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Self-assembly of colloidal nanocrystals (NCs) into superlattices (SLs) is an appealing strategy to design hierarchically organized materials with promising functionalities. Mechanistic studies are still needed to uncover the design principles for SL self-assembly, but such studies have been difficult to perform due to the fast time and short length scales of NC systems. To address this challenge, we developed an apparatus to directly measure the evolving phases in situ and in real time of an electrostatically stabilized Au NC solution before, during, and after it is quenched to form SLs using small-angle X-ray scattering. By developing a quantitative model, we fit the time-dependent scattering patterns to obtain the phase diagram of the system and the kinetics of the colloidal and SL phases as a function of varying quench conditions. The extracted phase diagram is consistent with particles whose interactions are short in range relative to their diameter. We find the degree of SL order is primarily determined by fast (subsecond) initial nucleation and growth kinetics, while coarsening at later times depends nonmonotonically on the driving force for self-assembly. We validate these results by direct comparison with simulations and use them to suggest dynamic design principles to optimize the crystallinity within a finite time window. The combination of this measurement methodology, quantitative analysis, and simulation should be generalizable to elucidate and better control the microscopic self-assembly pathways of a wide range of bottom-up assembled systems and architectures.

The flange holes on large aluminum ball shells are processed on-site by industrial robots, and the flange holes need to ensure the hole position and axial accuracy requirements at the same time, but it is challenging to ensure that these two indexes meet the requirements at the same time due to the lower machining accuracy of the industrial robots. For this reason, the paper proposes a robot integrated error compensation method for hole position and axial deviation constraints. First, the robot machining path is generated, and the cutting allowance and hole inner wall measurement strategy are determined by running the machining path empty before machining. Integrated error compensation is then introduced and a new hole surface is constructed as a mirror surface under its conditions. The tool path is adjusted according to the mirror compensation principle to ensure consistency between the machined and target holes. The reconstructed target hole surface satisfies the integrated error constraints and realizes the balanced constraints of positional and axial tolerances, making full use of both tolerances. Finally, the method's effectiveness has been verified in a large-scale work. Experimental results show that hole position error is reduced from uncompensated (1.03, − 0.51) mm to compensated (0.25, − 0.005) mm, and axial error from uncompensated 22.32 mm to compensated 1.39 mm. [ABSTRACT FROM AUTHOR]

Soil electrical conductivity has an important influence on the growth and development of plants. The existing real-time soil electrical conductivity detection device is affected by temperature, inconvenient to use, expensive, etc.; therefore, based on the classical four-terminal method of soil electrical conductivity detection principle, in this study, we aim to improve the limitations of the constant current source, selecting the high-performance integrated chip AD5941, optimizing the detection circuit and probe structure, improving the achievability of the detection circuit, and designing a type of in situ on-line real-time access to a soil electrical conductivity detection device, and improve the detection accuracy by temperature compensation. In this paper, dynamic performance, steady state performance, radial sensitivity range, and calibration test are carried out for the soil electrical conductivity detection prototype. The test results show that the dynamic response speed of the prototype is less than 50 ms, the steady state error is not more than ±2%, and the radial measurement sensitivity range is 8~10 cm. A comparison with the commercial sensor shows that the linear fit of the two measurements reaches 0.9995, and the absolute error ranges from −61.40 µS/cm to 23.90 µS/cm, with a relative error range of −1.94~1.86%. It shows that the performance of the two sensors is comparable, but the quality/price ratio of the prototype is much higher than that of the commercialized product. In this study, it is demonstrated that a high-precision, low-cost, and easy-to-use in situ online soil electrical conductivity detection device can be provided for agricultural and forestry production. [ABSTRACT FROM AUTHOR]

Ocean salinity plays an important role in oceanographic research as one of the fundamental parameters. An optical salinometer based on the Michelson interferometer (MI) suitable for in situ measurement in deep-sea environments is proposed in this work, and it features real-time calibration and multichannel multiplexing using the frequency modulated continuous wave (FMCW) technique. The symmetrical sapphire structure used to withstand deep-sea pressure can not only achieve automatic temperature compensation, but also counteract the changes in optical path length under deep-sea pressure. A model formula suitable for optical salinity demodulation is proposed through the nonlinear least squares fitting method. In vertical profile testing, the optical salinometer demonstrated remarkable tracking performance, achieving an error of less than 0.001 psu. The sensor displays a stable salinity demodulation error within ±0.002 psu during a three-month long-term test at a depth of 4000 m. High stability and resolution make this optical salinometer have broad development prospects in ocean observation. [ABSTRACT FROM AUTHOR]

The dynamic load distribution within in-service axlebox bearings of high-speed trains is crucial for the fatigue reliability assessment and forward design of axlebox bearings. This paper presents an in situ measurement of the dynamic load distribution in the four rows of two axlebox bearings on a bogie wheelset of a high-speed train under polygonal wheel–rail excitation. The measurement employed an improved strain-based method to measure the dynamic radial load distribution of roller bearings. The four rows of two axlebox bearings on a wheelset exhibited different ranges of loaded zones and different means of distributed loads. Besides, the mean value and standard deviation of measured roller–raceway contact loads showed non-monotonic variations with the frequency of wheel–rail excitation. The fatigue life of the four bearing rows under polygonal wheel–rail excitation was quantitatively predicted by compiling the measured roller–raceway contact load spectra of the most loaded position and considering the load spectra as input. [ABSTRACT FROM AUTHOR]

Abstract The dynamic load distribution within in-service axlebox bearings of high-speed trains is crucial for the fatigue reliability assessment and forward design of axlebox bearings. This paper presents an in situ measurement of the dynamic load distribution in the four rows of two axlebox bearings on a bogie wheelset of a high-speed train under polygonal wheel–rail excitation. The measurement employed an improved strain-based method to measure the dynamic radial load distribution of roller bearings. The four rows of two axlebox bearings on a wheelset exhibited different ranges of loaded zones and different means of distributed loads. Besides, the mean value and standard deviation of measured roller–raceway contact loads showed non-monotonic variations with the frequency of wheel–rail excitation. The fatigue life of the four bearing rows under polygonal wheel–rail excitation was quantitatively predicted by compiling the measured roller–raceway contact load spectra of the most loaded position and considering the load spectra as input.

