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Cigarette butt (CB) waste is abundant and difficult to biodegrade, which is dangerous for both the environment and human health. The key reason CBs are littered is that people do not know much about the harm CBs pose to the environment. Recycling CBs in infrastructure construction can help raise people's awareness. To promote the recycling of CB waste, this paper aimed to determine the feasibility of using CBs as a modifier for asphalt binders. In this research, CBs were preprocessed and mixed with virgin asphalt binder as a fiber modifier. Comprehensive laboratory investigations, including a softening point test, viscosity test, storage stability test, and temperature sweep test, were performed, along with a frequency sweep test, to evaluate the performance of the modified samples. During this investigation, samples were prepared with 1%, 2%, 3%, and 4% CBs. The results of the CB-modified samples were compared with the sample consisting of fresh bitumen (0% fiber). The results show that the physical and rheological properties of bitumen with incorporated CBs improved significantly, and CBs could be used instead of virgin cellulose fiber as a fiber modifier. However, CB-modified asphalt reduced the storage stability and low-temperature performance of the samples. Further research should focus on improving the storage stability and low-temperature performance of CB-modified asphalt binders to facilitate their application in asphalt pavements. [ABSTRACT FROM AUTHOR]

Three beaches on the Eastern Black Sea coast of Türkiye, with different usage purposes and urbanization, were evaluated regarding marine litter densities and categories in four seasons. 3573 marine litter items were collected, classified, and recorded. In an area of 3,000 m2, the highest amount of litter was counted in summer with a total of 1473 pieces of litter (Average: 0.491 ± 0.131 items/m2), and the lowest was counted in the spring months with 577 pieces of litter (Average: 0.192 ± 0.026 items/m2). Plastics (79 ± 0.9%) were the most predominant, and litter items mainly consisted of metal (7.2 ± 0.5%) and paper/cardboard (5.6 ± 0.6%.). Beach litter was also associated with fishing activities and tourism. It was observed that litter relatively increased during the fishing season in the region where fishing activities were intense. SIMPER analysis revealed that Çamburnu, located near a fishing port, exhibited a significantly different litter composition, with fishing gear being the most dominant category. [ABSTRACT FROM AUTHOR]

Cigarette filter microplastics are composed of cellulose acetate that does not undergo biological or photo-degradation. These microplastics are readily dispersed and can be found abundantly in water, soil, and air. These fibers possess high absorption capabilities, allowing them to collect and retain pollutants such as toxic elements. As a result, they are regarded as potential dangers to living organisms. The purpose of this study was to analyze the immune response of human peripheral blood mononuclear cells (PBMCs) when exposed to cigarette filter microfibers, measuring the secretion of the inflammatory cytokines TNFα (tumor necrosis factor-alpha) and IL-6 (interleukin-6). In this study, we examined how used cigarette cellulose acetate microfibers affect the viability of peripheral blood mononuclear cells in an appropriate culture medium at three concentrations: 50, 100, and 200 µg/ml. In addition, this study investigated the release of inflammatory cytokines TNFα and IL6 from PBMCs exposed to 200 µg/ml cigarette filter cellulose acetate. The results showed that increasing the concentration of cellulose acetate fibers of one of the brands in the culture medium has a significant effect on reducing cell viability. The 200 µg/ml in DW is more effective than 50 and 100 µg/ml in reducing cell viability. Peripheral blood mononuclear cells showed an inflammatory immune response when exposed to 200 µg/ml cellulose acetate from cigarette filters. They produced inflammatory cytokines that showed a significant increase compared to the control sample. In general, it can be concluded that cellulose acetate fibers in contact with body cells stimulate them and cause an inflammatory response. [ABSTRACT FROM AUTHOR]

Cigarette butts are classified as plastic waste due to their composition of cellulose acetate fibers and are commonly found in beach sand. Their persistence in the environment, low biodegradability, and potential to interact with metals and metalloids during the aging process make them a significant subject of interest for research on coastal marine ecosystems. The aim of this study is to investigate the presence of metals such as hexavalent chromium Cr (VI), cadmium (Cd), and the metalloid arsenic (As) in cigarette butts (CBs), cigarette butt fibers (CBFs), and sand on a tourist beach in Cartagena, Colombia. The goal is to establish a baseline for potential contamination on the beach due to these elements. The methodology includes collecting samples of CBs, CBFs, and sand from different beach usage zones (active, rest, and service) and conducting standardized laboratory tests using atomic absorption spectroscopy for As and Cd and the standard colorimetric method for Cr (VI). The main findings indicate that arsenic levels reached 7.69, 5.75, and 3.47 mg As/kg in the sand, CBs, and CBFs, respectively. Cadmium and hexavalent chromium were found to be below the detection limit for the applied methodology. Additionally, mercury was detected at a concentration of 0.37 mg Hg/L in CBFs in the active zone in October. [ABSTRACT FROM AUTHOR]

