that of the reference rough anchor. The snakeskin-inspired anchors mobilized direction-dependent skin friction, resulting in pullout skin friction values that were as much as 3.0 and 4.5 times greater than those generated during installation in the sand and silt sites, respectively, due to mobilized passive resistances during pullout. The results indicate that the snakeskin-inspired anchors can outperform conventional driven anchors in sands. However, the possible effects of installation disturbance should be evaluated carefully in sensitive, structured soils. [ABSTRACT FROM AUTHOR]

The mimesis of biological mechanisms by artificial devices constitutes the modern, rapidly expanding, multidisciplinary biomimetics sector. In the broader bioinspiration perspective, however, bioarchitectures may perform independent functions without necessarily mimicking their biological generators. In this paper, we explore such Bioarchitectonic notions and demonstrate three-dimensional photonics by the exact replication of insect organs using ultra-porous silica aerogels. The subsequent conformal systolic transformation yields their miniaturized affine 'clones' having higher mass density and refractive index. Focusing on the paradigms of ommatidia, the compound eye of the hornet Vespa crabro flavofasciata and the microtrichia of the scarab Protaetia cuprea phoebe, we fabricate their aerogel replicas and derivative clones and investigate their photonic functionalities. Ultralight aerogel microlens arrays are proven to be functional photonic devices having a focal length f ~ 1000 μm and f-number f/30 in the visible spectrum. Stepwise systolic transformation yields denser and affine functional elements, ultimately fused silica clones, exhibiting strong focusing properties due to their very short focal length of f ~ 35 μm and f/3.5. The fabricated transparent aerogel and xerogel replicas of microtrichia demonstrate a remarkable optical waveguiding performance, delivering light to their sub-100 nm nanotips. Dense fused silica conical clones deliver light through sub-50 nm nanotips, enabling nanoscale light–matter interactions. Super-resolution bioarchitectonics offers new and alternative tools and promises novel developments and applications in nanophotonics and other nanotechnology sectors. [ABSTRACT FROM AUTHOR]

The design of iron clusters featuring a bimetallic core and several protonation sites in the second coordination sphere of the metal centers is important for modeling the activity of polymetallic active sites such as the H-cluster of [FeFe]-hydrogenases. For this purpose, the syntheses of complexes [Fe3(CO)5(κ2-PPh2NR2)(μ-pdt)2] (R = Ph (1), Bn (2)) and [Fe3(CO)5(κ2-PPh2NR2)(μ-adtBn)(μ-pdt)] (R = Ph (3), Bn (4)) were carried out by reacting hexacarbonyl precursors [Fe2(CO)6(µ-xdt)] (xdt = pdt (propanedithiolate), adtBn (azadithiolate) with mononuclear complexes [Fe(κ2-pdt)(CO)2(κ2-PPh2NR2)] (PPh2NR2 = (PPhCH2NRCH2)2, R = Ph, Bn) in order to introduce amine functions, through well-known PPh2NR2 diphosphine, into the vicinity of the triiron core. The investigation of the reactivity of these triiron species towards the proton (in the presence of CF3SO3H) and the influence of the pendant amines on the redox properties of these complexes were explored using spectroscopic and electrochemical methods. The protonation sites in such triiron clusters and their relationships were identified. The orientation of the first and second protonation processes depends on the arrangement of the second coordination sphere. The similarities and differences, due to the extended metal nuclearity, with their dinuclear counterparts [Fe2(CO)4(κ2-PPh2NR2)(μ-pdt)], were highlighted. [ABSTRACT FROM AUTHOR]