Diamond anvil cells have garnered significant attention in high‐pressure studies as a valuable tool for investigating material preparation, phase transition dynamics, and ultra‐high‐pressure physical chemistry. Its potential applications span fields such as materials science, condensed matter physics, chemistry, and geology. This study conducts a comprehensive review of the utilization of laser‐heated diamond anvil cell (LH‐DAC) devices in conjunction with in situ optical characterization techniques, such as X‐Ray and Raman scattering. Further, diverse in situ performance measurement methods encompassing electrical, thermal, magnetic, and acoustic analyses are examined. The development and role of the prevailing in situ measurement techniques have been described, along with the current progress in applied research for each technique. This study aims to facilitate the discovery of new structures and properties of materials under high pressure–temperature conditions. [ABSTRACT FROM AUTHOR]

The insulating performance of double windows. Investigations in the test stand and in practice Box windows are essential components of our architectural heritage and have proven themselves over centuries due to their good sound and thermal insulation properties over a long lifecycle. In the course of thermal improvements of the building envelope, often historical windows are replaced by industrially manufactured constructions. The main argument for this window replacement is the high heat transfer of box windows. However, for these historical windows, measurement results from the actual existing structures are not used; instead, normatively defined default values are employed and compared with the heat transfer of insulated glass systems. These default values are three to four times higher than the laboratory values of industrially manufactured windows. Furthermore, the energy consumption of different window constructions is not evaluated over the entire lifecycle, and ecological aspects such as sustainability and repairability are rarely considered in these calculations. [ABSTRACT FROM AUTHOR]

AbstractWe report the development of a novel fiberoptic laser-induced breakdown spectroscopy (FOLIBS) system for material characterization applications. The system utilizes a 1000-µm optical fiber to transport the laser beam to remote locations for elemental analysis via laser-induced breakdown spectroscopy. Air-fiber interface damage, internal damage, and air breakdown issues during laser-fiber coupling are identified and corresponding solutions are presented. For evaluating the physical properties of the plasma generated by the FOLIBS system, spectroscopic characterization is carried out using a titanium sample. The spectral features collected from a natural uranium sample are also presented. Hence, this rapid, remote, and flexible measurement technique is promising for in situ measurements in hazardous environments in nuclear energy, nuclear safeguards, and nonproliferation applications. [ABSTRACT FROM AUTHOR]

Soil compaction and soil bulk density are key soil properties affecting soil health and soil ecosystem services like crop production, water retention and purification and carbon sequestration. The standard method for soil bulk density measurements using Kopecky rings is very labour intensive, time consuming and leaves notable damage to the field. Accurate data on bulk density are therefore scarce. To enable large‐scale data collection, we tested a new portable gamma ray sensor (RhoC) for in situ field and dry bulk density measurements up to 1 m depth. In this first validation study, measurements with the RhoC‐sensor were compared with classic ring sampling. Measurements were made in two agricultural fields in the Netherlands (a sandy clay loam and a sandy soil), with large variation in subsoil compaction. At 10 locations within each field, three soil density profiles were made. Each profile comprised six depth measurements (every 10 cm from 10 to 60 cm depth) using the RhoC‐sensor and Kopecky rings, resulting in 30 pairwise profiles and 180 measurements in total per field. At an average soil density of 1.5 g/cm3, the relative uncertainty was 9% for the Kopecky rings and 15% for the RhoC‐sensor. Because the RhoC‐sensor is easy and quick to use, the higher relative uncertainty can easily be compensated for by making additional measurements per location. In conclusion, the RhoC‐sensor allows a reliable quantitative in situ assessment of both field and dry bulk density. This provides the much‐needed possibility for rapid and accurate assessment of soil compaction. The acquisition of this data supports the calculation of soil organic carbon stocks and is indispensable for (national) soil monitoring, to assess soil health and to inform sustainable land management practices for sustained or improved soil health and provision of soil ecosystem services, such as requested in the proposed EU Directive on Soil Monitoring and Resilience. [ABSTRACT FROM AUTHOR]

The in situ acoustic measurement of seafloor sediment is an important technical means to obtain the acoustic parameters of seafloor. The time‐of‐flight method is commonly used to calculate the sound speed in seafloor sediment. Accurate identification of signal feature points is essential for determining travel time or travel time difference of acoustic signals. However, the precise identification of feature points, such as the take‐off point of the first wave of a sound wave signal, is challenging. The conventional manual identification method is inefficient and prone to errors. The development of a feature point auto‐identification method is imperative for accurately calculating the travel time of acoustic signals. In this study, we employed the cross‐correlation method, the level threshold method and the short window‐long window energy ratio method to extract the acoustic travel time differences and calculate the sound speeds in seawater and in seafloor sediment. We then analysed the effectiveness of these calculated results. The sound speeds in seawater obtained through the aforementioned methods were compared with the sound speeds measured using a sound velocity profiler. The comparison revealed that these processing methods exhibit a high level of accuracy. The sound speed results in sediments show that the programme‐based auto‐identification methods significantly reduce the standard deviation compared to the manual identification method. This study successfully assessed the processing accuracy of different methods and expanded the processing methods for in situ acoustic signals of seafloor sediments. [ABSTRACT FROM AUTHOR]

This paper presents the results of a mesocosm experiment for the evaluation of remote sensing chlorophyll-a (chl-a) concentration estimations in an anthropogenic water reservoir. The chl-a presence in the water causes changes in the water surface reflectance spectrum, especially in the green and red part, but many factors could affect the remote measurements of chl-a content. The in situ mesocosm method of the experiment was used for investigating the spectral reflectance of the inland water surface in a wide range of chl-a concentrations. Eight specially designed measurement boxes were placed into the water. In half of the boxes, the devices to support the development of the submerged water plant were installed. During the experiment, simultaneously, spectral data from the water surface were gathered and physical–chemical analyses of water were carried out. The obtained results confirm the usefulness of the mesocosm experiment for the remote sensing chl-a concentration algorithms being developed. The concentration of dissolved organic carbon was identified as a key factor that interfered with remote chl-a estimations in the analyzed reservoir. [ABSTRACT FROM AUTHOR]

Biaxially prestressed large concrete structures of the confinement building in nuclear power plants (NPPs) should meet the safety requirement for the extension of the service time. Long‐term delayed strains of concrete are one of the key factors determining the safety factor in these structures. This article presents 30‐year long in situ measurement results of strain evolution of confinement buildings in four different NPPs. The delayed strains are predicted at a material level using the next‐generation Eurocode‐2, and the influence of temperature as proposed by the fib model code 2010, making use of delayed strain characteristics of the corresponding concrete from a previous study. We found that the default law given in Eurocode underestimates the delayed strain. However, with the possibility of adjusting the shrinkage and creep laws, the prediction results fit with a good accuracy for the in situ measurement. [ABSTRACT FROM AUTHOR]

Building materials, such as brick and concrete, are known indoor radon (222Rn) and thoron (220Rn) sources. Most radon and thoron exhalation studies are based on the laboratory testing of pieces and blocks of such materials. To discuss if laboratory findings can be applied to a real-world environment, we conducted intensive in situ exhalation tests on two solid concrete interior walls of an apartment in Japan for over a year. Exhalation rates of radon (JRn) and thoron (JTn) were measured using an accumulation chamber and dedicated monitors, alongside monitoring indoor air temperature (T) and absolute humidity (AHin). There were weak correlations between JRn or JTn and T or AHin at one tested wall, and moderate correlations of JRn and strong correlations of JTn with T or AHin at the other wall, meaning more or less seasonal variations. The findings aligned with previous laboratory experiments on JRn but lacked corresponding data for JTn. Additionally, a moderate or strong correlation between JRn and JTn was observed for both tested walls. Comparison with theoretical calculations revealed a new issue regarding the impact of each process of emanation and migration within concrete pores on radon and thoron exhalation. Overall, this study provides insight into parameterizing radon and thoron source inputs in modeling the spatiotemporal dynamics of indoor radon and thoron. [ABSTRACT FROM AUTHOR]