Copyright of GeSec: Revista de Gestao e Secretariado is the property of Sindicato das Secretarias e Secretarios do Estado de Sao Paulo (SINSESP) and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Environmental & Social Management Journal / Revista de Gestão Social e Ambiental is the property of Environmental & Social Management Journal and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The purpose of this paper is to investigate how public administration can reduce cigarette butt littering in public areas. Cigarette butt littering is a problem for every local government unit; however, policy solutions are either very difficult to implement or expensive. This paper demonstrates the potential of behavioural science, namely nudges employing gamification, salience, and priming. Design/Methodology/Approach: In collaboration with local public administration, two field quasi-experiments were conducted to explore the effectiveness of low-complexity behavioural measures to tackle cigarette butt littering in heterogeneous public spaces. The study tested both the effectiveness of a single behavioural measure and the follow-up effect of a combination of low-complexity measures. In the first quasi-experiment, a standalone intervention (priming stickers) and the follow-up combination of measures (priming stickers with gamified ballot bins) were tested. In the second quasi-experiment, a standalone salience nudge (crime scene) was first implemented, followed by a combination of the initial (crime scene) and follow-up salience (toxicity) nudges to nudge smokers from cigarette butt littering in public space. Both quasi-experiments used a before-and-after design. Findings: The results suggest that a single behavioural intervention may be sufficient to achieve the desired behavioural change, and reinforcing its effects within a relatively short time period with a follow-up intervention may not deliver any additional statistically significant effects. Originality/Value: This research contributes to public administration research, specifically by applying behavioural insights and experimental approaches to studying public policies. Although this approach is gaining popularity, there remains a lack of evidence from field (quasi-)experimental studies on the effects of behavioural interventions in reducing pollution in public spaces. [ABSTRACT FROM AUTHOR]

This study demonstrated the biodegradation of two different brands of cigarette butts (CBs), which are primarily composed of cellulose acetate, by four distinct microorganisms. These included the white rot fungus Pleurotus ostreatus, the brown rot fungus Lentinus lepideus, and the bacteria Bacillus cereus and Pseudomonas putida. After 31 days of treatment, weight loss measurements revealed a mass loss of 24–34%, where B. cereus exhibited the greatest efficacy in terms of mass loss for both brands of CBs. Fourier-Transform Infrared Spectroscopy (FTIR), confocal microscopy, and scanning electron microscopy (SEM) confirmed changes in the surface of the CBs, attributable to structural wear and material breakdown, indicating effective biodegradation by the evaluated microorganisms. Furthermore, the analyses confirmed changes in the surface of the CBs, attributable to structural wear and material breakdown, indicating effective biodegradation by the evaluated microorganisms. [ABSTRACT FROM AUTHOR]

Copyright of Journal of Anatolian Environmental & Animal Science is the property of Bulent Verep and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Background: Beachgoers have been identified as the primary contributors to contamination along the Persian Gulf in Bushehr port, where they frequently visit the beaches. In response to this issue, a comprehensive cleanup program was initiated by the Systems Environmental Health and Energy Re-search Center (SEHERC) with the valuable assistance of students from Bushehr University of Medical Sciences. The primary objective of this program was to enhance the environmental awareness and educa-tion of beachgoers. Materials and Methods: To effectively execute the cleanup program, a specific time slot during peak beachgoing hours (18:15-19:15) on May 13, 2023 and a prominent location at Bushehr beaches, namely Marjan Park, were strategically chosen, and the waste materials left on the beach by the beachgoers were collected during the cleanup program. Results: During the designated cleanup period, significant quantities of waste were successfully collected and categorized. Noteworthy items included 7622 cigarette butts (totaling 1.66 kg), bottle caps, disposable food packaging, bottles, various plastic items, disposable hookah mouthpieces, glass shards, drinking straws, fishing nets, plastic ropes, and discarded baby diapers that had been abandoned on the beach by the beachgoers. Conclusion: A notable achievement of this study was the active involvement and enthusiastic participa-tion of the beachgoers, particularly the children. Their engagement served as a catalyst for positive out-comes. Furthermore, recognizing the need for widespread impact, the local television station generously provided coverage of the program, thereby enhancing its reach and effectiveness.

