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Tilapia aquaculture is rapidly expanding worldwide, particularly in Bangladesh. However, metal pollution in aquaculture presents significant environmental and human health risks. This study aimed to evaluate the concentrations of 13 potentially toxic metals (As, Be, Cd, Co, Cr, Cu, Hg, Ni, Pb, V, Mn, Se, and Zn) in Nile tilapia (Oreochromis niloticus), surface water, and sediment from freshwater and brackish water aquaculture ponds. The study also assessed the associated environmental and human health risks. Samples of tilapia, water, and sediment were collected between October and November 2021 and analyzed using Inductively Coupled Plasma Mass Spectrometry (ICP-MS). The estimated daily intake (EDI) of As, Cr, Pb, Se, and Zn in tilapia muscle of both freshwater and brackish water, as well as Cd and Ni in brackish water, exceeded recommended EDI values. The Target Hazard Quotient (THQ) was less than 1 for most metals, except for As in brackish water tilapia and Cr in both freshwater and brackish water tilapia, indicating potential health risks. The Target Cancer Risk (TR) values for As in both freshwater and brackish water tilapia, and for Cr and Ni in freshwater tilapia, exceeded acceptable ranges. While the concentrations of metals in surface water of both freshwater and brackish water tilapia farms varied, all mean concentrations were below WHO recommended limits. The contamination factor (Cf) values were less than 1 for all metals in both types of aquaculture ponds, except for Zn in freshwater sediment and Se in brackish water sediment. Additionally, the calculated risk indices including the Pollution Load Index (PLI), Geoaccumulation Index (Igeo), Ecological Risk Factor (Er), and Potential Ecological Risk Factor (PER) for sediment were below the risk thresholds values (PLI < 1, Igeo < 0, Er < 40, and PER < 150). The significant positive correlations were found between tilapia muscle and the sediment of the respective ponds for arsenic (As) (ρ= 0.8, p<0.002) and Cr (ρ= 0.7, p<0.02). Although the levels of studied metals in water and sediment from freshwater and brackish water aquaculture ponds were generally within recommended guidelines, this study underscores the need for continuous monitoring and preventative measures, particularly to address elevated levels of As and Cr in tilapia muscle, which may pose potential risks to human health. [ABSTRACT FROM AUTHOR]

AbstractQuinolone antibiotics are widely utilized in aquaculture, but little is known about the health effects of their residues. This study used UPLC-MS/MS to analyze the distribution of 11 quinolone antibiotics in cultured fish sold in a coastal city in southeast China - Fujian Province and to assess their health risks. The study found 35.77% of 260 cultured fish samples detected quinolones, with three exceeding the MRL and one containing the banned drug ofloxacin. Of the 11 quinolones tested, three were found in cultured fish, with enrofloxacin at up to 246.0 μg kg−1, followed by ciprofloxacin and ofloxacin. The distribution of antibiotic detection rates showed no significant differences across regions or time periods; however, notable variations were observed among different fish species. The dietary exposure assessment revealed that consuming cultured fish does not pose a health risk to residents. Nevertheless, there are still instances that exceed regulatory limits. Therefore, routine monitoring and risk assessment are essential for enhancing regulatory measures and protecting public health. [ABSTRACT FROM AUTHOR]

The present study aims to evaluate the distribution of organochlorine pesticides in the Loktak Lake and its draining rivers over a spatial and seasonal scale. Organochlorine pesticides including α- HCH, β- HCH, γ- HCH, δ- HCH, Aldrin, 4,4-DDE, Endrin, Endosulfan II, 4,4-DDD, Endrin Aldehyde, Endosulfan sulphate and 4,4-DDT were analysed in the water and sediments adopting gas chromatography and mass spectrometric techniques. The concentration of pesticides recorded the highest concentration of 2271 ng/l in the water samples and 5319 ng/g in sediment samples. In water samples, Endosulfan II, Endrin and γ- HCH were present at the higher concentrations, whereas α-BHC was recorded at the lowest at 0.78 ng/l. In sediment samples, 4, 4-DDT recorded the highest concentration, followed by 4,4-DDD and Endosulfan II. Human health risk assessment based on water consumption shows higher risk potential from five pesticides. Pesticides in the region may pose a threat to the wetland comprising vital flora and fauna of the biodiversity hotspot. The bacterial population was more or less related to the pesticide concentration, with a lower population at less contaminated sites. [ABSTRACT FROM AUTHOR]

The contribution of mica mining activities to fluoride (F−) contamination in groundwater has been chased in this study. For the purpose, groundwater samples (n = 40, replicated thrice) were collected during the post-monsoons (September–October) from a mica mining area in the Tisri block of Giridih district, Jharkhand. The study has employed a synergy of classical aquifer chemistry, statistical approaches, different indices, Self-Organising Maps (SOM), and Sobol sensitivity index (SSI) to unveil the underlying aquifer chemistry, identify the impacts of mining activities on groundwater quality and its associated health hazard. Fluoride levels varied from 0.34 to 2.8 ppm, with 40% of samples exceeding the World Health Organization's permissible limit (1.5 ppm). Physicochemical analysis revealed significant differences in electrical conductivity (EC), total dissolved solids (TDS), total hardness (TH) and major ion concentrations (Na+, HCO3−, Ca2+) between fluoride-contaminated (FC) and fluoride-uncontaminated (FU) groups. Higher Na+ and HCO3− associated with F− contaminated samples, were indicative of silicate weathering and carbonate dissolution as primary geogenic sources for this ion. Health risk assessment (HRA) revealed hazard quotient (HQ) values exceeding unity, indicating non-carcinogenic risks, particularly for children in most samples from group FC. The mean Water Quality Index (WQI) of FC group (156.76 ± 7.30) was significantly higher (p < 0.05) than group FU indicating of its unsuitability. SOM could accurately (80%) predict presence of fluoride in water samples based on other major ions. Sobol sensitivity analysis successfully identified fluoride concentration and body weight as most impactful parameters affecting human health. The integration of advanced modelling techniques and geospatial analysis as Inverse Distance Weightage (IDW) maps has provided a robust framework for ongoing groundwater quality monitoring in mining-affected regions and can help proactive intervention in risk-prone areas. Overall, this comprehensive study takes us a step ahead towards ensuring safe drinking water access for the global community. [ABSTRACT FROM AUTHOR]

The emergence of large-scale time-series data and advancements in computational power have opened new avenues for analyzing the spatiotemporal evolution of groundwater chemistry, water quality, and human health risks. This paper utilizes hydrogeochemical methods to elucidate the controlling factors of water chemical components based on the test results of 124 groundwater samples collected from 31 monitoring wells in Fuxin City, Liaoning Province, China, from 2018 to 2021. By integrating the Random Forest and Enhanced Water Quality Index methods for water quality assessment and employing the Human Health Risk Assessment (HHRA) model to analyze human health risks, our findings indicate that the groundwater is mildly alkaline, with SO4·Cl–Ca·Mg and HCO3–Ca·Mg as the dominant hydrochemical types, primarily derived from the dissolution of carbonate and silicate minerals such as dolomite, limestone, and andesite, and cation exchange reactions. The EI_RF water quality evaluation model reveals that the overall water quality in the study area is poor, with Class I and II water quality zones mainly located in the northeastern and central parts of the study area, showing a gradual transition from Class I and II in the northeast to Classes IV and V in the southwest, significantly influenced by NO3−, TH, TDS, and SO42−. The HHRA model results indicate that the potential non-carcinogenic risk of groundwater nitrates has a severe impact on infants, with the spatial distribution being low in the northeast and high in the southwest. Due to industrial activities, agricultural practices, and population growth, certain areas in developing countries such as China and India exhibit nitrate concentrations significantly higher than those in most international regions, highlighting global environmental and public health challenges. This underscores the importance of enhancing groundwater monitoring and implementing measures to mitigate pollution. These research outcomes hold significant implications for the government in formulating rational protection and management measures to ensure the sustainable utilization of groundwater resources. [ABSTRACT FROM AUTHOR]

In coastal plains, saline water intrusion (SWI) and potentially hazardous pollutants are harmful to local human health. The southern Laizhou Bay has become a typical representative of the northern silty coast due to its extensive silt sedimentation and the significant impact of human activities. This research focuses on a portion of the southern Laizhou Bay, using GIS-based spatial analysis, water quality index methods and health risk assessments to evaluate the impact of saltwater intrusion and potential hazardous pollutants. The results show that the groundwater in the study area is significantly impacted by saline water intrusion, leading to major ion concentrations that far exceed World Health Organization (WHO) standards. The groundwater chemical types of brine and brackish water in the study area are mainly Cl-Na, and the main chemical types of fresh water are HCO3-Ca·Na. The average concentration sequence of the main ions in groundwater is K+ > HCO3− > Cl− > Na+ > SO42− > Ca2+ > Mg2+. The average hazard quotient (HQ) sequence in typical pollutants is Cl− > F− > NO3-N > Se > Mn > NO2-N > Cu > Pb > Zn > Fe, and the carcinogenic risk (CR) sequence caused by carcinogenic heavy metals is Cd > As > Cr. The noncarcinogenic health risk area is mainly distributed in the northwest of the study area, while the potential carcinogenic risk area is in the central region. The Cl is the greatest noncarcinogenic risk to adults and children. The mean HQ values for adults and children were 95.69 and 146.98, indicating a significant noncarcinogenic risk. The mean CR values for adults and children were 0.00037 and 0.00057, suggesting a relatively low carcinogenic risk. SWI is the main influencing factor on human health; therefore, it is necessary to prevent and control SWI. Moreover, potentially hazardous pollutants are carcinogenic and noncarcinogenic risks and are caused by agriculture, industry and other human activities. The findings of this research offer scientific insights for groundwater pollution control and saline water intrusion management in similar coastal areas. [ABSTRACT FROM AUTHOR]