The super volume changes and severe mechanical degradation have been a hindrance in the wide application of silicon based composite electrodes in commercial lithium-ion batteries (LIBs). Calendering, one procedure in producing LIBs' electrodes, is indispensable to ensure low porosity and energy density. However, the repercussions of the calendering process on the physical characteristics related to the behavior of silicon (Si) based electrodes during the electrochemical reaction have not been well understood. Thus, on account of the deformation characteristic of cantilever electrodes, an in-situ technique is employed to analyze the repercussions of calendering status on the coupled electro-chemo-mechanical performances. During the electrochemical cycling, Young's modulus and diffusion-induced stress in composite electrodes are quantified. The results show that the swelling strain, the stress and the modulus of the Si-based electrode and the calendering degree are positively correlated. Meanwhile, the stress induced by diffusion in the active layer tends to increase in the stage of lithiation and reverses during the delithiation process. Accompany with the SEM analysis, we conclude that the calendering process can induce larger stress, driving the formation of cracks in electrodes. These findings can help understand how the calendering process could affect the capacity dissipating and lifetime of Si based electrodes.

This study was conducted to compare the results of in situ and in vitro methods that can be used for measuring gas exchange parameters in two pine species. The study was carried out in a mixed Pinus nigra Arn. subsp. pallasiana (Lamb). Holmboe and Pinus brutia Ten. plantation in Kemer/Burdur, which has a semi-arid climate type located in the Western Mediterranean Region of Türkiye. In the first method, gas exchange parameters (net photosynthetic rate-Anet, stomatal conductance-gs and transpiration rate-E) were measured directly on the tree using a mobile scaffold to reach to the tree canopy (in situ conditions). In the second method, branches were cut at approximately 50 cm and gas exchange parameters were determined in the same needles after the branch was immediately submerged in water (in vitro conditions). Measurements were taken between June and October 2022. Student’s t-test was conducted to compare the results of in situ and in vitro photosynthesis measurement methods. No statistically significant differences were found between the results of the compared methods in terms of gas exchange parameters for both species. The results of the study showed that in vitro measurements of photosynthesis can be preferred to in situ measurements of photosynthesis in P. nigra and P. brutia under field conditions where access to the canopy of tall trees is not possible.

Abstract The Korean space weather monitor (KSEM) aboard the GEO-KOMPSAT-2A (GK2A) has been continuously measuring energetic particle flux in geostationary orbit at 128.2°E longitude since July 2019. The particle detector (PD) component of KSEM comprises six particle telescopes viewing different directions that provide near-real-time electron flux observations within the energy range of 100 keV to 3.8 MeV. The KSEM PD on the GK2A satellite, together with the MPS-HI on the GOES-16 satellite 156.6° away, can provide valuable simultaneous observations of the asymmetric space environment and contributes to our understanding of this dynamic region. In this study, we present recent energetic electron flux measurements obtained from the KSEM PD and conduct preliminary cross-comparisons with data from the Magnetosphere Particle Sensor–High (MPS-HI) PD, which is part of the SEISS instrument suite onboard GOES-16. The inter-comparisons show that the electron fluxes of the two detectors are in reasonable similarity except for some energy bands under quiet conditions. Additionally, we provide a brief overview of the electron flux responses of both KSEM PD and MPS-HI under enhanced space environment conditions, which shows differences based on sensor characteristics and satellite location. Graphical Abstract

In this study, an in situ measurement method of spin polarization in single‐beam atomic magnetometer is presented. Modeling magnetic linewidth by incorporating nonlinear attenuation along the propagation direction of light and employing the output response equation of magnetometers at zero‐field resonance. Utilizing the model for fitting to extract relaxation rate information, the photon absorption cross‐sections at three temperatures are estimated to be 2.12×10−13$2.12\times 10^{-13}$, 1.85×10−13$1.85\times 10^{-13}$, and 1.64×10−13$1.64\times 10^{-13}$cm2$\mathrm{{c m}^2}$, respectively. Further, the spin polarization curves are obtained by introducing the spin polarization equations. Given the diminishing marginal utility resulting from the enhancement of performance through increased spin polarization, long‐term sensitivity is employed to determine optimal spin polarization range. The optimal long‐term sensitivity for four displayed states is 15.3±5.5$15.3 \pm 5.5$fTHz−1/2$\text{fTHz}^{-1/2}$ (@31.5Hz), while the ultimate minimum sensitivity is 10.7 fTHz−1/2$\text{fTHz}^{-1/2}$ (@31.5Hz). The optimal spin polarization ranges at three temperatures are 78.9%–87.1%, 82.3%–88.5%, and 84.5%–88.4%, respectively. The measurement method applied to single‐beam magnetometer can be easily extended to multi‐axis vector magnetometer. The determination of optimal spin polarization range is of great significance for the performance and stability of the magnetometer system, improving the sensitivity of magnetic field measurement, and ensuring its widespread application in bio‐magnetic measurement. [ABSTRACT FROM AUTHOR]

A new construction of a potentiometric sensor was introduced for the first time. It relies on the use of two membranes instead of one, as in the well-known coated-disc electrode. For this purpose, a new electrode body was constructed, including not one, but two glassy carbon discs covered with an ion-selective membrane. This solution allows for the sensor properties to be enhanced without using additional materials (layers or additives) on the membrane. The new construction is particularly useful for in situ measurements in environmental samples. Two ion-selective polymeric membranes were used, namely H+ and K+-selective membranes, to confirm the universality of the idea. The tests conducted included chronopotentiometric tests, electrochemical impedance spectroscopy, and potentiometric measurements. The electrical and analytical parameters of the sensors were evaluated and compared for all tested electrodes to evaluate the properties of the planar electrode versus previously known constructions. Research has shown that the application of two membranes instead of one allows for the resistance of an electrode to be lowered and for the electrical capacitance to be elevated. Improving the electrical properties of an electrode resulted in the enhancement of its analytical properties. The pH measurement range of the planar electrode is 2–11, which is much wider in contrast to that of the single-membrane electrode. The linear range of the K+-selective planar electrode is wider than that of the coated-disc electrode and equals 10−6 to 10−1 M. The response time turned out to be a few seconds shorter, and the potential drift was smaller due to the application of an additional membrane in the electrode construction. This research creates a new opportunity to design robust potentiometric sensors, as the presented construction is universal and can be used to obtain electrodes selective to various ions. [ABSTRACT FROM AUTHOR]