This study was aimed to survey toxicity of waterpipe wastes leachates on Peronia peronii in aquatic and sediment environments as two exposure media. For this, leachates of four tobacco types including burnt traditional tobacco (BTT), fresh traditional tobacco (FTT), burnt fruit-flavored tobacco (BFT) and fresh fruit-flavored tobacco (FFT)) were prepared and used to assess their toxic effects on P. peronei in two aquatic and sediment media. The in-vivo toxic effects of five different concentrations of waterpipe tobacco waste leachates on P. peronii were evaluated. The LC50 values of BTTs leachates to P. peronii were 17.50, 16.05, 11.31 and 9.38 g/L at exposure times of 24, 48, 72 and 96 h, respectively in aquatic media. These values for BFTs leachates were 14.86, 12.38, 9.53 and 7.46 g/L at exposure times of 24, 48, 72 and 96 h, respectively. In the case of sediment media, the LC50 values of BTTs leachates were 15.33, 13.70, 9.09 and 6.70 g/L at exposure times of 24, 48, 72 and 96 h, respectively while these values for BFTs leachates were 12.00, 10.32, 8.20 and 5.65 g/L. Fruit-flavored tobacco leachates had significantly higher toxicity than traditional tobacco leachates for P. peronii. The findings also showed significant differences between the LC50 values of different leachates in different media of water and sediment. The results demonstrated that even small amount of tobacco waste (~ 5 to 6 g/L) can lead to P. peronii mortality and may also pose a hazard to other aquatic and benthic organisms. The results obtained from the present study can be used as a baseline data to assess local effects causing from unsafe disposal of post-consumption tobacco waste in beach areas. In addition, these findings can lead to encouraging decision-makers to focus more on the types of tobacco waste in the municipal solid waste management system and to implement a source separation process for these wastes. [ABSTRACT FROM AUTHOR]

Using waste as a raw material for the synthesis of construction materials is gaining increasing attention due to the declining availability of natural resources. This research seeks to assess the impact of using cellulose acetate microfibers (CAMs) derived from discarded cigarettes as a reinforcement for alkali-activated materials (AAMs). In this context, seven blends were elaborated with the addition of various percentages of CAMs (0%, 0.2%, 0.4%, 0.6%, 0.8%, 1%, and 1.5%) per dry mass of fly ash, and using an alkaline solution composed of Na2SiO3 and 10 M NaOH solution. Then the physico-mechanical, thermal, and environmental properties of these composites were evaluated. The experimental results indicated that the addition of CAMs led to lighter composites, which decreased compressive strength, P-wave velocity, and density, while slightly increasing flexural strength, porosity, and water absorption. Moreover, a slight enhancement in thermal insulation capacity was observed (up to ∼9.28%). The microstructural analyses, encompassing XRD, FT-IR, and SEM/EDX examinations, revealed the formation of geopolymeric gels N-A-S-H and C-A-S-H in all specimens. The Toxicity Characteristic Leaching Procedure indicated that the released contaminants were within the regulatory limits, as well as the binder exhibited a remarkable decrease in carbon dioxide emissions and energy demand by 77.23% and 57.92% in comparison to cement. Thus, the prepared materials are viewed as a more environmentally responsible choice for reducing greenhouse gas emissions while avoiding potential toxicity issues.

Abstract Cigarette butts (CBs) have become the most ubiquitous form of anthropogenic litter globally. CBs contain various hazardous chemicals that persist in the environment for longer period. These substances are susceptible to leaching into the environment through waterways. The recent study was aimed to evaluate the effects of disposed CBs on the growth and development of Azolla pinnata, an aquatic plant. It was found that after a span of 6 days, the root length, surface area, number of fronds, and photosynthetic efficacy of plant were considerably diminished on the exposure of CBs (concentrations 0 to 40). The exposure of CBs led to a decrease in the FM, FV/F0, and φP0, in contrast, the φD0 increased in response to CBs concentration. Moreover, ABS/CSm, TR0/CSm, and ET0/CSm displayed a negative correlation with CB-induced chemical stress. The performance indices were also decreased (p-value ≤ 0.05) at the highest concentration of CBs. LD50 and LD90 represent the lethal dose, obtained value for LD50 is 20.30 CBs and LD90 is 35.26 CBs through probit analysis. Our results demonstrate that the CBs cause irreversible damage of photosynthetic machinery in plants and also reflect the efficacy of chlorophyll a fluorescence analysis and JIP test for assessing the toxicity of CBs in plants.

Cigarette butts (CBs) are small residues with mixed composition. Produced in large amounts, their accumulation in the environment has become alarming. It is possible to classify more than 7000 chemical components generated either in the burning process or when distilled from the tobacco. The aim of this work was to describe the rate of release of phenolic compounds from CBs, to determine the content of these compounds in freshly smoked CBs and to monitor the release of phenols from CBs into fresh natural waters. The kinetics of release of selected phenolic compounds (hydroquinone, resorcinol, pyrocatechol, phenol, guaiacol, o-cresol, m-cresol, p-cresol) into water was monitored for 48 h. More than 90% of the content was extracted within 10 h for all analytes. The phenolic content was determined in the CBs of five different brands. The total content of phenols determined for each sample of freshly smoked CB was 215–861 µg/CB. For all CBs analysed, phenol, pyrocatechol and hydroquinone were the most abundant analytes, accounting for up to 75% of the content of all phenols determined. Phenol was the most abundant analyte (64.6–267.8 µg/CB) in all analysed samples. The content of pyrocatechol, the second most abundant analyte, was 45.6–221.2 µg/CB and the third most abundant analyte was hydroquinone (41.71–157.5 µg/CB). Monitoring the release of phenols from CBs into fresh natural waters (river, stream, pond) under steady and slight moving conditions showed that the kinetics of release is not influenced by the type of water. On the contrary, the process of decomposition of the released compounds is influenced by the type of water. The maximum concentrations of individual phenols in CBs extracts were comparable to those determined via laboratory extraction, thus indicating that within 72 h, most of the phenolic compounds are released from CBs into natural water. This research provides missing information on the phenolic content in CBs and the rate of release into water. It thus complements previously published information on CBs as a source of environmental contamination. [ABSTRACT FROM AUTHOR]