Quarrying of rock aggregates generates produced water that, if not handled properly will be a source of pollution for nearby water bodies, thus affecting the chemistry of the water. This study examined the chemistry, impact of quarrying activities on water resources and the health consequences/risks posed by ingestion of the water by humans in the Akamkpa quarry region in southeastern Nigeria. Thirty (30) water samples consisting of pond water, stream water, hand dug wells, and borehole samples were collected and analyzed for their physicochemical parameters using standard methods. The results obtained from the analyses indicated that the water was moderately acidic, fresh, and not salty, with many parameters below the recommended standards with Ca2+, and HCO3− being the dominant ions present in the water resources. Rock weathering processes including silicate weathering as illustrated by hydrochemical facies, cross plots, and Gibbs diagrams are the dominant mechanisms influencing the quality and major ions chemistry of the water resources with minor contributions from dissolution, anthropogenic activities, and ion exchange. Ca-Mg-SO4-Cl and Na–K-HCO3− are the most important water types. Although the water quality index shows that the water is suitable for human use and irrigation, the mean values of As, Cd, Pb, and Se are above the acceptable limits. Additionally, the calculated contamination factor revealed the water resources are moderate to highly contaminated by As, Cd, Cr, Mo, Pb, Sb, and Se, and are therefore unsuitable for consumption with regards to these parameters. However, the residual sodium carbonate and water hazard index (WHI) values showed that 38% to 90% of sites in the quarry area were unsuitable for cultivation, 10–30% were in the low to medium impact category, and 60% were classified as risky and are from high to very high impact category. A non-cancer study of inhabitants living in the vicinity of the quarry area indicated that 6.7% of the sites have values greater than one, indicating that it may endanger the health of the people. Therefore, constant monitoring of the water quality is recommended as long-term use of contaminated water can harm humans, plants, and soils. [ABSTRACT FROM AUTHOR]

Contamination of water resources by heavy metals causes health problems for humans. This study attempts to investigate the heavy metal contamination levels, health risks and sources of appraisal of groundwater and surface water in the mountain-bounded catchment and low-grade basement rock-dominated area of ​​the Irob, Tigray. Eighteen grab water samples (13 borehole water, 2 spring water and 3 surface water) were collected and analyzed for pH, electrical conductivity, total dissolved solids and heavy metals using standard procedures. The findings were contrasted with those of the standards set by the World Health Organization and the United States Environmental Protection Agency. Integrated techniques, including indexed and statistical methods, were used to determine the contamination levels of metals, risks to human health and sources. The result shows that the pH value, electrical conductivity and total dissolved solids fluctuated between 7.4 and 7.9, 516 and 2410 µs/cm and 396.7 mg/l and 1719 mg/l, respectively. The findings indicate that 94.4% of the water samples had levels of contamination above the critical limit for all three indices: the heavy metal evaluation index (HEI), the degree of contamination (cd) and the heavy metal pollution index. The hazard index of metals for adults and children was greater than 1. 88.9% of the water samples showed a cancer risk value above the recommended value (CR > 1 × 10–4) for Cd and Cr for both adults and children. Multivariate statistical analyses indicate that weathering of bedrocks and partly anthropogenic influences are responsible for the metal contamination. The study concludes that some water samples sources are unfit for human consumption that can pose health risks over time. Therefore, it is recommended to treat contaminated water sources to protect and sustain public health. [ABSTRACT FROM AUTHOR]

Assessing groundwater quality is essential for ensuring the sustainability of agriculture and ecosystems. This study evaluates groundwater contamination by heavy metals (HMs) using GIS approaches, multivariate statistical analysis (MSA), pollution indices (heavy metal pollution index (HPI), metal index (MI), degree of contamination (Cd), ecological risk index (ERI), and pollution index (PI)), and human health risk assessment (HHRA). The results revealed significant variations in heavy metal concentrations across the study area, with the highest concentrations found in the southern and southeastern parts, characterized by intense agricultural activities and uncontrolled landfills. Statistical analyses indicated both natural and anthropogenic sources of contamination. Pollution indices showed medium to high water pollution levels, with HPI values ranging from 20.23 to 128.60, MI values from 3.34 to 12.17, and Cd values from 2.90 to 11.73, indicating varying degrees of contamination. ERI values suggested a low ecological risk across all samples. However, health risk assessments highlighted significant non-carcinogenic and carcinogenic risks, particularly for children, with TCR values for some heavy metals like Ni and Cr exceeding safe limits, indicating potential health hazards. The findings provide a valuable framework for policymakers to develop targeted strategies for mitigating groundwater contamination and ensuring sustainable water quality management. [ABSTRACT FROM AUTHOR]

The present article assesses, for the first time, the level of heavy metal pollution, determines possible sources and evaluates the health risks associated with groundwater in the Angads plain in Morocco, by employing a combination of tools including indices, statistical multivariate techniques and models for health risk assessment. The findings revealed that the concentrations of several heavy metals (95.83% for As and 41.66% for Pb) were above the WHO limit values. The heavy metal pollution index (HPI) and the heavy metal evaluation index (HEI) revealed that all samples were fit for consumption. Health risks revealed that the hazard index (HI) values for dermal exposure were below the limit, while for oral exposure, 95.83% of samples were above the limit. In addition, the carcinogenic risk (CR) results revealed that there is a possibility of cancer development due to lifetime exposure to this groundwater. [ABSTRACT FROM AUTHOR]

Abstract Quarrying of rock aggregates generates produced water that, if not handled properly will be a source of pollution for nearby water bodies, thus affecting the chemistry of the water. This study examined the chemistry, impact of quarrying activities on water resources and the health consequences/risks posed by ingestion of the water by humans in the Akamkpa quarry region in southeastern Nigeria. Thirty (30) water samples consisting of pond water, stream water, hand dug wells, and borehole samples were collected and analyzed for their physicochemical parameters using standard methods. The results obtained from the analyses indicated that the water was moderately acidic, fresh, and not salty, with many parameters below the recommended standards with Ca2+, and HCO3 − being the dominant ions present in the water resources. Rock weathering processes including silicate weathering as illustrated by hydrochemical facies, cross plots, and Gibbs diagrams are the dominant mechanisms influencing the quality and major ions chemistry of the water resources with minor contributions from dissolution, anthropogenic activities, and ion exchange. Ca-Mg-SO4-Cl and Na–K-HCO3 − are the most important water types. Although the water quality index shows that the water is suitable for human use and irrigation, the mean values of As, Cd, Pb, and Se are above the acceptable limits. Additionally, the calculated contamination factor revealed the water resources are moderate to highly contaminated by As, Cd, Cr, Mo, Pb, Sb, and Se, and are therefore unsuitable for consumption with regards to these parameters. However, the residual sodium carbonate and water hazard index (WHI) values showed that 38% to 90% of sites in the quarry area were unsuitable for cultivation, 10–30% were in the low to medium impact category, and 60% were classified as risky and are from high to very high impact category. A non-cancer study of inhabitants living in the vicinity of the quarry area indicated that 6.7% of the sites have values greater than one, indicating that it may endanger the health of the people. Therefore, constant monitoring of the water quality is recommended as long-term use of contaminated water can harm humans, plants, and soils.

The present article assesses, for the first time, the level of heavy metal pollution, determines possible sources and evaluates the health risks associated with groundwater in the Angads plain in Morocco, by employing a combination of tools including indices, statistical multivariate techniques and models for health risk assessment. The findings revealed that the concentrations of several heavy metals (95.83% for As and 41.66% for Pb) were above the WHO limit values. The heavy metal pollution index (HPI) and the heavy metal evaluation index (HEI) revealed that all samples were fit for consumption. Health risks revealed that the hazard index (HI) values for dermal exposure were below the limit, while for oral exposure, 95.83% of samples were above the limit. In addition, the carcinogenic risk (CR) results revealed that there is a possibility of cancer development due to lifetime exposure to this groundwater.