The acoustic properties of seafloor sediments on continental slopes play a crucial role in underwater acoustic propagation, communication, and detection. To investigate the acoustic characteristics and spatial distribution patterns of sediments on the continental slope, a geoacoustic experiment was conducted in the northwestern South China Sea. The experiment covered two sections: one crossing the shelf and slope in the downslope direction, and the other near the shelf break in the along-slope direction. In situ techniques, sediment sampling, and laboratory measurements were used to acquire data on sediment acoustic properties (such as sound speed and attenuation) and physical properties (including particle composition, density, porosity, and mean grain size). The experimental findings revealed several key points: (1) Acoustic properties of shallow water coarse-grained sediments and deep-sea sediments were higher when measured in the laboratory compared to in situ measurements. (2) Relationships between measured attenuation and physical properties, as well as between sound speed and mean grain size, showed deviations from previous empirical equations. (3) Sediment acoustic and physical properties exhibited significant variations in the downslope direction, while showing gradual variations in the along-slope direction. These variations can be attributed to sedimentary environmental factors such as material sources, hydrodynamic conditions, and water depth. [ABSTRACT FROM AUTHOR]

Building thermal performance testing requires in situ measurement techniques that are well supported and validated by simulation with statistics to improve the accuracy of the results. Local on-site performance of building components is different from the theoretical one, influenced by factors affecting the building's thermal conditions. The current paper reviews the factors influencing the measured U-value results in the heat flux method based on quantitative findings of other studies through regression and correlation statistics. The findings regarding the current status of knowledge are limited to in situ methods without detailed insights of response time, sensitivity analysis, and thermal boundary conditions in the local context. Regression analysis between wall characteristics, time duration, temperature difference, and the measured U-value shows a very strong and statistically significant impact of these variables on the accuracy of the measured U-value of low transmittance walls. The R2 value indicates that three variables can collectively explain 91% of the variance in the measured U-value. There is a linear correlation between the wall characteristics and the measured U-value and a non-linear correlation between the time duration, temperature difference, and the measured U-value. Future work will focus on developing a measurement framework that considers time-dependent variables, dynamic weather, and uncertainty with high accuracy for different boundary conditions. [ABSTRACT FROM AUTHOR]

Knowledge of aerosol radiative effects in the Tibetan Plateau (TP) is limited due to the lack of reliable aerosol optical properties, especially the single scattering albedo (SSA). We firstly reported in situ measurement of SSA in Lhasa using a cavity enhanced albedometer (CEA) at λ = 532 nm from 22nd May to 11th June 2021. Unexpected strong aerosol absorbing ability was observed with an average SSA of 0.69. Based on spectral absorptions measured by Aethalometer (AE33), black carbon (BC) was found to be the dominated absorbing species, accounting for about 83% at λ = 370 nm, followed by primary and secondary brown carbon (BrCpri and BrCsec). The average direct aerosol radiative forcing at the top of atmosphere (DARFTOA) was 2.83 W/m2, indicating aerosol warming effect on the Earth‐atmosphere system. Even though aerosol loading is low, aerosol heating effect plays a significant role on TP warming due to strong absorbing ability. Plain Language Summary: The Tibetan Plateau (TP) has experienced rapid warming over the past decades, but the key factors affecting TP climate change haven't yet been clearly understood. Aerosol single scattering albedo (SSA) is a key optical parameter determining aerosol warming or cooling effect; however, reliable SSA measurement is scarce in TP. This study firstly reported in situ measurement of SSA in Lhasa and explored the direct radiative effect of aerosol on TP warming. Strong aerosol absorption, mainly contributed by black carbon (BC), was observed with an average SSA value of 0.69 in this city. Besides Lhasa, other sites over TP were also reported with low SSA (≤0.77) from surface measurement. The strong aerosol absorption could cause heating effect on the Earth‐atmosphere system. To relieve TP warming, reasonable pollutant emission control strategies should be taken urgently to weaken aerosol absorbing ability. Key Points: Unexpected low aerosol single scattering albedo was observed in Lhasa via in situ measurement of multiple optical parameters simultaneouslyBlack carbon was the dominant contributor (∼83%) to aerosol absorption at 370 nm, followed by primary and secondary brown carbonThe strong absorption in Lhasa exerted positive direct aerosol radiative forcing (warming effect) at the top of atmosphere [ABSTRACT FROM AUTHOR]

The Korean space weather monitor (KSEM) aboard the GEO-KOMPSAT-2A (GK2A) has been continuously measuring energetic particle flux in geostationary orbit at 128.2°E longitude since July 2019. The particle detector (PD) component of KSEM comprises six particle telescopes viewing different directions that provide near-real-time electron flux observations within the energy range of 100 keV to 3.8 MeV. The KSEM PD on the GK2A satellite, together with the MPS-HI on the GOES-16 satellite 156.6° away, can provide valuable simultaneous observations of the asymmetric space environment and contributes to our understanding of this dynamic region. In this study, we present recent energetic electron flux measurements obtained from the KSEM PD and conduct preliminary cross-comparisons with data from the Magnetosphere Particle Sensor–High (MPS-HI) PD, which is part of the SEISS instrument suite onboard GOES-16. The inter-comparisons show that the electron fluxes of the two detectors are in reasonable similarity except for some energy bands under quiet conditions. Additionally, we provide a brief overview of the electron flux responses of both KSEM PD and MPS-HI under enhanced space environment conditions, which shows differences based on sensor characteristics and satellite location. [ABSTRACT FROM AUTHOR]

This technical report explains details on the results of the investigation to build a subsurface structural model and a selection of earthquake data at the target site of the blind prediction exercise for "The 6th International Association of Seismology and Physics of the Earth's Interior/International Association of Earthquake Engineering International Symposium on the Effect of Surface Geology on Seismic Motion (ESG6)." The selection process of the target site in the Kumamoto Plain, Japan, in ESG6 was explained with a historical review of the blind prediction tests in the previous ESG conferences. We have collected existing subsurface structural and earthquake data and conducted geophysical and geotechnical surveys in and around the target site to generate important velocity structure and the earthquake data used in the blind test. Microtremor data were obtained in triangular arrays ranging in side lengths from 1 to 962 m, and active surface wave data were derived along a 36-m line at the site. These data were provided for the prediction of a subsurface structural model in the first step of the blind prediction exercise. We also conducted a velocity logging in a borehole to a bottom depth of 39 m at the site and laboratory tests of soil samples from the borehole. We constructed a velocity profile of the shallow and deep sedimentary layers from a combination of the geophysical and geotechnical data at the site, and validated it by comparing the characteristics of the ground motion data from the moderate event. This "preferred velocity model" was provided as a standard model to the participants in the second and third steps of the blind prediction test to predict the earthquake ground motions of a moderate event and the mainshock of the 2016 Kumamoto earthquake. [ABSTRACT FROM AUTHOR]