Trillion of cigarette butts are annually littered without being recycled. This work aims at valorizing the whole cigarette butts and their components (paper, filter and tobacco) into Fe‐Nx‐C electrocatalysts for oxygen reduction reaction (ORR) in acid and alkaline media. The pristine wastes were pyrolyzed at 450 °C, activated with KOH at 700 °C, blended with iron phthalocyanine (FePc) precursor, and heat‐treated at 600 °C to produce a robust Fe‐Nx‐C material with ORR active units. The effect of the cigarette components on the final electrocatalytic activity was evaluated by thoroughly investigating the surface chemistry with XPS. The electrocatalysts displayed similar results among the different components in both media due to comparable surface chemistry, especially concerning the nitrogen functional groups. The highest performance was obtained in alkaline where the electrocatalysts from whole cigarettes and paper (CIGF_450 and CIGPF_450) showed an E1/2 of 0.89 V vs RHE, slightly larger than that of Pt/C with 40 wt % of Pt, which encouraged to replace Pt‐based electrocatalysts in alkaline fuel cells. [ABSTRACT FROM AUTHOR]

Cigarette butts (CBs) are one of the most common types of litter in the world. Due to the toxic substances they contain, the waste generated poses a harmful risk to the environment, and therefore there is an urgent need for alternative solutions to landfill storage. Thus, this work presents a possible revalorization of this waste material, which implies interesting environmental benefits. CBs were used as sacrificial templates for the preparation of CaO-based materials by impregnation with calcium and magnesium nitrates followed by flaming combustion. These materials presented enhanced porosity for their use in the Calcium Looping process applied either to thermochemical energy storage or CO 2 capture applications. The influence of the concentration of Ca and Mg in the impregnating solutions on the multicycle reactivity of the samples was studied. An improved multicycle performance was obtained in terms of conversion for both applications. [ABSTRACT FROM AUTHOR]

Invasive parasites are a major threat to biodiversity worldwide, so understanding the factors that control them is necessary to improve the health of affected host species. In the Galápagos Islands, the invasive nest ectoparasite, the avian vampire fly (Philornis downsi), is causing up to 100% mortality in nestling Darwin's finches. However, urban finch nests have fewer flies than non-urban finch nests. One explanation is that finches incorporate cigarette butts into their nests, which can decrease nest parasite abundance for other bird species. For our study, we exposed larval flies to cigarette tobacco-treated (concentrated or diluted) or untreated cotton, then characterized pupation success, pupal deformities and success, and adult fly eclosure success and size. The influence of moisture on the effect of tobacco treatment on fly health was also determined. Flies reared in the tobacco treatments as larvae had lower pupation success, larger pupal volume, and a higher prevalence of pupal deformities compared to control flies, regardless of moisture treatment. Furthermore, we found that tobacco-treated flies had lower eclosure success. In fact, very few tobacco-treated flies survived to adulthood. We also collected finch nests and quantified the prevalence and mass of cigarette butts and abundance of flies in the nests. Although most urban finch nests contain cigarette butts (73%), the mass of cigarette butts was very low and did not correlate with fly abundance. Compared to past studies, finch nests require ten times as many cigarette butts to affect fly survival. Although tobacco can negatively affect vampire flies, finches likely do not incorporate enough cigarette butts to affect fly fitness. [ABSTRACT FROM AUTHOR]

Cigarette butts (CBs) are non-biodegradable harmful residues of synthetic origin and are widespread in marine environments around the world. Although environmental factors are often primarily responsible for the fragmentation of microplastics in the marine environment, biotic factors have recently been shown to be equally important in plastic debris. This study evaluates the role of the Hediste diversicolor polychaete in the fragmentation of CBs in the marine environment. Polychaetes were exposed to three concentrations of CB (0 (as the control), 0.25, and 1 butt L−1) at two different temperatures (15 °C and 23 °C) for 28 days. At each temperature, aquaria without polychaetes were used to study the effect of the burrowing activity of the polychaete on CB fragmentation. Toxicants analysed from exposed sediments increased their concentration in a dose-dependent manner to the CB concentration at a temperature of 15 °C but not at 23 °C. CBs did not directly decrease Hediste survival, but prolonged elevated temperatures increased the polychaetes' susceptibility. The negative effects of CBs on burial success and burrowing behaviour could not be offset by the reduced start time caused by elevated temperatures. Regardless of temperature, both the weight loss and physical fragmentation of CBs buried in polychaete-contaminated sediments were significantly higher than those without Hediste, with no differences between the two concentrations tested. FTIR-ATR analysis used to evaluate CB degradation in relation to cellulose acetate decomposition showed a greater degradation of this compound in treatments with Hediste than in those without polychaetes (~2.75 times), but these differences were not significant. This study is a promising initial step for future research, as any factor that facilitates the fragmentation of this prevalent and hazardous waste must be carefully studied to extract the maximum benefit to help to reduce CBs in the marine environment. [ABSTRACT FROM AUTHOR]