Scrap-iron smelting, a critical industry for metal recycling, is notorious for releasing potentially toxic elements (PTEs) into the environment. This study investigates pollution levels, sources, and health risks of ten PTEs (Fe, As, Cd, Zn, Cu, Mn, Pb, Cr, Co, and Ni) in indoor and outdoor areas surrounding a major scrap-iron recycling plant in northcentral Nigeria. The potential sources of studied PTEs pollution during the rainy and dry seasons were evaluated using Positive Matrix Factorization (PMF) model. Ecological risk assessments of studied PTEs were conducted using different pollution indices such as Enrichment Factor (EF), Geo-accumulation Index (Igeo), Contamination Factor (Cf), Potential Ecological Risks Index (PERI), Nemerov Integrated Pollution Index (NIPI), and Nemerov Integrated Risk Index (NIRI). Out of the 10 PTEs studied, Cd had the highest pollution level and exhibited a high potential to cause cancer in children during the two seasons considered. Sources of PTEs identified for rainy season included recycling process, electronic waste, coal combustion, steel production, and other smelting activities whereas steel production, electronic waste, coal combustion, recycling process, and traffic emission contributed to the PTE levels obtained in the dry season. This study contributes to the understanding of the environmental impact of scrap-iron smelting operations and advocate for the implementation of sustainable practices that protect both human health and the environment.Highlights: Seasonal variation of ten PTEs in indoor and outdoor areas near a scrap iron recycling were investigated. Electronic waste, and fossil fuel combustion were identified as most contributing factors. Cd was the major contaminant that posed higher ecological risks. Concerted effort is required to reduce human exposure. [ABSTRACT FROM AUTHOR]

Abstract Contamination of water resources by heavy metals causes health problems for humans. This study attempts to investigate the heavy metal contamination levels, health risks and sources of appraisal of groundwater and surface water in the mountain-bounded catchment and low-grade basement rock-dominated area of ​​the Irob, Tigray. Eighteen grab water samples (13 borehole water, 2 spring water and 3 surface water) were collected and analyzed for pH, electrical conductivity, total dissolved solids and heavy metals using standard procedures. The findings were contrasted with those of the standards set by the World Health Organization and the United States Environmental Protection Agency. Integrated techniques, including indexed and statistical methods, were used to determine the contamination levels of metals, risks to human health and sources. The result shows that the pH value, electrical conductivity and total dissolved solids fluctuated between 7.4 and 7.9, 516 and 2410 µs/cm and 396.7 mg/l and 1719 mg/l, respectively. The findings indicate that 94.4% of the water samples had levels of contamination above the critical limit for all three indices: the heavy metal evaluation index (HEI), the degree of contamination (cd) and the heavy metal pollution index. The hazard index of metals for adults and children was greater than 1. 88.9% of the water samples showed a cancer risk value above the recommended value (CR > 1 × 10–4) for Cd and Cr for both adults and children. Multivariate statistical analyses indicate that weathering of bedrocks and partly anthropogenic influences are responsible for the metal contamination. The study concludes that some water samples sources are unfit for human consumption that can pose health risks over time. Therefore, it is recommended to treat contaminated water sources to protect and sustain public health.

Abstract This study evaluated the source apportionment and level of contamination with potential toxic elements (PTEs)—As, Cd, Cr, Cu, Ni, Pb and Zn—in a riparian zone of the Sava River by calculating the Enrichment Factor (EF) and the Geo-Accumulation Index (Igeo). The study analysed the non-carcinogenic and carcinogenic health risks to both adults and children in the local population. Soil and sediment samples collected during high and low water events from 12 sites along 945 km of the river were screened. Elevated soil contents of As, Cr, Cu, Ni, and Zn were observed along the middle and lower stretches from Županja (ZUP) to Belgrade (BEO), and an elevated Cu content was detected in the upper stretch Čatež (CAT), highlighting these elements as a potential risk for the human population. Elevated As, Cd Cr, Ni, and Zn levels in the sediment were also detected, with the Ni content three times higher than the Permissible Exposure Limit (PEL) values, indicating high contamination. The study established that As, Cr, and Ni primarily originate from geological sources; Cu, Pb, and Zn are predominantly from anthropogenic sources; and Cd originates from both geological and anthropogenic sources. Although the EF and Igeo varied along the entire river stretch, they were significantly higher for most elements in the lower stretch, indicating intensive anthropogenic contamination and potential health risks. The carcinogenic and non-carcinogenic risks associated with soils and sediments during high and low water events did not imply a potential risk for adults. However, As, Cd, Cr, and Pb potentially pose the greatest non-carcinogenic risk for children in both high and low water events, with ingestion as the main route of exposure. According to our findings, the elevated concentrations of As, Cd, Cr, and Pb in the Sava River basin (SRB) pose a significant potential health risk to the local population based on several factors: the high levels of these elements, their potential contamination risk as determined by the EF and Igeo, and their bioavailability and solubility. Although the cumulative Total Hazard Index (THI) and Total Carcinogenic Risk (TCR) values are low, particularly in the lower stretch of the Sava River, these elements still present a high potential health threat.

Background: The total suspended particles (TSPs) and selected risk element contents were determined in two medium-sized cities, Litvínov and Sokolov (both in North Bohemia, Czech Republic), where the environment is adversely affected by opencast brown coal mining, coal-related industries, and the petrochemical industry. Methods: TSP samples were collected monthly for three years. Results and Discussion: The results showed significant (p < 0.05) differences in the TSP deposition in different seasons of the year, with the highest values in spring, followed by summer, and the lowest in autumn and winter. This is most likely due to increased coal mining activity in the spring and summer. The amount of the elements associated with the TSP showed mostly a similar pattern. The potential risk of these elements for human health was assessed as the average daily dose (ADD) for ingestion of the individual elements and subsequently calculated hazard quotients (HQ). Elevated oral ADD levels were recorded, especially for children. Among the risk elements, arsenic (As) and lead (Pb) were identified as the most hazardous. Conclusions: The results indicated that the TSP-related risk elements do not represent a serious health risk, but many questions concerning the sources of elements in the area and their bioaccessibility remain open for further research. [ABSTRACT FROM AUTHOR]

Iron-steel (IS) and textile (T) are among the major polluting industries worldwide which generate large quantities of effluents containing potentially toxic metals (PTMs). Irrigation application of these effluents due to freshwater shortage is a common practice in developing countries. The current research endeavors to investigate potentially toxic metals in IS and T effluents, contamination status and ecological risk assessment of irrigated soils, PTMs accumulation in grains of diverse wheat germplasm and human health risk appraisal. Soil irrigation with effluents significantly enhanced soil nitrate-nitrogen (T, 285.86 mg/kg; IS, 539.70 mg/kg), phosphorus (T, 8.35 mg/kg; IS, 11.44 mg/kg), organic matter (T, 6.05%; IS, 4.48%) and PTMs contents compared to control (C). Enrichment factor and geo-accumulation index revealed substantial contamination trend of PTMs in IS (Ni > Cr > Co > Cd > Pb > Zn > Mn) and T (Co > Cd > Ni > Cu > Cr) treated soils. Potential ecological risk index and modified potential ecological risk index placed T (very high risk) and IS (considerable risk) irrigated soils in respective categories, with highest risk contributions from Cd, Co and Ni. The interactive effects for PTMs accumulation in grains of 30 wheat genotypes were recorded significant. Average PTMs accumulation in grains for the three irrigation treatments was IS > T > C for Zn, Cr, Mn, Pb, Fe, Ni and T > IS > C for Co, Cd, Cu. Multivariate statistical analysis (principal component analyses) was used to identify the wheat genotypes with higher or lower grain PTMs accumulative potential on effluent irrigation. The genotypes with a lower grain PTMs accumulation and human health risks are recommended for cultivation in agro-systems receiving IS and T effluents, in order to safeguard wheat crop and human health. [ABSTRACT FROM AUTHOR]

Microplastics have been recently detected in many environmental media and living organisms, yet their transfer and toxicity to humans are poorly known. Here, we review microplastic transfer in the food chain with focus on microplastic pollution sources, methods to analyze microplastics in food, health impact of food-related microplastic exposure, and remediation of microplastic pollution. Microplastic pollution sources include seafood, food additives, packaging materials, and agricultural and industrial products. Remediation techniques comprise the use of microbial enzymes and biofilms. Microplastic detection methods in food rely on separation and quantification by optical detection, scanning electron micrography, and Fourier-transform infrared spectroscopy. Human health impact following microplastic ingestion include cancers, organ and respiration damage, and reproductive impairments. Overall, microplastic toxicity is mainly due to their ability to enter the metabolism, adsorption into the circulatory system for translocation, and difficulty, if not impossibility, of excretion. [ABSTRACT FROM AUTHOR]