Orthogonal cutting on Ti-6Al-4V produces segmented chips which results from localized deformation within the Primary Shear Zone (PSZ). For in situ visualization of the material flow during Ti-6Al-4V chip formation, a new high-speed optical system is proposed. Difficulties arise from the submillimetric size of the cutting zone. Therefore, a dedicated optical system with coaxial illumination is designed allowing for local scale analysis of chip formation. In this paper, the cutting forces were measured highlighting the unsteady nature of Ti-6Al-4V chip segmentation. For kinematic fields measurement, a novel method of Digital Image Correlation (DIC) technique is applied on the recorded images from the cutting zone. It allows for the identification of the localized deformation bands. Then, the level of the cumulative strain fields reached in the PSZ was presented and analyzed. The effect of the rake angle on the strain fields was studied. Using a 0∘ rake angle, the segment chip was found to be more subjected to deformation than in the case using 15∘. Accuracy of the measured strain fields was discussed function of the main source of errors. In addition, the chip morphology and microstructure were investigated with a scanning electron microscopy (SEM). It shows crack opening along the PSZ and high material failure near the tool-chip interface which explains the difficulties of DIC application in the context of kinematic fields measurement during orthogonal cutting. Finally, correlation between the measured strain fields and the mean value of the chip segment width was made. [ABSTRACT FROM AUTHOR]

Achieving target coating thickness is one of the main objectives in thermal spraying. Despite this, there is a lack of measurement methods that could evaluate in situ the coating thickness with a sufficient accuracy that could be used as a robust feedback signal for online, closed-loop process control. This paper presents a novel approach for in situ spatially resolved coating thickness measurements. The measurement technique is based on a high-resolution 3D camera to capture the surface topography and include it in the thickness measurement. The technique provides results of total coating thickness with excellent accuracy when compared to the reference microscopical method. It also gives a 3D view of the coating thicknesses around the observed area as well as information about the thickness of individual coating layers. Moreover, the approach enables in situ evaluation of surface roughness, and a nondestructive estimation of coating porosity. [ABSTRACT FROM AUTHOR]

The acoustic emission (AE) technique is an effective method for monitoring grinding wheels, and numerous studies have been published on applying an AE to monitor grinding wheels. However, there are few studies on the effect of the location of the AE sensor in stably acquiring the AE signals generated during deterioration in cylindrical grinding wheels. In this study, we propose a stable method for detecting the deterioration of a cubic boron nitride (cBN) grinding wheel during cylindrical grinding using AE. We compared the AE signals acquired during grinding from an AE sensor located on the hydrostatic bearing, which supports the grinding wheel shaft, with those from the tailstock spindle. Although positioning the AE sensor on the hydrostatic bearing was found to reduce the AE signal intensity, the AE signal variations were smaller at the same grinding position, and the effect of the grinding position was less than that for the tailstock spindle. Moreover, positioning an AE sensor on the hydrostatic bearing is considered to provide the characteristics of AE signals specifically focused on the changes in cBN on the grinding wheel surface allowing the surface roughness of the workpiece to be estimated during grinding. [ABSTRACT FROM AUTHOR]

Ocean salinity plays an important role in oceanographic research as one of the fundamental parameters. An optical salinometer based on the Michelson interferometer (MI) suitable for in situ measurement in deep-sea environments is proposed in this work, and it features real-time calibration and multichannel multiplexing using the frequency modulated continuous wave (FMCW) technique. The symmetrical sapphire structure used to withstand deep-sea pressure can not only achieve automatic temperature compensation, but also counteract the changes in optical path length under deep-sea pressure. A model formula suitable for optical salinity demodulation is proposed through the nonlinear least squares fitting method. In vertical profile testing, the optical salinometer demonstrated remarkable tracking performance, achieving an error of less than 0.001 psu. The sensor displays a stable salinity demodulation error within ±0.002 psu during a three-month long-term test at a depth of 4000 m. High stability and resolution make this optical salinometer have broad development prospects in ocean observation.

Soil electrical conductivity has an important influence on the growth and development of plants. The existing real-time soil electrical conductivity detection device is affected by temperature, inconvenient to use, expensive, etc.; therefore, based on the classical four-terminal method of soil electrical conductivity detection principle, in this study, we aim to improve the limitations of the constant current source, selecting the high-performance integrated chip AD5941, optimizing the detection circuit and probe structure, improving the achievability of the detection circuit, and designing a type of in situ on-line real-time access to a soil electrical conductivity detection device, and improve the detection accuracy by temperature compensation. In this paper, dynamic performance, steady state performance, radial sensitivity range, and calibration test are carried out for the soil electrical conductivity detection prototype. The test results show that the dynamic response speed of the prototype is less than 50 ms, the steady state error is not more than ±2%, and the radial measurement sensitivity range is 8~10 cm. A comparison with the commercial sensor shows that the linear fit of the two measurements reaches 0.9995, and the absolute error ranges from −61.40 µS/cm to 23.90 µS/cm, with a relative error range of −1.94~1.86%. It shows that the performance of the two sensors is comparable, but the quality/price ratio of the prototype is much higher than that of the commercialized product. In this study, it is demonstrated that a high-precision, low-cost, and easy-to-use in situ online soil electrical conductivity detection device can be provided for agricultural and forestry production.

In drilling small holes with diameters of 1 mm or less, minute clogging and twining of chips or the adhesion of the workpiece material can become factors in causing breakages of the drill bit; moreover, it can be difficult to identify the machining state. Acoustic emission (AE) sensing is a nondestructive inspection technique that measures the elastic-stress waves that are generated when a material is deformed and fractured. AE sensing permits highly sensitive measurements to be made without changing the rigidity of the experimental system, unlike force sensing of cutting resistance, etc. In the present study, attempts were made to identify the machining state and tool wear, and to predict abnormalities in small-diameter drilling by using the change in the frequency of AE signal waveforms arising from deformation and fracture. It was shown that it is possible to predict the breakage of the drill bit by detecting high-frequency AE signals at about 1 MHz, caused by the adhesion of the workpiece material. In addition, a correlation map of the AE frequency spectrum for identifying the machining state in a drilling operation is suggested. [ABSTRACT FROM AUTHOR]

The 2-week, virtual Future of the Search for Life science and engineering workshop brought together more than 100 scientists, engineers, and technologists in March and April 2022 to provide their expert opinion on the interconnections between life-detection science and technology. Participants identified the advances in measurement and sampling technologies they believed to be necessary to perform in situ searches for life elsewhere in our Solar System, 20 years or more in the future. Among suggested measurements for these searches, those pertaining to three potential indicators of life termed "dynamic disequilibrium," "catalysis," and "informational polymers" were identified as particularly promising avenues for further exploration. For these three indicators, small breakout groups of participants identified measurement needs and knowledge gaps, along with corresponding constraints on sample handling (acquisition and processing) approaches for a variety of environments on Enceladus, Europa, Mars, and Titan. Despite the diversity of these environments, sample processing approaches all tend to be more complex than those that have been implemented on missions or envisioned for mission concepts to date. The approaches considered by workshop breakout groups progress from nondestructive to destructive measurement techniques, and most involve the need for fluid (especially liquid) sample processing. Sample processing needs were identified as technology gaps. These gaps include technology and associated sampling strategies that allow the preservation of the thermal, mechanical, and chemical integrity of the samples upon acquisition; and to optimize the sample information obtained by operating suites of instruments on common samples. Crucially, the interplay between science-driven life-detection strategies and their technological implementation highlights the need for an unprecedented level of payload integration and extensive collaboration between scientists and engineers, starting from concept formulation through mission deployment of life-detection instruments and sample processing systems. [ABSTRACT FROM AUTHOR]