This review explores the extensive applications of plants in areas of biomimetics and bioinspiration, highlighting their role in developing sustainable solutions across various fields such as medicine, materials science, and environmental technology. Plants not only serve essential ecological functions but also provide a rich source of inspiration for innovations in green nanotechnology, biomedicine, and architecture. In the past decade, the focus has shifted towards utilizing plant-based and vegetal waste materials in creating eco-friendly and cost-effective materials with remarkable properties. These materials are employed in making advancements in drug delivery, environmental remediation, and the production of renewable energy. Specifically, the review discusses the use of (nano)bionic plants capable of detecting explosives and environmental contaminants, underscoring their potential in improving quality of life and even in lifesaving applications. The work also refers to the architectural inspirations drawn from the plant world to develop novel design concepts that are both functional and aesthetic. It elaborates on how engineered plants and vegetal waste have been transformed into value-added materials through innovative applications, especially highlighting their roles in wastewater treatment and as electronic components. Moreover, the integration of plants in the synthesis of biocompatible materials for medical applications such as tissue engineering scaffolds and artificial muscles demonstrates their versatility and capacity to replace more traditional synthetic materials, aligning with global sustainability goals. This paper provides a comprehensive overview of the current and potential uses of living plants in technological advancements, advocating for a deeper exploration of vegetal materials to address pressing environmental and technological challenges. [ABSTRACT FROM AUTHOR]

The aim of this work is to develop an experimental method suitable for the mechanical testing of highly non-standard biological samples such as snake skin with osteoderms. The objective of the method is to determine, whether the osteoderms provide a protective function for the animal in its natural environment. For this purpose, a simulation of rodents biting the skin based on uni-axial compressive loading using a synthetic tooth as a penetrator was developed with an emphasis on integration with X-ray scanners to facilitate in-situ testing. To identify and characterise the structure of snake skin and to prove the protective function of osteoderms, all samples were subjected to high resolution X-ray computed tomography. The results of the experiments are presented in the form of stress-strain curves and a map of the tangent modulus. [ABSTRACT FROM AUTHOR]

The reaction of the dianionic species [Fe2(CO)6(μ-PPh)2]2− with tBuN(CH2Cl)2 gives the di-iron carbonyl aza-diphosphido-bridged complex [Fe2(CO)6(µ-{P(Ph)CH2}2NtBu)] (1). Attempts to prepare 1 by click-chemistry by reacting [Fe2(CO)6(μ-PHPh)2] with CH2O and tBuNH2 afforded a bis-phosphido compound [Fe2(CO)6(µ-P(Ph)CH2NHtBu)2] (2) which exists as two, syn and anti, isolable isomers depending on the relative orientation of the groups carried by the phosphorus atoms. In the presence of HBF4.Et2O, in dichloromethane, 1 leads to the stabilized ammonium species [Fe2(CO)6(µ-{P(Ph)CH2}2NHtBu)](BF4) (3). The derivatives 1–3 were characterized by IR and 1H, 31P-{1H} NMR spectroscopies. Their structures in a solid state were determined by X-ray diffraction analyses, which accord with their spectroscopic characteristics. [ABSTRACT FROM AUTHOR]

This study provides a brief discussion of the major nanopharmaceuticals formulations as well as the impact of nanotechnology on the future of pharmaceuticals. Effective and eco-friendly strategies of biofabrication are also highlighted. Modern approaches to designing pharmaceutical nanoformulations (e.g., 3D printing, Phyto-Nanotechnology, Biomimetics/Bioinspiration, etc.) are outlined. This paper discusses the need to use natural resources for the "green" design of new nanoformulations with therapeutic efficiency. Nanopharmaceuticals research is still in its early stages, and the preparation of nanomaterials must be carefully considered. Therefore, safety and long-term effects of pharmaceutical nanoformulations must not be overlooked. The testing of nanopharmaceuticals represents an essential point in their further applications. Vegetal scaffolds obtained by decellularizing plant leaves represent a valuable, bioinspired model for nanopharmaceutical testing that avoids using animals. Nanoformulations are critical in various fields, especially in pharmacy, medicine, agriculture, and material science, due to their unique properties and advantages over conventional formulations that allows improved solubility, bioavailability, targeted drug delivery, controlled release, and reduced toxicity. Nanopharmaceuticals have transitioned from experimental stages to being a vital component of clinical practice, significantly improving outcomes in medical fields for cancer treatment, infectious diseases, neurological disorders, personalized medicine, and advanced diagnostics. Here are the key points highlighting their importance. The significant challenges, opportunities, and future directions are mentioned in the final section. [ABSTRACT FROM AUTHOR]

