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2 results on '"heterocyclic silyene complexes"'

1. A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces

Author

Mikko M. Hänninen, Kuntal Pal, Thomas Pugh, Richard A. Layfield, and Benjamin M. Day

Subjects
010405 organic chemistry, Ligand, Stereochemistry, Silylene, 010402 general chemistry, 01 natural sciences, London dispersion force, bonding, 0104 chemical sciences, Inorganic Chemistry, chemistry.chemical_compound, chemistry, Computational chemistry, Amide, heterocyclic silyene complexes, ta116, Isopropyl
Abstract

The structural and bonding properties of a three-coordinate N-heterocyclic silyene (NHSi) complex of the iron(II) amide [Fe{N(SiMe3)2}2] are reported. Computational studies reveal that dispersion forces between the amido SiMe3 substituents and the isopropyl substituents on the NHSi ligand significantly enhance the stability of the complex, along with Fe-to-Si π-backbonding.

Published
2016

2. A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces

Author

Hänninen, Mikko M., Pal, Kuntal, Day, Benjamin M., Pugh, Thomas, and Layfield, Richard A.

Subjects
heterocyclic silyene complexes, kompleksiyhdisteet, bonding
Abstract

The structural and bonding properties of a three-coordinate N-heterocyclic silyene (NHSi) complex of the iron(II) amide [Fe{N(SiMe3)2}2] are reported. Computational studies reveal that dispersion forces between the amido SiMe3 substituents and the isopropyl substituents on the NHSi ligand significantly enhance the stability of the complex, along with Fe-to-Si π-backbonding. peerReviewed

Published
2016

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