Long‐term atmospheric water vapour hydrogen (δ2H), oxygen (δ18O) and deuterium excess (d‐excess) can provide unique insights into the land‐atmosphere coupling processes. The in‐situ measurements of atmospheric water vapour δ2H, δ18O and d‐excess were conducted above a reed wetland of Liaodong Bay (2019–2020). We found significant inter‐annual variations in atmospheric water vapour isotopes between the two growing (May–September) seasons. The δ2H, δ18O and d‐excess of atmospheric water vapour exhibited different seasonal and diurnal cycles concerning the vertical measurement heights, especially in 2019. The isotopic differences of atmospheric water vapour among vertical measurement heights were more evident in the daytime. Rainfall events directly impacted the diurnal patterns of water vapour isotopes, and the influences depended on rainfall intensities. However, only weak correlations existed between water vapour isotopes and local meteorological factors (R2 = 0.01–0.16, p < 0.001), such as water vapour concentration (w), Relative Humidity (RH) and surface air temperature (Ta). Based on the back‐air trajectory analyses, the spatial–temporal dynamics of atmospheric water vapour isotopes are highly synchronized with monsoon activities. Different water vapour sources influence the water vapour isotope in this region and the higher d‐excess value is related to the intense convection brought by the monsoon. High‐resolution measurements of atmospheric water vapour isotopes will improve our understanding of the hydrological cycles in coastal areas. [ABSTRACT FROM AUTHOR]

Numerous factors influence the acoustic characteristics of seafloor sediments, necessitating a comprehensive study that combines theoretical analysis, laboratory measurements and in situ measurements to support acoustic prediction and inversion. In this study, a porosity-based effective density fluid model (P-EDFM) is established to analyze the variation of acoustic properties with the porosity of seafloor sediments. On the biases of P-EDFM, the attribute of measured sound velocity and acoustic attenuation coefficient of seafloor sediment in Series 9B of the SAX99 was well interpreted within the frequency range of 25-100 kHz. The in situ measured sound velocity ratio was well predicated by the P-EDFM in the East China Sea and Yellow Sea. It reveals that the in situ sound velocity ratio decreases with increasing bulk porosity and with decreasing bulk density. The scattering and differences in the acoustic attenuation coefficient measured in situ in seafloor sediments are found to be greater than those observed for sound velocity. After considering the influence of temperature in the P-EDFM, the prediction of in situ sound velocity aligns well with the measured dataset. While, the acoustic attenuation coefficient exhibits an inflection point, increasing initially and then decreasing with changes in porosity, similar to the observed pattern in Hamilton’s observation and estimation. By incorporating temperature and frequency influences, the in situ measurements of sound velocity of seafloor sediments are corrected into laboratory sound velocities by using the P-EDFM. The result reveals the sediment samples’ sampling and transmitting process has a much greater impact on the sound velocity of sandy sediment in the East China Sea compared to muddy sediment. Overall, P-EDFM can predict the in situ sound velocity and sound attenuation coefficient under different temperatures and frequencies, with a lower prediction error for sound velocity compared to sound attenuation coefficient. [ABSTRACT FROM AUTHOR]

Land surface temperature (LST) is a crucial parameter in climate and ecology, exerting significant influence on meteorological conditions, ecosystems, and human life. LST data sources are diverse, with remote sensing being the prevailing means of acquisition. FY-4A/AGRI offers high-quality LST products for East Asia. We conducted a comprehensive evaluation and refined analysis of surface heat resources in Hunan Province, central China, over a two-year period using the 4 km/1 h resolution product in this study. The results demonstrate that the FY-4A LST product effectively captures surface temperature (R = 0.893), albeit with a relatively high error level (Bias = −6.295 °C; RMSE = 8.58 °C), particularly in capturing high LST values. The performance of this product is superior in the eastern flat terrain area of Hunan Province compared to its performance in the western mountainous region due to environmental conditions causing systematic errors that contribute to instability in detection deviation for this product. Surface heat resources are more abundant in eastern Hunan Province than in mountainous areas located west and southwardly, and the detailed distribution of them at finer scales is mainly influenced by terrain and climate conditions. There is no obvious seasonal difference in the distribution of heat resources except in winter, and rapid urbanization within Chang–Zhu–Tan urban agglomeration over two years has significantly altered the spatial distribution pattern of surface heat resources across Hunan Province. These findings provide a quantitative baseline for assessing FY-4A satellite's detection capability while serving as a reference for further application of its LST products and establishing foundations for divisional classification and utilization strategies pertaining to surface heat resources within Hunan Province. [ABSTRACT FROM AUTHOR]

Water quality indicators, including biological, chemical and physical properties, are usually determined by collecting data from the field and analyzing them in the laboratory. Although these in situ measurements are costly and time-consuming, they offer high accuracy. This study focuses on the estimation of particulate organic carbon (POC) as a water quality parameter using a combination of machine learning algorithms and hyperspectral in situ data. A data-driven approach that does not need any domain knowledge was used. We were interested in POC generated by bacteria, phytoplankton, zooplankton, detritus and sediments in the Mediterranean Sea from 15 May to 10 June 2017. Therefore, the objective of this study was to use five regression frameworks from machine learning algorithms to estimate POC with hyperspectral in situ data and evaluate their performance. Based on the coefficient of determination R², the best-performing modes were nearest neighbors (KNN), gradient boosting (GB) and random forest (RF), with an R² in the range of 72.33 to 74.7%. These machine learning models can be used to investigate more water quality parameters, as they reveal the great potential of this approach. [ABSTRACT FROM AUTHOR]

Abstract Knowledge of aerosol radiative effects in the Tibetan Plateau (TP) is limited due to the lack of reliable aerosol optical properties, especially the single scattering albedo (SSA). We firstly reported in situ measurement of SSA in Lhasa using a cavity enhanced albedometer (CEA) at λ = 532 nm from 22nd May to 11th June 2021. Unexpected strong aerosol absorbing ability was observed with an average SSA of 0.69. Based on spectral absorptions measured by Aethalometer (AE33), black carbon (BC) was found to be the dominated absorbing species, accounting for about 83% at λ = 370 nm, followed by primary and secondary brown carbon (BrCpri and BrCsec). The average direct aerosol radiative forcing at the top of atmosphere (DARFTOA) was 2.83 W/m2, indicating aerosol warming effect on the Earth‐atmosphere system. Even though aerosol loading is low, aerosol heating effect plays a significant role on TP warming due to strong absorbing ability.

