Search

Your search keyword '"dithiooxalato ligand"' showing total 3 results
Start Over Descriptor "dithiooxalato ligand"
3 results on '"dithiooxalato ligand"'

1. Effect of Transition Metal Substitution on the Charge-Transfer Phase Transition and Ferromagnetism of Dithiooxalato-Bridged Hetero Metal Complexes, (n-C3H7)4N[FeII1−xMnIIxFeIII(dto)3]

Author

Masaya Enomoto, Hiromichi Ida, Atsushi Okazawa, and Norimichi Kojima

Subjects
charge-transfer phase transition, iron mixed-valence complex, hetero metal complex, dithiooxalato ligand, substitution of 3d transition metal ion, ferromagnetism, dielectric response, 57Fe Mössbauer spectroscopy, Crystallography, QD901-999
Abstract

The dithiooxalato-bridged iron mixed-valence complex (n-C3H7)4N[FeIIFeIII(dto)3] (dto = dithiooxalato) undergoes a novel charge-transfer phase transition (CTPT) accompanied by electron transfer between adjacent FeII and FeIII sites. The CTPT influences the ferromagnetic transition temperature according to the change of spin configuration on the iron sites. To reveal the mechanism of the CTPT, we have synthesized the series of metal-substituted complexes (n-C3H7)4N[FeII1-xMnIIxFeIII(dto)3] (x = 0⁻1) and investigated their physical properties by means of magnetic susceptibility and dielectric constant measurements. With increasing MnII concentration, x, MnII-substituted complexes show the disappearance of CTPT above x = 0.04, while the ferromagnetic phase remains in the whole range of x. These results are quite different from the physical properties of the ZnII-substituted complex, (n-C3H7)4N[FeII1-xZnIIxFeIII(dto)3], which is attributed to the difference of ion radius as well as the spin states of MnII and ZnII.

Published
2018
Full Text
View/download PDF

2. Effect of Transition Metal Substitution on the Charge-Transfer Phase Transition and Ferromagnetism of Dithiooxalato-Bridged Hetero Metal Complexes, (n-C3H7)4N[FeII1−xMnIIxFeIII(dto)3]

Author

Hiromichi Ida, Norimichi Kojima, Masaya Enomoto, and Atsushi Okazawa

Subjects
Phase transition, Materials science, Spin states, General Chemical Engineering, 010402 general chemistry, dielectric response, 01 natural sciences, Inorganic Chemistry, iron mixed-valence complex, Electron transfer, Transition metal, 57Fe Mössbauer spectroscopy, General Materials Science, dithiooxalato ligand, Ionic radius, 010405 organic chemistry, Transition temperature, substitution of 3d transition metal ion, charge-transfer phase transition, Condensed Matter Physics, ferromagnetism, Magnetic susceptibility, hetero metal complex, 0104 chemical sciences, Crystallography, Ferromagnetism
Abstract

The dithiooxalato-bridged iron mixed-valence complex (n-C3H7)4N[FeIIFeIII(dto)3] (dto = dithiooxalato) undergoes a novel charge-transfer phase transition (CTPT) accompanied by electron transfer between adjacent FeII and FeIII sites. The CTPT influences the ferromagnetic transition temperature according to the change of spin configuration on the iron sites. To reveal the mechanism of the CTPT, we have synthesized the series of metal-substituted complexes (n-C3H7)4N[FeII1-xMnIIxFeIII(dto)3] (x = 0&ndash, 1) and investigated their physical properties by means of magnetic susceptibility and dielectric constant measurements. With increasing MnII concentration, x, MnII-substituted complexes show the disappearance of CTPT above x = 0.04, while the ferromagnetic phase remains in the whole range of x. These results are quite different from the physical properties of the ZnII-substituted complex, (n-C3H7)4N[FeII1-xZnIIxFeIII(dto)3], which is attributed to the difference of ion radius as well as the spin states of MnII and ZnII.

Published
2018
Full Text
View/download PDF

3. Effect of Transition Metal Substitution on the Charge-Transfer Phase Transition and Ferromagnetism of Dithiooxalato-Bridged Hetero Metal Complexes, (n-C3H7)4N[FeII1−xMnIIxFeIII(dto)3].

Author

Enomoto, Masaya, Ida, Hiromichi, Okazawa, Atsushi, and Kojima, Norimichi

Subjects
FERROMAGNETISM, IRON
Abstract

The dithiooxalato-bridged iron mixed-valence complex (n-C3H7)4N[FeIIFeIII(dto)3] (dto = dithiooxalato) undergoes a novel charge-transfer phase transition (CTPT) accompanied by electron transfer between adjacent FeII and FeIII sites. The CTPT influences the ferromagnetic transition temperature according to the change of spin configuration on the iron sites. To reveal the mechanism of the CTPT, we have synthesized the series of metal-substituted complexes (n-C3H7)4N[FeII1-xMnIIxFeIII(dto)3] (x = 0–1) and investigated their physical properties by means of magnetic susceptibility and dielectric constant measurements. With increasing MnII concentration, x, MnII-substituted complexes show the disappearance of CTPT above x = 0.04, while the ferromagnetic phase remains in the whole range of x. These results are quite different from the physical properties of the ZnII-substituted complex, (n-C3H7)4N[FeII1-xZnIIxFeIII(dto)3], which is attributed to the difference of ion radius as well as the spin states of MnII and ZnII. [ABSTRACT FROM AUTHOR]

Published
2018
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results