The soil, comprising minerals, organic matter, and living organisms, serves as a critical component of our environment. However, anthropogenic activities, such as uncontrolled sewage disposal and industrial waste, have led to pervasive soil pollution, impacting ecosystems and human health. This comprehensive study scrutinizes the intricate dynamics of soil pollution resulting from open waste dumping, specifically examining its impact on the health of local communities and the environment in Haridwar municipality. In this study, four solid waste dumping sites were meticulously surveyed, with soil samples analyzed for 19 parameters through statistical tools like one-way ANOVA, Kruskal–Wallis tests, soil pollution indices, and potential health risk assessment. The Geo-accumulation Index (Igeo) and contamination factor (CF) followed the heavy metals in the order of Zn > Mn > Fe > Cu in all selected sites. Additionally, a potential health risk assessment considered ingestion, inhalation, and dermal exposure pathways, revealing a high non-carcinogenic risk of metals (Mn > Fe > Zn > Cu) for both children and adults. In the ingestion pathway, the hazard quotient indicated a high risk of metals for both children and adults in the range of 1192.73 to 2066.94 for child and 191.98 to 312.16 for adults. Crucially, the HQ revealed potential health risks, emphasizing the urgency of addressing metal contamination. However, the findings indicate that dumping sites directly or indirectly affects the local people of Haridwar municipality. Therefore, this study provides a baseline framework for minimizing the impact of dumping sites on local population and the environment. [ABSTRACT FROM AUTHOR]

This study evaluated the source apportionment and level of contamination with potential toxic elements (PTEs)—As, Cd, Cr, Cu, Ni, Pb and Zn—in a riparian zone of the Sava River by calculating the Enrichment Factor (EF) and the Geo-Accumulation Index (Igeo). The study analysed the non-carcinogenic and carcinogenic health risks to both adults and children in the local population. Soil and sediment samples collected during high and low water events from 12 sites along 945 km of the river were screened. Elevated soil contents of As, Cr, Cu, Ni, and Zn were observed along the middle and lower stretches from Županja (ZUP) to Belgrade (BEO), and an elevated Cu content was detected in the upper stretch Čatež (CAT), highlighting these elements as a potential risk for the human population. Elevated As, Cd Cr, Ni, and Zn levels in the sediment were also detected, with the Ni content three times higher than the Permissible Exposure Limit (PEL) values, indicating high contamination. The study established that As, Cr, and Ni primarily originate from geological sources; Cu, Pb, and Zn are predominantly from anthropogenic sources; and Cd originates from both geological and anthropogenic sources. Although the EF and Igeo varied along the entire river stretch, they were significantly higher for most elements in the lower stretch, indicating intensive anthropogenic contamination and potential health risks. The carcinogenic and non-carcinogenic risks associated with soils and sediments during high and low water events did not imply a potential risk for adults. However, As, Cd, Cr, and Pb potentially pose the greatest non-carcinogenic risk for children in both high and low water events, with ingestion as the main route of exposure. According to our findings, the elevated concentrations of As, Cd, Cr, and Pb in the Sava River basin (SRB) pose a significant potential health risk to the local population based on several factors: the high levels of these elements, their potential contamination risk as determined by the EF and Igeo, and their bioavailability and solubility. Although the cumulative Total Hazard Index (THI) and Total Carcinogenic Risk (TCR) values are low, particularly in the lower stretch of the Sava River, these elements still present a high potential health threat. [ABSTRACT FROM AUTHOR]

This study was performed to determine the status and ecological risk as well as provide a basis for the prevention and control of antibiotic contamination in the drinking water sources of Anhui Province. Ultra Performance Liquid Chromatography (UPLC-MS/MS) was used to measure the detection rate and concentrations of nine antibiotics, classified as sulfonamides (SAs) or tetracyclines (TCs), in water collected from 51 sampling points and from areas with different seasonal characteristics. The risks of the main antibiotics (Sulfamethoxazole (SMZ), Doxycycline (DOC), Sulfadiazine (SDZ), Sulfamerazine (SM2), Sulfadimethoxine (SDM), Doxycycline (DOC), Tetracycline (TC), Oxytetracyline (OTC), and Chlortetracycline (CTC). to the ecosystem and human beings were evaluated using risk quotients (RQs) and target hazard quotients (THQs), respectively. Nine antibiotics were detected in tap water and surface water at concentrations ranging from 1.71 ng L-1-21.92 ng L-1 and 1.54 ng L-1-78.74 ng L-1, respectively. SMZ and DOC were detected in both tap water and surface water. Their highest detection rates in tap water were 59.1% and 63.6%, respectively, and those in surface water were 81.25% and 43.8%, respectively. SDZ, SMZ, SM2, SDM, DOC, TC, OTC, and CTC were detected in the dry and flood seasons, with levels ranging from 2.43 ng L-1-49.43 ng L-1. Among the detected target antibiotics, SMZ, SM2, TC, OTC, and CTC had higher detection rates. The total concentrations of detected antibiotics were higher in fall than in the other seasons. TC and OTC present in different water sources posed a moderate risk. SDZ present in surface water posed a higher ecological risk than that present in tap water and ground water. Meanwhile, the presence of DOC in tap water and the low risk caused by SDM in surface waters should be emphasized. [ABSTRACT FROM AUTHOR]

Priority polycyclic aromatic hydrocarbons (PAHs) and heavy metals (HMs) were investigated in heavy-traffic roadside soils in Ibadan, Nigeria to assess the level of contamination and human health risk. PAHs and HMs were analyzed using gas chromatography-mass spectrometry (GC-MS) and atomic absorption spectroscopy. The concentrations of ∑11PAHs were 263.2 ± 20.9 to 380.0 ± 23.8 µg kg–1, with a dominance of the higher molecular PAHs, and the soils can be classified as weakly contaminated. The most abundant PAH was fluoranthene. Also, five carcinogenic PAH were identified in the study. PAH diagnostic ratios suggested mixed pyrogenic and petrogenic sources. Roadside soil concentrations (mg kg−1) of Cd, Ni and Pb were 1.3 ± 1.2–5.3 ± 7.4, 15.0 ± 7.3–24.5 ± 4.8 and 41.6 ± 13.7–56.8 ± 8.3, respectively. Pollution indices revealed roadside soils were highly contaminated with Cd and Pb according to contamination factor and geoaccumulation index. Cd presented a considerable to high ecological risk. Health risk assessment for children and adults revealed soil ingestion was the main exposure pathway to metals. The hazard quotient (HQ) and health index (HI) were within the safe level (<1.0), although, HI values were higher for children. The cancer risk of exposure to Pb in roadside soils (1.18 E–06 to 1.61 E–06) was within safe limit (1.0 E–04 to 1.0 E–06). This study provides the basis for the reduction of anthropogenic emissions of PAHs and HMs. [ABSTRACT FROM AUTHOR]

Despite the numerous sensory, organoleptic and nutritional qualities, fish meat may also contain some toxic compounds with negative effects on human health. Polycyclic aromatic hydrocarbons (PAHs) are a class of chemicals resulting from incomplete combustion, found at high levels in thermally processed foods, especially in smoked fish. This research studied the influence of wood type (beech, plum and oak) and fish species (rainbow trout, carp and Siberian sturgeon) on PAH contamination in hot smoked fish. Benzo(a)Piren, Σ4PAHs and Σ15PAHs were considered as main indicators of PAH contamination. All-PAHs was quantified in all samples, indicating a specific dynamic of values due to the influence of variables. Generally, BaP (benzo(a)pyrene) content in the samples ranged from 0.11 µg/kg to 8.63 µg/kg, Σ4PAHs from 0.70 µg/kg to 45.24 µg/kg and Σ15PAHs from 17.54 µg/kg to 450.47 µg/kg. Thus, plum wood promoted the highest levels of PAHs, followed by oak and beech. Carp and Siberian sturgeon presented the highest concentrations of PAHs. Some of these parameters had levels that exceeded the limits allowed by legislation via Commission Regulation (EU) No 835/2011. Results revealed BaP levels > 2 µg/kg when plum wood was used in rainbow trout (4.04 µg/kg), carp (4.47 µg/kg) and Siberian sturgeon (8.63 µg/kg). Moreover, the same trend was found for Σ4PAHs, which exceeded 12 µg/kg in rainbow trout (17.57 µg/kg), carp (45.24 µg/kg) and Siberian sturgeon (44.97 µg/kg). [ABSTRACT FROM AUTHOR]

An in-depth understanding of nitrate-contaminated surface water and groundwater quality and associated risks is important for groundwater management. Hydrochemical characteristics and driving forces of groundwater quality and non-carcinogenic risks of nitrate were revealed by the integrated approaches of self-organizing map analysis, spatial visualization by geography information system, entropy and irrigation water quality indices, and human health risk model. Groundwater samples were categorized into two clusters by SOM analysis. Cluster I including three samples were Ca-SO4 type and cluster II of remaining 136 samples were Ca-HCO3 type. Hydrochemical compositions of two cluster samples were dominated by water–rock interaction: (1) calcite and gypsum dissolution for cluster I samples and (2) calcite dissolution, silicate weathering, and positive cation exchange for cluster II samples. Nitrate contamination occurred in both cluster I and II samples, primarily induced by agricultural nitrogen fertilizer. The EWQI results showed that 90.97% in total groundwater samples were suitable for drinking purpose, while the IWQI results demonstrated that 65.03% in total groundwater samples were appropriate for irrigation purpose. The HHR model and Monte Carlo simulation indicated that the non-carcinogenic nitrated risk was highest in children. Exposure frequency was the most sensitive factor (86.33% in total) influencing the total non-carcinogenic risk, indicated by sensitivity analysis. Compared with the two clusters of groundwater, surface water has a shorter circulation cycle and lower ion concentrations resulting in better water quality. This study can provide scientific basis for groundwater quality evaluation in other parts of the world. [ABSTRACT FROM AUTHOR]