In this work, we describe the recovery of cellulose acetate (r-CA) polymer from waste cigarette butts (CBs) and their subsequent conversion into feedstock for 3D printing technology. The extraction process for CBs includes two stages: initial washes in water, followed by additional washes in ethanol. A final step involves a dissolution and reprecipitation process, resulting in the creation of a fine powder. The recovery polymer has been analysed and compared to commercial cellulose acetate (p-CA) and unsmoked cigarette filter (u-CA) to assess its purity and examine alterations in its physicochemical properties. The CA powder has also been plasticized with different biocompatible plasticizers to improve the mechanical properties of the CA. We analyze the rheological properties to identify the suitable composition as feedstock for 3D printing. [ABSTRACT FROM AUTHOR]

Cigarette butts, often discarded as litter, are considered a common form of waste, containing a variety of pollutants within this hazardous residue. This study, which was designed to assess the environmental release of certain metals from cigarette butts, investigates a variety of scenarios under varying climatic conditions. Thus, in order to assess the level of metal contamination, samples of cigarette butts were collected in urban areas from seven popular brands in China, smoked artificially, and examined through graphite furnace atomic absorption (GF-AAS). The findings indicated mean concentrations of 1.77 for Cr, 2.88 for Ni, 12.93 for Cu, 24.25 for Zn, and 1.77 µg/g for Pb in the case of newly smoked butts. The emission of each of the metals increases to 8–10% when cigarette butts remain in the environment for an extended period of time. Furthermore, rainfall can accelerate metal leaching, reaching values of 18–20% compared to the controlled scenario. The worst-case scenario releases 2129.31 kg/year of metals into the environment, while the best-case scenario sees a lower release of 844.97 kg/year. The data reflect variations in metal emissions across different scenarios. There was also a strong correlation between cigarette butts in public spaces and cities. This research highlights the need to educate smokers and increase urban maintenance efficiency to reduce this litter and the metals it leaches into the environment. [ABSTRACT FROM AUTHOR]

Oil spills and dye pollution are currently severe problems that the world is facing due to their negative influences on the ecosystem. In this study, two novel promising and economical procedures for synthesizing high-value engineering aerogels from discarded cigarette butts are successfully developed. Cellulose acetate (CA) fibers separated from the cigarette waste are converted into aerogels via two eco-friendly methods: the sol-gel method with alkali-urea (AU) and the crosslinker method with polyvinyl alcohol (PVA) followed by the freeze-drying process. The two types of aerogels both have a highly porous structure with a porosity of 96.88–98.01%. The pore size of CA-PVA aerogel is in the range of 50–100 µm, while the CA-AU aerogels exhibit an extremely smaller pore size of 10–50 µm. Since the water contact angle after methyltrimethoxysilane coating is in a range of 120–133°, these aerogels have great potential for oil adsorption. The modified CA-PVA aerogels and CA-AU aerogel respectively exhibit significant maximum oil adsorption capacity of 25.22 g.g−1 and 14.89 g.g−1 in less than 10 sec, which can be promising prospects for oil spill treatment. The CA-AU aerogel also exhibits as a promising material for dye removal application with the highest crystal violet (CV) adsorption capacity is more than 38 mg/g. The study results show the great potential of two aerogels in environmental treatment. While CA-PVA aerogel is more suitable for oil adsorption due to its better oil adsorption capacity, the CA-AU aerogel can be versatilely applied for both oil and dye treatment. Highlights: Fabricating aerogels from cigarette waste via two methods: the NaOH-urea and the crosslinker method. The alkaline solution changes the original fibrillated morphology of CA fibers in sol-gel method. The morphology of CA fibers is remained in crosslinker method. Two types of aerogels quickly reach equilibrium in oil adsorption capacity in less than 10 s. The highest crystal violet (CV) adsorption capacity of CA-AU aerogel is more than 38 mg/g. [ABSTRACT FROM AUTHOR]

Cigarette butts (CBs) pollution is a critical global environmental issue, yet limited research exists on CBs pollution in both coastal and inland Chinese cities with varying development levels. This study investigated CBs occurrence, contamination, Cigarette Butts Pollution Index (CBPI), and heavy metal leakage in four cities. The results of CBs collected over multiple days revealed higher contamination levels in coastal city of Dalian (0.10 ± 0.03 CBs/m²), inland cities of Baoding (0.06 ± 0.02 CBs/m²) and Meizhou (0.07 ± 0.02 CBs/m²) compared to first-tier coastal city of Guangzhou (0.03 ± 0.02 CBs/m²). Patterns of CBs occurrence and CBPI varied across land usage and cities development level. SEM and EDS analysis identified microplastics and heavy metal particles released from CBs in water environments. ICP-MS detected a total of 629.7 µg/L of 14 heavy metals. Approximately 1.9 ± 0.9 g/km² of heavy metals are leaked daily in Chinese cities due to CBs, posing a severe threat to soil and water safety given the indiscriminate disposal of CBs. This study offers scientific insights into CBs pollution and underscores the pressing need for effective measures to mitigate environmental hazards, particularly heavy metal and microplastics contamination released from CBs in China. [ABSTRACT FROM AUTHOR]