Catalytic conversions in fine-chemical and pharmaceutical production are increasingly performed in trickle-bed rectors. Optimisation of these processes is usually based on end of pipe measurement made at specific residence times. This process is both time-consuming and the data sometimes challenging to interpret. In the present work, operando nuclear magnetic resonance (NMR) techniques both at the scale of the whole bed (global) and spatially resolved within the bed (local) are used to gain new insights into the catalytic conversion process under reaction conditions. Spatially resolved spectroscopic and diffusion-T2-relaxation (D-T2) methods interrogate local differences in chemical conversion and selectivity, and mass transport (molecular self-diffusion) respectively, thereby providing valuable information for process simulation models. This capability is demonstrated using the continuous flow three phase (gas-liquid-solid) hydrogenation of benzonitrile over a fixed bed of 0.5 wt% Pd/Al2O3 catalyst pellets yielding toluene and benzylamine. Global 1H spectroscopic and D-T2 were used to monitor chemical conversion and the approach to steady state; these were subsequently followed by spatially resolved 1H spectra and spatially resolved D-T2 correlations to examine the local differences in axial conversion and selectivity of the catalyst bed packing. At steady-state a global conversion of 63% was achieved with 65% and 25% selectivity to benzylamine and toluene respectively. Heterogeneities in the local (axial) conversion and selectivity differed by 31% along the total catalyst bed length. These techniques should be applicable to many three-phase heterogeneous catalytic systems provided that the T2 relaxation time of the reactants and products is not prohibitively small.

Building materials, such as brick and concrete, are known indoor radon (222Rn) and thoron (220Rn) sources. Most radon and thoron exhalation studies are based on the laboratory testing of pieces and blocks of such materials. To discuss if laboratory findings can be applied to a real-world environment, we conducted intensive in situ exhalation tests on two solid concrete interior walls of an apartment in Japan for over a year. Exhalation rates of radon (JRn) and thoron (JTn) were measured using an accumulation chamber and dedicated monitors, alongside monitoring indoor air temperature (T) and absolute humidity (AHin). There were weak correlations between JRn or JTn and T or AHin at one tested wall, and moderate correlations of JRn and strong correlations of JTn with T or AHin at the other wall, meaning more or less seasonal variations. The findings aligned with previous laboratory experiments on JRn but lacked corresponding data for JTn. Additionally, a moderate or strong correlation between JRn and JTn was observed for both tested walls. Comparison with theoretical calculations revealed a new issue regarding the impact of each process of emanation and migration within concrete pores on radon and thoron exhalation. Overall, this study provides insight into parameterizing radon and thoron source inputs in modeling the spatiotemporal dynamics of indoor radon and thoron.

Clogging is one of the major factors affecting the performance of drip irrigation systems. It can be of a physical, chemical or biological nature but currently no method offers non-destructive field measurements of clogging. The aim is to propose a new method for monitoring and discriminating physical and chemical clogging. It is based on near infrared (NIR) spectroscopy combined with multivariate analysis methods. Kaolinite (physical clogging) and calcium carbonate (chemical clogging) were monitored in a transparent millifluidic cellflow. The evolution of clogging throughout the experiment was monitored by applying a multivariate curve regression – alternating least-squares (MCR-ALS) on absorption spectra. Comparison of the MCR-ALS results with the reference thickness measured by optical coherence tomography (OCT) indicated that absorbance spectroscopy coupled with MCR-ALS allows for accurate monitoring of the clogging thickness of kaolinite and calcium carbonate deposits. The detection of clogging and the monitoring of its thickness in the channel could be performed during both experiments. In addition, based on the spectra, a partial least squares-discriminant analysis (PLS-DA) model was developed to distinguish between the two types of clogging materials. Discrimination between both materials using PLS-DA model was achieved with accuracy greater than 97%. The proposed strategy highlights the potential of NIR spectroscopy coupled with MCR-ALS and PLS-DA methods to monitor the evolution of thickness and nature of clogging in a millifluidic cellflow. These results thus indicate a new methodology for detecting, monitoring and discriminating in situ clogging in the field. • Accurate spectral method for in situ monitoring and discrimination of clogging. • MCR-ALS method allows for clogging quantification with precision around 100 μm. • PLS-DA allows for clogging classification with accuracy greater than 97%. [ABSTRACT FROM AUTHOR]

In situ measurement can enable accurate evaluation of a building's as-built performance. However, when measuring whole house performance, party walls introduce measurement uncertainty. Subsequently, it is common to "adjust" measurements to isolate heat transfer through party walls. This study explores the behaviour and impact of party walls in QUB and coheating measurements of a semi-detached house, presenting empirical evidence on the validity of these measurements where a party wall is present. Two different party wall heat transfer behaviours were observed through heat flux density measurements. Thermal charging is apparent in QUB tests and the initial stages of coheating. After 48 h of coheating, the party wall has become heat saturated and exhibits stable heat transfer. Consequently, using heat flux density measurements to isolate party wall heat transfer in QUB tests, where thermal saturation has not been achieved, can result in misleading inferences. The coheating and QUB measurements without party wall adjustment are in close agreement, irrespective of differing heating patterns in the neighbouring property. The generalisation of these findings is problematic since they describe the impact of the case study-specific built form and the test conditions. Future work to explore the impact of built form and test conditions is needed. [ABSTRACT FROM AUTHOR]

The demonstrative space plasma physics communities in the world have been conducting intensive research and development activities for instrument miniaturization because compact and lightweight sensors are required for installation on micro/small satellites and CubeSats in ongoing and future space exploration missions. Recently, we designed a novel type of space plasma instrument capable of simultaneous energy analyses of low‐energy (∼eV to several 10s of keV) electrons and ions with a single sensor head consisting of triple‐dome analyzer with triple‐layer collimator for covering 360° field‐of‐view similar to that of the prevailing top‐hat type. Two separate but correlated electrostatic fields, produced by a single high‐voltage supply unit in double gaps of the triple‐dome/layer structures, are used for electron/ion energy analyses. In the breadboard model (BBM) designed here, the energy/angular resolutions and the analyzer constants (ratios of measured particle energy to applied voltage) are approximately 9.0%/3.5° and 4.0, and 10%/4° and 4.4 for the electron and ion energy analyses, respectively. We also fabricated the first BBM of the triple‐dome type of electrostatic analyzer for experimental performance tests in electron/ion beamline facility. According to the experimental data by the two‐dimensionally position‐sensitive particle detector, the calibrated properties of energy/angular analyses and the other sensor performance show good agreement with numerical design results. The performance of the triple‐dome analyzer would satisfy observation requirements, as represented by measurements of three‐dimensional velocity distributions of electrons and ions in future missions using spin‐type microsatellites/CubeSats under stringent resource conditions. Key Points: We designed an electrostatic analyzer with a 360° field‐of‐view for simultaneous electron and ion measurements from eV/q to 10s of keV/qThe sensor consists of triple domes following a deflecting collimator ring with possibilities of future application and modificationsThe experimental results in our beamline calibration facility showed good agreement with instrumental properties by the numerical design [ABSTRACT FROM AUTHOR]