Sewage irrigation solves rural water problems, pollutants in wastewater are retained in agricultural soils and enter the human body through crops, jeopardizing human health. Here, contamination features, source apportionments, and associated health risks from agricultural soils were systematically investigated in the Dongdagou Watershed. According to descriptive statistics and heavy metal evaluation, Dongdagou Watershed were mainly polluted by Cd, Cu, Pb, Zn, and As, to different degrees. Health risk assessment results showed that the total hazard indices (THI) for preschool children were 3.20–4.11 and the total carcinogenic risks (TCR) were 9.09 × 10–5 to 1.38 × 10–4. Monte Carlo simulation showed that THI values of 83.16–92.87% of children were > 1 and TCR values of 4.36–13.69% of children exceeded 10–4, indicating the HI risk to preschool children is unacceptable, and the carcinogenic risk could not be ignored. Positive matrix factorization analysis showed that Cd, Zn, and Cu in the soil are primarily from industrial activity, such as sewage irrigation (75.6%); Pb is primarily from atmospheric deposition; and Mn, Ni, and Hg are mainly derived from natural historical pollution sources. The source-oriented health risk assessment showed that sewage irrigation was the most important anthropogenic health risk source for children. [ABSTRACT FROM AUTHOR]

Soil is a component of the environment. An environmental policy should identify the sources of trace metals in the soil and their effects on people and living beings. The concentrations of 29 surface soil samples (0–25 cm) were determined using the methods EPA 3050B. The data were analyzed using simple and robust statistical analysis that allowed for determining geochemical baseline values. Principal component and correlation analyses were performed, which, together with a spatial analysis, allowed us to distinguish between geogenic and anthropogenic sources. The degree of soil contamination was evaluated using different ecological indices, and the health risks to children and adults were calculated using formulas proposed by the United States Environmental Protection Agency (USEPA). The median concentrations of the analyzed elements correspond to Al 17,666 (mg/kg), As 8.7 (mg/kg), Ba 61.4 (mg/kg), Cd 0.17 (mg/kg), Cr 11.3 (mg/kg), Cu 20.5 (mg/kg), Fe 25,953 (mg/kg), Hg 0.06 (mg/kg), Mn 499 (mg/kg), Ni 20.8 (mg/kg), Pb 15.9 (mg/kg), and Zn 60.6 (mg/kg). In the principal component analysis, four factors were identified that explain 70.3% of the variability of the elements, which, together with the correlation analysis, suggest that the origin of the elements is mainly geogenic with some possible anthropic contributions. The elements analyzed in the soil with moderate contamination correspond to As, Cd, and Pb, in addition, As is the only element that indicated a value above the limit for carcinogenic risk in children. The estimated geochemical baseline values correspond to Al 34,734 (mg/kg), As 15.3 (mg/kg), Ba 113 (mg/kg), Cd 0.41 (mg/kg), Cr 33.8 (mg/kg), Cu 42.9 (mg/kg), Fe 46,181 (mg/kg), Hg 0.12 (mg/kg), Mn 1015 (mg/kg), Ni 42.2 (mg/kg), Pb 21.6 (mg/kg), and Zn 121 (mg/kg). 89.7% of the total samples are at a low level of contamination. The carcinogenic risk due to As in children represents 3.4% of the total samples, so it is considered insignificant. [ABSTRACT FROM AUTHOR]

TheOmo River passes through Omorate town, where domestic, municipal, and industrial waste from the town and its vicinities, including agrochemicals, flows into the river. Hence, this research aims to assess heavy metal contamination levels and associated risks in the Lower Omo River, located in the semiarid region of Southern Africa. The mean concentrations of the detected heavy metals in the river water were 0.439mg/L for (Mn), 0.1 (Zn), 0.168 (Cu), 0.393 (Cr), 0.318 (Pb), 0.007 (Ni), 8.926 (Fe), and0.06 (Co). The order for the mean concentrations of the heavy metals in the water was Fe >Mn > Cr > Pb > Cu > Zn > Cu > Co > Ni. The mean levels of lead (Pb), manganese (Mn), and chromium (Cr) were above the acceptable limits for water set by WHO. The HPI value indicates that all water sample sites were heavily polluted. The HQs through oral ingestion and dermal for both children and adults were in the order of Cr >Pb> Mn > Fe >Cu > Co > Ni > Zn. The HQ value greater than 1 was examined for Cr, Pb, and Mn both in children and adults through ingestion and dermal route from the River water. The CRs for both children and adults via ingestion of the River water followed the order Cr > Pb. According to CRI value, the River water could be classified as very high environmental risk. [ABSTRACT FROM AUTHOR]

Mercury cycling in coastal metropolitan areas on the west coast of India becomes complex due to the combined effects of both intensive domestic anthropogenic emissions and marine air masses. The present study is based on yearlong data of continuous measurements of gaseous elemental mercury (GEM) concentration concurrent with meteorological parameters and some air pollutants at a coastal urban site in Mumbai, on the west coast of India, for the first time. The concentration of GEM was found in a range between 2.2 and 12.3 ng/m3, with a mean of 3.1 ± 1.1 ng/m3, which was significantly higher than the continental background values in the Northern Hemisphere (~ 1.5 ng/m3). Unlike particulates, GEM starts increasing post-winter to peak during the monsoon and decrease towards winter. July had the highest concentration of GEM followed by October, and a minimum in January. GEM exhibited a distinct diurnal cycle, mainly with a broad peak in the early morning, a narrow one by nightfall, and a minimum in the afternoon. The peaks and their timing suggest the origin of urban mobility and the start of local activities. A positive correlation between SO2, PM2.5, temperature, relative humidity, and GEM indicates that emissions from local industrial plants in the Mumbai coastal area. Principal component analysis (PCA) and cluster analysis (CA) confirm this fact. Monthly back trajectory analysis showed that air mass flows are predominantly from the Arabian Sea and local human activities. Assessment of human health risks by USEPA model reveals that the hazardous quotient, HQ < 1, implies negligible carcinogenic risk. GEM observations in Mumbai during the study period are below the World Health Organization's (WHO) safe limit (200 ng/m3) for long-term inhalation. [ABSTRACT FROM AUTHOR]

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Although fish are rich sources of various trace metals in their bodies, when these metals exceed health safety limits, it becomes a global concern. Fish exposed to trace metal pollution in their aquatic ecosystems can lead to bioaccumulation and transfer to consumers. Monitoring trace metal contamination of fish food is crucial because they can reach humans through the aquatic food chain, resulting in health problems. Therefore, a first attempt was made for the analysis of trace metals in two cyprinid fish species, namely Cyprinus carpio (Common carp) and Tor soro (Mahseer), which were abundantly found in Khanozai Dam and assessing their potential health impacts when consumed by humans. A total of 200 fish specimens were collected from this area. These specimens were divided equally between the two carp species, with 100 individuals from each species. The fish specimens were collected over 12 months, from June 2020 to May 2021 to determine the concentration of some trace metals, i.e. Manganese (Mn), Calcium (Ca), Iron (Fe), Potassium (K), and Zinc (Zn), Sodium (Na), Phosphorus (P), Magnesium (Mg), and Chlorine (Cl) using a Flame Atomic Absorption Spectrophotometer with a multi-element hollow cathode lamp. The obtained results from the trace metal analysis of Cyprinus carpio and Tor soro in this study revealed that both calcium and phosphorus were present in higher concentrations. However, iron, manganese, and zinc were not detected in both species. Additionally, magnesium was also not detected in C. carpio. For Cyprinus carpio, the arrangement was Ca > P > K > Na > Cl, while for Tor soro, it was Ca > P > Na > K > Cl > Mg in decreasing order. The health risks associated with fish consumption were assessed using factors like estimated daily intake (EDI), Target Hazard Quotient (THQ), and Total Target Hazard Quotient (TTHQ). The THQ values for all analyzed trace metals in both carp species exceeded the maximum value of 1.0, except for Cl in Tor soro. This suggests the potential for various health-related diseases in regular consumers due to their elevated levels. In both species, the TTHQ factor also surpassed the standard value of 1.0, indicating an acute health risk for humans. Although EDI values did not surpass the recommended daily allowance (RDA), continuous consumption of these contaminated fish from this area could lead to severe health complications. Therefore, these results strongly indicated that the elevated levels of trace metals found in the highly abundant cyprinid species of Khanozai Dam could pose serious health-related issues for the local inhabitants. [ABSTRACT FROM AUTHOR]