Cigarette butts (CBs) have become the most ubiquitous form of anthropogenic litter globally. CBs contain various hazardous chemicals that persist in the environment for longer period. These substances are susceptible to leaching into the environment through waterways. The recent study was aimed to evaluate the effects of disposed CBs on the growth and development of Azolla pinnata, an aquatic plant. It was found that after a span of 6 days, the root length, surface area, number of fronds, and photosynthetic efficacy of plant were considerably diminished on the exposure of CBs (concentrations 0 to 40). The exposure of CBs led to a decrease in the FM, FV/F0, and φP0, in contrast, the φD0 increased in response to CBs concentration. Moreover, ABS/CSm, TR0/CSm, and ET0/CSm displayed a negative correlation with CB-induced chemical stress. The performance indices were also decreased (p-value ≤ 0.05) at the highest concentration of CBs. LD50 and LD90 represent the lethal dose, obtained value for LD50 is 20.30 CBs and LD90 is 35.26 CBs through probit analysis. Our results demonstrate that the CBs cause irreversible damage of photosynthetic machinery in plants and also reflect the efficacy of chlorophyll a fluorescence analysis and JIP test for assessing the toxicity of CBs in plants. [ABSTRACT FROM AUTHOR]

This study demonstrated the biodegradation of two different brands of cigarette butts (CBs), which are primarily composed of cellulose acetate, by four distinct microorganisms. These included the white rot fungus Pleurotus ostreatus, the brown rot fungus Lentinus lepideus, and the bacteria Bacillus cereus and Pseudomonas putida. After 31 days of treatment, weight loss measurements revealed a mass loss of 24–34%, where B. cereus exhibited the greatest efficacy in terms of mass loss for both brands of CBs. Fourier-Transform Infrared Spectroscopy (FTIR), confocal microscopy, and scanning electron microscopy (SEM) confirmed changes in the surface of the CBs, attributable to structural wear and material breakdown, indicating effective biodegradation by the evaluated microorganisms. Furthermore, the analyses confirmed changes in the surface of the CBs, attributable to structural wear and material breakdown, indicating effective biodegradation by the evaluated microorganisms.

Abstract Trillion of cigarette butts are annually littered without being recycled. This work aims at valorizing the whole cigarette butts and their components (paper, filter and tobacco) into Fe‐Nx‐C electrocatalysts for oxygen reduction reaction (ORR) in acid and alkaline media. The pristine wastes were pyrolyzed at 450 °C, activated with KOH at 700 °C, blended with iron phthalocyanine (FePc) precursor, and heat‐treated at 600 °C to produce a robust Fe‐Nx‐C material with ORR active units. The effect of the cigarette components on the final electrocatalytic activity was evaluated by thoroughly investigating the surface chemistry with XPS. The electrocatalysts displayed similar results among the different components in both media due to comparable surface chemistry, especially concerning the nitrogen functional groups. The highest performance was obtained in alkaline where the electrocatalysts from whole cigarettes and paper (CIGF_450 and CIGPF_450) showed an E1/2 of 0.89 V vs RHE, slightly larger than that of Pt/C with 40 wt % of Pt, which encouraged to replace Pt‐based electrocatalysts in alkaline fuel cells.

Cigarette butts (CBs) are emerging polluting toxic plastic and microplastic elements that present a major challenge to environmental issues and recycling technologies. This is due to their complex composition consisting of cellulose acetate, cigarette paper, tar particles, tobacco, and heavy metals, thus, making it difficult to mechanically recycle, landfill, or incinerate them. In order to maximize their economic performance, this research aims to convert CBs into valuable volatile and chemical products using thermochemical treatment. Pyrolysis experiments were performed on each CB component separately (paper, filter, and tobacco) and their mixture (MIX) to determine the most complex part in the reaction and their effect on the synthesized pyrolysis vapour (PV) products. The experiments were carried out using thermogravimetric analyser (TGA) at heating rates 5, 10, 15, 20, 25, and 30 °C/min. The PVs generated from each batch under the specified heating conditions were analysed using Fourier transform infrared spectroscopy (TG/FTIR) and gas chromatography–mass spectrometry (GC/MS). Meanwhile, the complexity of reaction of CB components was investigated using three isoconversional model-free methods (Friedman, KAS, and FWO) and two nonlinear isoconversional models (Vyazovkin and Cai). The FTIR results showed that the PV products were rich in aromatic hydrocarbons (paper), carbonyl C = O (filter), CO2 (tobacco), and CO2 and carbonyl C = O (MIX). Whereas, phenol (paper; 42%), acetic acid (filter; 94%), pyridine (tobacco; 45%), and acetic acid (MIX: 74%) were the major GC/MS compounds at lower heating rates, and phenol (paper; 50%), acetic acid (filter; 93%), pyridine (tobacco; 39%), and several compounds in MIX sample (propanal, acetic acid, propanone, limonene, and pyridine) were manifested at higher heating rates. Finally, the kinetic results showed that tobacco represents the most complex part in decomposition of CBs (348 kJ/mol) compared to paper (238 kJ/mol) and filter (269 kJ/mol). Meanwhile, mixing all these components together reduced the complexity up to 184 kJ/mol (MIX), which contributed to decrease in energy consumption during the treatment at industrial scale. [ABSTRACT FROM AUTHOR]