The residual stress inside stock materials is a fundamental property related to the quality of manufactured parts in terms of geometric/dimensional stability and fatigue life. For large parts that must meet high-precision requirements, accurately measuring and predicting the residual stress field has been a major challenge. Existing technologies for measuring the residual stress field are either strain-based measurement methods or non-destructive methods with low efficiency and accuracy. This paper reports a new non-destructive method for inferencing the residual stress field based on deformation forces. In the proposed method, the residual stress field of a workpiece is inferred based on the characteristics of the deformation forces that reflect the overall effect of the unbalanced residual stress field after material removal operations. The relationship between deformation forces and the residual stress field is modeled based on the principle of virtual work, and the residual stress field inference problem is solved using an enforced regularization method. Theoretical verification is presented and actual experiment cases are tested, showing reliable accuracy and flexibility for large aviation structural parts. The underlying principle of the method provides an important reference for predicting and compensating workpiece deformation caused by residual stress using dynamic machining monitoring data in the context of digital and intelligent manufacturing.

A new construction of a potentiometric sensor was introduced for the first time. It relies on the use of two membranes instead of one, as in the well-known coated-disc electrode. For this purpose, a new electrode body was constructed, including not one, but two glassy carbon discs covered with an ion-selective membrane. This solution allows for the sensor properties to be enhanced without using additional materials (layers or additives) on the membrane. The new construction is particularly useful for in situ measurements in environmental samples. Two ion-selective polymeric membranes were used, namely H+ and K+-selective membranes, to confirm the universality of the idea. The tests conducted included chronopotentiometric tests, electrochemical impedance spectroscopy, and potentiometric measurements. The electrical and analytical parameters of the sensors were evaluated and compared for all tested electrodes to evaluate the properties of the planar electrode versus previously known constructions. Research has shown that the application of two membranes instead of one allows for the resistance of an electrode to be lowered and for the electrical capacitance to be elevated. Improving the electrical properties of an electrode resulted in the enhancement of its analytical properties. The pH measurement range of the planar electrode is 2–11, which is much wider in contrast to that of the single-membrane electrode. The linear range of the K+-selective planar electrode is wider than that of the coated-disc electrode and equals 10−6 to 10−1 M. The response time turned out to be a few seconds shorter, and the potential drift was smaller due to the application of an additional membrane in the electrode construction. This research creates a new opportunity to design robust potentiometric sensors, as the presented construction is universal and can be used to obtain electrodes selective to various ions.

The acoustic properties of seafloor sediments on continental slopes play a crucial role in underwater acoustic propagation, communication, and detection. To investigate the acoustic characteristics and spatial distribution patterns of sediments on the continental slope, a geoacoustic experiment was conducted in the northwestern South China Sea. The experiment covered two sections: one crossing the shelf and slope in the downslope direction, and the other near the shelf break in the along-slope direction. In situ techniques, sediment sampling, and laboratory measurements were used to acquire data on sediment acoustic properties (such as sound speed and attenuation) and physical properties (including particle composition, density, porosity, and mean grain size). The experimental findings revealed several key points: (1) Acoustic properties of shallow water coarse-grained sediments and deep-sea sediments were higher when measured in the laboratory compared to in situ measurements. (2) Relationships between measured attenuation and physical properties, as well as between sound speed and mean grain size, showed deviations from previous empirical equations. (3) Sediment acoustic and physical properties exhibited significant variations in the downslope direction, while showing gradual variations in the along-slope direction. These variations can be attributed to sedimentary environmental factors such as material sources, hydrodynamic conditions, and water depth.

The Palm Grove ecosystems situated in the southeastern region of Morocco are highly vulnerable to compromise, encountering significant challenges due to insufficient precipitation and limited availability of groundwater. The objective of this study is to evaluate the groundwater quality of the Tinejdad-Touroug aquifer for domestic and irrigation purposes. Groundwater flows from southwest to northeast mostly in Quaternary conglomerate-lacustrine facies in the Rheris basin. The results show that the domination of the major ions is in the following order: Cl−>HCO3−>SO42−>Na+>Ca2+>Mg2+>NO3−>K+>NO2−>NH4+. Piper diagram showed the predominance of a single mixed chemical facies Cl-SO4-Ca-Mg, as well as the presence of exceptions of some samples that showed other facies variations. The water quality index (WQI) assessments of the campaigns that were examined demonstrate that the recorded percentages of poor quality water ranged from 40% to 90% while the percentages of good quality water varied from 7.7% to 54.5%. The remaining samples reveal different classes with varying percentages. Most of the sites in all campaigns had drinking water parameters that exceeded the values established by the World Health Organization (WHO) and Moroccan standards. Nevertheless, the parameters of Temperature, pH, TH, DO, Ca2+, SO42−, K+, NH4+, and bacteriological parameters were within the required limits. The results of the assessment based on electrical conductivity suggest a significant increase in salinity levels, with an average of 2744.75 µS/cm in 2000, 3248.58 µS/cm in 2007, and 2957.84 µS/cm in 2021. The findings of the study reveal a positive assessment regarding the quality of the water samples examined during the eight sampling campaigns, as indicated by the PI and KR indices. However, additional investigation of the SAR, Na%, and MH indices revealed that three water samples acquired from separate surveys are not appropriate for irrigation purposes, showing that groundwater must be controlled until it can be properly used. The outcomes accentuate the necessity of consistent monitoring and evaluation of water quality parameters to establish the safe and sustainable exploitation of water resources for domestic and agricultural purposes. Elevated salinity levels in Quaternary aquifers resulting from natural mechanisms such as increased rates of evaporation and geological factors may have contributed to the degradation of groundwater quality.

Accurate and rapid in situ measurements of the thermal resistance (R-value) of building envelopes are necessary for assessing planned performance and identifying appropriate retrofitting strategies. Although there are several approaches for in situ R-value estimation, the average method of ISO 9869-1 based on the heat flow meter method is the most widely used. However, discrepancies between theoretical and in situ R-values are frequently reported in many studies that employ this method. This study aimed to investigate the cause of this discrepancy in estimating in situ R-values of highly insulated building walls using the average method of ISO 9869-1 by conducting long-term experiments. This study was made possible due to a specially constructed test wall wherein more sensors were installed than are required by the ISO 9869-1 standard. The findings showed that discrepancies between heat fluxes on the internal surface and heat passing through the wall is the main cause of the error in in situ R-value estimation. Measurement results from winter showed that deviation from the theoretical R-value was 9.12% for the average method and 0.6% for the extended average method, determined by additionally using the temperature and heat flux inside the wall. [ABSTRACT FROM AUTHOR]