Objectives: The present study was to evaluate the bioaccumulation of heavy metals and possible human health risk from contaminated seafood resources from the Cochin Estuarine System, Southwest coast of India. Methods: Water, sediment, fish, and shellfish samples were collected from the Cochin Estuarine System during the monsoon and non-monsoon period and were analyzed for heavy metals. Human health risk from contaminated fishes was analyzed using deterministic and probabilistic risk assessment methods. Results: Water, sediment, and biota exhibited elevated concentrations of heavy metals during non-monsoon periods. Zinc was the most abundant metal, while cadmium had the lowest concentration among the three mediums. The presence of cadmium in the estuary posed a moderate to very high ecological risk. Zinc, cadmium, and chromium exceeded the toxicity threshold outlined in the sediment quality guidelines. All metals except cadmium showed significant variation between species and season (p < 0.05). Chromium and zinc correlated positively with fish size, while Cu, Cd, Mn, and Ni showed a negative correlation (p < 0.05). Chromium had the highest accumulation in herbivores, and Cd was highest in filter feeders. Cadmium and lead exceeded the standards of the Food Safety and Standards Authority of India and the Food and Agriculture Organization. The estimated daily intake and target hazard quotient of individual metals were found to be very low. In the Monte Carlo simulation, the 95th percentile of the hazard index (0.80) indicates that consumers are close to experiencing non-carcinogenic health risks. The cancer risk for cadmium (2.15E−3) and chromium (3.90E−4) suggests that consumers may be vulnerable to long-term risk. Cadmium was found to be the most influencing metal in the risk analysis. Conclusion: The results indicate the need for regular monitoring and risk assessment of heavy metals, especially lead, cadmium, and chromium, in seafood resources across coastal areas to ensure food security. [ABSTRACT FROM AUTHOR]

Food contamination by heavy metals is a concerning issue worldwide. The presence of elevated levels of heavy metals in commonly consumed rice has emerged as a critical issue in ensuring food safety. This research encompassed the collection of 44 rice samples, representing seven distinct varieties, through a randomized sampling approach across various retail markets within Dhaka city. The investigation of heavy metal content (including Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Cd, Hg, and Pb) within the rice samples was carried out employing Inductively Coupled Plasma Mass Spectrometry (ICP-MS). The findings disclosed substantial disparities in heavy metal concentrations among the different rice varieties. Notably, the concentrations of Cr (0.99 mg/kg), Fe (8.35 mg/kg), Pb (0.49 mg/kg), and Co (0.02 mg/kg) were observed to exceed the established maximum permissible limits. This contamination of the rice varieties may stem from either natural processes or human activities. Utilizing these metal concentrations, this study employed Monte-Carlo simulation to calculate health risk and probabilistic health risk. The Target Hazard Quotients (THQs) for Cr, Fe, and As exceeded the threshold of 1 in each rice variety, particularly in Amon and Lal Biroi in Mymensingh, Najirshail in Bogra, 28 in Sherpur and Kushtia, Miniket in Bogra and Rajshahi, and lastly, paijam in Rangpur and Tangail. Furthermore, the Hazard Index (HI) exceeded 1 in all rice varieties, implying that the consumption of these selected rice grains may have a substantial impact on overall food quality and its potential health consequences. Both carcinogenic risk and probabilistic risk for As, Ni, Cd, Cr, and Pb were found to surpass the threshold levels and safe limits, respectively. This suggests that individuals who have regularly consumed these rice varieties may face a heightened probability of developing cancer in the future, as predicted. According to sensitivity analysis, metal concentration and food ingestion rate (FIR) are the most relevant components that contribute to the significant impact of carcinogenic health hazards. Finally, the study concluded that heavy metal intake from food poses a risk to human health, necessitating the effective monitoring based on each geographic location and identify the source of this heavy metal to limit its exposure.

Antibiotics residues even low concentrations increases human health risk and ecological risk. The current study was conducted with the aims of meta-analysis concentrations of antibiotics in river water including amoxicillin (AMX), tetracyclines (TCN), sulfamethoxazole (SMX), ciprofloxacin (CIP), trimethoprim (TMP), azithromycin (AZM) and amoxicillin (AMX) and estimates human health and ecological risks. Search was performed in databases including Scopus, PubMed, Web of Science, Embase, Science direct, Cochrane, Science Direct, Google Scholar were used to retrieve scientific papers from January 1, 2004 to June 15, 2024. The concentration of antibiotics residues was meta-analyzed using random effects model in water river water based on type of antibiotics subgroups. Human health risk assessment from ingestion and dermal contact routs was estimated using target hazard quotient (THQ), total target hazard quotient (TTHQ), carcinogenic (CR) and ecological hazard quotient (EHQ) of antibiotics in river water was estimated using monte carlo simulations (MCS) model. Sixty-two papers on antibiotics in river water with 272 data-reports (n = 28,522) were included. The rank order of antibiotics residues in river water based on pooled concentration was SMX (66.086 ng/L) > CIP (26.005 ng/L) > TCN (17.888 ng/L) > TMP (6.591 ng/L) > AZM (2.077 ng/L) > AMX (0.029 ng/L). The overall pooled concentration of antibiotics residues in river water was 24.262 ng/L, 95 %CI (23.110–25.413 ng/L). TTHQ for adults and children due to antibiotics in water was 2.41E-3 and 2.36E-3, respectively. The sort of antibiotics based on their quota in TTHQ for adults and children was AMX > CIP > TMP > AZM > TCN > SMX. Total CR in adults and children was 2.41E-03 and 2.36E-03, respectively. The sort of antibiotics based on percentile 95 % EHQ was SMX (7.70E+03) > TCN (7.63E+01) > TMP (7.03E-03) > CIP (2.86E-03) > AMX (5.71E-04) and TEHQ values due to antibiotics in river water in China was equal to 7.78E+03. Current study suggests that conduct effective monitoring and water quality control plans to reduce concentration of antibiotics especially SMX, TCN, and CIP in river water of China.

Assessing and predicting quality of groundwater is crucial in managing groundwater availability effectively. In the current study, groundwater quality was thoroughly appraised using various indexing methods, including the drinking water quality index (DWQI), pollution index of heavy metals (HPI), pollution index (PI), metal index (MI), degree of contamination (Cd), and risk indicators, like hazard quotient (HQ) and total hazard indicator (HI). The assessments were augmented through multivariate analytical techniques, models based on recurrent neural networks (RNNs), and integration of geographic information system (GIS) technology. The analysis measured physicochemical parameters across 48 groundwater wells from El-Menoufia region, revealing distinct water types influenced by ion exchange, rock-water interactions, and silicate weathering. Notably, the groundwater showed elevated levels of certain metals, particularly manganese (Mn) and lead (Pb), exceeding the drinking water limits. The DWQI deemed the bulk of the tested samples suitable for consumption, assigning them to the ''good'' category, whereas a small number were considered inferior quality. The HPI, MI, and Cd indices indicated significant pollution in the central study region. The PI revealed that Pb, Mn, and Fe were significant contributors to water pollution, falling between classes IV (strongly affected) and V (seriously affected). HQ and HI analyses identified the central area of the study as particularly prone to metal contamination, signifying a high risk to children via oral and dermal routes and to adults through oral exposure alone (non-carcinogenic risk). The adults had no health risks due to dermal contact. Finally, the RNN simulation model effectively predicted the health and water quality indices in training and testing series. For instance, the RNN model excelled in predicting the DWQI, with three key parameters being crucial. The model demonstrated an excellent fit on the training set, achieving an R2 of 1.00 with a very low root mean of squared error (RMSE) of 0.01. However, on the testing set, the model's performance slightly decreased, showing an R2 of 0.96 and an RMSE of 2.73. Regarding HPI, the RNN model performed exceptionally well as the primary predictor, with R2 values of 1.00 (RMSE = 0.01) and 0.93 (RMSE = 27.35) for the training and testing sets, respectively. This study provides a unique perspective for improving the integration of various techniques to gain a more comprehensive understanding of groundwater quality and its associated health risks, with a strong focus on feature selection strategies to enhance model accuracy and interpretability.

The accumulation of toxic elements from sediments poses imminent threats to both the environment and humans. The variation of elements in different sedimentary systems within the same watershed is of significant importance for distinguishing the human activities and adopting relevant management strategies. Based on the surface sediment samples from the Lake Keluke and its wetland, the content and grain size of elements were analyzed. The human health risk indicated in the area the potentially toxic elements (PTEs: Cr, Cu, Zn, Cd and Pb) were at no non-carcinogenic risk to adults or children. Except for Cd, the pollution levels of other PTEs were clean, and potential ecological risk with a low level. However, the pollution of Cd implicated a moderate to heavy pollution intensity and a high ecological risk. According to principal component analysis (PCA), and self-organizing maps (SOM), the main sources of PTEs were of the weathering and leaching of bedrocks; transportation and human agriculture activities. The watershed should reduce pollution caused by human activities and implement efficient agricultural practices.