Background: Beachgoers have been identified as the primary contributors to contamination along the Persian Gulf in Bushehr port, where they frequently visit the beaches. In response to this issue, a comprehensive cleanup program was initiated by the Systems Environmental Health and Energy Research Center (SEHERC) with the valuable assistance of students from Bushehr University of Medical Sciences. The primary objective of this program was to enhance the environmental awareness and education of beachgoers. Materials and Methods: To effectively execute the cleanup program, a specific time slot during peak beachgoing hours (18:15-19:15) on May 13, 2023 and a prominent location at Bushehr beaches, namely Marjan Park, were strategically chosen, and the waste materials left on the beach by the beachgoers were collected during the cleanup program. Results: During the designated cleanup period, significant quantities of waste were successfully collected and categorized. Noteworthy items included 7622 cigarette butts (totaling 1.66 kg), bottle caps, disposable food packaging, bottles, various plastic items, disposable hookah mouthpieces, glass shards, drinking straws, fishing nets, plastic ropes, and discarded baby diapers that had been abandoned on the beach by the beachgoers. Conclusion: A notable achievement of this study was the active involvement and enthusiastic participation of the beachgoers, particularly the children. Their engagement served as a catalyst for positive outcomes. Furthermore, recognizing the need for widespread impact, the local television station generously provided coverage of the program, thereby enhancing its reach and effectiveness. [ABSTRACT FROM AUTHOR]

This study explores the spatial and temporal distribution of beach litter accumulation rates at seven sites in Cadiz Bay, Southwest Spain, during October 2022 (i.e., autumn) and March 2023 (i.e., spring). Beach litter was collected during low tide conditions at the strandline during two series of 10 consecutive daily surveys. The main aim of this paper is to comprehensively analyze the influence of seasonality and hydrodynamic and wind patterns on litter abundance and composition. In October, 4199 items (22.58 kg) were recorded, increasing to 4634 items (22.68 kg) in March. Overall, the average litter abundance remained relatively consistent but notable variations were observed at different beach locations. Plastic litter was the most abundant in the total litter amount with 71.13% and 88.39% in October and March, respectively. Litter categories increased from 90 to 107 from October to March and the top 10 litter categories included cigarette butts (1746 in autumn and 514 in spring), plastic fragments (985 and 339) and plastic packaging (297 and 211). Statistical analyses showed no significant seasonal impact on litter quantities but confirmed seasonal variations in litter types. For instance, cigarette butts were more abundant in October, i.e., in autumn, as they are linked to the intensive use of beaches during the summer period (June–September), while wet wipes were prevalent in March, i.e., in spring, because they are associated with an increase in wastewater and river discharges recorded during the late autumn and winter months (November–February). No clear correlations were found between litter quantity and wave height, but specific patterns emerged at exposed and sheltered beaches. The findings provide valuable insights for optimizing coastal clean-up efforts with customized strategies. Further investigations are needed to fully understand the relationships between litter and environmental factors. [ABSTRACT FROM AUTHOR]

The amount and composition of litter was evaluated during May and June 2021 at two urban beaches, i.e., La Victoria and La Cortadura, in Cádiz, SW Spain. Surveys were carried out daily in the morning and in the evening during the weekends to quantify the daily accumulation of beach litter and relate it to the number of beach users, which was assessed at around 1:00 p.m. Litter amount was also related to cleanup operations that were very mechanically and manually carried out each day very early in the morning. A total of 8108 items were collected at the two investigated sectors during the study period and beach visitors were quantified in 22 surveys. Plastic was the most common material, representing 82% in La Victoria and 68% in La Cortadura. The most common items were cigarette butts and small, hard plastic fragments. Some litter items that were hazardous to beach visitors were identified, such as broken glass. The number of visitors was positively related to the amount of litter. Significant differences were seen in the litter abundance between the morning and evening assessments since the beaches were cleaned daily and bins were available to facilitate trash disposal. Cleaning operations remove many of the litter items but always leave small quantities of small items uncollected. Efforts to prevent litter on these beaches should focus on informing visitors properly in order to avoid littering and on improving cleanup operations. [ABSTRACT FROM AUTHOR]

