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Atrazine is an herbicide with a high soil leaching capacity, contaminating subsurface water sources. Once the water table is contaminated, riparian species can be exposed to atrazine. In this way, understanding the impacts of this exposure must be evaluated for planning strategies that minimize the effects of this herbicide on native forest species. We aimed to evaluate forest species' sensitivity and antioxidant response to exposure to subsurface waters contaminated with atrazine, as well the dissipation this herbicide. The experiment was conducted in a greenhouse in a completely randomized design, with three replications and one plant per experimental unit. The treatments were arranged in a 2 × 10 factorial. The first factor corresponded to the presence or absence (control) of the atrazine in the subsurface water. The second factor comprised 10 forest species: Amburana cearensis, Anadenanthera macrocarpa, Bauhinia cheilantha, Enterolobium contortisiliquum, Hymenaea courbaril, Libidibia ferrea, Mimosa caesalpiniifolia, Mimosa tenuiflora, Myracrodruon urundeuva, and Tabebuia aurea. The forest species studied showed different sensitivity levels to atrazine in subsurface water. A. cearensis and B. cheilantha species do not have efficient antioxidant systems to prevent severe oxidative damage. The species A. macrocarpa, E. contortisiliquum, L. ferrea, and M. caesalpiniifolia are moderately affected by atrazine. H. courbaril, M. urundeuva, and T. aurea showed greater tolerance to atrazine due to the action of the antioxidant system of these species, avoiding membrane degradation events linked to the production of reactive oxygen species (ROS). Among the forest species, H. courbaril has the most significant remedial potential due to its greater tolerance and reduced atrazine concentrations in the soil., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Herbicide mixtures have often been used to control weeds in crops worldwide, but the behavior of these mixtures in the environment is still poorly understood. Laboratory and greenhouse tests have been conducted to study the interaction of the herbicides diuron, hexazinone, and sulfometuron-methyl which have been applied alone and in binary and ternary mixtures in the processes of sorption, desorption, half-life, and leaching in the soil. A new index of the risk of leaching of these herbicides has also been proposed. The sorption and desorption study has been carried out by the batch equilibrium method. The dissipation of the herbicides has been evaluated for 180 days to determine the half-life (t 1/2 ). The leaching tests have been carried out on soil columns. The herbicides isolated and in mixtures have been quantified using ultra-high performance liquid chromatography coupled to the mass spectrometer. Diuron, hexazinone, and sulfometuron-methyl in binary and ternary mixtures have less sorption capacity and greater desorption when compared to these isolated herbicides. Dissipation of diuron alone is slower, with a half-life (t 1/2 ) = 101 days compared to mixtures (t 1/2 between 44 and 66 days). For hexazinone and sulfometuron-methyl, the dissipation rate is lower in mixtures (t 1/2 over 26 and 16 days), with a more pronounced effect in mixtures with the presence of diuron (t 1/2 = 47 and 56 and 17 and 22 days). The binary and ternary mixtures of diuron, hexazinone, and sulfometuron-methyl promoted more significant transport in depth (with the three herbicides quantified to depth P4, P7, and P7, respectively) compared to the application of these isolated herbicides (quantified to depth P2, P4, and P5). Considering the herbicides' desorption and solubility, the new index proposed to estimate the leaching potential allowed a more rigorous assessment concerning the risk of leaching these pesticides, with hexazinone and sulfometuron-methyl presenting a higher risk of contamination of groundwater., (© 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

The speed of the sorption reaction alters the bioavailability of herbicides in the soil and, consequently, the transport and transformation processes of the molecule in the environment. In this research, the sorption kinetics of sulfometuron-methyl was evaluated in different Brazilian soils in which sugarcane is grown. The sorption speed was carried out by the batch equilibrium method. The amount of sulfometuron-methyl adsorbed and remaining in the soil solution was used to build kinetic models in fifteen soils. Pearson's correlation coefficients were determined between maximum sorption capacity and soil properties. The pseudo-second-order model presented the best fit to report the sorption kinetics of sulfometuron-methyl in soils. The sorption equilibrium time varied between 69.1 and 524.7 min. The properties of cation exchange capacity (CEC), soil hydrogenionic potential (pH), and total organic carbon (TOC) affected the sorption kinetics of sulfometuron-methyl. The pH showed a negative correlation with the maximum adsorption capacity at equilibrium, while TOC and CEC positively correlated with the maximum adsorption. The results demonstrate that the sorption speed of sulfometuron-methyl varies between soils; this must be considered when defining the rate of use of the herbicide for weed control, minimizing the risk of environmental contamination.

Pre-emergent herbicides have been developed for their long residual effect; however, they can make sensitive successor cultures unfeasible. Waste remediation techniques are needed for sustainable agricultural systems; for this, the edaphoclimatic asymmetries in the country must be considered. This study aimed to evaluate the remedial capacity of the herbicide diclosulam by covering crops under different edaphoclimatic conditions. Treatments were arranged in an n  × 2 factorial scheme, the first factor being the number of plant species in each location and the second being the presence or absence of diclosulam in the soil. The physiological and growth characteristics of 15 potential phytoremediation species were evaluated. Herbicide residues in the environment were positively correlated with the soil pH; organic matter, aluminum, and silt contents; and aluminum saturation. The effectiveness of phytoremediation varied between species and between regions. Plant species suitable for efficient phytoremidation systems of diclosulam residues were Canavalia ensiformis for Couto Magalhães de Minas, Cajanus cajan and Canavalia ensiformis for Diamantina, Raphanus sativus for Erechim and Cajanus cajan for São João Evangelista.

Weed control efficiency and the environmental contamination potential of herbicides depend on soil sorption and desorption. Among the indexes that evaluate the soil adsorption processes, the coefficients sorption (Kf s ) and desorption (Kf d ) obtained by Freundlich isotherms can provide accurate information about the behavior of an herbicide in the soil. The values of Kf s and Kf d of an herbicide vary according to the physicochemical characteristics of the soil, so it is possible to estimate these coefficients with high precision if good predictive mathematical models are constructed. Therefore, our objective aimed to evaluate the use of multiple regression models (MLR) associated with multivariate techniques to estimate the coefficient Kf s and Kf d for the hexazinone based on the chemical and physical attributes of soils. The correlation analyses, principal components, and clustering analysis allowed the multiple linear regression technique to generate models with higher adjustment coefficient (R 2 ) for Kf s (0.73 to 0.99) and Kf d (0.94 to 0.99), and lower root mean squared error (RMSE) for Kf s (0.003 to 0.065) and Kf d (0.018 to 0.120). Regression models created from groups of soils showed greater prediction performance for Kf s and Kf d . The organic matter followed by the cation exchange capacity was the most important attributes of soils in sorption and desorption processes of hexazinone.