Coastal erosion, extreme climate events, and the loss of biodiversity are important consequences of climate change that directly impact our society. The needs to develop effective engineering practices using nature as model and mentor are now emerging aimed to develop high-performance coastal infrastructures integrating and sustaining local marine ecosystems. In this scenario, the present article describes the concept development and preliminary experimentation of simplified bioinspired models to evaluate their hydraulic performances. This study is part of a future vision to develop submerged barriers, printed with eco-friendly materials, characterized by high hydraulic performances and cable of supporting local biodiversity. Following a top-down approach, the functional features of key organisms were abstracted and transferred to create three bioinspired models. The hydraulic performance of these models is analyzed in terms of wave transmission, reflection, and dissipation under various wave conditions. Under certain circumstances, the bioinspired barriers demonstrate wave attenuation comparable to traditional submerged breakwaters. A method based on skin friction and drag-related processes provides a simple heuristic explanation of how the shape of the models affect the transmission coefficient. The results achieved offer valuable insights for the design of future coastal defense systems that are inspired by, and integrated with, natural ecosystems. [ABSTRACT FROM AUTHOR]

Unmanned aerial vehicles (UAVs) offer an efficient solution for power grid maintenance, but collision avoidance during return flights is challenged by crossing power lines, especially for small drones with limited computational resources. Conventional visual systems struggle to detect thin, intricate power lines, which are often overlooked or misinterpreted. While deep learning methods have improved static power line detection in images, they still struggle with dynamic scenarios where collision risks are not detected in real time. Inspired by the hypothesis that the Lobula Giant Movement Detector (LGMD) distinguishes sparse and incoherent motion in the background by detecting continuous and clustered motion contours of the looming object, we propose a Scale-Invariant Looming Detector (SILD). SILD detects motion by preprocessing video frames, enhances motion regions using attention masks, and simulates biological arousal to recognize looming threats while suppressing noise. It also predicts impending collisions during high-speed flight and overcomes the limitations of motion vision to ensure consistent sensitivity to looming objects at different scales. We compare SILD with existing static power line detection techniques, including the Hough transform and D-LinkNet with a dilated convolution-based encoder–decoder architecture. Our results show that SILD strikes an effective balance between detection accuracy and real-time processing efficiency. It is well suited for UAV-based power line detection, where high precision and low-latency performance are essential. Furthermore, we evaluated the performance of the model under various conditions and successfully deployed it on a UAV-embedded board for collision avoidance testing at power lines. This approach provides a novel perspective for UAV obstacle avoidance in power line scenarios.

The oscillatory pitch motion at the leading edge of a millimeter‐scale flexible sheet on the water surface can generate undulatory locomotion for swimming, similar to a honeybee vibrating its wings for propulsion. The influence of various parameters on such swimming strategy remains unexplored. This study uses magnetic milliswimmers to probe the propulsion mechanics and impact of different parameters. It is found that this undulatory propulsion is driven by capillary forces and added mass effects related to undulatory waves of the milliswimmers, along with radiation stress stemming from capillary waves at the interface. Modifying the parameters such as actuation frequency, pitch amplitude, bending stiffness, and hydrofoil length alters the body waveform, thus, affecting the propulsion speed and energy efficiency. Although undulatory motion is not a prerequisite for water surface propulsion, optimizing body stiffness to achieve a proper undulatory waveform is crucial for efficient swimming, balancing energy consumption, and speed. The study also reveals that the induced water flow is confined near the water surface, and the flow structures evolve with varying factors. These discoveries advance the understanding of undulatory water surface propulsion and have implications for the optimal design of small‐scale swimming soft robots in the future. [ABSTRACT FROM AUTHOR]