Introduction: The concentrations and risks of metals (Cd, Pb, Cr, Ni, Cu, Co, Mn, Zn and Fe) in organs of sheep from Southern Nigeria were investigated in this study. Methodology: A total of 105 sheep organs (kidney, liver and muscles) were collected from abattoirs in five widely distributed areas (Asaba, Benin, Onitsha, Sapele and Warri) in southern Nigeria. The organs were digested using a mixture of nitric and perchloric acids and thereafter the metal concentrations in the digested sample solutions were determined using an atomic absorption spectrophotometer. Results: The mean concentrations of metals (mg kg−1) were as follows: Cd: 0.05–0.37, Pb 0.86 to 1.99, Cr: 2.20–3.03, Ni: 1.87–3.54, Cu: 17.4–24.3, Co: 1.45–4.30, Mn 192–410, Zn: 41.8–117 and Fe: 423–1068. The concentrations of the metals in the organs were in the order of Fe > Mn > Zn > Cu > Ni > Cr > Co > Pb > Cd while the ability of the sheep organs to accumulate the studied metals followed the order of liver > kidney > muscles. The estimated daily intake values suggested that except for Mn, the intake of metals from the ingestion of these sheep organs was below their respective PTDI. The hazard index and total cancer risk values show that there are no possible risks of non-cancer and cancer risks associated with the consumption of the sheep's organs. Conclusion: Although there are no health risks associated with the metals in the sheep organs from southern Nigeria, there is, however, a need for continuous monitoring of contaminants in sheep and other animal organs.

Xanthates, derivatives of xanthic acid, are widely utilized across industries such as agrochemicals, rubber processing, pharmaceuticals, metallurgical, paper and mining to help separate metals from ore. Despite their prevalent use, many registered xanthates lack comprehensive information on potential risks to human health and the environment. The mining sector, a significant consumer of xanthates, drives demand. However, emissions into the environment remain poorly understood, especially concerning water quality. A recent EU parliamentary voting on water legislation highlights the urgency to address water pollution and the potential toxicity of xanthates. While limited data exist on xanthate presence in the environment, existing studies indicate their toxicity and contribution to environmental pollution, primarily due to carbon disulfide, a decomposition product. Concerns are mounting over the release of xanthates and carbon disulfide, particularly in mining areas near populated regions and river tributaries, raising questions about downstream impacts and public health risks. Proposed expansions of xanthate-reliant mining activities in Europe, heighten concerns about emissions and water quality impacts. Current databases lack xanthate-related monitoring data, hindering environmental and health risk assessments. Addressing this gap requires water sampling and chemical analysis and investigations into the use, occurrence, and potential impacts of xanthates from industrial activities on water bodies, including those used for drinking water production is imperative.

Excessive heavy metal concentrations in water can pose a threat to human health. The research analyzed 160 groundwater samples used for hygiene and sanitation, of which 62 were used for consumption, and 98 other types of drinking water were analyzed. The research findings indicate that 6% of groundwater for hygiene and sanitation and 13% of drinking water (7.8% groundwater, 5.2% refill water) were deemed unfit for use due to elevated concentrations of certain heavy metals surpassing the maximum limits. As, Cd, Co, Hg, Mn, and Pb were detected in several drinking water samples deemed unsuitable for consumption. Several heavy metals suspected to originate from natural sources are Co, Fe, Mn, As, and Zn, while Pb, Cd, Hg, and Co are suspected to have anthropogenic sources. Only arsenic exposure through the ingestion pathway posed a non-carcinogenic health risk to the local population. Children were found to be more susceptible than adult males and females. The estimated average non-carcinogenic risk levels based on the water sources were refill water > well water > rainwater > spring water. Therefore, it is essential to monitor raw water sources at refill water depots in the study area and implement policies related to the quality of raw water sources, technology maintenance processes, and the quality of processed water from refill water depots. Additionally, the community should be educated about household-scale water treatment to minimize health risks and consider using untreated well water and rainwater for consumption.

Microplastics (MPs) pollution and its associated toxicity raising concerns among scientists as a result of their toxicological impacts on human health and the ecosystem. This study aims to investigate the microplastics and heavy metals (HMs) contamination in seventeen freshwater fish species collected from the Southwestern region of Bangladesh. Microplastics extracted from these species using the hydrogen peroxide digestion method and characterized by Attenuated Total Reflection- Fourier Transform Infrared Spectroscopy (ATR-FTIR). Atomic Absorption Spectrometry (AAS) was used to determine the concentration of HMs in different species for evaluating human health risks. A total of 142 microplastic particles were extracted with an average concentration of 1.13 ± 0.84 items per individual of fish, where the highest microplastics were found in C. punctata (3.43 ± 3.15 items) and lowest in A. mola (0.14 ± 0.38 items). Identified microplastics were dominated by Cu (0.01–1.14; 0.50 ± 0.44) > Pb (0.04–0.58; 0.22 ± 0.12) > Cd (0.00–0.11; 0.03 ± 0.03), respectively. Heavy metals-based human health risk assessment results show that there are no major non-carcinogenic health risks (THI

A new type of bio-composite material is being produced from water-recovered resources such as cellulose fibres from wastewater, calcite from the drinking water softening process, and grass and reed from waterboard sites. These raw materials may be contaminated with pathogens and chemicals such as Escherichia coli, heavy metals, and resin compounds. A novel risk assessment framework is proposed here, addressing human health risks during the production of new bio-composite materials. The developed framework consists of a combination of existing risk assessment methods and is based on three main steps: hazard identification, qualitative risk mapping, and quantitative risk assessment. The HAZOP and Event Tree Analysis methodologies were used for hazard identification and risk mapping stages. Then, human health risks were quantitatively assessed using quantitative chemical risk assessment, evaluating cancer and non-cancer risk, and quantitative microbial risk assessment. The deterministic and the stochastic approaches were performed for this purpose. The contamination of raw materials may pose human health concerns, resulting in cancer risk above the threshold. Microbial risk is also above the safety threshold. Additional analysis would be significant as future research to better assess the microbial risk in biocomposite production. The framework has been effectively used for chemical and microbial risk assessment. HIGHLIGHTS Production of new water resource recovery-based bio-composite materials.; The safety of these materials, from production and application perspectives, needs to be assessed.; Novel risk assessment framework focusing on human health risk assessment.; Hazard identification, qualitative risk mapping, and quantitative risk assessment: QCRA and QMRA.; Future research directions to improve the developed framework.;

ABSTRACTThe current study evaluated the contamination level of potentially toxic elements (PTEs) and their associated risk in street dust in the vicinity of Mahd Ad Dhahab gold mine, KSA. 25 street dust samples were collected and then subjected to magnetic susceptibility (χ) measurements and analysed for Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mg, Mn, Pb and Zn contents. The results revealed that the study area is contaminated by Cd, Zn, Hg, Cu, Pb and As, since their concentrations were higher than the background and displayed high values of coefficient of variation (41.86, 14.9, 11.05, 10.1, 8 and 5.3, respectively) combined with high enrichment factor (181.7, 167.5, 183.6, 122.8, 151.7 and 33.95, respectively). The higher concentrations of these elements, associated with higher χ values, were recorded close to the mining area. The correlation coefficient and heatmap categorized the studied PTEs into two groups; The first group comprised Al, Co, Cr, Fe, Mg and Mn of geogenic origin; the second included As, Cd, Cu, Hg, Pb and Zn, along with χ, which controlled by anthropogenic sources. Ecological risk assessment values indicated that 28% of the samples have very strong ecological risk. Regarding human health risk, among different pathways, ingestion is a primary pathway of PTEs harming human health. The non-carcinogenic risks from Cd, Cu and Pb and carcinogenic risk from As exceeded the acceptable level to local children. The study demonstrated that mining activities are the main source of street dust contamination in the area.