Cigarette butts, composed of cellulose acetate, are non-biodegradable municipal waste. In this study, a highly porous carbon (KCBC) derived from cigarette butts via hydrothermal and K2CO3 activation was successfully prepared to turn the waste into high-value products. The as-formed porous carbon was tested for adsorptive removal of chloramphenicol (CAP) in this study. The result showed that the prepared KCBC exhibited an excellent adsorption capacity for CAP (450.13 mg/g), mainly benefiting from the high specific surface area (1421.27 m2/g) and rich porous structure. Adsorption isotherms, adsorption kinetics, and adsorption thermodynamics were used to study the adsorption behavior of CAP on KCBC. Results suggested that the adsorption process was a spontaneous, endothermic, entropy increase reaction. Moreover, alkaline pH and the presence of fulvic acid (FA) were not conducive to the adsorption progress, although the adsorption capacity was maintained at relatively high levels. The adsorption mechanism showed that both physical adsorption and chemical adsorption occurred during the adsorption process. Using methanol could effectively desorb CAP, and the KCBC had excellent reusability after five cycles. KCBC also exhibited outstanding adsorption effects on other antibiotics (e.g., tetracycline hydrochloride, sulfamethoxazole, metronidazole, and ciprofloxacin). This study provided a new perspective on the resource utilization of cigarette butts and the treatment of antibiotics-containing wastewater. [ABSTRACT FROM AUTHOR]

Cigarette butts (CBs) are the most diffuse waste in the world, often abandoned into the environment without proper disposal. They are dangerous because of the numerous harmful chemicals potentially released by them into the environment. In the literature, there are several technological options for CB recycling, but some critical concerns could affect their effectiveness due to the quality and quantity of CB litter that is collected in the proper way. The extended producer responsibility scheme for CBs is proposed at the Europe level as an action to tackle CB litter and encourage sustainable product development. The present paper focuses on analyzing the existing literature to identify critical issues within the policy framework, social behavior, waste collection and transport, and technological processes. The collection and transport of CB waste is a major issue, being a key step for bringing CB to the recycling process. The main concern is the small quantity of CBs collected: 0.06% of the municipal waste and 0.18% of the unsorted waste in the case study's administrative area of Perugia. Another crucial issue is the need for behavioral interventions to increase education and awareness of citizens that are smokers, addressing the discrepancy between smokers' behaviors and beliefs. The main results, along with the critical issues related to the topics, are highlighted. [ABSTRACT FROM AUTHOR]

Fabrication of ceramic materials with interconnected pores is necessary to improve thermal energy storage efficiency in high‐temperature infiltration technology. In the present study, industrial wastes such as coal gangue, steel slag, etc., were selected as the raw materials to prepare ceramics with interconnected pores. By adopting 50% cigarette butts as the pore‐forming agent, steel slag–coal gangue mixtures with a mass ratio of steel slag to coal gangue of 1:9 were sintered at 1100°C, and ceramics with interconnected elongated pores were prepared successfully. The highest apparent porosity and lowest volume density of the as‐prepared ceramics were ca. 73% and.74 g/cm3, respectively. Further measurements of the thermophysical properties indicated that no obvious mass loss was observed in the temperature range from ambient temperature to 800°C. The maximum values of specific heat and thermal conductivity were 1.38 J/(g K) and 1.661 W/(m K), respectively, and meanwhile the minimum compressive strength could exceed 3.5 MPa. These research results implied that the as‐prepared steel slag–coal gangue ceramics can provide long‐term service and offer excellent thermal stability over a wide temperature range. Therefore, they should have potential applications in high‐temperature infiltration technology. [ABSTRACT FROM AUTHOR]

Background and Objective: Today, cigarette butts have become one of the most significant forms of waste. This study aims to assess the level of cigarette butts pollution along the Guilan coasts and explore the factors influencing their distribution. Additionally, this study discusses experiences and management options related to this issue. Materials and Methods: In this study, we implemented a standard sampling method adapted from the "NOAA Marine Debris Program" to collect samples from eight beaches. Each station yielded 18 square quadrant measuring 1 × 1 m2. We estimated the severity of cigarette butt pollution along the Iranian coastline and conducted a review of published articles on the harmful effects of cigarette butts. Results: The density of cigarette butts ranged from 0.22 to 2.11 items/m2. Bojagh National Park showed the lowest contamination of cigarette butts, while Bandar Anzali exhibited the highest. The results indicate an increase in cigarette butt pollution on beaches in densely populated cities compared to less developed coastal areas. Moreover, stations corresponding to tourist beaches and coasts with gentle slopes have a higher potential for cigarette butt accumulation. The level of cigarette butts pollution along the coasts of Bandar Anzali may be attributed to the extensive tourism activities on these beaches. Conclusion: Given the high level of cigarette butt pollution on crowded coasts, it is imperative to identify beaches with a higher potential for waste accumulation and implement plans for coastal waste cleanup. Furthermore, effective management programs should be developed to promote cultural awareness and reduce cigarette butt contamination. [ABSTRACT FROM AUTHOR]