The adverse effects of antimony (Sb) pollution on ecosystems and human health caused by its use, enrichment, and bioaccumulation have become global environmental problems, particularly in China. Based on a scientometric analysis of the research topics and evolution of Sb pollution, 210 peer-reviewed articles across 264 locations in China were selected to analyze Sb concentrations, changes, and risks in different environments (i.e., soil, sediment, and water). Substantially elevated concentrations were reported in the chosen environments throughout the studied literature, with approximately 36.6%, 41.3% and 20.8% of the soil, water and sediment sampling sites, respectively, exceeding the national and international guidelines. Although Sb concentrations were stable in water and sediment, those in soil slightly increased slightly over the past two decades. The majority of studies and the highest Sb concentrations were typically concentrated in Hunan, Guangxi, and Guizhou, where most Sb deposits and intensive mining and smelting activities are concentrated. A temporal analysis over three crucial periods of the Sb industry further indicated that Sb concentrations and pollution had increased in several provinces in recent years. The estimated risk quotient, using Monte Carlo simulations, indicated that species were markedly affected by Sb contamination, with 21.6% of events occurring in the high-risk category. The ingestion of contaminated soils posed the highest potential health risk to the population, with 47.9% of the events indicated to represent at least a low risk. Risks of water ingestion were estimated to exist in 4.9% of the simulated exposure events. More environmental campaigns for Sb pollution control are urgently needed, especially in Sb hotspots, to reduce environmental pressure and avoid direct and indirect hazards to organisms and populations. [ABSTRACT FROM AUTHOR]

The production of oil and natural gas has recently played a significant role in boosting the economy. In this process, the discharge of industrial waste through activities like exploration and extraction operations cause elevated levels of dissolved chemicals, which severely degrade water sources and render them unsafe for human consumption. The aim of the present study was to evaluate the distribution of nineteen physicochemical parameters including heavy metals (pH, EC, TDS, TH, As, Cr, Cu, Ni, Pb, Zn, Ca2+, Mg2+, Na+, K+, Cl−, F−, SO42−, NO3− and HCO3−) in groundwater samples collected around oil and natural gas drilling sites and assess the knowledge gap for a sustainable and safe environment. Groundwater quality was assessed using various hydrogeochemical parameters and pollution indices such as the geoaccumulation index (Igeo), enrichment factor (EF), contamination factor (CF), degree of contamination (Cdeg) with principal component (PCA) and regression coefficient analysis to identify the collective contamination source. The potential ecological risk indices (PERI) and health risk assessments were made using exposure factors references from USEPA's database. The major findings indicated the Piper diagram is predominantly characterised by the Ca–Cl type whereas, Gibb's plot showed evaporation and rock–water interaction influencing groundwater chemistry. Water quality index (WQI) results indicated 2% of samples were excellent, 22% were good, 20% were poor, 8% were extremely poor, and 48% were unsuitable for drinking. The pollution index of groundwater (PIG) showed that 50% of samples from the study area were unsafe to drink. The human health risk assessment revealed significant noncarcinogenic and carcinogenic effects to both adults and children. The study area's geology indicates that the presence of elements in groundwater is primarily due to drilling activities, as no geological formations show high concentrations. The implications of this study highlighted the current status of groundwater quality by identifying the main pollutants arising due to drilling extraction methods and developing a strategy aimed at mitigating both point and non-point sources of contamination. [ABSTRACT FROM AUTHOR]

The quality of freshwater sources is a key factor in sustainable development. This study investigated the water quality suitability of Ossiomo River for human consumption and the implications for public health. Water samples were collected and analysed from October 2021 to March 2022. Results indicated that the water physico-chemical parameters from sampled locations were within their respective National Environmental Standards and Regulation Enforcement Agency (NESRA) permissible limits except for pH (< 6.5), dissolved oxygen (< 6.0mg L−1), cadmium (> 0.005m /L−1), manganese (> 0.05mg L−1) and total hydrocarbon content (>10mg L−1). Comprehensive pollution index (0.4–1.0) and water quality index (251.57–765.37) values indicate that the water body was slightly polluted and unsuitable for human consumption (WQI > 50). Health risk assessment showed that children and adults were predisposed to non-carcinogenic risk (HIoral > 1) and carcinogenic risk (ICR: 1.21E-02 and 2.84E-03) from heavy metals through oral exposure. Natural run-off and anthropogenic activities were identified sources of heavy metals and hydrocarbons within the catchment. The study has provided data for water resource quality monitoring and raised concerns as to the need for immediate action to safeguard the public health of communities surrounding the Ossiomo River, through the provision of alternative sources of potable water. [ABSTRACT FROM AUTHOR]

Plastic waste pollution is one of the biggest problems in the world today. The amount of plastic in the environment continues to increase, and human exposure to microplastic (MP) has become a reality. This subject has attracted the attention of the whole world. The MP problem has also been noticed by the scientific community. The term microplastic is mostly used to define synthetic material with a high polymer content that can have a size range from 0.1 to 5000 µm. This paper aims to characterize the routes of exposure to MP, define its pollution sources, and identify food types contaminated with plastics. This review addresses the current state of knowledge on this type of particles, with particular emphasis on their influence on human health. Adverse effects of MP depend on routes and sources of exposure. The most common route of exposure is believed to be the gastrointestinal tract. Sources of MP include fish, shellfish, water as well as tea, beer, wine, energy drinks, soft drinks, milk, salt, sugar, honey, poultry meat, fruits, and vegetables. Studies have shown that particles of PET, PE, PP, PS, PVC, PA, and PC are the most frequently found in food. [ABSTRACT FROM AUTHOR]

Nitrate pollution in aquatic ecosystems has received growing concern, particularly in fragile karst basins. In this study, hydrochemical compositions, multiple stable isotopes (δ2H–H2O, δ18Ο–Η2Ο, δ15Ν–ΝΟ3−, and δ18Ο–ΝΟ3−), and Bayesian stable isotope mixing model (MixSIAR) were applied to elucidate nitrate pollution sources in groundwater of the Yangzhuang Basin. The Durov diagram identified the dominant groundwater chemical face as Ca–HCO3 type. The NO3− concentration ranged from 10.89 to 90.45 mg/L (average 47.34 mg/L), showing an increasing trend from the upstream forest and grassland to the downstream agricultural dominant area. It is worth noting that 47.2% of groundwater samples exceeded the NO3− threshold value of 50 mg/L for drinking water recommended by the World Health Organization. The relationship between NO3−/Cl− and Cl− ratios suggested that most groundwater samples were located in nitrate mixed endmember from agricultural input, soil organic nitrogen, and manure & sewage. The Self-Organizing Map (SOM) and Pearson correlations analysis further indicated that the application of calcium fertilizer, sodium fertilizer, and livestock and poultry excrement in farmland elevated NO3− level in groundwater. The output results of the MixSIAR model showed that the primary sources of NO3− in groundwater were soil organic nitrogen (55.3%), followed by chemical fertilizers (28.5%), sewage & manure (12.7%), and atmospheric deposition (3.4%). Microbial nitrification was a dominant nitrogen conversion pathway elevating NO3− levels in groundwater, while the denitrification can be neglectable across the study area. The human health risk assessment (HHRA) model identified that about 88.9%, 77.8%, 72.2%, and 50.0% of groundwater samples posing nitrate's non-carcinogenic health hazards (HQ > 1) through oral intake for infants, children, females, and males, respectively. The findings of this study can offer useful biogeochemical information on nitrogen pollution in karst groundwater to support sustainable groundwater management in similar human-affected karst regions. [ABSTRACT FROM AUTHOR]

Microplastics (MPs) are plastic particles between 0.1 and 5000 µm in size that have attracted considerable attention from the scientific community and the general public, as they threaten the environment. Microplastics contribute to various harmful effects, including lipid peroxidation, DNA damage, activation of mitogen-activated protein kinase pathways, cell membrane breakages, mitochondrial dysfunction, lysosomal defects, inflammation, and apoptosis. They affect cells, tissues, organs, and overall health, potentially contributing to conditions like cancer and cardiovascular disease. They pose a significant danger due to their widespread occurrence in food. In recent years, information has emerged indicating that MPs can cause oxidative stress (OS), a known factor in accelerating the aging of organisms. This comprehensive evaluation exposed notable variability in the reported connection between MPs and OS. This work aims to provide a critical review of whether the harmfulness of plastic particles that constitute environmental contaminants may result from OS through a comprehensive analysis of recent research and existing scientific literature, as well as an assessment of the characteristics of MPs causing OS. Additionally, the article covers the analytical methodology used in this field. The conclusions of this review point to the necessity for further research into the effects of MPs on OS. [ABSTRACT FROM AUTHOR]

Water plays an essential role in sustaining life on Earth as an indispensable natural resource. In recent decades, dependence on groundwater for domestic and industrial purposes has become inevitable. The Ranipet industrial environs (RIE) has many tanneries and chemical industries, which affects the groundwater quality. This study assessed groundwater quality and its suitability for domestic, agricultural, and human health risk assessments. 40 groundwater samples (28 open wells and 12 bore wells) were collected during pre-monsoon 2022 and analyzed by employing multivariate statistics, standard scatter plots, irrigation indices, and health risk assessment. The results of hydrogeochemical analysis and multivariate statistics affirmed that electrical conductivity (EC), total dissolved solids (TDS), calcium (Ca2+), and magnesium (Mg2+) have controlled the hydrochemistry of RIE. Cadmium (Cd) at 46% and chromium (Cr) at 33% have contaminated the groundwater in the study area, making it unsuitable for human consumption and irrigation. The agricultural indices analysis results show groundwater quality ranging from very poor to unsuitable making it unsuitable and also affects crop productivity. Hazard index (HI) results infer that Cr and Cd severely contaminated the RIE's groundwater, encompassing 14 villages, making the groundwater unfit for drinking, domestic use, and irrigation. Hazard quotient (HQ) and incremental lifetime cancer risk (ILCR) analysis revealed that 2 in 100 infants and 3 in 1000 people over the age of 63 are likely to develop cancer due to Cr and Cd in the REI. This is a need-of-the-hour problem, addressing this issue with preventive measures to ensure the protection of groundwater sources will lead to achieving the Sustainable Development Goal 6 (Clean Water and Sanitation). [ABSTRACT FROM AUTHOR]